• Title/Summary/Keyword: Natural hydrogen treatment

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Anodic Performances of Surface-Treated Natural Graphite for Lithium Ion Capacitors

  • Park, Chul Min;Jo, Yong Nam;Park, Jung Woo;Yu, Ji-Sang;Kim, Jeom-Soo;Choi, Jungkyu;Kim, Young-Jun
    • Bulletin of the Korean Chemical Society
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    • v.35 no.9
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    • pp.2630-2634
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    • 2014
  • The surface of natural graphite was modified by the use of hydrogen peroxide and evaluated as an anode material for lithium ion capacitors (LICs). The surface treatment was carried out under various ultrasonic conditions of 200, 300, and 400W, which were applied to a mixture of natural graphite and hydrogen peroxide solution for 1 h. While the bulk structure was maintained, the hexagonal symmetry and physical properties of natural graphite, such as BET surface area, tap density, and particle size, were affected by the surface treatment. FT-IR and XPS measurements confirmed the signature of C=O on the surface of graphite samples after treatment. Both the pristine and surface-treated graphites showed a similar reversible capacity of $370mAhg^{-1}$, and the coulombic efficiency of surface-treated graphite decreased with higher ultrasonic energies (89.1%, 89.0%, and 88.0% for 200, 300, and 400 W) comparing with pristine graphite (89.4%). The capacity retention of LICs was greatly improved with the treated natural graphite. The graphite treated under the ultrasonic energy of 300 W and pristine natural graphite showed capacity retention of 77.5% and 42.9%, implying that the surface treatment was an effective method for the improvement of natural graphite as an anode material for LICs.

Evaluation of Advanced Oxidation Process(AOP) as a Pretreatment Process of Biological Activated Carbon in Drinking Water Treatment (정수처리에서 생물활성탄의 전처리로서 고급산화처리법의 평가)

  • Kim Woo-Hang
    • Journal of Environmental Science International
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    • v.8 no.6
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    • pp.725-730
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    • 1999
  • The advanced oxidation process (AOP) using ozone combined with hydrogen peroxide and ultraviolet treatment were evaluated for biodegradable dissolved organic carbon (EDOC) formation and dissolved organic carbon (DOC) removal. Oxidation treatment were conducted alone or combination with ozone, hydrogen peroxide and ultraviolet processes. Ozone dosage of ozone process was varied from $0.5mg/l{\ell}\cdot}min$ to $5mg/{\ell}{\cdot}min$. Ozone/hydrogen peroxide process was done using $20mg/{\ell}{\cdot}min$ of hydrogen peroxide concentration. Ozone/ultraviolet process was irradiated with $12mW/cm^2$ of density and 254nm. Ozone dosage was varied from $0.5mg/{\ell}{\cdot}min$ to $5mg/{\ell}{\cdot}min$ at the ozone/hydrogen peroxide and ozone/ultraviolet processes too. Contact time of all the process was 20 minutes. Oxidation treatment were performed on microfiltration effluent samples. BDOC formation was reached to an optimum at ozone dosage of $1.5mg/{\ell}{\cdot}min$ in the ozone/hydrogen peroxide process and $1mg/{\ell}{\cdot}min$ in ozone/ultraviolet process, after which BDOC formation was decreased at higher ozone dosages. But BDOC formation was increased with ozone dosages increasing in ozone process. The efficiency of DOC removal was higher AOPs than ozone process. Ozone/ultraviolet proces was the highest for DOC removal efficiency in each process. THMFP. removal efficiency by ozone/ultraviolet process was higher than that by each of ozone process and ozone/hydrogen peroxide process.

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Extracts from the Red Algae Gracilaria vermiculophylla have Antioxidant Effects in Human Bone Marrow Mesenchymal Stem Cells

  • Jeong, Sin-Gu;Lee, Jae-Joon;Kim, Ho-Tae;Ahn, Min-Ji;Son, Hee-Kyoung;Lee, Jun Sik;Oh, Won Keun;Cho, Tae Oh;Cho, Goang-Won
    • Journal of Integrative Natural Science
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    • v.11 no.2
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    • pp.69-75
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    • 2018
  • The red algae Gracilaria vermiculophylla is widely spread around seaside areas across the globe, and has been used as a food resource in Southeast Asian countries. Previous studies have shown that Gracilaria red algae extracts have beneficial antihypercholesterolemic, antioxidant, anti-inflammatory, and antimicrobial effects. In this study, we investigated the antioxidant effects of Gracilaria vermiculophylla extracts (GV-Ex) on human bone marrow mesenchymal stem cells (hBM-MSCs). The acetone and DMSO/ethanol solvents of the tested GV contain higher total flavonoid and polyphenolic contents that can strongly scavenge reactive oxygen species (ROS). Pre-treatment with GV-Ex protected hBM-MSCs against oxidative stress induced by hydrogen peroxide treatment. The protective effects of GV-Ex treatment were confirmed by MTT assay. The elevated levels of ROS in hBM-MSCs caused by hydrogen peroxide induced oxidative stress were significantly decreased by GV extract treatment. The levels of the antioxidant proteins superoxide dismutase 1 (SOD1), superoxide dismutase 2 (SOD2), and catalase (CAT) were also restored or protected by GV-Ex treatment, suggesting that GV extracts moderate excess ROS levels and prevent cells from oxidative damage.

Role of Plant Extracts to Remove Hydrogen Sulfide in the Air-Lifter Reactor (Air-lift 반응기내 황화수소제거시 식물정유추출물의 역할)

  • Park, Jong-Woo;Park, Young-G.;Kim, Jeong-In
    • KSBB Journal
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    • v.25 no.5
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    • pp.421-428
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    • 2010
  • This paper reports on the experimental investigation carried out to evaluate the physical optimal conditions in the absorption column to remove odorous hydrogen sulfide gas. Hydrogen sulfide gas, as a highly undesirable contaminant, is most widely emitted from environmental treatment facilities. The absorbent mixed with natural second metabolites extracted from conifer trees and chemical absorbent of 2-aminoethanol was applied to remove it via chemical neutralization. The absorbent of natural second metabolites was achieved by a removal efficiency of 20-40% by itself depending on the treatment conditions, but the complex absorbent mixed with 0.1% amine chemical provides the removal efficiency of 98%. The optimal removal efficiencies have been examined against the two major parameters of temperature and pH. This study shows that the aqueous solution by natural second metabolites can be used as an appropriate absorbent in the column absorbed for the removal of hydrogen sulfide gas.

Crystallographic and Spectroscopic Characterization of Talc proposed Mineral Carbonation after Heat Treatment (탄산염광물화용 활석의 열처리에 따른 결정학적 분광학적 특성변화)

  • Choi, Weon-Kyung;Cho, Tae-Hwan;Lee, Jae-Keun
    • Transactions of the Korean hydrogen and new energy society
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    • v.17 no.1
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    • pp.109-116
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    • 2006
  • The heat treatment characteristics of natural talc sample was investigated in diverse analytical view point. The mass decrease comes to heat treatment was resulted by the continuous and the discontinuous process and the obtained result show very similar two step profiles with 8.9 % mass decrease. The dehydroxylation of -OH groups contained talc crystal was analyzed by spectroscopic method and the crystallographic variations was also observed after heat treatment. According to XPS result, the magnesium hydroxide($Mg(OH)_2$) of untreated talc powder changed to magnesium oxides(MgO) after heat treatment.

Highly Stabilized Protocrystalline Silicon Multilayer Solar Cells (고 안정화 프로터결정 실리콘 다층막 태양전지)

  • Lim Koeng Su;Kwak Joong Hwan;Kwon Seong Won;Myong Seung Yeop
    • 한국신재생에너지학회:학술대회논문집
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    • 2005.06a
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    • pp.102-108
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    • 2005
  • We have developed highly stabilized (p-i-n)-type protocrystalline silicon (pc-Si:H) multilayer solar cells. To achieve a high conversion efficiency, we applied a double-layer p-type amorphous silicon-carbon alloy $(p-a-Si_{1-x}C_x:H)$ structure to the pc-Si:H multilayer solar cells. The less pronounced initial short wavelength quantum efficiency variation as a function of bias voltage proves that the double $(p-a-Si_{1-x}C_x:H)$ layer structure successfully reduces recombination at the p/i interface. It was found that a natural hydrogen treatment involving an etch of the defective undiluted p-a-SiC:H window layer before the hydrogen-diluted p-a-SiC:H buffer layer deposition and an improvement of the order in the window layer. Thus, we achieved a highly stabilized efficiency of $9.0\%$ without any back reflector.

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Study on the Treatment of Hydrogen Chloride Gas used in Semiconductor Process by using Gas Adsorption Agents such as Zeolite Resins, ZnO, and AgMnO3 (제올라이트 수지 및 ZnO, AgMnO3 등의 무기흡착제를 이용한 반도체 공정에서 사용되는 염산가스의 처리 및 측정에 관한 연구)

  • Park, Jeong-Jun;Lim, H.B.;Hwang, Cheong-Soo
    • Analytical Science and Technology
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    • v.16 no.3
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    • pp.218-225
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    • 2003
  • Hydrogen Chloride is among the most problematic gases used in semiconductor process. It raises serious environmental and health problems due to its extreme toxicity. This study is to develop a method to effectively remove hydrogen chloride gas during the process by using various types of inorganic gas adsorption agents, which have not been attempted in the conventional methods. The removal efficiency of the gas was both qualitatively and quantitatively measured by a FT-IR spectrophotometer. The whole device for the measurement has been designed and built in our lab. The removal efficiencies of hydrogen chloride gas were compared between those tested resins; zeolite A, modified AgA zeolite, ZnO, and $AgMnO_3$. The experimental result revealed that ZnO showed the best efficiency that had removed 0.067 g of HCl per 1 g of the resin used.

Monitoring and Characterization of Bacterial Contamination in a High-Purity Water System Used for Semiconductor Manufacturing

  • Kim, In -Seop;Lee, Geon-Hyoung;Lee, Kye-Joon
    • Journal of Microbiology
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    • v.38 no.2
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    • pp.99-104
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    • 2000
  • Hydrogen peroxide has been used in cleaning the piping of an advanced high-purity water system that supplies ultra-high purity water (UHPW) for 16 megabyte DRAM semiconductor manufacturing. The level of hydrogen peroxide-resistant bacteria in UHPW water was monitored prior to and after disinfecting the piping with hydrogen peroxide. Most of the bacteria isolated after hydrogen peroxide disinfection were highly resistant to hydrogen peroxide. However, the percentage of resistant bacteria decreased with time. The hydrogen peroxide-resistant bacteria were identified as Micrococcus luteus, Bacillus cereus, Alcaligenes latus, Xanthomonas sp. and Flavobacterium indologenes. The susceptibility of the bacteria to hydrogen peroxide was tested as either planktonic cells or attached cells on glass. Attached bacteria as the biofilm on glass exhibited increased hydrogen peroxide resistnace, with the resistance increasing with respect to the age of the biofilm regrowth on piping after hydrogen peroxide treatment. In order to optimize the cleaning strategy for piping of the high-purity water system, the disinfecting effect of hydrogen preoxide and peracetic acid on the bacteria was evaluated. The combined use of hydrogen peroxide and peracetic acid was very effective in killing attached bacteria as well as planktonic bacteria.

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A Study on Emission Reductions of Diesel Engine Using Plasmatron Fuel Converter (플라즈마트론을 이용한 디젤 엔진의 매연저감에 관한 연구)

  • Ki, Ho-Beom;Kim, Bong-Soo;Kwak, Yong-Hwan;Kim, Woo-Hyung;Lim, Won-Kyung;Chae, Jae-Ou
    • 한국연소학회:학술대회논문집
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    • 2006.10a
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    • pp.104-109
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    • 2006
  • Improvements in internal combustion engine and aftertreatment technologies are needed to meet future environmental quality goals. Plasmatron fuel converters provide a rapid response, compact means to transform a wide range of hydrocarbon fuels (including gasoline, natural gas and diesel fuel) into hydrogen-rich gas. Hydrogen-rich gas can be used as an additive to provide NOx reductions of more than 80% in diesel engine vehicles by enabling very lean operation or heavy exhaust engine recirculation. For diesel engines, use of compact plasmatron reformers to produce hydrogen-rich gas for the regeneration of NOx absorber/absorbers and particulate traps for diesel engine exhaust after-treatment could provide significant advantages. Recent tests of conversion of diesel fuel to hydrogen-rich gas using a low current plasmatron fuel converter with non-equilibrium plasma features are described.

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Odor Reduction Technology in Sewage Treatment Facility Using Biofilter with Reed Grass(Phragmites australls) (갈대(Phragmites australls)수초를 적용한 바이오필터에서의 하수처리시설 악취저감기술)

  • Chung, Jin-Do;Kim, Kyu-Yeol
    • Journal of Korean Society of Water and Wastewater
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    • v.27 no.3
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    • pp.373-382
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    • 2013
  • In this study, a biological odor treatment system was proposed to remove odor(foul smell) materials causing several problems in the closed sewage treatment plant. This odor treatment system was composed of a two-step biofilter system in one reactor. The two-step biofilter reactor was constructed with natural purification layer in upper part and artificial purification layer in lower part. The reed grasses of water purification plants were planted in the surface area and mixed porous ceramic media were filled with the lower part of biofilter reactor. By using the above experimental apparatus, the ammonia gas removal efficiency was attained to 98.3 % and the hydrogen sulfide gas removal efficiency was appeared more than 97.7 % which shows more effective than the conventional odor removal process.