• Title/Summary/Keyword: Ni-coating

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Ti-based Quasicrystal Layers Produced by Plasma Thermal Spraying

  • Takasaki, Akito;Uematsu, Susumu;Kelton, K.F.
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09a
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    • pp.51-52
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    • 2006
  • [ $Ti_{45}Zr_{38}Ni_{17}$ ] powders were thermally sprayed onto mild steel substrates in air and under a reduced pressure of argon. Several oxides were formed after thermally-spraying the mechanically-alloyed powders in air. After spraying in a reduced pressure of argon, the coating layers obtained from the gently mixed powders consisted of the elemental metals, but an amorphous phase primarily appeared in the thermally-sprayed mechanically-alloyed powders, which transformed into the icosahedral quasicrystal phase and a minor $Ti_2Ni-type$ crystal phase after annealing at 828 K. The Vickers hardness and the contact angle with pure water for the quasicrystal layers were about 7 GPa and $92^{\circ}$ respectively.

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EMI shielding Effectiveness and the Physical Properties of Commercial EMI shielding Fabrics (시판 전자기파 차단 직물의 차폐효과 및 물성)

  • 한은경;오경화;김은애
    • Journal of the Korean Society of Clothing and Textiles
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    • v.23 no.5
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    • pp.694-702
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    • 1999
  • By using commercial available electromagnetic interference (EMI) shielding fabrics, EMI shielding effectiveness(SE) and the physical properties were investigated. Thirteen specimens were chosen six fabrics were non-electrolytic plated with Cu, six plated with Cu+Ni and one plated with Ni, SE was measured by RF Impedance Analyzer HP4291A(Hewlett Co, Ltd)at the frequency of 100MHz-1.8GHz. The results showed that the commercial EMI shielding fabrics provided SE values over 30dB at the frequency of 100MHz-1.8GHz. Fabrics plated with Cu showed more effective shielding than those plated with Ni. The thickness of coating and fabric count were also influential factors on SE. Tensile properties were acceptable for lining fabrics but water vapor transport properties indicated that the better treatment condition were suggested to improve comfort properties.

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Codeposition of Al and Cr by pack cementation (팩 세멘테이션에 의한 Al 및 Cr의 동시 코팅)

  • Sohn, Hee-Sik;Lee, Yoon-Je;Kim, Moon-Il
    • Journal of the Korean Society for Heat Treatment
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    • v.8 no.2
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    • pp.127-136
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    • 1995
  • The simultaneous addition of Al and Cr to the surface of Ni-and Fe-base alloy provides enhanced resistance to oxidation and corrosion in high temperatures. However, because of the large differences in thermodynamic stabilities of the volatile halides of Al and Cr, the codeposition of Al and Cr by halideactivated pack cementation is only possible for very specific, limited combinations of conditions. In this study, the experiments on the combinations of various metallic source powders and activators were conducted in order to obtain codeposition layers of Al and Cr on Ni with adequate composition by pack cementation. When Cr-Al masteralloy was used as a source powder, it was not easy to control Al and Cr content sensitively in the coating layers. On the other hand, when pure Cr and Al powder was used, ${\beta}$-NiAl layer containing about 20wt % Cr was obtained.

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Development of Advanced Polymeric Binders for High Voltage LiNi0.5Mn1.5O4 cathodes in Lithium-ion batteries (고전압 LiNi0.5Mn1.5O4 양극 고성능 바인더 개발 연구)

  • Dae Hui Yun;Sunghun Choi
    • Journal of Industrial Technology
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    • v.43 no.1
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    • pp.43-48
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    • 2023
  • Spinel LiNi0.5Mn1.5O4 (LNMO) has been considered as one of most promising cathode material, because of its low-cost and competitive energy density. However, 4.7V vs. Li/Li+ of high operating potential facilitates electrolyte degradation on cathode-electrolyte interface during charge-discharge process. In particular, commercial polyvinylidene fluoride (PVDF) is not sutaible for LNMO cathode binder because its weak van der waals force induces thick and non-uniform coverage on the cathode surface. In this review, we study high performance binders for LNMO cathode, which forms uniform coating layer to prevent direct contact between electrolyte and LNMO particle as well as modifying high quality cathode electrolyte interphase, improved cell performace.

Mechanical Properties of Ni Films and $Ni-Al_2O_3$ Composite Films Fabricated by Electroplating (전기도금법으로 제조한 Ni 박막과 $Ni-Al_2O_3$ 복합박막의 기계적 성질)

  • Jun S. W.;Won H. J.;Lee K. Y.;Lee J. H.;Byun J. Y.;Oh T. S.
    • Journal of the Microelectronics and Packaging Society
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    • v.12 no.3 s.36
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    • pp.259-265
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    • 2005
  • Characteristics of electroplated Ni films and $Ni-Al_2O_3$ composite films, such as yield strength, fracture elongation, and $Al_2O_3$ content, were evaluated as a function of electroplating current density. $Al_2O_3$ content was $11.48\~11.64\;vol\%$ for $Ni-Al_2O_3$ composite films electroplated at $5\~20\;mA/cm^2$, and decreased to $8.41\;vol\%$ at $30\;mA/cm^2$ $Ni-Al_2O_3$ possessed yield strengths higher than those of Ni films. Especially, $Ni-Al_2O_3$ fabricated at $5\;mA/cm^2$ exhibited $50\%$ improved yield strength. Fracture elongations of Ni and $Ni-Al_2O_3$ decreased with increasing the electroplating current density. $Ni-Al_2O_3$ electroplated at $5\;mA/cm^2$ exhibited more uniform dispersion of $Al_2O_3$ and higher yield strength and larger fracture elongation than the composite films processed at other current densities.

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P-Type Doping of Graphene Films by Hybridization with Nickel Nanoparticles

  • Lee, Su Il;Song, Wooseok;Kim, Yooseok;song, Inkyung;Park, Sangeun;Cha, Myung-Jun;Jung, Dae Sung;Jung, Min Wook;An, Ki-Seok;Park, Chong-Yun
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.02a
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    • pp.208-208
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    • 2013
  • Graphene has emerged as a fascinating material for next-generation nanoelectronics due to its outstanding electronic properties. In particular, graphene-based field effect transistors (GFETs) have been a promising research subject due to their superior response times, which are due to extremely high electron mobility at room temperature. The biggest challenges in GFET applications are control of carrier concentration and opening the bandgap of graphene. To overcome these problems, three approaches to doping graphene have been developed. Here we demonstrate the decoration of Ni nanoparticles (NPs) on graphene films by simple annealing for p-type doping of graphene. Ni NPs/graphene films were fabricated by coating a $NiCl2{\cdot}6H2O$ solution onto graphene followedby annealing. Scanning electron microscopy and atomic force microscopy revealed that high-density, uniformly sized Ni NPs were formed on the graphene films and the density of the Ni NPs increased gradually with increasing $NiCl2{\cdot}6H2O$ concentration. The formation of Ni NPs on graphene films was explained by heat-driven dechlorination and subsequent particlization, as investigated by X-ray photoelectron spectroscopy. The doping effect of Ni NPs onto graphene films was verified by Raman spectroscopy and electrical transport measurements.

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Development of Hybrid Metals Coated Carbon Fibers for High-Efficient Electromagnetic Interference Shielding (고효율 전자파 차폐를 위한 이종금속 코팅 탄소섬유 개발)

  • Moon, Jai Joung;Park, Ok-Kyung;Lee, Joong Hee
    • Composites Research
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    • v.33 no.4
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    • pp.191-197
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    • 2020
  • In this study, a hybrid metals such as copper (Cu) and nickel (Ni) coated carbon fibers (Ni-Cu/CFs) was prepared by wet laid method to develop a randomly oriented sheet material for high-efficiency electromagnetic interference shielding with the enhanced durability. The prepared sheet materials show a high electromagnetic interference shielding efficiency of 69.4 to 93.0 dB. In addition, the hybrid metals coated Ni-Cu/CFs sheets showed very high durability with harsh chemical/thermal environments due to the effective corrosive and mechanical resistances of Ni surface. In this context, the Ni-Cu/CF sheet possesses longer service life than the Cu/CF sheet, that is, 1.7 times longer.

Evaluation of Bond Strength in cp-Ti and Non-precious Metal-Ceramic System Using a Gold Bonding Agent (티타늄과 비귀금속 합금에 중간층으로 적용한 Au bonding agent의 금속-도재 결합에 대한 평가)

  • Lee, Jung-Hwan;Ahn, Jae-Seok
    • Journal of Technologic Dentistry
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    • v.31 no.4
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    • pp.15-23
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    • 2009
  • The aim of this study was to evaluate the bond strength of using a Au bonding agent applied on cp-Ti and nonprecious metal-gold-ceramic system. Metallic frameworks(diameter: 5mm, height: 20mm)(N=56, n=7per group) cast in Ni-Cr alloy, Co-Cr alloy and cp-Ti were obtained using acrylic templates and airborne particle abraded with $110{\mu}m$ aluminum oxide. Au bonding agent was applied on wash opaque firing as intermediate layer. SEM and SEM/EDS line profile were performed on the cutting the cross-section of the metal substrate-porcelain with intermediate Au coating. Groups were tested using shear bond strength(SBS) testing at 0.5mm/min. The mean SBS values for the ceramic-Au layer-metal combination were significantly higher than those ceramic-metal combination. While ceramic-Au layer-cp-Ti combinations failed to increase bond strength instead of using a titanium bonding porcelain. The appication of using Au intermediate layer significantly improve the bond strength combination with metal-ceramic system.

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Effect of Sulfate-based Cathode-Electrolyte Interphases on Electrochemical Performance of Ni-rich Cathode Material

  • Chae, Bum-Jin;Song, Hye Ji;Mun, Junyoung;Yim, Taeeun
    • Journal of Electrochemical Science and Technology
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    • v.11 no.4
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    • pp.361-367
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    • 2020
  • Recently, layered nickel-rich cathode materials (NCM) have attracted considerable attention as advanced alternative cathode materials for use in lithium-ion batteries (LIBs). However, their inferior surface stability that gives rise to rapid fading of cycling performance is a significant drawback. This paper proposes a simple and convenient coating method that improves the surface stability of NCM using sulfate-based solvents that create artificial cathode-electrolyte interphases (CEI) on the NCM surface. SOx-based artificial CEI layer is successfully coated on the surface of the NCM through a wet-coating process that uses dimethyl sulfone (DMS) and dimethyl sulfoxide (DMSO) as liquid precursors. It is found that the SOx-based artificial CEI layer is well developed on the surface of NCM with a thickness of a few nanometers, and it does not degrade the layered structure of NCM. In cycling performance tests, cells with DMS- or DMSO-modified NCM811 cathodes exhibited improved specific capacity retention at room temperature as well as at high temperature (DMS-NCM811: 99.4%, DMSO-NCM811: 88.6%, and NCM811: 78.4%), as the SOx-based artificial CEI layer effectively suppresses undesired surface reactions such as electrolyte decomposition.

Thin Film Energy Storage Device with Spray-Coated Sliver Paste Current Collector

  • Yoon, Seong Man;Jang, Yunseok;Jo, Jeongdai;Go, Jeung Sang
    • ETRI Journal
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    • v.39 no.6
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    • pp.874-879
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    • 2017
  • This paper challenges the fabrication of a thin film energy storage device on a flexible polymer substrate specifically by replacing most commonly used metal foil current collectors with coated current collectors. Mass-manufacturable spray-coating technology enables the fabrication of two different half-cell electric double layer capacitors (EDLC) with a spray-coated silver paste current collector and a Ni foil current collector. The larger specific capacitances of the half-cell EDLC with the spray-coated silver current collector are obtained as 103.86 F/g and 76.8 F/g for scan rates of 10 mV/s and 500 mV/s, respectively. Further, even though the half-cell EDLC with the spray-coated current collector is heavier than that with the Ni foil current collector, smaller Warburg impedance and contact resistance are characterized from Nyquist plots. For the applied voltages ranging from -0.5 V to 0.5 V, the spray-coated thin film energy storage device exhibits a better performance.