• 대한금속재료학회지
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• 제48권3호
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• pp.194-202
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• 2010

Application of a stronger and more durable material for reactor pressure vessels (RPVs) might be an effective way to insure the integrity and increase the efficiency of nuclear power plants. A series of research projects to apply the SA508 Gr.4 steel in ASME code to RPVs are in progress because of its excellent strength and durability compared to commercial RPV steel (SA508 Gr.3 steel). In this study, the microstructural characteristics and mechanical properties of SA508 Gr.3 Mn-Mo-Ni low alloy steel and SA508 Gr.4N Ni-Mo-Cr low alloy steel were investigated. The differences in the stable phases between these two low alloy steels were evaluated by means of a thermodynamic calculation using ThermoCalc. They were then compared to microstructural features and correlated with mechanical properties. Mn-Mo-Ni low alloy steel shows the upper bainite structure that has coarse cementite in the lath boundaries. However, Ni-Mo-Cr low alloy steel shows the mixture of lower bainite and tempered martensite structure that homogeneously precipitates the small carbides such as $M_{23}C_6$ and $M_7C_3$ due to an increase of hardenability and Cr addition. In the mechanical properties, Ni-Mo-Cr low alloy steel has higher strength and toughness than Mn-Mo-Ni low alloy steel. Ni and Cr additions increase the strength by solid solution hardening. In addition, microstructural changes from upper bainite to tempered martensite improve the strength of the low alloy steel by grain refining effect, and the changes in the precipitation behavior by Cr addition improve the ductile-brittle transition behavior along with a toughening effect of Ni addition.

• 대한금속재료학회지
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• 제49권8호
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• pp.628-634
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• 2011

SA508 Gr.4N Ni-Cr-Mo low alloy steel, in which Ni and Cr contents are higher than in commercial SA508 Gr.3 Mn-Mo-Ni low alloy steels, may be a candidate reactor pressure vessel (RPV) material with higher strength and toughness from its tempered martensitic microstructure. The inner surface of the RPV is weld-cladded with stainless steels to prevent corrosion. The goal of this study is to evaluate the microstructural properties of the clad interface between Ni-Cr-Mo low alloy steel and stainless weldment, and the effects of post weld heat treatment (PWHT) on the properties. The properties of the clad interface were compared with those of commercial Mn-Mo-Ni low alloy steel. Multi-layer welding of model alloys with ER308L and ER309L stainless steel by the SAW method was performed, and then PWHT was conducted at $610^{\circ}C$ for 30 h. The microstructural changes of the clad interface were analyzed using OM, SEM and TEM, and micro-Vickers hardness tests were performed. Before PWHT, the heat affected zone (HAZ) showed higher hardness than base and weld metals due to formation of martensite after welding in both steels. In addition, the hardness of the HAZ in Ni-Cr-Mo low alloy steel was higher than that in Mn-Mo-Ni low alloy steel due to a comparatively high martensite fraction. The hardness of the HAZ decreased after PWHT in both steels, but the dark region was formed near the fusion line in which the hardness was locally high. In the case of Mn-Mo-Ni low alloy steel, formation of fine Cr-carbides in the weld region near the fusion line by diffusion of C from the base metal resulted in locally high hardness in the dark region. However, the precipitates of the region in the Ni-Cr-Mo low alloy steel were similar to that in the base metal, and the hardness in the region was not greatly different from that in the base metal.

• 대한금속재료학회지
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• 제46권12호
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• pp.771-779
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• 2008

An effective way of increasing the strength and fracture toughness of reactor pressure vessel steels is to change the material specification from that of Mn-Mo-Ni low alloy steel(SA508 Gr.3) to Ni-Mo-Cr low alloy steel(SA508 Gr.4N). In this study, we evaluate the effects of alloying elements on the microstructural characteristics of Ni-Mo-Cr low alloy steel. The changes in the stable phase of the SA508 Gr.4N low alloy steel with alloying elements were evaluated by means of a thermodynamic calculation conducted with the software ThermoCalc. The changes were then compared with the observed microstructural results. The calculation of Ni-Mo-Cr low alloy steels confirms that the ferrite formation temperature decreases as the Ni content increases because of the austenite stabilization effect. Consequently, in the microscopic observation, the lath martensitic structure becomes finer as the Ni content increases. However, Ni does not affect the carbide phases such as $M_{23}C_6 $ and $M_7C_3$. When the Cr content decreases, the carbide phases become unstable and carbide coarsening can be observed. With an increase in the Mo content, the $M_2C$ phase becomes stable instead of the $M_7C_3$ phase. This behavior is also observed in TEM. From the calculation results and the observation results of the microstructure, the thermodynamic calculation can be used to predict the precipitation behavior.

• 분석과학
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• 제16권1호
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• pp.82-89
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• 2003

Isotope dilution mass spectrometry (IDMS) was applied to the determination of Ni, Cr, Mo in low alloy steel reference materials. The Mo isotope ratio measurement was performed by dynamic reaction cell inductively coupled plasma mass spectrometry (DRC-ICP/MS) using ammonia as a reaction cell gas. In the case of Ni and Cr measurement, all data were obtained at medium resolution mode (m/${\Delta}m=3000$) of double focusing sector field high resolution inductively coupled plasma mass spectrometry (HR-ICP/MS). For the method validation of the technique was assessed using the certified reference materials such as NIST SRM 361, NIST SRM 362, NIST SRM 363, NIST SRM 364, NIST SRM 36b. This method was applied to the determination of Ni, Cr and Mo in low alloy steel sample (CCQM-P25) provided by NMIJ for international comparison study.

• 한국항행학회논문지
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• 제28권4호
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• pp.532-537
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• 2024

본 연구에서는 항공기 및 고속전철 등 대형 수송기기의 제동디스크에 적용되는 Ni-Cr-Mo-V계 및 Ni-Cr-Mo계 저합금강의 합금 성분 변화에 따른 마모 특성을 평가하였다. 경도시험 결과, C-Mo-V강의 경도는 39.4±0.9HRc로 가장 높았고, Ni-Cr-Mo강이 32.4±0.6HRc로 가장 낮았다. 마찰계수는 수직하중이 증가함에 따라 감소하는 경향을 보였으며, 수직하중 1 N에서 Ni-Cr-Mo강의 마찰계수가 0.842, 수직하중 5 N에서 Mn-Cr-V강이 0.696으로 가장 높았다. Ni-Cr-Mo강은 수직하중 1 N에서 마모흔의 폭 711 ㎛, 깊이 8.24 ㎛, 마모량 11 mg, 수직하중 5 N에서 폭 1,017 ㎛, 깊이 19.17 ㎛, 마모량 17 mg으로 가장 큰 마모흔의 폭, 깊이 및 마모량을 보여주었다. 마모기구 분석 결과, 모든 시편에서 패임, 박리 및 응착이 관찰되었고, Ni-Cr-Mo강에서 소성변형이 더 우세하게 관찰되었다.

• 대한금속재료학회지
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• 제47권9호
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• pp.533-541
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• 2009

Materials used for a reactor pressure vessel(RPV) are required high strength and toughness, which determine the safety margin and life of a reactor. Ni-Mo-Cr low alloy steel shows better mechanical properties than existing RPV steels due to higher Ni and Cr contents compared to the existing RPV steels. The present study focuses on effects of Ni, Cr contents on the cleavage fracture toughness of Ni-Mo-Cr low alloy steels in the transition temperature region. The fracture toughness was characterized by a 3-point bend test of precracked Charpy V-notch(PCVN) specimens based on ASTM E1921-08. The test results indicated that the fracture toughness was considerably improved with an increase of Ni and Cr contents. Especially, control of Cr content was more effective in improving fracture toughness than manipulating Ni content, though Charpy impact toughness was changed more extensively by adjusting Ni content. These differences between changes in the fracture toughness and that in the impact toughness were derived from microstructural features, such as martensite lath size and carbide precipitation behavior.

• 한국압력기기공학회 논문집
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• 제10권1호
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• pp.100-106
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• 2014

There is a growing need to introduce advanced pressure vessel steels with higher strength and toughness for the optimizatiooCn of the design and construction of longer life and larger capacity nuclear power plants. SA508 Gr.4N Ni-Cr-Mo low alloy steels have superior strength and fracture toughness, compared to SA508 Gr.3 Mn-Mo-Ni low alloy steel. Therefore, the application of SA508 Gr.4N low alloy steel could be considered to satisfy the strength and toughness required in advanced nuclear power plants. The purpose of this study is to characterize the microstructure and mechanical properties of SA508 Gr.4N low alloy steels. 1 ton ingot of SA508 Gr.4N model alloy was fabricated by vacuum induction melting followed by forging, quenching, and tempering. The predominant microstructure of the SA508 Gr.4N model alloy is tempered martensite having small packet and fine Cr-rich carbides. The yield strength at room temperature was 540MPa, and it was decreased with an increase of test temperature while DSA phenomenon occurred at around $288^{\circ}C$. Overall transition property of SA508 Gr.4N model alloy was much better than SA508 Gr.3 low alloy steel. The index temperature, $T_{41J}$, of SA508 Gr.4N model alloy was $-132^{\circ}C$ in Charpy impact tests, and reference nil-ductility transition temperature, $RT_{NDT}$ of $-105^{\circ}C$ was obtained from drop weight tests. From the fracture toughness tests performed in accordance with the ASTM standard E1921 Master curve method, the reference temperature, $T_0$ was $-147^{\circ}C$, which was improved more than $60^{\circ}C$ compared to SA508 Gr.3 low alloy steels.

• 대한금속재료학회지
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• 제48권2호
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• pp.122-132
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• 2010

Higher strength and fracture toughness of reactor pressure vessel steels can be obtained by changing the material specification from that of Mn-Mo-Ni low alloy steel (SA508 Gr.3) to Ni-Mo-Cr low alloy steel (SA508 Gr.4N). However, the operation temperature of the reactor pressure vessel is more than $300^{\circ}C$ and the reactor operates for over 40 years. Therefore, we need to have phase stability in the high temperature range in order to apply the SA508 Gr.4N low alloy steel for a reactor pressure vessel. It is very important to evaluate the temper embrittlement phenomena of SA508 Gr.4N for an RPV application. In this study, we have performed a Charpy impact test and tensile test of SA508 Gr.4N low alloy steel with changing impurity element contents such as Mn and P. And also, the mechanical properties of these low alloy steels after longterm heat treatment ($450^{\circ}C$, 2000hr) are evaluated. Further, evaluation of the temper embrittlement by fracture analysis was carried out. Temper embrittlement occurs in KL4-Ref and KL4-P, which show a decrease of the elongation and a shifting of the transition curve toward high temperature. The reason for the temper embrittlement is the grain boundary segregation of the impurity element P and the alloying element Ni. However, KL4-Ref shows temper embrittlement phenomena despite the same contents of P and Ni compared with SC-KL4. This result may be caused by the Mn contents. In addition, the behavior of embrittlement is not largely affected by the formation of $M_3P$ phosphide or the coarsening of Cr carbides.

• 대한금속재료학회지
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• 제47권3호
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• pp.139-146
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• 2009

The heat-affected zone (HAZ) of SA508 Gr.4N Ni-Mo-Cr low alloy steel, which has higher Ni and Cr contents than SA508 Gr.3 Mn-Mo-Ni low alloy steel, was investigated on the microstructure and mechanical properties. The HAZ was categorized into seven characteristic zones (CGCG, FGCG, ICCG, SCCG, FGFG, ICIC and SCSC-HAZ) according to the peak temperature from the thermal cycle experienced during multi-pass welding. Post Weld Heat Treatment (PWHT) was conducted in the temperature range of $550{\sim}610^{\circ}C$ for 30 hours to evaluate the effect of PWHT conditions on the microstructure and mechanical properties. Before PWHT, CGHAZ and FGFGHAZ showed high yield strength (YS) ranging from 1000 to 1250 MPa, while YS of SCSCHAZ decreased from 607 MPa (observed for base metal) to 501 MPa. The Charpy impact energies of sub-HAZs fell below 100J at $-29^{\circ}C$, except in the SCSCHAZ. By applying PWHT to sub-HAZ specimens, YS decreased as the PWHT temperature increased. In the case of CGHAZs and FGFGHAZ heat-treated at $610^{\circ}C$, YS dropped drastically to the range of 654~686 MPa. From the Charpy impact test, the upper-shelf energy (USE) increased to approximately 250J and Index temperature ($T_{68J}$) decreased below $-50^{\circ}C$. Specifically, in FGFG, ICIC and SCSC-HAZ, $T_{68J}$ was below -110, which was lower than the case of base metal.

• 열처리공학회지
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• 제10권4호
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• pp.266-277
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• 1997

Near-threshold fatigue crack growth characteristics was investigated on the Ni-Cr-Mo-V low alloy steel, which has the different microstructure obtained by tempering at various temperature. The specimens were austenized at $950^{\circ}C$ and then followed by tempering at $200^{\circ}C$, $530^{\circ}C$ and $600^{\circ}C$. Strain rate was obtained from strain gauge attached on the crack tip and crack opening point was observed through load-strain curve. Threshold stress intensity range(${\Delta}K_{th}$) was increased with increasing tempering tempuerature, but the effective threshold stress intensity rage (${\Delta}K_{eff,\;th}$) was not affected with the increasing temperature. Grain size increased with increasing tempering temperature.