• 방사성폐기물학회지
• /
• 제2권1호
• /
• pp.69-75
• /
• 2004

고리 1호기 원자로압력용기의 중성자속과 방사화생성물 재고량을 계산하기 위하여 DORT 코드와 ORIGEN2 코드를 사용하였다. DORT 코드를 이용해 중성자속을 계산하기 위하여 노심을 중앙부터 원자로압력용기까지 방위각 방향으로 94 mesh로 분할하였다. 원자로압력용기 영역의 중성자속을 이용하여 주요 핵종의 단면적을 재계산하였다. 원자로압력용기의 경우, $^{55}$Fe, $^{60}$Co, $^{59}$ Ni 및 $^{63}$ Ni의 핵종이 총 방사능의 약 95%를 차지하였으며, 해체 후 50년 이상 냉각후의 총 방사능은 정지시점과 비교하여 약 0.2% 이하로 감소하는 것으로 평가되었다. 총 중량이 210 ton인 원자로압력용기의 총 방사능은 5.25${\times}$$10^{6}$GBq이었다. ORIGEN2 계산 결과를 검증하기 위하여 고리 1호기 원자로압력용기의 계산값과 실측값에 대한 비교 검증을 수행하였으며, 그 결과는 서로 일치함을 확인할 수 있었다.

• 열처리공학회지
• /
• 제21권6호
• /
• pp.307-313
• /
• 2008

The tensile deformation and shape recovery behaviors were studied in Ni-Ti shape memory wires showing different transformation characteristics by annealing at $200{\sim}600^{\circ}C$. Both R phase ${\rightarrow}$ B19' martensitic transformation at lower temperature and B2 ${\rightarrow}$ R phase transformation at higher temperature occurred in the shape memory wires annealed at $200{\sim}500^{\circ}C$. Transformation temperature and heat flow of B19' martensite increase but those of R phase main almost constant even with increasing annealing temperature. In the case of wires annealed and then cooled to $20^{\circ}C$, plateau on stress-strain curves in tensile testing can be observed due to the collapse of R phase variants and the formation of deformation-induced B19' martensite. In the case of wires annealed and then cooled to $-196^{\circ}C$, however, plateau on stress-strain curves does not appear and stress increases steadily with increasing tensile deformation. Comparing shape recovery rate with cooling temperature after annealing, shape recovery rate of the wire cooled to $20^{\circ}C$ is higher than that of the wire cooled to $-196^{\circ}C$ after annealing, and maximum shape recovery rate of 95% appears in the wire annealed at $400^{\circ}C$ and then cooled to $20^{\circ}C$. $R_s$ and $R_f$ temperatures measured during shape recovery tests are higher than $A_s$ and $A_f$ temperatures measured by DSC tests even at the same annealing temperature.

• 대한기계학회논문집B
• /
• 제38권3호
• /
• pp.227-234
• /
• 2014

전기 자동차의 연료 소모량은 배터리 성능에 의존한다. 배터리의 성능은 작동온도에 민감하기 때문에, 배터리 온도 관리는 성능과 내구성을 보장한다. 특히, 배터리 팩에서의 모듈의 온도 분포는 냉각특성에 영향을 미친다. 이 연구는 모듈 사이의 온도 분포를 확인 할 수 있는 배터리 열적 모델링에 초점을 두었다. 본 연구의 배터리 모델은 NiMH 각형 모델이며, 10개의 모듈로 구성되어졌다. 배터리 열 모델은 열 발생, 채널을 통과하는 대류 열 전달 그리고 모듈 사이의 전도 열 전달로 구성되었다. 배터리 내에서 발생되는 열발생 모델은 충/방전 동안의 전기적인 저항열에 의해 계산되어 진다. 모델은 전 하이브리드 자동차의 운전 동안 적절한 열관리의 전략을 결정한다.

• 한국주조공학회지
• /
• 제29권3호
• /
• pp.120-127
• /
• 2009

The characterestics of high Si-high Mo ductile cast iron, high Si-high Mo C.V. cast iron and Ni-resist cast iron were compared and evaluated. The nodule count of the last one was lower and the nodularity was higher than those for the first one, respectively. The first two had ferritic matrices with small amounts of molybdenum carbides. The first one had the highest tensile strength and the last one the lowest elongation. This had the highest high temperature strength and that of the second one was greatly increased from the room temperature strength. The volumes of the first two were decreased during cooling and that of the last one changed little. The thermal expansion coefficient of the last one was the highest and the first one the lowest. During high temperature oxidation, even though the volume of the first one was increased, the weight was decreased and the volume and weight of the second one were increased. The change of the increased weight of the last one was more than that of thickness.

• 한국추진공학회지
• /
• 제25권3호
• /
• pp.56-61
• /
• 2021

본 연구에서는 극초음속 비행체의 냉각제로 사용되는 액체탄화수소 연료와 흡열 촉매의 안정적 사용을 위해 Al₂O₃와 H-ZSM-5를 stainless steel tube 내벽에 코팅하는 연구를 수행하였다. 액체탄화수소 연료의 흡열분해 반응에서 coke 생성이 불가피하며, stainless steel tube reactor를 냉각채널로 사용하게 됨에 따라 Fe, Ni 금속이 filamentous coke 생성을 유발한다. 이에 따라 stainless steel에 H-ZSM-5를 코팅함으로써, Fe과 Ni 금속이 액체탄화수소 연료에 직접 노출되는 것을 방지하고 filamentous coke 생성을 억제하고자 하였다. 또한 stainless steel과 H-ZSM-5 사이에는 Al₂O₃을 코팅하여, 부착 강도를 증진 시키고자 하였다.

• 한국진공학회:학술대회논문집
• /
• 한국진공학회 2016년도 제50회 동계 정기학술대회 초록집
• /
• pp.129-129
• /
• 2016

Graphene, as a single layer of $sp^2$-bonded carbon atoms packed into a 2D honeycomb crystal lattice, has attracted much attention due to its outstanding properties. In order to synthesize high quality graphene, transition metals, such as nickel and copper, have been widely employed as catalysts, which needs transfer to desired substrates for various applications. However, the transfer steps are not only complicated but also inevitably induce defects, impurities, wrinkles, and cracks of graphene. Furthermore, the direct synthesis of graphene on dielectric surfaces has still been a premature field for practical applications. Therefore, cost effective and concise methods for transfer-free graphene are essentially required for commercialization. Here, we report a facile transfer-free graphene synthesis method through nickel and carbon co-deposited layer. In order to fabricate 100 nm thick NiC layer on the top of $SiO_2/Si$ substrates, DC reactive magnetron sputtering was performed at a gas pressure of 2 mTorr with various Ar : $CH_4$ gas flow ratio and the 200 W DC input power was applied to a Ni target at room temperature. Then, the sample was annealed under 200 sccm Ar flow and pressure of 1 Torr at $1000^{\circ}C$ for 4 min employing a rapid thermal annealing (RTA) equipment. During the RTA process, the carbon atoms diffused through the NiC layer and deposited on both sides of the NiC layer to form graphene upon cooling. The remained NiC layer was removed by using a 0.5 M $FeCl_3$ aqueous solution, and graphene was then directly obtained on $SiO_2/Si$ without any transfer process. In order to confirm the quality of resulted graphene layer, Raman spectroscopy was implemented. Raman mapping revealed that the resulted graphene was at high quality with low degree of $sp^3$-type structural defects. Additionally, sheet resistance and transmittance of the produced graphene were analyzed by a four-point probe method and UV-vis spectroscopy, respectively. This facile non-transfer process would consequently facilitate the future graphene research and industrial applications.

• 한국결정성장학회지
• /
• 제24권4호
• /
• pp.151-157
• /
• 2014

The degradation mechanisms of thermal barrier coatings (TBCs) were investigated in different thermal fatigue condition in terms of microstructural analyses. The isothermal and cyclic oxidation tests were conducted to atmospheric plasma sprayed-TBCs on NIMONIC 263 substrates. The delamination occurred by the oxide layer formation at the interface, the Ni/Cr-based oxide was formed after Al-based oxide layer grew up to ${\sim}10{\mu}m$ in the isothermal condition. In the cyclic oxidation with dwell time, the failure occurred earlier (500 hr) than in the isothermal oxidation (900 hr) at same temperature. The thickness of Al-based oxide layer of the delaminated specimen in the cyclic condition was ${\sim}4{\mu}m$ and the interfacial cracks were observed. The acoustic emission method revealed that the cracks generated during the cooling step. It was considered that the specimens were prevented from the formation of the Al-based oxide by cooling treatment, and the degradation mode in the cyclic test was dominantly interfacial cracking by the difference of thermal expansion coefficients of the coating layers.

• Journal of Magnetics
• /
• 제7권3호
• /
• pp.80-93
• /
• 2002

The role of magnetic anisotropy of the antiferromagnetic layer on the magnetization process of exchange coupled polycrystalline ferromagnetidantiferromagnetic bilayers is discussed. In order to elucidate the magnetic torque response of Ni-Fe/Mn-Ir bilayers, the single spin ensemble model is newly introduced, taking into account the two-dimensionally random distribution of the magnetic anisotropy axes of the antiferromagnetic grains. The mechanism of the reversible inducement of the exchange anisotropy along desirable directions by field cooling procedure is successfully explained with the new model. Unidirectional anisotropy constant, J$k$, of polycrystalline Ni-Fe/Mn-Ir and Co-Fe/Mn-Ir bilayers is investigated as functions of the chemical composition of both the ferromagnetic layer and the antiferromagnetic layer. The effects of microstructure and surface modification of the antiferromagnetic layer on JK are also discussed. As a notable result, an extra large value of J$k$, which exceeds 0.5 erg/cm$^2$, is obtained for $Co_{70}Fe_{30}Mn_{75}Ir_{25}$ bilayer with the ultra-thin (50${\AA}$∼100${\AA}$) Mn-Ir layer. The exchange anisotropy of $Co_{70}Fe_{30}$ 40 ${\AA}/Mn_{75}Ir_{25}$ 100 ${\AA}$ bilayer is stable for thermal annealing up to $400{^{\circ}C}$, which is sufficiently high for the application of spin valve magnetoresistive devices.

• 대한기계학회논문집A
• /
• 제21권3호
• /
• pp.439-446
• /
• 1997

A traditional notion of composites has been composed as a uniform dispersoid, but now it is proposed without regard to such rule with process development. Functionally Graded Material(FGM) consists of a new material design that is to make intentionally irregular dispersion state. In this study, thermal stress analysis of plasma spraying PSZ/NiCrAlY gradient material was conducted theoretically using a finite-element program. A formations of the model are direct bonding material(NFGM) and FGM with PSZ and NiCrAlY component element. The temperature conditions were $700^{\circ}C$ to 1100.deg. C assuming a cooling-down precess up to room temperature. Fracture damage mechanism was analyzed by the parameters of residual stress.

• 대한기계학회논문집
• /
• 제18권11호
• /
• pp.2913-2921
• /
• 1994

In SMA(shape memory alloy), the degradation by fatigue is one of the most important problems to be overcome, when SMA is used for robot-actuator material. The actuator is operated repeatitively for long time and its repeating operation develops the fatigue degradation of SMA. The fatigue degradation changes the transformation temperature and deformation behavior and results in inaccurate operation control of robot. Accordingly, the changing behavior of transformation temperature and deformation which results from repeating operation is to be investigated in advance and the scheme to resolve those problems have to be made for the design of actuator. In this study, the fatigue tests were carried out on SMA specimens prepared to have different condition of aging time and pre-strain with the direct-current heating-cooling method, which was a general method of operation in robot actuators. The behavior of transformation temperature and deformation were examined and analyzed in each specimen and the study was performed to establish the optimistic manufacturing condition of SMA against the fatigue degradation.