• Proceedings of the Korean Magnestics Society Conference
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• 1995.10a
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• pp.64-65
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• 1995

• Analytical Science and Technology
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• v.8 no.3
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• pp.341-350
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• 1995

$Nd_{14}Fe_{80}B_6$ ribbon alloy was manufactured with using melt-spinning method and analyzed the magnetic properties according to the manufacturing conditions. The microstructure and magnetic properties of melt-spun ribbons are sensitively dependent on the quench rate and annealing conditions. As-quenched $Nd_{14}Fe_{80}B_6$ ribbons with optimum magnetic properties are obtained at wheel speed($v_s$) of about 20m/sec and over quenched ribbons show optimum magnetic properties at $v_s$=22m/see when annealed for 30 minutes at $600^{\circ}C$ under vacuum. The crystallization temperature($T_k$) of $Nd_2Fe_{14}B$ phase is about $595^{\circ}C$ in the DTA analysis.

• Proceedings of the Korean Magnestics Society Conference
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• 1994.03a
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• pp.62-63
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• 1994

• Proceedings of the KAIS Fall Conference
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• 2002.05a
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• pp.52-54
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• 2002

본 연구는 고특성 소결자석 제조용 strip-cast 합금을 개발하기 위한 기초단계 연구로서 파양한 조건을 통해 strip-cast 합금을 제조한 후, 제조조건이 합금의 미세조직 형성에 미치는 영향을 조사하였다. 조성이 Nd/sub 15/Fe/sub 77/B/sub 8/인 strip-cast 합금을 다양한 방법으로 제조한 결과, wheel speed 즉, 냉각속도가 5 m/s 이하에서 strip 표면에 수직한 방향으로 수지상정이 잘 발달한 것을 발견하였으나, 그 이상의 냉각속도에서는 수지상정이 붕괴되며 미세한 결정질로만 구성된 것으로 관찰되었다. 따라서 잘 발달된 수지상정을 얻기 위해서는 냉각속도를 5 m/s로 유지해야 함을 알 수 있었다 이 때 수지상정간 간격은 약 4-7㎛로써 고특성 소결자석의 기준에 잘 부합되었다. 한편 XRD 분석결과, 냉각속도 5 m/s이하에서는 <001> 방향으로 뚜렷하게 preferred orientation이 일어난 것을 확인하였으며, 이것은 strip 합금의 분쇄 및 소결시에 결정립 배향성에 유리하게 작용하여 최종 소결자석의 자기적 특성 향상에 기여할 것으로 예상된다.

• Proceedings of the Korean Magnestics Society Conference
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• 1998.05a
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• pp.80-81
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• 1998

• Proceedings of the Korean Magnestics Society Conference
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• 1998.05a
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• pp.92-93
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• 1998

• Proceedings of the Korean Magnestics Society Conference
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• 2000.09a
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• pp.379-380
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• 2000

• Journal of Powder Materials
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• v.16 no.4
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• pp.285-290
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• 2009

HDDR treated anisotropic Nd-Fe-B powders have been widely used, due to their excellent magnetic properties, especially for sheet motors and sunroof motors of hybrid and electric vehicles. Final microstructure and coercivity of such Nd-Fe-B powders depend on the state of starting mother alloys, so additional homogenization treatment is required for improving magnetic properties of them. In this study, a homogenization treatment was performed at $900\sim1140^{\circ}C$ in order to control the grain size and Nd-rich phase distribution, and at the same time to improve coercivity of the HDDR treated magnetic powders. FE-SEM was used for observing grain size of the HDDR treated powder and EPMA was employed to observe distribution of Nd-rich phase. Magnetic properties were analyzed with a vibrating sample magnetometer.

• Proceedings of the Korean Magnestics Society Conference
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• 1995.05a
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• pp.52-53
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• 1995

• Korean Journal of Materials Research
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• v.11 no.7
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• pp.609-614
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• 2001

This study was carried out to obtain a basic data on the production of the Nd-Fe-B system rare earth anisotropic bonded magnet by R-D & HDDR process. The reduction reaction of Nd$_2$O$_3$by metallic Ca and the diffusion reaction of Nd into Fe-B alloy powder were investigated for the production the Nd-Fe-B alloy powder. We concluded that a proper quantity of metallic Ca was about 1.3 times of theoretical equivalent from the yields of Nd and B after the R-D reaction at 100$0^{\circ}C$ for 1h. In the XRD analysis the diffusion reaction of Nd into the center of Fe-B alloy powder for the completed homogenization was required through about 45min at 110$0^{\circ}C$ for the R-D reaction, and also the maximum efficiency on the yield of Nd was obtained with such a condition. Residual Ca and oxygen contents of the final powder sample after washing were detected in 0.17wt% and 0.42wt% by ICP and oxygen analyzer, respectively.