• 제목/요약/키워드: Nd-Cu-Zn

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An Investigation of the Hazards Associated with Cucumber and Hot Pepper Cultivation Areas to Establish a Good Agricultural Practices (GAP) Model (오이와 고추생산 환경에서의 GAP 모델 개발을 위한 위해요소 조사)

  • Shim, Won-Bo;Lee, Chae-Won;Jeong, Myeong-Jin;Kim, Jeong-Sook;Ryu, Jae-Gee;Chung, Duck-Hwa
    • Korean Journal of Food Science and Technology
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    • v.46 no.1
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    • pp.108-114
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    • 2014
  • To analyze the hazards associated with cucumber and hot pepper cultivation areas, a total of 72 samples were obtained and tested to detect the presence of biological (sanitary indicative, pathogenic bacteria and fungi) and chemical hazards (heavy metals and pesticide residues). The levels of sanitary indicative bacteria (aerobic plate counts and coliforms) and fungi were ND-7.2 and ND-4.8 log CFU/(g, mL, hand, or $100cm^2$) in cucumber cultivation areas, and ND-6.8 and 0.4-5.3 log CFU/(g, mL, hand, or $100cm^2$) in hot pepper cultivation areas. More specifically, the soil of hot pepper cultivation areas was contaminated with coliforms at a maximum level of 5.6 log CFU/g. Staphylococcus aureus was detected only in glove samples at a level of 1.4 log CFU/$100cm^2$ and Bacillus cereus was detected in the majority of samples at a level of ND-4.8 log CFU/(g, mL, hand, or $100cm^2$). Listeria monocytogenes, Escherichia coli O157:H7, and Salmonella spp. were not detected. Heavy metal (Zn, Cu, Ni, Pb, and Hg) chemical hazards were detected at levels lower than the regulation limit. Residual insecticides were not detected in cucumbers; however, hexaconazole was detected at a level of 0.016 mg/kg (maximum residue limit: 0.3 mg/kg) in hot peppers.

A Study on the Water Quality of Domestic Mineral Water (Saeng Su) (국내 보존음료수(생수)의 성분에 관한 연구)

  • 류의형;이중근;김성조
    • Journal of Environmental Health Sciences
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    • v.16 no.2
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    • pp.41-45
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    • 1990
  • This study was performed to analyze for the mineral water (Saeng Su) from 12 pure beverage Co. products, which was obtained during March to May in 1988. The results were as follows: 1. The analytical results of contaminant materials in all the samples were suitable for drinking water standard. The mean value of NH$_{3}$-N, NO$_{3}$-N, Cl-and KMnO$_{4}$ consumption were ND, 49mg/l, 1.08mg/l and 8.14mg/l, respectively. 2. Total bacterial counts were 3/cc in average and Coliforms was negative in all samples. 3. The analytical results of Heavy metals were not detected or detected in a small amount, and the contents were different from each company. The CN, Hg, P were not detected in all the samples and the mean value of Cu, Fe, Mn were 0.0087mg/l, 0.0303mg/l, 0.018mg/l, respectively and it's contents were low. 4. The mean value of Pb, Zn, Cr$^{+6}$, As and Cd were 0.016mg/l, 0.015mg/l, 0.0025mg/l. 0.0059mg/l and 0.0011mg/l respectively.

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Ion Exchange Separation of Minor Elements from Iron for the Analysis of S/G Sludge

  • Park, Kyoung-Kyun;Choi, Kwang-Soon;Kim, Jong-Goo
    • Proceedings of the Korean Nuclear Society Conference
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    • 2005.05a
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    • pp.309-310
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    • 2005
  • Some minor elements(Al, B, Ba, Ca, Cd, Co, Cr, Cu, Gd, Mg, Mn, Mo, Nd, Ni, P, Pb, Si, Sn, Sr, Ti, V, Yb, Zn and Zr) in iron compounds such as the S/G sludge of a power plant were separated from iron by anionic and cationic exchange methods. If a ICP-AES or AAS determination follows this method, minor elements of more than 2 or 20 ppm of Fe can be determined with an error less than 20% except Sn and Mo. Alkaline elements were excluded from this study since they can be easily recovered from an anionic exchange. Application to real sludge samples is ongoing.

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Monitoring of Heavy Metals in Fishes in Korea -As, Cd, Cu. Pb, Mn, Zn, Total Hg - (유통 중인 어류의 중금속 모니터링 - 비소, 카드뮴, 구리, 납, 망간, 아연, 총수은 -)

  • Kim, Hee-Yun;Kim, Seo-Young;Lee, Jin-Ha;Jang, Young-Mi;Lee, Myoung-Sook;Park, Jong-Seok;Lee, Kwang-Ho;Kim, Jin-Chul
    • Korean Journal of Food Science and Technology
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    • v.39 no.4
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    • pp.353-359
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    • 2007
  • This survey was carried out to estimate the heavy metal contents of fishes (531 ocean fishes and 80 freshwater fishes) sold in and around Korea from April to October in 2006 . The contents of arsenic (As), cadmium (Cd), copper (Cu), lead (Pb), manganese (Mn), zinc (Zn) and mercury (Hg) were estimated by inductively coupled plasma-mass spectrometry (ICP-MS) and a mercury analyzer. The concentrations [mean (minimum-maximum) mg/kg] of heavy metals in the ocean fishes were as follows: As=2.523 (0.140-65.543), Cd=0.017 (0.000-0.108), Cu=0.569 (0.040-5.634), Pb=0.023 (0.000-0.323), Hg=0.068 (0.002-0.754), Mn=0.395 (0.016-4.651) and Zn=6.086 (0.529-34.729). The concentrations of heavy metals in the freshwater fishes were: As=0.370 (0.024-2.231), Cd=0.01l (ND-0.086), Cu=0.628 (0.003-1.962), Pb=0.026 (ND-0.423), Hg=0.058 (0.006-0.349), Mn=1.150 (0.069-7.230) and Zn=9.980 (3.463-82.737). The weekly intakes of Cd, Hg and Pb from fish were 0.9, 1.6 and 0.9%, respectively, as compared with the Provisional Tolerable Weekly Intake (PTWl) established by Joint FAO/WHO Expert Committee for food safety evaluation.

Injury Responses of Woody Landscape Plants to Air Pollutants(I) -Sulfur and Heavy Metal Content- (조경수목(造景樹木)의 대기오염물질(大氣汚染物質)에 대한 피해반응(被害反應)(I) -엽내유황(葉內硫黃) 및 중금속(重金屬) 함량(含量)을 중심으로-)

  • Kim, Myung Hee;Lee, Soo Wook
    • Journal of Korean Society of Forest Science
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    • v.82 no.3
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    • pp.271-282
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    • 1993
  • This study was conducted to investigate the absorbing and/or filtering capacity of woody landscape plants growing in urban and industrial regions of Seoul and Taejon. Korea. Total sulfur content and heavy metal content were analyzed in tree foliage of Pinus densiflora, Pinus koraiensis, Ginkgo biloba. Liriodendron tulipifera, Platanus occidentalis. The total sulfur content in the leaves of woody landscape plants in Seoul and Taejon were remarkably higher than those of the tree leaves in Kwangreung. The total sulfur content of deciduous trees had 2.6 times more than that of coniferous trees. the former had better absorbing capacity of $SO_2$ gas. Especially Ginkgo biloba and Platanus occidentalis were recommanded as absorption trees of $SO_2$ because sulfur content levels of them were the highest among all species and increased until tall coloration. While coniferous trees showed no changes in total sulfur content between four seasons. deciduous trees increased in sulfur during the growing season. Pb content of all species in polluted area were higher than those in unpolluted area. In polluted area, while coniferous trees had higher absorption and accumulation of Pb, deciduous trees had higher absorption of Zn. The content of Pb, Zn and Cu in needle of Pinus koraiensis were more than those of Pinus densiflora, In Pinus koraiensis and Pinus densiflora, heavy metal content in the 2nd year needle were higher than thous in the current year needle. In Pinus densiflora, Pinus koraiensis Liriodendron tulipifera and Platanus occidentalis there was a positive correlation between total sulfur and heavy metals [(Pb+Zn+Cu)/3] content.

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Effects of Alismatis Rhizoma Pharmacopuncture at BL23 on Cisplatin-Induced Acute Renal Failure in Rats (신수(BL23) 택사약침이 Cisplatin으로 유발된 급성신부전 백서에 미치는 영향)

  • Kim, Myung Sik;Kim, Jae Hong;Youn, Dae Hwan;Jeong, Hyun Woo;Cho, Myoung Rae
    • Korean Journal of Acupuncture
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    • v.36 no.1
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    • pp.63-73
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    • 2019
  • Objectives : This study was designed to investigate the effects of Alismatis Rhizoma (AR) pharmacopuncture at BL23 on acute renal failure induced by cisplatin. Methods : The Sprague-Dawley rats were divided into Normal group (no injection of cisplatin and no treatment), Control group (cisplatin injection without treatment), Acu group (needling at BL23 after cisplatin injection), AR-PA1 group (treated with $0.3571mg/kg/20{\mu}l$ of AR pharmacopuncture at BL23 after cisplatin injection), and AR-PA2 group (treated with $1.7855mg/kg/20{\mu}l$ of AR pharmacopuncture at BL23 after cisplatin injection). Each treatment was given once daily for 8 days. Changes in body weight, kidney weight, tumor necrosis factor-alpha ($TNF-{\alpha}$), interleukin-6 (IL-6), Cu-Zn superoxide dismutase (Cu-Zn SOD), glutathione peroxidase (GPx), serum blood urea nitrogen (serum BUN), and serum creatinine were observed. Results : Body weight was significantly increased in AR-PA1 on $4^{th}$ and $6^{th}$ days and AR-PA2 on $2^{nd}$ day. $TNF-{\alpha}$ was significantly decreased in Acu, AR-PA1 and AR-PA2 groups. Cu-Zn SOD was significantly increased in AR-PA2 group. GPx was significantly increased in AR-PA1 and AR-PA2 groups. But kidney weight, IL-6, serum BUN and serum creatinine were not significantly changed in any groups compared to control group. Conclusions : In acute renal failure induced by cisplatin, AR pharmacopuncture has a mitigating effect on the inflammatory reaction related to the increase of $TNF-{\alpha}$ in the kidney tissue and a protective effect on the oxidative stress of the kidney tissue. However it is unlikely to restore the glomerular function or inhibit the renal swelling.

A Study of material analysis and its experimentation of metamorphosis and its utilities in Copper Alloy plates for contemporary metal craft (현대금속공예용 동합금판의 재료분석과 형질변환 실험 및 응용에 관한 연구)

  • Lim, Ock-Soo
    • Archives of design research
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    • v.17 no.4
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    • pp.241-250
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    • 2004
  • In this research, the copper alloy plates C2200, C5210, C7701, C8113 were selected to make datum and to identify further usage of metal craft experimentation. For its experimentation, the general welding and TIG welding methods were researched; for 2nd experimentation, the Reticulation and Electroforming skill's differences in color and temperature were researched. With these methods 3 different kinds of works are introduced for sample studies. For this research, Dr. Lee, Dong-Woo who works in Poongsan Metal Co, supported 4 kinds of copper alloy metals. Which are Commercial bronze (Cu-Zn), Deoxidiged Copper(Cu-Sn-P), Nickel Silver (Cu-Ni-Zn), and White Bronze (Cu-Ni); they were applied partly and wholly by the method of Laminatin, Reticulation, Fusing, and Electroforming skills. In case of C2200, the brass, the A. C. TIG welding method is better under 2mm slight plate; the D.C. TIG welding is better upper 2mm plate; and 250~300$^{\circ}C$ is recommended for remain heat treatment. In case of C5210, not having Hydrogen in high temperature return period, doesn't need Oxygen in high temperature and hardening in comparative high temperature neither, it is good for welding. It contains Sn 2-9% ad P 0.03-0.4% generally; and in accordance with the growth rate of Sn contain amount, the harden temperature boundary become broad. In case of cold moment after welding, they are recommended that higher speed TIG welding, smaller melting site and less than 200$^{\circ}C$ for pre-heating temperature. In case of C7701, the 10-20% Ni, 15-30% Zn are widely used.. If it is upper 30% Zn, it become (${\alpha}+{\beta}$) system and adhesive power rate become lower, and the productivity become lower in low temperature but the productivity become higher in high temperature. Nickel Silver's resistance of electricity is well; and the heatproof and incorrodibility is good, too. Lastly, in case of C8113, good at persistence in salty and grind; high in strength of high temperature. In case of white brass, contain 10-30% Nickel and hardened in high temperature and become single phrase. For these reason, the crystallization particles easily become large, if the resistance become higher small amount of Pb, P, S separation rate become higher.

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Comparative Assessment of INAA and ICP-MS for the Determination of Trace Elements in Airborne Particulate Matter (대기입자 중 미량원소의 정량을 위한 기기 중성자방사화분석과 유도결합플라즈마 질량분석법의 비교 평가)

  • Lim, Jong-Myoung;Lee, Jin-Hong;Chung, Yong-Sam
    • Journal of Korean Society of Environmental Engineers
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    • v.28 no.10
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    • pp.1038-1045
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    • 2006
  • A series of experiments was conducted to test the compatibilities of two different techniques to determine elemental concentrations by INAA and ICP-MS based on both the NIST SRM 2783(air particulate on filter media) and the field samples for PM10. For NIST SRM the results of INAA were more accurate and precise for all target elements than those of ICP-MS. The comparative data set for PM10 samples collected in an industrial complex area showed that mean of concentration ratio, derived for the two different methods such as C(INNA/ICP-MS), were distinguished from each other: (1) Ba, Cu, K Mg, Na, and Sb: $0.9{\sim}1.1$; (2) Al, Co, Fe, and Mn: $0.8{\sim}1.2$; and (3) Se, Ti, and Zn: >1.3. When the results obtained from both methods were evaluated in terms of regression analysis, paired t-test, and Wilcoxon signed-rank test, the results of many elements determined from PM10 samples(such as Al, Ba, Co, Cu, Fe, K, Mn, Nd, and Sb) exhibited a fairly good agreement between the two methods, despite a wide range of variation.

The Treatment of Heavy Metal-cyanide Complexes Wastewater by $Zn^{+2}/Fe^{+2}$ Ion and Coprecipitation in Practical Plant(I) (아연백법 및 공침공정을 이용한 복합 중금속-시안착염 폐수의 현장처리(I))

  • Lee, Jong-Cheul;Kang, Ik-Joong
    • Journal of Korean Society of Environmental Engineers
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    • v.29 no.12
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    • pp.1381-1389
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    • 2007
  • Wastewater discharged by industrial activities of metal finishing and electroplating units is often contaminated by a variety of toxic or otherwise harmful substances which have a negative effects on the water environment. The treatment method of heavy metal-cyanide complexes wastewater by alkaline chlorination have already well-known($1^{st}$ Oxidation: pH 10, reaction time 30 min, ORP 350 mV, $2^{nd}$ Oxidation: ORP 650 mV). In this case, the efficiency for the removal of ferro/ferri cyanide by this general alkaline chlorination is very high as 99%. But the permissible limit of Korean waste-water discharge couldn't be satisfied. The initial concentration of cyanide was 374 mg/L(the Korean permissible limit of cyanide is 1.0 mg/L max.). So a particular focus was given to the treatment of heavy metal-cyanide complexes wastewater by $Zn^{+2}/Fe^{+2}$ ion and coprecipitation after alkaline chlorination. And we could meet the Korean permissible limit of cyanide(the final concentration of cyanide: 0.30 mg/L) by $Zn^{+2}/Fe^{+2}$ ion and coprecipitation(reaction time: 30 min, pH: 8.0, rpm: 240). The removal of Chromium ion by reduction(pH: 2.0 max, ORP: 250 mV) and the precipitation of metal hydroxide(pH: 9.5) is treated as 99% of removal efficiency. The removal of Copper and Nickel ion has been treated by $Na_2S$ coagulation-flocculation as 99% min of the efficiency(pH: $9.09\sim10.0$, dosage of $Na_2S:0.5\sim3.0$ mol). It is important to note that the removal of ferro/ferri cyanide of heavy metal-cyanide complexes wastewater should be employed by $Zn^{+2}/Fe^{+2}$ ion and coprecipitation as well as the alkaline chlorination for the Korean permissible limit of waste-water discharge.

A Research of Soil Environmental Health in Urban Garden, Gwangju (광주 도시텃밭 토양 환경의 건강성 조사)

  • Jang, Gil-Sik;Kim, Yun-Hee;Choi, Young-Seop;Kim, Seung-Ho;Kim, Jong-Min;Bae, Seok-Jin;Cho, Young-Gwan;Koo, Tae-Hyoung
    • Korean Journal of Environmental Agriculture
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    • v.35 no.2
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    • pp.87-96
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    • 2016
  • BACKGROUND: The objective of this study is to evaluate the soil quality to cultivate crops in urban garden.METHODS AND RESULTS: During the period of six month from March to August 2015, measured eight heavy metals, seven Organic items and Fluorine on seventeen urban sites and thirty-one suburban sites in Gwangju city.METHODS AND RESULTS: The average concentration and range of heavy metal in soil are 0.15 mg/kg(ND-0.6) for Cd, 14.9 mg/kg(1.5-33.3) for Cu, 4.4 mg/kg(0.4-71.8) for As, 0.05 mg/kg(ND-1.366) for Hg, 24.7 mg/kg(13.1-62.7) for Pb, 102.5 mg/kg(49.1-276.4) for Zn and 9.2 mg/kg(ND-90.1) for Ni but Cr6+ is not detected. The average value and range of soil fertility items are 253.5mg/kg(76.6-1766.0) for fluorine, 6.4(4.8-7.7) for pH, 20.3 g/kg(5.0-44.0) for orangic matters, 562.7 mg/kg (28.0-1672.0) for available phosphate, 0.6 cmol+/kg (0.1-2.3) for K, 9.7 cmol+/kg (2.7-22.0) for Ca, 3.0 cmol+/kg (0.9-7.4) for Mg, 1.0 ds/m(0.2-2.9) for conductivity. The concentration of Hg in Suburban area is 0.005 mg/kg lower than 0.134 mg/kg in urban area. Also, the concentration of As, Cd, Ni and Zn is lower than urban area as 32%, 37%, 51%, 71% respectively.CONCLUSION: According to SPI index of soil contamination, 39 sites are first degree and 8 sites are second degree and 1 site(41th) is fourth degree. Pb and Cd are not detected and As is detected tiny amounts in plants grown polluted soil, so heavy metals have not moved to plants.