• 제목/요약/키워드: Ni-Cr

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Failure Mechanisms for Zirconia Based Thermal Barrier Coatings

  • Lee, Eui Y.;Kim, Jong H.
    • The Korean Journal of Ceramics
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    • 제4권4호
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    • pp.340-344
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    • 1998
  • Failure mechanisms were investigated for the two layer thermal barrier coatings consisting of NiCrAlY bond coat and $ZrO_2$-8wt.% $Y_2O_3$ ceramic coating during cyclic oxidation. $Al_2O_3$ developed at the ceramic coating/bond coat interface first, followed by the Cr/Ni rich oxides such as $NiCr_2O_4$ and $Ni(Al, Cr)_2O_4$ during cyclic oxidation. It was observed that the spalling of ceramic coatings took place primarily within the NiCrAlY bond coat oxidation products or at the interface between the bond coat oxidation products and zirconia based ceramic coating or the bond coat. It was also observed that the fracture within these oxidation products occurred with the formation of $Ni(Cr, Al)_2O_4$ spinel or Cr/Ni rich oxides. It was therefore concluded that the formation of these oxides was a life-limiting event for the thermal barrier coatings.

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Fe-Cr-Ni 합금의 저온에서의 자기적 성질에 관한 연구 (A Study on the low temperature magnetic properties of Fe-Cr-Ni alloys)

  • 안병덕;김진옥;장경호;송기영
    • 한국자기학회지
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    • 제3권4호
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    • pp.277-283
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    • 1993
  • 세개의 오스테 나이트계의 Fe-Cr-Ni 스테인레스 합금강들의 DC 자화율의 온도의존성을 4.2-300 K 온도영역에서 측정하였다. 측정결과 두개의 합금강들은 two-magnetic-phase 모델(spin glass와 초상자성)을 만족하였으며 나머지 하나는 자기적 2중 천이현상을 나타내었다. 또한 Ni/Cr의 비가 증가할수록 자화율의 최 대값이 증가하고 이 값을 나타내는 온도는 감소하였다.

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오스테나이트계 스테인리스강 모재 및 용접부의 인장특성과 내식성에 관한 연구 (A study on the tensile property and corrosion resistance of austenitic stainless base and weld metal)

  • 정호신;김조권;엄동석
    • Journal of Welding and Joining
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    • 제14권4호
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    • pp.71-78
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    • 1996
  • The effect of chemical composition on mechanical properry and corrosion resistance of austenitic stainless steel was investigated. The main results obtained were as follows : 1. There was a linear relationship between the tensile strength of stainless steel and the $Cr_{eq}/Ni_{eq}$. The larger the $Cr_{eq}/Ni_{eq}$ was the higher the tensile strength of stainless steel. 2. There was a good correlationship between $Cr_{eq}/Ni_{eq}$ and intergranular, gerneral corrsion rate. 3. Intergranular corrosion rate decreased linearly with increasing Cr content. 4. General corrosion rate decreased linearly with increasing Ni content. 5. Logarithm corrosion rate of intergranular and general corrosion has a linear relationship with all of the factor of $Cr_{eq}/Ni_{eq}$, Cr and Ni content.

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Ni-Mo-Cr계 저합금강의 천이온도영역에서의 파괴인성에 미치는 Ni 및 Cr 함량의 영향 (Effects of Ni and Cr Contents on the Fracture Toughness of Ni-Mo-Cr Low Alloy Steels in the Transition Temperature Region)

  • 이기형;박상규;김민철;이봉상;위당문
    • 대한금속재료학회지
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    • 제47권9호
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    • pp.533-541
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    • 2009
  • Materials used for a reactor pressure vessel(RPV) are required high strength and toughness, which determine the safety margin and life of a reactor. Ni-Mo-Cr low alloy steel shows better mechanical properties than existing RPV steels due to higher Ni and Cr contents compared to the existing RPV steels. The present study focuses on effects of Ni, Cr contents on the cleavage fracture toughness of Ni-Mo-Cr low alloy steels in the transition temperature region. The fracture toughness was characterized by a 3-point bend test of precracked Charpy V-notch(PCVN) specimens based on ASTM E1921-08. The test results indicated that the fracture toughness was considerably improved with an increase of Ni and Cr contents. Especially, control of Cr content was more effective in improving fracture toughness than manipulating Ni content, though Charpy impact toughness was changed more extensively by adjusting Ni content. These differences between changes in the fracture toughness and that in the impact toughness were derived from microstructural features, such as martensite lath size and carbide precipitation behavior.

NiCr 박막 저항계의 열적 안정성에 관한 연구 (The Study on Thermal Stability of NiCr Thin-films Resistor)

  • 김인성;정순종;김도한;송재성
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2001년도 추계학술대회 논문집 전기물성,응용부문
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    • pp.168-170
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    • 2001
  • The NiCr is an important material for present thin-film resistor application owing to its low TCR and thermal stability. In this work, the NiCr thin films were deposited on corning glass substrate by reactive magnetron sputtering and the annealing at temperatures range from 300 to $500^{\circ}C$ for 20 min in vacuum. X-ray, AFM, $R_s$(surface leakage current) have been used to study the structural and electrical properties of the NiCr thin films. The high precision NiCr thin films resistor with TCR(temperature coefficient of resistance) of less then 10 ppm/$^{\circ}C$ was obtained under in in-situ annealing at $300^{\circ}C$ on Cr buffer layer substrate. It is clear that the NiCr thin-films resistor electrical properties are low TCR related with it's annealing and buffer layer condition. NiCr thin film resistor having a good thermal stability and low TCR properties are expected for the application to the dielectric material of passive component.

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NiCr 박막의 어닐링과 열적안정성에 관한 연구 (The Study on Thermal Stability of NiCr Thin-films)

  • 김인성;민복기;송재성
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2004년도 추계학술대회 논문집 Vol.17
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    • pp.81-84
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    • 2004
  • The NiCr is an important material for present thin-film resistor application owing to its low TCR and thermal stability. In this work, the NiCr thin films were deposited on coming glass substrate by reactive magnetron sputtering and the annealing at temperatures range from 300 to $500^{\circ}C$ for 20 min in vacuum. X-ray, AFM, $R_s$(surface leakage current) have been used to study the structural and electrical properties of the NiCr thin films. The high precision NiCr thin films resistor with TCR(temperature coefficient of resistance) of less then $10\;ppm/^{\circ}C$ was obtained under in in-situ annealing at $300^{\circ}C$ on Cr buffer layer substrate. It is clear that the NiCr thin-films resistor electrical properties are low TCR related with it's annealing and buffer layer condition. NiCr thin film resistor having a good thermal stability and low TCR properties are expected for the application to the dielectric material of passive component.

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1N 염산 용액에서 Fe-Cr-Ni-W 합금의 양분극 거동에 관한 연구 (The Anodicc PolarizationBehavior of Fe-Cr-Ni-W alloy in 1N HCI Solution)

  • 윤재돈;강성군
    • 한국표면공학회지
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    • 제21권4호
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    • pp.176-182
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    • 1988
  • Effects of Cr, Ni and W on the anodic polarization behavior were investigated for Fe-Cr-Ni-W alloys in deaerated 1N HCI solution. Surface films formed on the polarization were analysed using AES, SEM and EDAX. A higerconcentration of tungten was found in the surface oxide film compared to the matrix. It played an importanet role on incresing the stability of the passive film. The presence of an adequate amount of Cr was essential to increase the pitting resistance of the alloys in acid chloride media. Under 12 wt%cr,alloys containing 6wt%W did not exhidit any passivity at all. The main role of Ni was to control the microstructure rather than to modify the corrosion resistance. In 23 cr-14Ni-^W alloy, the duplex microstructure of ferrite($\delta$-phase) in an austenic matrix was developed. The reson why proferred pitting appeared in austenite and ferrite/austenite interface was that ferrite had more amount of Cr and W than austenite.

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전해 Cr/Ni-P 도금막의 열 사이클 신뢰성 및 균열거동 분석 (Thermal Cycle Reliabilties and Cracking Characteristics of Electroplated Cr/Ni-P Coatings)

  • 이진아;손기락;이규환;박영배
    • 마이크로전자및패키징학회지
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    • 제26권4호
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    • pp.133-140
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    • 2019
  • 열 사이클 조건이 전해 Cr/Ni-P 이중도금 시편의 접합강도 및 균열성장거동에 미치는 영향을 분석하였다. 전해 Ni-P 도금층을 열처리를 통해 결정화 시킨 후 전해 Cr 도금 후 한번 더 열처리한 결과, Cr/Ni-P 계면에서 상호확산으로 인해 Cr-Ni 고용체 band layer가 관찰되었다. 열 사이클 전 접합강도는 25.6 MPa이였으나, 1,000사이클 후 Cr 도금층의 균열 밀도 및 표면 거칠기 증가로 인해 도금층과 접착제 사이의 기계적 고착효과가 향상되어 접착제와 Cr 도금층 사이에서 박리되었고, 접합강도는 47.6 MPa로 점차적으로 증가하였다.

교정용 철사의 인장 특성에 관한 연구 (THE STUDY 0F TENS10N CHARACTERISTICS IN ORTHODONTIC WIRES)

  • 박대한;유영규
    • 대한치과교정학회지
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    • 제14권2호
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    • pp.241-248
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    • 1984
  • The mechanical properties of Cr-Ni alloy of austenitic stainless steel and Co-Cr alloy orthodontic wires were studied in tension. The wires (0.018 inch) were tested in the as-manufactured and heat-treated conditions. Instron type tension testing machine was used for this study. Mean values and standard deviations were computed. The results were as follows; 1. The Cr-Ni orthodontic wires of austenitic stainless steel are generally superior than the Co-Cr orthodontic wires in ultimate tensile strength, In the elongation, however, Co-Cr orthodontic wire are superior than Cr-Ni orthodontic wires. 2. Increase in the degree of strength by heat treatment are more clearly shown in Co-Cr orthodontic wires than Cr-Ni orthodontic wires. And the elongation is decreased by heat treatment in both case. 3. The changes of the degree of strength by cooling method we not clearly shown, but in Cr-Ni orthodontic wires, air cooling are more effective, in Co-Cr orthodontic wires, cooling effect are scarcely shown.

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Ni-Cr과 Co-Cr 합금을 이용한 치과보철물의 부식 특성 및 도재 접합성 (Corrosion Characteristics of Ni-Cr and Co-Cr Alloy Used as a Dental Prosthesis and Its Adhesion to Porcelain)

  • 김기정;최병기;오두록;최병상
    • Corrosion Science and Technology
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    • 제15권3호
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    • pp.141-146
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    • 2016
  • By using Ni-Cr and Co-Cr alloys, porcelain fused to metal (PFM) samples were prepared to examine the interface and the surface corrosion behavior. The potentiodynamic polarization analysis showed that the corrosion current density of Co-Cr alloy ($1.61{\times}10^{-6}A/cm^2$) was three times lower than that of Ni-Cr alloy ($4.83{\times}10^{-6}A/cm^2$) at room temperature. A dental prosthesis consisting of the porcelain fused to Ni-Cr alloy extracted from a patient after approximately four years of usage was examined to assess its resistance to corrosion. OM and SEM images of the metal part revealed a typical pitting corrosion. As compared to porcelain fused to Ni-Cr alloy having a thick layer (${\sim}10{\mu}m$) of oxide at the interface, a relatively thin oxide layer (less than $5{\mu}m$) was formed on Co-Cr alloy, indicating that the interface between Co-Cr alloy and porcelain may have a better adhesion strength than the interface between Ni-Cr alloy and porcelain.