• Title/Summary/Keyword: Ni-Ti shape-memory alloys

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A Study on the Shape Memory Characteristic Behaviors of Ti-42.5at%Ni-10at.% Cu Alloys (Ti-42.5at.%Ni-10at.%Cu합금의 형상기억특성에 관한 연구)

  • Woo, Heung-Sik;Park, Yong-Gyu
    • Journal of the Korean Society of Safety
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    • v.24 no.1
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    • pp.26-30
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    • 2009
  • Shape memory recoverable stress and strain of Ti-42.5at%Ni-10at%Cu alloys were measured by means of constant temperature tensile tests. The alloys' transformation behavior is B2 - B19 by DSC result. The strain by tensile stress were perfectly recovered by heating at any testing conditions but shape memory recoverable stress increased to 66MPa and then slightly decreased. Transformation temperatures from thermal cycling under constant uniaxial applied tensile loads linearly increased by increasing tensile load and their thermal hysteresis are about 110K and their maximum recoverable strain is 6.5% at 100MPa condition.

Phase Transformation and Reversible Shape Memory Effect of Ti-Ni-Cu Alloys (Ti-Ni-Cu 합금의 상변태 및 가역형상기억효과)

  • Hong, S.W.;Lee, O.Y.;Kim, D.K.
    • Journal of the Korean Society for Heat Treatment
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    • v.5 no.3
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    • pp.149-156
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    • 1992
  • Transformation behavior and reversible shape memory effct of Ti-Ni-Cu alloys with various Cu content has been investigated by means of electrical resistivity measurement, differential scanning calorimetry. X-ray diffraction and strain gage sensor. The transformation sequence in Ti-Ni-Cu alloys substituted by Cu for Ni up to 5at.% occurs to $B2{\leftrightarrow}B19^{\prime}$ and it proceeds in two stages by addition of 10 at.%Cu. i.e. $B2{\leftrightarrow}B19{\leftrightarrow}B19^{\prime}$. But the content of Cu increases up to 20at.%, it has been transformed in one stage ; $B2{\leftrightarrow}B19$. The shape change of Ti-40Ni-10Cu alloy which was constrain aged in circular form bended in $B2{\leftrightarrow}B19$ transformation but it spreaded out in $B19{\leftrightarrow}B19^{\prime}$ transformation. The amount of reversible shape change (${\Delta}{\varepsilon}$) of Ti-47Ni-3Cu alloy constrain aged at $400^{\circ}C$ after solution treatment has a maximum value of about $5.6{\times}10^{-3}$, but that of cold rolled and constrain aged specimens exhibits a little value independent of Cu concentrations.

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Shape Memory Characteristics and Crystallization Annealing of Amorphous $Ti_{50}-Ni_{30}-Cu_{20}$ Ribbons (비정질 $Ti_{50}-Ni_{30}-Cu_{20}$ 리본의 결정화 열처리와 형상기억특성 변화)

  • Kim, Yoen-Wook;Yun, Young-Mok
    • Journal of Korea Foundry Society
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    • v.28 no.1
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    • pp.31-36
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    • 2008
  • Ti-Ni-Cu alloys are very attractive shape memory alloys for applications as actuators because of a large transformation elongation and a small transformation hysteresis. Rapidly solidified Ti-Ni alloy ribbons have been known to have the shape memory effect and superelasticity superior to the alloy ingots fabricated by conventional casting. In this study, solidification structures and shape memory characteristics of $Ti-Ni_{30}-Cu_{20}$ alloy ribbons prepared by melt spinning were investigated by means of DSC and XRD. Operating parameters to fabricate the amorphous ribbons were the wheel velocity of 55 m/s and the melt spinning temperature of $1500^{\circ}C$. The crystallization temperature was measured to be $440^{\circ}C$. The crystallized ribbons exhibited very fine microstructure after annealing at $440^{\circ}C$ for 10 minutes and $460^{\circ}C$ for 5 minutes and was deformed up to about 6.8% and 6.23% in ductile manner, respectively. Stress-strain curve of the ribbon exhibited a flat stress-plateau at 64 MPa and this is associated with the stress-induced a B2-B19 martensitic transformation. During cycle deformation with the applied stress of 220 MPa, transformation hysteresis and elongation associated with the B2-B19 transformation were observed to be $4.3^{\circ}C$ and 3.6%.

Characterization of Co-Ni Based Ferromagnetic Shape Memory Alloy (자성 Co-Ni 계 형상기억합금의 특성)

  • Han, Ji-Won;Park, Sung Bum
    • Journal of the Korean Society of Safety
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    • v.30 no.4
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    • pp.8-13
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    • 2015
  • The magnetic shape memory alloys have recently received a lot of attention due to the considerable progress achieved in understanding the particular importance and the development of the factors. Among these alloys, the ferromagnetic Co-Ni- alloys have been concerned specially because of the thermoelastic character of the fcc (g) - bct (a) martensitic transformation which exhibits under the action of the temperature (shape memory effect), the stress (superelasticity) and the magnetic field (magnetoelasticity). The morphological, the crystallographical, and the thermal characteristics of thermally induced martensite in Co-35.3Ni-11.3Al(wt.%) and Co-28.1Ni-47.4Fe-3.3Ti (wt.%) alloy have been investigated by the scanning electron microscope (SEM), the X-ray Diffraction (XRD), and the differential scanning calorimeter (DSC).

A kind of NiTi-wire shape memory alloy damper to simultaneously damp tension, compression and torsion

  • Han, Yu-Lin;Yin, Hai-Yang;Xiao, Er-Tian;Sun, Zhi-Lin;Li, Ai-Qun
    • Structural Engineering and Mechanics
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    • v.22 no.2
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    • pp.241-262
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    • 2006
  • NiTi-wire shape memory alloy (SMA) dampers, that utilize NiTi SMA wires to simultaneously damp tension, compression and torsion, was developed for structural control implementation in this study. First, eight reduced-scale NiTi-wire SMA dampers were constructed. Then tension, compression and torsion experiments using the eight reduced-scale NiTi-wire SMA dampers of different specification were done. The experimental results revealed all of the eight reduced-scale NiTi-wire SMA dampers had the ability to simultaneously supply tension-compression damping and torsion damping. Finally, mechanics analysis of the NiTi-wire SMA dampers was done based on a model of the SMA-wire restoring force and on tension-compression and torsion damping analysis. The damping analytical results were found to be similar to the damping experimental results.

Transformation Behavior of Ti-(45-x)Ni-5Cu-xCr (at%) (x = 0.5-2.0) Shape Memory Alloys

  • Im, Yeon-Min;Jeon, Young-Min;Kim, Min-Su;Lee, Yong-Hee;Kim, Min-Kyun;Nam, Tae-Hyun
    • Transactions on Electrical and Electronic Materials
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    • v.12 no.1
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    • pp.28-31
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    • 2011
  • Transformation behavior and shape memory characteristics of Ti-(45-x)Ni-5Cu-xCr (x=0.5-2.0) alloys have been investigated by means of electrical resistivity measurements, differential scanning calorimetry, X-ray diffraction and thermal cycling tests under constant load. Two-stage B2-B19-B19' transformation occurred in Ti-(45-x)Ni-5Cu-xCr alloys. The B2-B19 transformation was separated clearly from the B19-B19' transformation in Ti-44.0Ni-5Cu-1.0Cr and Ti-43.5Ni-5Cu-1.5Cr alloys. A temperature range where the B19 martensite exists was expanded with increasing Cr content because decreasing rate of Ms (85 K / % Cr) was larger than that of Ms' (17 K / % Cr). Ti-(45-x)Ni-5Cu-xCr alloys were deformed in plastic manner with a fracture strain of 68% ~ 43% depending on Cr content. Substitution of Cr for Ni improves the critical stress for slip deformation in a Ti-45Ni-5Cu alloy due to solid solution hardening.

Effect of plastic deformation on the martensitic transformations in TiNi alloy

  • Belyaev, Fedor S.;Evard, Margarita E.;Volkov, Aleksandr E.
    • Smart Structures and Systems
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    • v.29 no.2
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    • pp.311-319
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    • 2022
  • A model of plastic deformation of the shape memory alloys which describes dislocation slip at the microlevel is developed. A condition similar to the Schmid law was adopted for the determination of dislocation slip onset. A description of the interaction of plastic deformation and martensitic transformations by taking into account the densities of deformation defects is proposed. It is shown that the model can correctly describe the effect of plastic strain on the shape memory effect. The proposed model is also capable of describing the two-way shape memory effect.

Three-dimensional Printing of Shape Memory Alloys

  • Carreno-Morelli, E.;Martinerie, S.;Bidaux, J.E.
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09a
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    • pp.256-257
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    • 2006
  • 3D printing of NiTi alloys has been successfully achieved. A novel printing process has been developed and used, which consists in selective deposition of a solvent on a granule bed. The granules are composed of metal powders and thermoplastic binder, which are mixed and sieved by conventional methods. A sound green strength is obtained after solvent evaporation. Sintered parts exhibit good density, proper phase composition and shape memory behaviour.

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Influence of Compositions of Sintered Ti-Ni Alloys on their Thermo-mechanical Properties

  • Kyogoku, Hideki;Ikeda, Tetsuya;Komatsu, Shinichiro
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09a
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    • pp.81-82
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    • 2006
  • This paper presents the influence of the compositions of sintered Ti-Ni alloys on their thermo-mechanical properties. The Ti-Ni alloys having various compositions from 50at%Ni to 51at%Ni were sintered using elemental Ti and Ni powders by a pulse-current pressure sintering equipment. The deformation resistance in stress-strain curves increased with an increase in Ni content. In the case of Ti-50at%Ni, tensile strength and elongation were more than 500 MPa and 7%, respectively. The increase in Ni content also makes the transformation temperatures lower. The deformation resistance at a test temperature change from 293K and 353K in isothermal tensile test increased with elevating test temperature.

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