• Title/Summary/Keyword: Near-infrared Absorption

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Evaluating Spectral Preprocessing Methods for Visible and Near Infrared Reflectance Spectroscopy to Predict Soil Carbon and Nitrogen in Mountainous Areas (산지토양의 탄소와 질소 예측을 위한 가시 근적외선 분광반사특성 분석의 전처리 방법 비교)

  • Jeong, Gwanyong
    • Journal of the Korean Geographical Society
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    • v.51 no.4
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    • pp.509-523
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    • 2016
  • The soil prediction can provide quantitative soil information for sustainable mountainous ecosystem management. Visible near infrared spectroscopy, one of soil prediction methods, has been applied to predict several soil properties with effective costs, rapid and nondesctructive analysis, and satisfactory accuracy. Spectral preprocessing is a essential procedure to correct noisy spectra for visible near infrared spectroscopy. However, there are no attempts to evaluate various spectral preprocessing methods. We tested 5 different pretreatments, namely continuum removal, Savitzky-Golay filter, discrete wavelet transform, 1st derivative, and 2nd derivative to predict soil carbon(C) and nitrogen(N). Partial least squares regression was used for the prediction method. The total of 153 soil samples was split into 122 samples for calibration and 31 samples for validation. In the all range, absorption was increased with increasing C contents. Specifically, the visible region (650nm and 700nm) showed high values of the correlation coefficient with soil C and N contents. For spectral preprocessing methods, continuum removal had the highest prediction accuracy(Root Mean Square Error) for C(9.53mg/g) and N(0.79mg/g). Therefore, continuum removal was selected as the best preprocessing method. Additionally, there were no distinct differences between Savitzky-Golay filter and discrete wavelet transform for visual assessment and the methods showed similar validation results. According to the results, we also recommended Savitzky-Golay filter that is a simple pre-treatment with continuum removal.

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Application of Near-Infrared Spectroscopy in Neurological Disorders: Especially in Orthostatic Intolerance (신경계 질환에서 근적외선분광분석법의 적용: 기립불내증을 중심으로)

  • Kim, Yoo Hwan;Paik, Seung-ho;Phillips V, Zephaniah;Seok, Hung Youl;Jeon, Nam-Joon;Kim, Beop-Min;Kim, Byung-Jo
    • Journal of the Korean neurological association
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    • v.35 no.1
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    • pp.8-15
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    • 2017
  • Near-infrared spectroscopy (NIRS), a noninvasive optical method, utilizes the characteristic absorption spectra of hemoglobin in the near-infrared range to provide information on cerebral hemodynamic changes in various clinical situations. NIRS monitoring have been used mainly to detect reduced perfusion of the brain during orthostatic stress for three common forms of orthostatic intolerance (OI); orthostatic hypotension, neurally mediated syncope, and postural orthostatic tachycardia syndrome. Autonomic function testing is an important diagnostic test to assess their autonomic nervous systems for patients with symptom of OI. However, these techniques cannot measure dynamic changes in cerebral blood flow. There are many experimentations about study of NIRS to reveal the pathophysiology of patients with OI. Research using NIRS in other neurologic diseases (stroke, epilepsy and migraine) are ongoing. NIRS have been experimentally used in all stages of stroke and may complement the established diagnostic and monitoring tools. NIRS also provide pathophysiological approach during rehabilitation and secondary prevention of stroke. The hemodynamic response to seizure has long been a topic for discussion in association with the neuronal damage resulting from convulsion. One critical issue when unpredictable events are to be detected is how continuous NIRS data are analyzed. Besides, NIRS studies targeting pathophysiological aspects of migraine may contribute to a deeper understanding of mechanisms relating to aura of migraine. NIRS monitoring may play an important role to trend regional hemodynamic distribution of flow in real time and also highlights the pathophysiology and management of not only patients with OI symptoms but also those with various neurologic diseases.

PRECIPITABLE WATER VAPOR CONDITIONS FOR INFRARED OBSERVATIONS AT KOREAN ASTRONOMICAL OBSERVATORIES (국내 천문대 상공의 수증기량 조건과 적외선 관측)

  • Lee, Sung-Ho;Baek, Jeong-Ho;Moon, Bong-Kon;Jin, Ho;Cho, Jung-Ho;Cha, Sang-Mok;Cho, Seoung-Hyun;Park, Yung-Sik;Yuk, In-Soo;Nam, Uk-Won;Pak, Soo-Jong
    • Journal of Astronomy and Space Sciences
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    • v.24 no.4
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    • pp.339-348
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    • 2007
  • KASINICS (Korea Astronomy and Space Science Institute Near Infrared Camera System) is equipped with a InSb array which can observe $1-5\;{\mu}m$ bands in near-infrared. The absorption and emission by telluric water vapor becomes serious in the bands longer than $3\;{\mu}m$. We measured PWV (precipitable Water Vapor) levels above Bohyusan Optical Astronomy Observatory and Sobaeksan Optical Astronomy Observatory from July 2006 to August 2007 using the GPS PWV measurement system of KASI. We found that monthly averaged PWVs are lower than the prediction using dew-point temperature and as low as above Kitt Peak from September to February.

Optical properties of $Zn_2AgGaSe_4$ and $Zn_2AgGaSe_4$ : $Co^{2+}$ crystals ($Zn_2AgGaSe_4$$Zn_2AgGaSe_4$ : $Co^{2+}$ 결정의 광학적 특성)

  • Kim, Hyung-Gon;Kim, Byung-Chul
    • Proceedings of the KIEE Conference
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    • 1999.11a
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    • pp.10-12
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    • 1999
  • Optical properties of $Zn_2AgGaSe_4$ and $Zn_2AgGaSe_4$:$Co^{2+}$ crystals are investigated in the visible and near-infrared regions at 298K. The direct band gap at 298K is 1.630eV for the $Zn_2AgGaSe_4$ and 1.567eV for the $Zn_2AgGaSe_4$:$Co^{2+}$ crystals, respectively. In the optical absorption and PAS spectrum of the $Zn_2AgGaSe_4$:$Co^{2+}$, we observed five impurity absorption peaks at $4220cm^{-1}$, $5952cm^{-1}$, $12422cm^{-1}$, $12987cm^{-1}$ and $14184cm^{-1}$. These impurity absorption peaks are attributed to the electronic transitions between the split energy levels of $Co^{2+}$ ions with Td symmetry of $Zn_2AgGaSe_4$ host lattice. The crystal field parameter Dq, the Racah parameter B and the spin-orbit coupling parameter $\lambda$ are given by $442cm^{-1}$, $425cm^{-1}$ and $440cm^{-1}$, respectively.

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2 - 4 ㎛ Spectroscopy of Red Point Sources in the Galactic Center

  • Jang, DaJeong;An, Deokkeun;Sellgren, Kris;Ramirez, Solange V.;Boogert, Adwin;Geballe, Tom
    • The Bulletin of The Korean Astronomical Society
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    • v.44 no.2
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    • pp.49.2-49.2
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    • 2019
  • We present results from our long-term observing campaign, using the NASA IRTF at Maunakea, to obtain 2 - 4 ㎛ spectra of 118 red point sources in the line of sight to the Galactic Center (GC). Our sample is largely composed of point sources selected from near- and mid-infrared photometry, but also includes a number of massive young stellar objects. Many of these sources show high foreground extinction as shown by deep 3.4 ㎛ aliphatic hydrocarbon absorption feature, which is a characteristic of the diffuse ISM and comes from the long line of sight through the diffuse medium toward the Central Molecular Zone (CMZ), the central 300 pc region of the GC. The deep 3.1 ㎛ H2O ice absorption band coming from the local, dense material in the GC CMZ suggests that most sources are likely located in the GC CMZ. A few of these sources show weak CCH3OH ice absorption at 3.535 ㎛, which can provide a strong constraint on the CCH3OH ice formation in the unique environment of the CMZ. From the best-fitting models, the optical depths of these features are determined and used to generate a well-rounded view of the ice composition across the GC CMZ and the spectral characteristics of massive YSOs in the GC.

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On the UV and IR Spectra of Dioxane Lignin from Bamboo Culm (죽재(竹材) Dioxane Lignin의 UV, IR Spectrum에 대하여)

  • Moon, Chang-Kuck;Jo, Jong-Soo
    • Journal of the Korean Wood Science and Technology
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    • v.15 no.4
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    • pp.26-31
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    • 1987
  • The ultraviolet and infrared spectra of dioxane lignin from bamboo were investigated. 1. Spectrum curve type considerably resembled that of wood lignin. There were 3 absorption peak positions at 210nm(max. peak), at 260-270nm(shallow mini. peak), at 280nm(lower max. peak) as in the wood lignin spectra. 2. The lower minimum peak near at 280 nm is the typical peak of lignin. This peak does not exist exactly at 280 nm but from 282nm to 285nm in this bamboo UV spectra. The absorption intensities are equal in this region and the peak is not sharp. 3. The absorption band of aromatic nucleus is near at wave number $1550cm^{-1}$ in the IR spectra of bamboo lignin. The intensity at about 1040-$1130cm^{-1}$ and at about 1230-$1275cm^{-1}$ were similar in the hardwood lignin but reverse to that of softwood lignin spectrum.

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IR Absorption Property in Nano-thick Nickel Silicides (저온에서 형성된 니켈실리사이드의 적외선 흡수 특성)

  • Han, Jeung-Jo;Song, Oh-Sung;Choi, Young-Youn
    • Korean Journal of Materials Research
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    • v.19 no.4
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    • pp.179-185
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    • 2009
  • We fabricated thermally evaporated 30 nm-Ni/(20 nm or 60 nm)a-Si:H/Si films to investigate the energy-saving property of silicides formed by rapid thermal annealing (RTA) at temperatures of $350^{\circ}C$, $450^{\circ}C$, $550^{\circ}C$, and $600^{\circ}C$ for 40 seconds. A transmission electron microscope (TEM) and a high resolution X-ray diffractometer (HRXRD) were used to determine the cross-sectional microstructure and phase changes. A UVVIS-NIR and FT-IR (Fourier transform infrared spectroscopy) were employed for near-IR and middle-IR absorbance. Through TEM and HRXRD analysis, for the nickel silicide formed at low temperatures below $450^{\circ}C$, we confirmed columnar-shaped structures with thicknesses of $20{\sim}30\;nm$ that had ${\delta}-Ni^2Si$ phases. Regarding the nickel silicide formed at high temperatures above $550^{\circ}C$, we confirmed that the nickel silicide had more than 50 nm-thick columnar-shaped structures with a $Ni_{31}Si_{12}$ phase. Through UV-VIS-NIR analysis, nickel silicide showed almost the same absorbance in the near IR region as well as ITO. However, in the middle IR region, the nickel silicides with low temperature showed similar absorbance to those from high temperature silicidation.

IGRINS Spectral Library

  • Park, Sunkyung;Lee, Jeong-Eun;Kang, Wonseok;Lee, Sang-Gak;Chun, Moo-Young;Kim, Kang-Min;Yuk, In-Soo;Lee, Jae-Joon;Mace, Gregory N.;Kim, Hwihyun;Kaplan, Kyle F.;Jaffe, Daniel T.
    • The Bulletin of The Korean Astronomical Society
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    • v.41 no.2
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    • pp.43.3-43.3
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    • 2016
  • We present a library of high-resolution (R~45,000) and high signal-to-noise ratio ($S/N{\geq}200$) near-infrared spectra of 147 standard stars. High quality spectra were obtained with Immersion GRating INfrared Spectrograph (IGRINS) covering the full range of H ($1.496-1.795{\mu}m$) and K ($2.080-2.460{\mu}m$) bands. The targets are mainly selected as MK standard stars which have well-defined spectral types and luminosity classes, and cover a wide range of effective temperatures and surface gravities. The spectra were corrected for telluric absorption lines and absolute flux calibrated using Two Micron All Sky Survey (2MASS) photometry. We find new spectral indices in H and K bands and provide their EWs. We describe empirical relations between the measured EWs and stellar atmosphere parameters such as effective temperature and surface gravity.

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Bio-Optical Modeling of Laguna de Bay Waters and Applications to Lake Monitoring Using ASTER Data

  • Paringit, EC.;Nadaoka, K.;Rubio, MCD;Tamura, H.;Blanco, Ariel C.
    • Proceedings of the KSRS Conference
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    • 2003.11a
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    • pp.667-669
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    • 2003
  • A bio-optical model was developed specific for turbid and shallow waters. Special studies were carried out to estimate absorption and scattering properties as well as backscattering probability of suspended matter. The inversion of bio-optical model allows for direct retrieval of turbidity and chlorophyll- a from the visible-near infrared (VNIR) range sensor. Time-series satellite imagery from ASTER AM-1 sensor, were used to monitor the Laguna de Bay water quality condition. Spatial distribution of temperature for the lake was extracted from the thermal infrared (TIR) sensor. Corresponding field surveys were conducted to parameterize the bio -optical model. In-situ measurements include suspended particle and chlorophyll-a concentrations profiles from nephelometric devices and processing of water samples. Hyperspectral measurements were used to validate results of the bio -optical model and satellite- based estimation. This study provides a theoretical basis and a practical illustration of applying space- based measurements on an operational basis.

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PROCESSING OF INTERSTELLAR MEDIUM AS DIVULGED BY AKARI

  • Onaka, Takashi;Mori, Tamami I.;Ohsawa, Ryou;Sakon, Itsuki;Bell, Aaron C.;Hammonds, Mark;Shimonishi, Takashi;Ishihara, Daisuke;Kaneda, Hidehiro;Okada, Yoko;Tanaka, Masahiro
    • Publications of The Korean Astronomical Society
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    • v.32 no.1
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    • pp.77-81
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    • 2017
  • A wide spectral coverage from near-infrared (NIR) to far-infrared (FIR) of AKARI both for imaging and spectroscopy enables us to efficiently study the emission from gas and dust in the interstellar medium (ISM). In particular, the Infrared Camera (IRC) onboard AKARI offers a unique opportunity to carry out sensitive spectroscopy in the NIR ($2-5{\mu}m$) for the first time from a spaceborn telescope. This spectral range contains a number of important dust bands and gas lines, such as the aromatic and aliphatic emission bands at 3.3 and $3.4-3.5{\mu}m$, $H_2O$ and $CO_2$ ices at 3.0 and $4.3{\mu}m$, CO, $H_2$, and H I gas emission lines. In this paper we concentrate on the aromatic and aliphatic emission and ice absorption features. The balance between dust supply and destruction suggests significant dust processing taking place as well as dust formation in the ISM. Detailed analysis of the aromatic and aliphatic bands of AKARI observations for a number of H ii regions and H ii region-like objects suggests processing of carbonaceous dust in the ISM. The ice formation process can also be studied with IRC NIR spectroscopy efficiently. In this review, dust processing in the ISM divulged by recent analysis of AKARI data is discussed.