• 대한기계학회논문집A
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• 제28권4호
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• pp.453-459
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• 2004

25Cr-20Ni series strainless steels have an excellent high temperature strength high oxidation and high corrosion resistance. However, further improvement can be expected of creep strength by work hardening prior creep. In the present study, the effect of prestraining at room temperature on the creep behavior of a Class M(STS310S) and a Class A(STS310J1TB) alloy containing precipitates have been examined. Prestaining was carried out at room temperature and range of prestrain was 0.5-2.5 % at STS310J1TB and 2.0-7.0% at STS310S. Creep behavior and creep rate of pre-strained specimens were compared with that of virgin specimens. Room temperature prestraining produced the creep life that is longer than that of a virgin specimen both for STS310J1TB and STS310S when creep test was carried out at the temperature lower than recrystallization temperature. The reason for this improvement of creep life was ascribable to the interaction between dislocations and precipitates in addition to the dislocation-dislocation interaction in STS310J1TB and the dislocation-dislocation interaction in STS310S. The beneficial effect of prestraining in STS310J1TB was larger than that of STS310S.

• 공업화학
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• 제32권4호
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• pp.478-482
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• 2021

고정층 상압 유통식 반응기를 사용하여 Ln(1)-Ni(5)/SBA-15 (Ln = Dy, Eu, Pr, Tb) 촉매상에서 메탄의 부분 산화 반응을 수행하여 수소의 수율을 조사하였다. X-ray photoelectron spectroscopy (XPS) 분석으로 Ni(5)/SBA-15 촉매에 1 wt%의 Eu를 첨가함으로써 Eu(1)-Ni(5)/SBA-15의 O1s와 Si2p의 핵심 전자 수준의 화학적 이동이 있었으며, O1s, Ni2p_3/2, Si2p의 원자의 비가 1.284, 1.298, 1.058로 증가하였다. 촉매 표면상에 O^-, O^2-의 산소와 Eu³⁺, Ni⁰, Ni²⁺, Si⁴⁺의 이온이 존재함을 알 수 있었다. Eu(1)-Ni(5)/SBA-15 촉매상에서 수소의 수율은 57.2%이었으며, Ln(1)-Ni(5)/SBA-15 (Ln = Dy, Pr, Tb)보다 우수한 수소 수율을 보여주었고 25 h의 반응에서 안정된 촉매 활성을 유지하였다. Eu를 Ni(5)/SBA-15에 1wt%를 첨가함으로서 금속과 담체 간에 강한 상호 작용에 의한 SMSI 효과로 산소 빈자리를 만들고 촉매 표면상에 Ni⁰, N²⁺의 나노입자의 분산을 증가시켜 촉매 활성을 유지시켰다.

• 한국수소및신에너지학회논문집
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• 제13권1호
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• pp.74-82
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• 2002

Ni nanoparticles이 표면에 분산된 mutiwall carbon nanotubes (MWNTs)의 수소저장 특성을 분석하였다. Metal nanoparticles의 분산 방법은 incipient wetness impregnation procedure을 사용하였는데, 이러한 Ni catalysts의 역할은 기존에 알려진 Li, K doping과 같은 개념으로 기상의 수소를 분해하여 carbon 표면에 chemical adsorption 시키는 역할을 하게 된다. 실제로 Ni nanoparticles이 6wt% loading된 경우에는 thermal desorption spectra를 분석한 결과 ~2.8wt% hydrogen이 ~340-520K의 온도범위에서 방출되는 것을 관찰할 수 있었다. Kissingers plot을 통해서 MWNTs와 hydrogen과 interaction energy를 구한 결과 ${\sim}31kJ/molH_2$를 얻을 수 있었으며 이 값은 기존의 SWNTs에 hydrogen이 physi-sorption에서 실험적으로 얻을 수 있었던 값보다 1.5배 큰 값이라고 할 수 있다. 자세한 수소저장 기구를 분석하기 위해서 FT-IR분석을 한 결과 C-Hn stretching vibrations이 관찰되었으며 mono-hydride와 weak di-hydride $sp^3$가 형성된 것으로 해석 될 수 있었다. 이와 같은 결과는 Ni nanoparticle들이 예상과 같이 hydrogen molecules을 dissociation하는 역할을 하는 것을 의미한다. 연속적인 thermal desorption 실험을 통해 가역성도 평가하였다.

• Journal of Magnetics
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• 제5권4호
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• pp.139-142
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• 2000

The interlayer coupling between adjacent ferromagnetic layers was examined for CoFe/Cu/NiFe trilayer systems. A series of films of CoFe (20 nm)/Cu($t_{cu}$)/NiFe (20 nm) trilayers with Cu spacer thickness, $t_{cu}$, in the range of 1~10 m was deposited on Si(100) wafers at room temperature by DC magnetron sputtering. In order to understand the dependence of the magnetic interaction between ferromagnetic $Co_{90}Fe_{10}$ (wt.%) and $Ni_{81}Fe_{19}$ (wt.%) layers separated by a nonmagnetic Cu spacer on the Cu layer thickness, we investigated the derivative ferromagnetic resonance (FMR) spectra. The FMR results were analyzed using the model of Layadi and Art-man for interlayer interaction. The interlayer coupling constant decreases in an oscillatory manner as the Cu spacer thickness increases up to 10 nm and approaches zero above 10 nm. The interlayer coupling constant is positive for all samples. Hence, it seems that the exchange coupling between adjacent CoFe and NiFe layers separated by a Cu layer is ferromagnetic.

• 센서학회지
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• 제25권3호
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• pp.218-222
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• 2016

Pure and V-doped NiO porous structures were prepared by the evaporation-induced surfactant assembly and subsequent pyrolysis of assembled structures, and their gas sensing characteristics were investigated. Pure NiO porous structures showed negligible gas responses (S=$R_g/R_a$, $R_g$: sensor resistance in analytic gas; $R_a$: sensor resistance in air) to 5 ppm trimethylamine (S=1.17) as well as other interfering gases such as ethanol, p-xylene, toluene, benzene and formaldehyde (S=1.02-1.13). In contrast, the V-doped NiO porous structures exhibited a high response and selectivity to 5 ppm trimethylamine (S=14.5) with low cross-responses to other interfering gases (S=4.0-8.7) at $350^{\circ}C$. The high gas response of V-doped NiO porous structures to trimethylamine was explained by electronic sensitization, that is, the increase in the chemoresistive variation due to the decrease in the hole concentration. The enhanced selectivity to trimethylamine was discussed in relation to the interaction between basic trimethylamine gas and acidic V catalysts.

• 분석과학
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• 제8권4호
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• pp.519-527
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• 1995

The retention mechanism of Ni(II)-${\alpha}$-isonitroso-${\beta}$-diketone imine chelates in reversed-phase HPLC has been studied by examining the effect of temperature, mobile phase composition in acetonitrile-water mixture, and molecular structure on retention. The empirical retention equation was investigated to evaluate the properties of S (hydrophilic index). The value of the S index of the Ni(II) chelates decrease with the increasing column temperature and a linear relationship between S and log $k{_w}^{\prime}$ has been found. The results showed that the S index is influenced by the interaction between Ni(II) chelates and mobile phase. Molecular properties, van der Waals molar volume, polarizability and dipole moment, of the Ni(II) chelates were calculated by Cerius 2 program and the calculations were performed at Universal Force Field (UFF) model. The S value and log $k{_w}^{\prime}$ increase with decreasing the dipole moment of Ni(II) chelates.

• Journal of Magnetics
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• 제12권2호
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• pp.64-67
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• 2007

Electronic structures of ordered double perovskites $Ba_2MReO_6$ (M=Mn, Fe, Co, and Ni) are investigated by using the linearized muffin-tin orbitals band method in the local spin-density approximation (LSDA) and the LSDA+U method. The half-metallic ferrimagnetic ground states are obtained for M=Fe and Ni in the LSDA+U, whereas the insulating ground state is obtained for M=Mn in the LSDA+U incorporating the spinorbit interaction. For M= Co, the antiferromagnetic ground state is stabilized in the LSDA+U by invoking the structural distortion.

• 한국자기학회지
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• 제5권5호
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• pp.749-752
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• 1995

Electronic structures of the Heusler compounds, XMnSb (X=Ni, Pd, and Pt) are investigated systematically by using the linearized muffiu-tin orbital (LMTO) band method. LMTO band calculations yield that, by including the spinorbit interactions, the NiMnSb and PtMnSb are half-metallic, while PdMnSb is normal metallic at the experimental lattice constant. The effect of the spin-orbit interaction is substantial in PtMnSb, in contrast to NiMnSb and PdMnSb. The calculated X d and Mn 3d angular momentum projected local density of states's reveal that the hybridization between the Mn 3d X d states increases from X = Pt to Pd and Ni.

• 한국해양공학회지
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• 제16권3호
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• pp.59-64
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• 2002

In the present study, we examined the influence of prestrain on creep strength of Class M alloy(STS310S) and Class A(STS310J1TB) alloys containing precipitates. Prestrain was given by prior creep at a higher stress than the following creep stresses. Creep behaviour before and after stress change and creep rate of pre-strained specimens were compared with that of virgin specimens. Pre-straining produced the strain region where the strain rate was lower than that of a virgin specimen both for STS310J1TB and STS310S steels. The reason for this phenomenon was ascribable to the viscous motion of dislocations, the interaction between dislocations and precipitates in a STS310J1TB steel, and the interaction of dislocations with sub-boundaries in a STS310S steen which has the higher dislocation density and smaller subgrain size resulted from pre-straining at higher stress.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2009년도 제38회 동계학술대회 초록집
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• pp.342-342
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• 2010

We have investigated an Au intercalated monolayer graphene on Ni(111) using angle-resolved photoemission spectroscopy (ARPES), high resolution photoemission spectroscopy (HRPES), and low energy electron diffraction (LEED) at the 3A2 ARUPS beamline in Pohang Accelerator Laboratory. We find the monolayer graphene is well grown on the Ni(111) surface by the adsorption of acetylene. However, the graphene does not show the characteristic $\pi$ band near the Fermi level due to its strong interaction with the underlying substrate. When Au is adsorbed on the surface and then annealed at high temperature, we observe that Au is intercalated underneath the monolayer graphene. The process of the Au intercalation was monitored by HRPES of corresponding Au 4f and C 1s core levels as well as the electronic structure of the $\sigma$, $\pi$ states at $\Gamma$, K points. The $\sigma$, $\pi$ bands of graphene shift towards the Fermi level and the $\pi$ band is clearly observed at K point after the intercalation of full monolayer Au. The full width at half maximum (FWHM) of the C 1s peak narrows to approximately 0.42 eV after intercalation. These results imply that the interaction between the graphene and substrate is considerably weakened after the Au intercalation. We will discuss the graphene is really closer to ideal free standing graphene suggested recently.