• 제목/요약/키워드: Ni trends

검색결과 63건 처리시간 0.024초

충남 서부 백동 사문암지역 식물체의 중금속 함량 (Heavy metal concentration of plants in Baekdong serpentine area, western part of chungnam)

  • 송석환;김명희;민일식;장인수
    • 한국토양환경학회지
    • /
    • 제4권2호
    • /
    • pp.113-125
    • /
    • 1999
  • 충남 서부 백동 사문암 지역에서 식물체내 중금속 오염정도를 알기 위해 사문암 지역과 각섬석 편암 및 편마암을 포함하는 인접 변성암으로 구성된 비 사문암 지역으로 나누어 식물체를 채취하였고 이들과 관계를 알기 위해 식물체가 서식하는 근접 지점에서 상부토양 및 모암시료도 채취 분석하였다. 이 결과 식물체에서 사문암 지역은 Ni. Cr, Co함량이, 비 사문암 지역은 Fe, Zn함량에서 각각 높았고 두 비사문암 지역 중 대부분 원소가 각섬석 편암 지역에서 높았다. 식물체내 평균 Ni, Co, Cr함량은 사문암, 각섬석 편암 및 편마암 순으로 감소하였고 쑥과 참억새의 절대원소함량은 사문암 지역에서 Fe, Ni 또는 Cr, Zn, Co, As, Sc순서로, 편마암 지역에서는 Fe, Zn, Cr, Ni순서로 감소했고 식물체 부분별 차이에서 대부분 원소에서 지하부가 높았다. 사문암과 편마암 지역 식물체 원소 함량 상대비에서 쑥에 비해 참억새가 대부분의 원소에서 낮은 값을 보였는데 이는 쑥보다 참억새가 척박한 사문암 토양내에서의 낮은 흡수량을, 그리고 비옥한 편마암 토양에서 높은 흡수량을 보이고 있음을 암시한다. 암석과 토양의 절대 원소 함량 비교에서 사문암 지역이 높은 Ni, Co및 Cr함량을 보였고, 이들 원소의 함량은 사문암, 각섬석 편암 및 편마암의 순으로 감소됐는데 이는 상부토양이 모암조성을 반영하기 때문일것으로 추정된다. 암석 및 상부토양의 절대 원소함량에서 사문암지역은 Fe, Cr또는 Ni, Co, Zn, As, Sc, 편마암지역은 Fe, Zn, Cr, Ni, Co또는 Sc순서로 각각 감소했으며 암석과 토양의 상대비는 사문암 지역이 Cr, As, Fe, Sc, Co, Ni, Zn, 편마암 지역은 Sc, Fe, Ni, Zn Cr, Co순서로 각각 감소했다. 상부토양과 식물체의 원소 함량 비교에서 토양이 대부분 원소에서 골았고, 각 원소의 증감에 따라 식물체와 토양은 유사한 경향을 보였다. 토양과 식물체의 각 원소 함량차이에서 사문암, 각섬석 편암, 편마암 순으로 감소했으며 편마암지역 토양이 식물체의 함량에 가장 근접했다. 토양과 식물체의 각 원소함량 관계에서 동종의 개체일지라도 상부토양차이에 따라서 식물체내 원소 흡수량은 상당한 차이를 보였다. 척박한 사문암 지역의 식물이 변성암 지역의 식물과 비교하여 높은 Ni, Co, Cr 함량을 보이면서도 생존하는 것은 이들 식물이 척박한 사문암 지역에서도 생존할 수 있는 내성종임을 암시한다. 상부지각 암석 평균치와 비교에서 사문암 지역의 쑥과 참억새는 상부지각 암석 평균치보다 Ni, Cr 함량에서 높았는데 이는 사문암 지역 식물체내에는 이들 원소들이 과량 축척되었음을 의미한다. 위 연구 결과와 기존 사문암을 모재로 발달된 중금속에 오염된 토양에 대한 연구들을 재고해 보았을 때 식물체를 이용한 토양내 중금속 제거를 위해서는 사문암 지역내 식물체의 생태학적인 연구와 중금속 축척정도등과 같은 추가적인 연구가 필요함을 강력히 암시한다.

  • PDF

경북지역 폐금속광산이 환경에 미치는 영향 (Environmental Effects Caused by Abandoned Metal Mines in the Kyungpook Province)

  • 이재영;김종근;이인호;이진국
    • 자원환경지질
    • /
    • 제26권4호
    • /
    • pp.465-472
    • /
    • 1993
  • The heavy metal contents are more abundant in stream waters, paddy soils and rice plants in the vicinity of abandoned mines compared to the surrounding areas in the Kyungpook province. However, these contents tend to decrease with distance from mines, and show some variation under different geological and geochemical environments. The Sin-stream waters have high contents of Cu=4.9 ppm, Pb=0.1 ppm, Zn=3.5 ppm and other heavy metals (Ni, Co, Cd) at Dalsung abandoned mine and low contents of Cu=0.4 ppm, Pb=0.1 ppm, Zn=0.1 ppm and other metals= 0.002 ppm in the surrounding area. The high contents decrease in the downstream in the area of calcareous sedimentary rocks. The paddy soils have high contents of approximately Cu=51 ppm, Pb=83 ppm, Zn=211 ppm, and Cd=11.3 ppm in the vicinity of Gunwi abandoned mine but low contents of Cu=4.5 ppm, Pb=2.9 ppm, Zn=60 ppm and Cd=0.4 ppm in the surrounding area. The Dadeog abandoned mine also shows similar trends to Gunwi mine. The contents of heavy metals of rice plants are high in the roots but trends to decrease through stem+leaf and become low in brown rices.

  • PDF

An Analysis of Research Trends in Mobile Learning through Comparison between Korea and China using Semantic Network Analysis

  • NI, Dan;LEE, Jiyon
    • Educational Technology International
    • /
    • 제20권2호
    • /
    • pp.169-194
    • /
    • 2019
  • This study aims to compare and analyze the trends of research on mobile learning conducted in Korea and China to suggest future directions and multifaceted subject areas in its study field. To achieve this purpose, 620 Chinese papers from CNKI (CSSCI and CSCD) database and 205 Korean papers from RISS database (KCI and KCI candidate) published between 2009 and 2018 were selected to be analyzed through applying the frequency analysis and visualized semantic network analysis. The criteria for analysis used in this study are four types: publication years, research subjects, research methods, and keywords. The results of this study are as follows. Firstly, in relation to the year of publication, Korea entered the peak of mobile learning research in 2016 (33 papers), and China reached high publications (94 papers) in 2017. Secondly, with regard to the research subjects, the most frequently studied subjects in Korea and China were targeted to college students, followed by general adult groups. Thirdly, in terms of research methods, quantitative research accounted for a high proportion in Korea, but in China, literature research showed a high frequency. Fourthly, the high frequency keywords appearing in mobile learning research of the two countries were mainly reflected in language learning. Based on the findings, several directions of future research for both countries were suggested.

금산 인삼의 화학적 특성

  • 송석환;민일식
    • 한국지하수토양환경학회:학술대회논문집
    • /
    • 한국지하수토양환경학회 2002년도 추계학술발표회
    • /
    • pp.148-151
    • /
    • 2002
  • To clarify of chemical contents for the Keumsan ginseng, two attempts have been done for two year: 2 year and 4 year-ginsengs coilected from the phyllite(Ph0 and granite area(Gr), and 1 year, 2 year and 3 year-ginsengs collected from the phyllite(Ph), shale(Sh) and granite (Gr), In the first attempt, the soil contents of the Ph are high in most of elements. In the comparisons between ages of the ginseng, regardless the area, most of the elements are high in the 4 year and these trends are distinctive in the granite area. In the comparisons of the areas, 2 year-ginsengs of the Ph show high contents in the most of the elements. Comparisons between upper part(leaf and branch) and root part of the ginsengs show that in the 2 year-ginseng, the Gr is high in the root part and the Ph is high in the upper part, while in the 4 year-ginseng, most of the elements are high in the root part. Comparisons between contents of soil and ginsengs show similar in crease and decrese trends. However, the 2 year-ginsengs show clear differences between two areas while in the 4 year-ginseng, differences between the Gr and Ph is not clear. It suggest that the ginsengs absorb eligible element contents with ages, despite of clear content differences of the different soils. In the second attempt, the Gr shows high W, Pb, Th, U, Sn and B contents wlile Ph and Sh show high Ni, Cr, Co, Sc, V, As, Cu and Zn contents. In the comparisons between ages of the ginseng, regardless the area, most of the elements are high in the 2 year, especially in the Gr and Ph. In the comparisons of the areas, 2 year-ginsengs of the Gr show low contents in the most of the elements, and the S1 show higher Ni, V, Th and U contents than the Ph. 3 year-ginsengs of the Gr show low contents in the most of the elements, while the S1 show high contents in the most of elements. relative to the Ph. Comparisons between upper part and root part of the ginsengs show that in the ginseng, regardless the ages, the upper part is high. Comparisons between contents of soil and ginsengs show similar increase and decrese trends, and soil is low than the ginsengs in the most of the elements

  • PDF

학술 연구 논의에서 발생하는 귀화식물의 부정적 인식과 문화적 배제 (Cultural Exclusion and Negative Perception related to Naturalized Plants Derived from Academic Discussion)

  • 유재심
    • 한국환경복원기술학회지
    • /
    • 제16권2호
    • /
    • pp.63-74
    • /
    • 2013
  • This study suggests that some of the negative arguments related to naturalized plants raised in academic discussions are unreasonable through an analysis of trends in the academia's research on naturalized plants in South Korea. A total of 117 academic papers related to "naturalized plants" on the Korean Studies Information Service System (KISS) website were re-classified by space, the number of vascular plant species, the number of naturalized plant species, naturalization index (NI), and urbanization index (UI). Correlation between human interference and naturalized plant distribution, and between sizes of conservation areas and naturalized plant distribution were analyzed. According to the results, while there was a tendency between urban population and UI ($r^2$ = 0.70, p = .000), the number of visitors in national parks had no relation to either the NI or the UI (r = 0.028 and r = 0.013, respectively). Likewise, there was no correlation between national parks or conservation areas and naturalized plant distribution (r = 0.014, r = 0.17, respectively). The average NI and the UI of forest areas were approximately twice as low as those of national parks. In estimated regression equation, when one hypothesizes that the entire 4,952 taxa of plants growing in South Korea, the number of naturalized plants, combining paleo-naturalized plants and neo-naturalized plants, amounted to 2,398 taxa, 48.43%. In the academia, Korean Endemic Plants are less than one quarter of 4,952 taxa. Such results signify that, contrary to discussions in the academia, it is meaningless to distinguish between naturalized plants and native plants. In certain aspects, academic discussions on naturalized plants in Korea have proceeded in a manner similar to cultural exclusion by mono-culturalism in a multi-cultural environment.

Long-term Trends in Pelagic Environments of the East Sea Ecosystem

  • Lee, Chung-Il;Lee, Jae-Young;Choi, Kwang-Ho;Park, Sung-Eun
    • Ocean Science Journal
    • /
    • 제43권1호
    • /
    • pp.1-7
    • /
    • 2008
  • Physical and biological environmental variations in the East Sea were investigated by analysing time-series of oceanographic data and meteorological indices. From 1971 to 2000, dominant periodicity in water temperature variations had two apparent periods of 3 to 4 years and of decades, especially in the southwestern part of the East Sea affected by the influence of inflowing Tsushima warm current. Fluctuating water temperature within a certain period appears to respond to El $Ni{\tilde{n}}o$ events with a time lag. It was found that there was a strong correlation between water temperature and El $Ni{\tilde{n}}o$ events with a time lag of 1.5 and 5.5 years for periods of 3 to 6 years and of decades, respectively. Corresponding with El $Ni{\tilde{n}}o$ events, water temperature variability also showed strong correlation with shift and/or changes in biological and chemical environments of nutrient concentrations, zooplankton biomass, and fisheries. However, there also occurred a short-term periodicity of water temperature variations. Within a period of 1 to 4 years, a relatively short-term cycle of water temperature variation had strong correlation with other climate indices such as Pacific Decadal Oscillation and monsoon index. After comparing coherence and phase spectrum between water temperature and different climate indices, we found that there was a shift of coherent periods to another climate index during the years when climate regime shift was reported.

인증표준물질을 이용한 중금속류와 플루오르화물 전처리방법 비교 연구 (Evaluation of analytical methods for several metals and fluoride by certified reference materials)

  • 전태완;정다위;신선경;최훈근;정영희
    • 분석과학
    • /
    • 제19권2호
    • /
    • pp.172-180
    • /
    • 2006
  • 본 연구는 유해폐기물에 의한 환경오염을 예방하기 위해 폐기물 시험방법과 신규 항목을 설정하기 위해 수행하였다. 국내외 유해폐기물의 규제기준, 시험항목 등을 조사검토하여 유해물질에 대한 우선순위를 선정하였다. 선정한 Ba, Be, Cr(VI), F, Ni, Sb, Se, V 8종의 유해물질을 함유한 오니, 폐유, 소각재 등 폐기물 인증표준물질을 사용하여 전처리방법을 비교분석하였다. 이 결과를 통해 시험방법(안)을 확립하고, 관련 항목 배출 가능성이 있는 표본사업장을 선정하여 시료 37건을 채취분석하였다.

Polymerization of Hydrosilanes and Vinyl Monomers in the Presence of Transition Metal Complex

  • Kim, Myoung-Hee;Lee, Jun;Cha, Hyo Chang;Shin, Joong-Hyeok;Woo, Hee-Gweon
    • 통합자연과학논문집
    • /
    • 제2권1호
    • /
    • pp.18-23
    • /
    • 2009
  • This minireview provides the chosen examples of our recent discoveries in the polymerization of hydrosilanes, dihydrosilole, lactones, and vinyl derivatives using various catalysts. Hydrosilanes and lactones copolymerize to give poly(lactone-co-silane)s with $Cp_2MCl_2$/Red-Al (M = Ti, Zr, Hf) catalyst. Hydrosilanes (including dihydrosilole) reduce noble metal complexes (e.g., $AgNO_3$, $Ag_2SO_4$, $HAuCl_4$, $H_2PtCl_6$) to give nanoparticles along with silicon polymers such as polysilanes, polysilole, polysiloxanes (and silicas) depending on the reaction conditions. Interestingly, phenylsilane dehydrocoupled to polyphenylsilane in the inert nitrogen atmosphere while phenylsilane dehydrocoupled to silica in the ambient air atmosphere. $Cp_2M/CX_4$ (M = Fe, Co, Ni; X = Cl, Br, I) combination initiate the polymerization of vinyl monomers. In the photopolymerization of vinyl monomers using $Cp_2M/CCl_4$ (M = Fe, Co, Ni), the photopolymerization of MMA initiated by $Cp_2M/CCl_4$ (M = Fe, Co, Ni) shows while the polymerization yield decreases in the order $Cp_2Fe$ > $Cp_2Ni$ > $Cp_2Co$, the molecular weight decreases in the order $Cp_2Co$ > $Cp_2Ni$ > $Cp_2Fe$. For the photohomopolymerization and photocopolymerization of MA and AA, the similar trends were observed. The photopolymerizations are not living. Many exciting possibilities remain to be examined and some of them are demonstrated in the body of the minireview.

  • PDF

수소 생산을 위한 바이오오일 수증기 개질 반응에서의 니켈계 촉매 연구동향 (Research Trends of Ni-based Catalysts on Steam Reforming of Bio-oils for H2 Production: A Review)

  • 이다해;서현명;송윤하;이재경
    • 청정기술
    • /
    • 제29권3호
    • /
    • pp.163-171
    • /
    • 2023
  • 최근 탄소중립을 위한 청정에너지로 주목받고 있는 수소는 기존에 화석연료의 수증기 개질 반응을 통한 생산에 의존해왔다. 하지만, 이산화탄소의 방출로 인한 한계가 있어 바이오매스 유래 바이오오일의 수증기 개질 반응이 대안으로 제안되고 있다. 바이오오일의 큰 분자량과 다양한 작용기를 가진 탄화수소들이 섞여 있는 복잡성으로 인해 Ni/Al2O3 개질 촉매의 비활성화되는 문제가 발생해 니켈계 촉매의 개선이 필요하다. 본 총설에서는 바이오오일의 수증기 개질 반응에 이용되는 니켈계 촉매의 개선을 활성상, 담체 및 조촉매의 관점에서 정리했다. 활성상은 고분자의 탄화수소들의 C-C, C-H 결합을 끊어 분해 및 전환하고, 귀금속 및 전이금속이 활용될 수 있다. 담체 및 조촉매는 격자산소를 이용하거나 산점을 억제해 촉매의 비활성화의 주요원인인 탄소 침적을 억제하는 방식으로 촉매를 개선할 수 있다. 바이오오일에 기반한 청정수소 생산에 있어 우수한 성능의 개질 촉매 개발은 중요한 역할을 할 것이다.

Surface Air Temperature Variations around the Antarctic Peninsula: Comparison of the West and East Sides of the Peninsula

  • Lee, Bang-Yong;Kwon, Tae-Yong;Lee, Jeong-Soon;Won, Young-In
    • Ocean and Polar Research
    • /
    • 제24권3호
    • /
    • pp.267-278
    • /
    • 2002
  • This study investigated the spatial characteristics of warming trends and the dipole-like pattern of temperature field in the Antarctic Peninsula using surface air temperature (SAT) of 10 stations in the vicinity of the Antarctic Peninsula. SAT data for the 1962-2001 period at 6 stations (Rothera, Faraday/Vernadsky, Bellingshausen, Orcadas, Esperanza, Halley) revealed in general the larger warming trends in autumn and winter except for Halley. The largest warming was shown for August in the west side of the Peninsula (more than $0.9^{\circ}C/decade$). On the other hand, the recent 14-year SAT data showed the strong warming trends at 9 stations except for Halley in the earlier period (April-June) than August for the 1962-2001 period. The largest warming appeared in May at Esperanza and Butler Island. SAT of the two sides showed significant positive correlations over most of the period except for the mid- and the late 1970s, in which significant negative correlations were found. In the correlation analysis between SAT and sea surface temperature (SST) anomalies in the NINO 3.4 region, strong negative correlation was found in the west side of the Peninsula. Details of the correlation analysis exhibited that the negative correlation was significantly strong from the early 1980s to the mid-1990s. However, it was difficult to find significant correlations of ENSO with SAT in the east side of the Peninsula. So, in this study it failed to find out clearly the out-of-phase relationship of SAT across the Antarctic Peninsula.