• 한국신재생에너지학회:학술대회논문집
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• 2007.06a
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• pp.24-27
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• 2007

한국에너지기술연구원에서는 가정용 고분자연료전지 열병합 발전시스템을 위한 통합형 천연가스 연료처리 시스템을 개발해 왔다. 본 고에서는 연료처리 시스템의 운전 시 모사 연료극 가스 공급이 미치는 영향에 대해 고찰하고, 부하 변동 시 각 단위 공정의 온도 변화와 CO 농도 변화 현상에 대처하기 위한 방법을 제시하고자 한다.

• Proceedings of the Korean Vacuum Society Conference
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• 2010.02a
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• pp.284-284
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• 2010

Currently, hydrogen has been produced by Steam Reforming or partial oxidation reforming processes mainly from oil, coal, and natural gas and results in the production of $CO_2$. However, these are influenced greatly on the green house effect of the earth. so it is important to find the new way to produce hydrogen utilizing water without producing any environmentally harmful by-products. In our research, we use microwave water plasma and photocatalyst to improve dissociation rate of water. At low pressure plasma, electron have high energy but density is low, so temperature of reactor is low. This may cause of recombination in the generated hydrogen and oxygen from splitting water. If it want to high dissociation rate of water, it is necessary to control of recombination of the hydrogen and oxygen using photocatalyst. We utilize the photocatalytic material($TiO_2$, ZnO) coated plasma reactor to use UV in the plasma. The quantity of hydrogen generated was measured by a Residual Gas Analyzer.

• New & Renewable Energy
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• v.3 no.2 s.10
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• pp.31-39
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• 2007

화석연료의 사용으로 인한 자원고갈과 지구온난화 영향 그리고 에너지 안보문제의 해결을 위해 세계 각국들은 대체에너지 개발에 많은 노력을 기울이고 있다. 그 중 수소는 다양한 경로를 통해 생산 가능하고, 수송연료로 사용 시, 유해 물질이 거의 배출되지 않는다는 장점 때문에 가장 주목받는 대체 에너지원이다. 현재는 수소생산 기술개발을 통해 상업화시기를 앞당기려고 하는 수소에너지 시대의 진입시점이라 할 수 있다. 그러나 수소는 생산경로에 따라 다양한 환경성 및 경제성 결과를 도출 할 수 있기 때문에 다양한 평가가 요구된다. 본 연구에서는 국내 수소생산 방식으로 개발/상용화되어있는 Natural Gas Steam Reforming (NGSR), Naphtha Steam Reforming (Naphtha SR), Water Electrolysis (WE)에 대하여, Life Cycle Assessment (LCA)와 Life Cycle Costing Analysis (LCCA) 방법을 사용하여, 수소경로 전반에 대한 즉, 원료채취부터 자동차로 주행하였을 때까지의 각 대상 수소경로의 환경성과 경제성을 평가하였다. LCA와 LCCA 결과는 Naphtha SR과 NGSR 수소경로에서 지구온난화와 화석자원 소모 부문 모두 기존연료 (가솔린, 디젤)와 비교해서 개선효과가 뚜렷하게 나타났으나, WE 수소경로는 오히려 환경부하가 증가되는 것으로 나타났다. 또한 경제성 측면에서는, 수소 판매 시 가솔린과 동일한 연료세율을 부과하더라도 수소가 가솔린에 비해 가격경쟁력을 확보하게 되는데, 이는 주행 시 수소자동차의 연비가 기존 차량에 비해 월등히 좋기 때문에 연료비용의 이점 때문이다. 만약, 수소에 연료세를 부과하지 않는 다면, Naphtha SR로 생산하여 유통한 수소가 수송연료로서 가장 뛰어난 비용효율성을 갖는 것으로 나타났다.

• International Journal of Naval Architecture and Ocean Engineering
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• v.3 no.2
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• pp.141-149
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• 2011

The world is facing a challenge in meeting its needs for energy. Global energy consumption in the last halfcentury has increased very rapidly and is expected to continue to grow over the next 50 years. However, it is expected to see significant differences between the last 50 years and the next. This paper aims at introducing a good solution to replace or work with conventional marine power plants. This includes the use of fuel cell power plant operated with hydrogen produced through water electrolysis or hydrogen produced from natural gas, gasoline, or diesel fuels through steam reforming processes to mitigate air pollution from ships.

• Transactions of the Korean hydrogen and new energy society
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• v.18 no.1
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• pp.95-108
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• 2007

There are several methods for the hydrogen production such as steam reforming of natural gas, photocatalytic method, biological method, electrolysis and thermochemical method, etc. These days it has been widely studying for the hydrogen production method having low hydrogen production cost and high efficiency. In this paper, patents in the hydrogen production by water electrolysis were gathered and analyzed. The search range was limited in the open patents of USA(US), European Union(EP), Japan(JP), and Korea(KR) from 1996 to 2005. Patents were gathered by using key-words searching and filtered by filtering criteria. The trends of the patents was analyzed by the years, countries, companies, and technologies.

• Transactions of the Korean hydrogen and new energy society
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• v.18 no.2
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• pp.197-206
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• 2007

There are several methods for the hydrogen production such as steam reforming of natural gas, photochemical method, biological method, electrolysis and thermochemical method, etc. Many researches have been widely performed for the hydrogen production method having low production cost and high efficiency. In this paper, the patents concerning the photochemical hydrogen production method were gathered and analyzed. The search range was limited in the open patents of USA(US), European Union(EP), Japan(JP), and Korea(KR) from 1996 to 2005. Patents were gathered by using key-words searching and filtered by filtering criteria. The patent application trend was analyzed by the years, countries, companies, and technologies.

• 한국신재생에너지학회:학술대회논문집
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• 2005.06a
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• pp.264-267
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• 2005

수소의 소규모 분산 생산 기술은 본격적 인 수소 인프라가 도입되기 전에 연료전지 자동차의 수소 충 전용이나 분산 발전형 연료전지의 수소 공급을 위해 필요하다. 생산 용량은 수소 기준으로 $10\~100 Nm^3/hr$ 정도로 현재로선 천연가스의 수증기 개질법이 가장 경제적인 공정으로 알려져 있다. 소규모 생산에 따른 열효율 저하를 줄이 기 위해 단위 공정들이 통합된 컴팩트 개질 시스템의 개발이 필요하다. 핵심 기술인 컴팩트 리포머의 국산화 기술 확보를 위하여 $20 Nm^3/hr$용량의 동심관형 리포머를 설계, 제작하였다. 내부구조는 제작의 단순화를 고려하여 중첩된 동심관이 배열되었고 압력 손실과 열웅력 발생을 억제하도록 유로를 배치하였다. 수증기개질 반응에 필요한 반응열은 리포머 본체에 부착된 버너를 이용하여 공급하였다. 성능 측정을 위한 부속 기기로 상온 흡착식 탈황기, 폐열 회수형 수증기 발생기, 반응물 예열을 위한 열교환기, 생성 가스 응축기를 설계 제작하여 전체 리포밍 시스템을 구성하였다. 반응 온도 $680\~720^{\circ}C$, 탄소 대 수중기 비(S/C ratio) $2.7\~3.2$ 조건에서 수증기 개질 반응을 수행하였다. 해당 반응 조건에서 메탄 전환율 $89\%$ 이상, 저위 발열량 기준 개질 열효율 $70\%$ 이상을 달성하였고 개질 생성가스 내 수소의 최대 유량은 $23.4Nm^3/h$였다. 개발된 리포밍 시스템은 고순도 수소 생산이 필요한 경우, 수소 수율 향상을 위한 고온 수성 가스 전화 반응기를 통합 가능하도록 열교환기 구성을 조정할 수 있으며 용융 탄산염 연료전지와 같이 고온형 연료전지의 경우 $550^{\circ}C$ 이상으로 개질 생성 가스를 공급하도록 구성할 수도 있다. 향후 리포머 본체의 개질 효율 향상 및 장치 소형화, 부속 기기의 최적화를 통한 전체 리포밍 시스템 개선, 스케일 업 설계를 위한 엔지니어링 설계 패키지 구성을 계획하고 있다.

• Journal of Energy Engineering
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• v.16 no.4
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• pp.170-180
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• 2007

This paper deals with the economy of scale for domestic on-site hydrogen stations fueled with natural gas and naptha. We evaluate the economic feasibility of on-site hydrogen stations with hydrogen production capacities of $30Nm^3/hr,\;100Nm^3/hr\;and\;300Nm^3/hr$. We build a classical economic feasibility model and we make some sensitivity analyses by changing the values of input factors such as the hydrogen sale price and the discount rate. The estimated hydrogen prices of steam methane reforming stations with production capacities of $30\;Nm^3/hr,\;100\;Nm^3/hr\;and\;300\;Nm^3/hr$ are 18,472 won/kg, 10,689 won/kg and 7,758 won/kg, respectively. Also, the hydrogen prices are about the same if we use naptha as a raw material for hydrogen energy instead of natural gas. It turns out that small and medium size domestic on-site hydrogen stations will not be economical in the near future. This indicates that we need to construct large scale on-site hydrogen fueling stations even for the initial phase of the hydrogen economy.

• Transactions of the Korean hydrogen and new energy society
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• v.17 no.3
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• pp.293-300
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• 2006

KIER has been developing a Ru-based preferential oxidation catalysts and a novel fuel processing system to provide hydrogen rich gas to residential PEMFCs system. The catalytic activity of Ru-based catalysts was investigated at different Ru loading amount and different support structure. The obtained result indicated that 2 wt% loaded Ru-based catalyst supported on ${\alpha}-Al_2O_3$ showed high activity in low temperature range and suppressed the methanation reaction. The developed prototype fuel processor showed thermal efficiency of 78% as a HHV basis with methane conversion of 92%. CO concentration below 10 ppm in the produced gas is achieved with separate preferential oxidation unit under the condition of $[O_2]/[CO]=2.0$. The partial load operation have been carried out to test the performance of fuel processor from 40% to 80% load, showing stable methane conversion and CO concentration below 10 ppm. The durability test for the daily start-stop and 8 h operation procedure is under investigation and shows no deterioration of its performance after 50 start-stop cycles. In addition to the system design and development.

• Applied Chemistry for Engineering
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• v.18 no.4
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• pp.337-343
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• 2007

The reforming catalyst and the electrodes in fuel cells can be poisoned by the organic sulfur compound which is added as an odorant for checking out the leakage of natural gas, and that makes a big problem of system degradation. In this study, various adsorbents, such as silica, ${\gamma}$-alumina, activated carbon, HZSM-5, Ultra-stable Y zeolite (USY), and beta zeolite (BEA), were utilized to remove tetra-hydrothiophene (THT) and tert-butylmercaptan (TBM), and to confirm the performance in the adsorption of those odorants by using a continuous adsorptive bed. The effects of Si/Al ratio of zeolites, adsorption temperature and the type of balance gas (methane or He) on the adsorption performance in the packed bed have been investigated. In addition, the competitive adsorption between TBM and THT on the adsorbents was also estimated. The result shows that H-type BEA zeolite exhibited the highest adsorption capacity for TBM and THT odorant, and the higher amount of THT was removed adsorptively on the same adsorbent than TBM. The physical and chemical adsorption of those compounds on acid sites of zeolite were confirmed by temperature programmed desorption (TPD) and infrared spectrum (IR) analyses.