• Title/Summary/Keyword: Natural filler

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Effects of Silane Concentration on the Silica-Silica Interaction Parameter (αF) of the Silica / Natural Rubber Compound (실란농도가 실리카 / 천연고무 복합소재의 실리카 입자간 상호 관계 계수 (αF)에 미치는 영향의 비교)

  • Kim, Sung-Min;Jang, Mi-Kyeong;Choi, Chang-Yong;Nah, Jae-Woon;Kim, Kwang-Jea
    • Elastomers and Composites
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    • v.47 no.1
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    • pp.23-29
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    • 2012
  • The silica-silica interaction parameter (${\alpha}_F$) of the silane treated silica filled natural rubber (NR) compound was investigated. As silane (TESPT) concentration increased from 2 to 12% (2, 4, 6, 8, 10, 12%), the ${\alpha}_F$ value increased at the same silica concentration (10, 20, 30, and 40 phr). It seemed the sulfur atoms in TESPT acted as a crosslinking agent in the compound. As silica concentration increased from 10 to 40 phr, the ${\alpha}_F$ value increased at the same silane concentration due to increased silica-silica interaction.

Measurements of the Silica-Silica Interaction Parameter (αF) of the Silane treated Silica Filled Natural Rubber Compound (실란처리된 실리카가 천연고무 복합소재 내에서 실리카 입자간 상호 관계 계수(αF)에 미치는 영향의 비교)

  • Kim, Sung-Min;Choi, Chang-Yong;Jang, Mi-Kyeong;Nah, Jae-Woon;Kim, Kwang-Jea
    • Elastomers and Composites
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    • v.47 no.1
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    • pp.18-22
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    • 2012
  • The silica-silica interaction parameter (${\alpha}_F$) of the silane treated silica filled natural rubber (NR) compound was investigated. The measured ${\alpha}_F$ values using mass fraction method following Wolff's theory were compared with volume fraction method. As silica concentration increased, the ${\alpha}_F$ value increased for both methods. The value of ${\alpha}_F$ expressed as volume fraction was higher than that of mass fraction, which resulted in large gaps between ${\alpha}_F$ values. The effect of accelerator (MBT) concentration on ${\alpha}_F$ values was compared.

Crock Resistance Properties of Natural Rubber Compounds for Tank Track Pads (군용 전투차량 궤도 pads용 천연고무 배합물의 내크랙성 향상을 위한 연구)

  • Shin, Jung-Eun;Kim, Yu-Seuk;Bae, Jong-Woo;Kim, Won-Ho
    • Elastomers and Composites
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    • v.33 no.5
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    • pp.335-344
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    • 1998
  • In this study, the tearing energy and the rate of crack propagation of natural rubber (NR) compounds were evaluated to improve the crack resistance of tank-track pads. Although the factors affecting the crack resistance properties of NR compounds are various in this experiment, the effects of filler(carbon black) and the crosslinking system were evaluated. When the amount of accelerator is equal to that of sulfur( eg. efficient vulcanization), the compound shows the most excellent in the aged mechanical properties and the crack resistance properties. The ISAF carbon black(CB) having a good reinforcing characteristics was better than any other CB grades in physical properties and processablity. The optimum content was 50phr.

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Thiazole Type Accelerator Effects on Silane/Silica Filled Natural Rubber Compound upon Vulcanization and Mechanical Properties (Thiazole계 가황촉진제가 실란/실리카 충전 천연고무 컴파운드의 가황 거동 및 기계적 물성에 미치는 영향)

  • Kim, Sung-Min;Kim, Kwang-Jea
    • Polymer(Korea)
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    • v.36 no.2
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    • pp.235-244
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    • 2012
  • A thiazole type accelerator MBT (2-mercapto benzothiazole) was added into silica filled natural rubber (NR) compound with various concentrations (0, 1, 2, 3, 4 phr). The effects of MBT on the cure rate, mechanical property, degree of rubber-filler interaction (${\alpha}_F$), crosslinking density, and viscoelastic property ($tan{\delta}$) were investigated. As accelerator concentration increased, the $t_{s2}$ and $t_{90}$ decreased and the crosslinking density and modulus at 300% elongation increased. The tensile strength and elongation increased up to 3 phr and no further increased at 4 phr. The $tan{\delta}$ value measured at room temperature was higher than that of the $70^{\circ}C$. The ${\alpha}_F$ value was not affected by the addition of MBT. The mechanisms for the vulcanization rate were reviewed.

Engineering Properties of Carbon Fiber and Glass Fiber Reinforced Recycled Polymer Concrete (탄소섬유 및 유리섬유로 보강한 재생 폴리머 콘크리트의 공학적 특성)

  • Noh, Jin Yong;Sung, Chan Yong
    • Journal of The Korean Society of Agricultural Engineers
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    • v.58 no.3
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    • pp.21-27
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    • 2016
  • This study was performed to evaluate engineering properties of carbon and glass fiber reinforced recycled polymer concrete. Fiber reinforced recycled polymer concrete were used recycled aggregate as coarse aggregate, natural aggregate as fine aggregate, $CaCO_3$ as filler, unsaturated polyester resin as binder, and carbon and glass fiber as fibers. The compressive and flexural strength of carbon fiber reinforced recycled polymer concrete were in the range of 68~81.5 MPa and 19.1~21.5 MPa at the curing 7days. Also, the compressive and flexural strength of glass fiber reinforced recycled polymer concrete were in the range of 69.4~85.1 MPa and 19~20.1 MPa at the curing 7days. Abrasion ratio of carbon and glass fiber reinforced recycled polymer concrete were decreased 21.6 % and 11.6 % by fiber content 0.9 %, respectively. After impact resistance test, drop numbers of initial and final fracture were increased with increase of fiber contents. Accordingly, carbon fiber and glass fiber reinforced recycled polymer concrete will greatly improve the hydraulic structures, underground utilities and agricultural structures.

Mechanical Property of Clay-polymer Nanofiber Composite Membrane (Clay를 함유한 Polysulfone 나노섬유 복합막의 제조 및 물리적 특성 연구)

  • Park, Yeji;Yun, Jaehan;Byun, Hongsik
    • Membrane Journal
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    • v.27 no.3
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    • pp.284-289
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    • 2017
  • In this study, natural clay as a filler was systematically integrated into polysulfone nanofibers to prepare polysulfone/clay composite membranes with mechanical properties. The composite nanofibers were formed by electrospinning of a mixed precursor of polysulfone and clay. The pore size of the composite membranes was adjusted by simply controlling the number of layers of nanofibers. The overall membrane properties were examined by SEM, contact angle, pore characteristics, tensile strength and water flux. In particular, the presence of clay within the nanofibers was confirmed with SEM images and the mechanical property of the composite nanofiber membranes was examined by tensile strength measurements. Thus, the prepared composite membranes were expected to be utilized for water treatment system.

Structure and Properties of the Organoclay Filled NR/BR Nanocomposites

  • Kim Won-Ho;Kim Sang-Kwon;Kang Jong-Hyub;Choe Young-Sun;Chang Young-Wook
    • Macromolecular Research
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    • v.14 no.2
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    • pp.187-193
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    • 2006
  • Organoclay, was applied as a filler, in place of carbon black and silica, to a natural rubber (NR)/butadiene rubber (BR) blend. A compounding method was used to disperse and separate the layered silicates. The effect of a coupling agent on the vulcanizates was evaluated using both the silica and organoclay filled compounds. After the compounding processes were completed, the XRD diffraction peaks disappeared, but then reappeared after vulcanization. The scorch times for the organoclay-filled compounds were very short compared to those for carbon black and silica-filled compounds. The organoclay-filled compounds showed high values of tensile strength, modulus, tear energy, and elongation at the break. When ranked by viscosity, the compounds appeared in the following order: silica > silica (Si-69) > organoclay > organoclay (Si-69) > carbon black. Fractional hysteresis, tensile set, and wear rates were very consistent with the viscosity of the vulcanizates. The Si 69 coupling agent increased reversion resistance, the maximum torque values in the ODR, modulus, and wear resistance, but decreased elongation at the break, fractional hysteresis, and tension set of the vulcanizates.

Thermal and Mechanical Properties of Waste Ground Nut-shell Reinforced Polyester Composites

  • Prabhakar, M.N.;Shah, Atta ur rehman;Song, Jung-Il
    • Composites Research
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    • v.28 no.3
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    • pp.118-123
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    • 2015
  • In the current study explain about the bio-based composites made by groundnut shell as reinforcement with polyester resin matrix. Groundnut shell is an abundantly available natural waste byproduct and poly ester resin is widely used to fabricate of composites for good balance of mechanical properties because it is relatively low price and ease of handling. Evaluate the mechanical properties of manufactured groundnut shell/polyester composites by varying the amounts (wt %) of groundnut shell. Particulate shell reinforced polyester composites incorporating varying amounts of groundnut shell (5, 10, 15 and 20%) were characterized for their tensile strength, flexural strength, and impact strength. The mechanical properties improved with increasing particle loading up to 15% and decreased thereafter. Increasing in strength with increased particle shell loading was attributed to increase in surface area which enhanced load transfer between the polyester matrix and ground shall particulates. Scanning electron microscopic studies have been carried out to study the morphology of the composite. Thermal studies and water absorption properties of the composites also studied in this paper.

AN EXPERIMENTAL STUDY ON THE FLOW OF CANAL SEALER BY MEANS OF LENTULO (근관내(根管內) 근관충전제(根管充塡劑)의 유입성(流入性)에 관(關)한 실험적(實驗的) 연구(硏究))

  • Lee, Myong-Chong
    • Restorative Dentistry and Endodontics
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    • v.1 no.1
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    • pp.34-38
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    • 1975
  • Artificial canals were prepared by means of engine reamer on the slab which was made of clear acrylic resin. The shape of this canal is similar to the natural canal, the size is almost same as Kerr File No. 70, and the length is about 20mm. Sealer, Zine oxide eugenol mixture was prepared as matched to spatula test. Lentulo filler was inserted as deep as middle portion and apical one-third portion of the canal and the dental engine was driven in the speed of 1,000 and 3,000 r.p.m. in 30 seconds and 60 seconds with feeding of the sealer. The author measured the excess flow of the canal sealer from Lentulo end. Following are the results obtained from this study. 1. Lentulo insertion at the middle portion 1,000 r.p.m. in 30 seconds case: 0.21mm Same as above in 60 seconds: 0.20mm 2. Lentulo insertion at apical-thirds. 1,000 r.p.m. in 30 seconds: 0.22mm. Same as above in 60 seconds: 0.20mm. 3. Lentulo insertion at middle portion. 3,000 r.p.m. in 30 seconds: 0.14mm Same as above in 60 seconds: 0.25mm. 4. Lentulo insertion at apical-thirds, 3,000 r.p.m. in 30 seconds: 0.11mm Same as above in 60 seconds: 0.27mm.

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Seismic Behavior Characteristics of Stone Pagoda According to Contact Surface Types (접촉면 처리 방식에 따른 석탑의 내진 특성 평가)

  • Kim, Ho-Soo;Kim, Dong-Kwan;Won, Tae-Ho;Jeon, Geon-Woo
    • Journal of Korean Association for Spatial Structures
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    • v.19 no.3
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    • pp.41-50
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    • 2019
  • The stone pagoda continued to be damaged by weathering and corrosion over time, and natural disasters such as earthquake are accelerating the destruction of cultural properties. Stone pagoda has discontinuous structure behavior and is very vulnerable to the seismic load acting in lateral direction. It is necessary to analyze various design variables as the contact surface characteristics play an important role in the dynamic behavior of stone pagodas. For this purpose, contact surface characteristics of stone pagoda can be classified according to surface roughness and filler type, and representative model is selected and structural modeling and analysis are performed using the discrete element method. Also, the seismic load according to the repetition period is calculated and the dynamic analysis is performed considering the discontinuous characteristics of the stone pagoda. Finally, the seismic behavior characteristics can be analyzed by the evaluation of stresses, displacements and structural safety.