• Carbon letters
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• 제13권4호
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• pp.212-220
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• 2012

Orange peel (OP) exhibits a sorption capacity towards anionic dyes such as reactive blue 19 (RB19). Cetyltrimethylammonium bromide (CTAB) as a cationic surfactant was used to modify the surface nature of OP to enhance its adsorption capacity for anionic dyes from an aqueous solution. Four adsorbents were investigated: the OP, sodium hydroxide-treated OP (SOP), CTAB-modified OP and CTAB-modified SOP. The physical and chemical properties of these sorbents were determined using nitrogen adsorption at 77 K and by scanning electron microscope and Fourier transform infrared spectroscopy techniques. The adsorption of the RB19 dye was assessed with these sorbents at different solution pH levels and temperatures. The effect of the contact time was considered to determine the order and rate constants of the adsorption process. The adsorption data were analyzed considering the Freundlich, Langmuir, Elovich and Tempkin models. The adsorption of RB19 by the assessed sorbents is of the chemisorption type following pseudo-first-order kinetics. CTAB modification brought about a significant increase in RB19 adsorption, which was ascribed to the grafting of the sorbent with a cationic surfactant.

• 한국재료학회지
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• 제27권5호
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• pp.255-262
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• 2017

Reactive oxygen species (ROS) can be produced by interactions between sunlight and light-absorbing substances in natural water environments and can completely destroy various organic pollutants in waste water. In this study, we used graphene oxide modified $Ag_2Se$ nanoparticles to enhance photochemically generated oxygen (PGO) species activity. Surface area and pore volumes of the $Ag_2Se-graphene$ ($Ag_2Se-G$) samples showed catastrophic decrease due to deposition of $Ag_2Se$. The generation of reactive oxygen species was detected through the oxidation reaction of DPCI to DPCO. The photocurrent density and the PGO effect increase in the case of the use of modified graphene. The PGO effect of the graphene modified with $Ag_2Se$ composites increased significantly due to a synergetic effect between graphene and the $Ag_2Se$ nanoparticles. The photocatalytic activity of sample was evaluated by measuring the degradation of organic pollutants such as methylene blue (MB) and industrial dyes such as Texbrite BA-L (TBA) under visible light.

• 한국의류학회지
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• 제29권6호
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• pp.745-752
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• 2005

Green tea has various medical effects. It was selected as new natural dyes guessing the effects of the biological activities are still appeared on dyeing. It was examined whether they have the function of Uv-blocker or not. Cotton, linen & Hanji were dyed with Green tea. Al, Cr, Cu, Fe and Sn were selected as the mordant and the UV blocking rate of dyed samples was measured. The results of this study as follows; 1 . The color of dyed samples with Green tea changed yellowish red except Hanji and linen mordanted with Fe. 2. K/S values of dyed samples with Green tea increased by the number of dyeing treatment(p<.01). 3. UVA and UVB blocking rate increased by the number of dyes. Cotton and Linen could block the UV radiation over $93\%$ and Hanji could block over $95\%$ after three times of dyeing. These results suggest that Hanji has possibility far various practical uses of clothing material in beautiful and functional aspect. It could have the biological effects when we put on dyed clothing material with Green tea.

• 펄프종이기술
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• 제43권3호
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• pp.88-97
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• 2011

We carried out cationization of Dak pulp (paper mulberry bast fiber pulp) which is raw material of Hanji (Traditional Korean Paper) using a (3-chloro-2-hydroxypropyl) trimethyl ammonium chloride to improve dyeability during a dyeing of Hanji with Gardenia (Gardenia jasminoides) and smoke tree (Cotinus coggygria). Fiber specific charge densities were determined using polyelectrolyte titration method and K/S values of dyed Hanji was calculated by Kubelka-Munk equation. As the result, fiber specific charge density increased with degree of cationization. Colors of Hanji dyed with Gardenia did not vary significantly with degree of cationization, but cationized Hanji dyed with smoke tree showed a large increase of a* value and reddish yellow color. After-mordanting did not decrease K/S value of dyes with cationized Hanji. K/S values of dyed Hanji decreased with increasing dyeing temperature. For smoke tree, the cationization impair lightfastness of dyed Hanji without mordant. After-mordanting with copper acetate or iron chloride improved lightfastness of dyed Hanji.

• 한국의류산업학회지
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• 제22권1호
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• pp.119-129
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• 2020

Unlike synthetic dyes, natural dyes do not affect the human body or create atmosphere pollution that are also mothproof, antibiotic and sterilized. This study examined the changes in dye adsorption properties according to mordant types and mordanting method to qualify trends using sage and rosemary extracts. Dyeability of sage extract is often similar to rosemary extract regardless of dyeing conditions. Dyeing properties of herb colorants on cotton, silk and wool fiber and effect of dyeing conditions on dye uptake were also compared. Dyed fabric showed a yellowish color and the dyeing affinity was somewhat good with rosemary extract. The surface color of the dyed fabrics was darkened by mordant treatment. The K/S value of herb colorants of protein fiber was higher than cellulose fiber. The concentration of mordant having the highest dyeing affinity was different from the mordant type. Regardless of the type of fiber, the K/S value of premordanting was the highest in mordanting method, and the K/S value of simultaneous mordanting indicated no noticeable mordant effect. The fastness of washing of silk fabric was reduced the most by mordant treatment. The lightfastness was reduced in Al mordant treatment regardless of the type of fiber. The lightfastness of wool increased somewhat by mordant treatment.

• 한국염색가공학회지
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• 제13권1호
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• pp.38-44
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• 2001

The adsorption ability of dyes on chitin, a natural polymer was investigated for decolorization of dye wastewater. Chitin was manufactured in lab by decalcification in dilute aqueous hydrochloric acid solution and deproteination in dilute aqueous sodium hydroxide solution with shrimp shells. Absorbance of residue solution of dyebaths after dye adsorptions of chtin were measured in varieties of dye concentration and dipping periods. Three kinds of Direct dyes -C.I. Direct Red 81 (red 81), C.I. Direct Brown l(brown 1) and C.I. Direct Green 26(green 26) - were used. Red 81 and brown 1 have smaller molecular weight than green 26. The results from experimentals were of]tamed as follows: 1) Adsorption of green 26 was improved in dyebath by addition of salt, but red 81 and brown 1 were not found any improvements. 2) Smaller size of chitin particles could be absorbed much more speedy. In this experiments, the smallest range of chitin particle size was $250\mu{m}$ and less. 3) The most efficient amount of chitin for 20m1 of dyebath was 0.2g, 4) Both of red 81 and brown 1 showed good and speedy adsorption abilities as dyestuffs of over 90 percent in just one minute in dyebath of 0.01% dye concentration. But green 26 was absorbed slowly because of its large molecular weight. It took 40minutes to absorb dyestuffs of over 90 percent in dyebath of 0.01% dye concentration.

• 한국의류학회지
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• 제25권3호
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• pp.617-628
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• 2001

Cotton and silk fabrics dyed with brazilein(Caesalpinia Sappan), berberine (Phellodendron Amurense), and shikonin(Lithospermum Erythrorhizon) were stored in the air, in the water, and under the ground for about one year. The change of the color, the flexibility, and the breaking strength were measured at the intervals of few weeks. The results are as follows; 1. The color of the fabrics changed most extensively in the fabrics that were under the ground, then in the order of the ones that were in the water, and in the air. The color of the fabrics changed to the achromatic color over the time. 2. The flexibility change among the dyes was similar. All the fabrics became stiff under the ground and in the water over the storage time. 3. In general, cotton and silk fabrics dyed with berberine showed better strength retention than the fabrics dyed with other substances. 4. The strength retention of cotton fabrics was high in the order of the fabrics which were in the air, in the water, and under the ground. Only minuscule change occurred in the strength of the cotton fabrics. The strength of the fabrics that were in the water and under the ground decreased remarkably after 30 weeks and 20 weeks respectively. 5. The strength retention of silk fabrics was high in the order of the fabrics which were in the air, under the ground, and in the water. In the air, the strength on silk fabrics decreased rapidly after 30 weeks. In the water, the strength of silk fabrics decreased more rapidly than that of the cotton fabrics. Under the ground, the strength retention of silk was higher than that of cotton.

• 한국의류학회지
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• 제30권1호
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• pp.115-124
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• 2006

Natural dyes are environmentally and human compatible. But they are not various or not fast in color. The mixed dyeing have been attempted to solve these disadventages of natural dyes. The persimmon juice dyed fabrics have brown-color and good hygienic properities however low color fastness. The onion dyeing show similar brown-color and have good color fastness caused by querectin existed in onion outer skins. Mixed dyeing was carryied out on silk fabrics using persimmion juice and onion outer skin extract in this study. The mixing method were persimmon juice dyeing and then onion dyeing(P-O), onion dyeing and then persimmon juice dyeing(O-P) and dyeing in the mixture of persimmon juice and onion outer skin extract simultaneously(P+O). The mordants were none-mordent, gallic acid after-treatment and alum after-treatment. Several persimmon juice dyed fabrics were irradiated for 2 hours before onion dyeing(PU-O). The color values of dyed silk fabrics were as follows. The persimmon juice dyed silk fabric developed to yellow-red color after 2 hours of uv irradiation. Onion dyed fabrics show similar yellow-red color after dyeing without uv irradiation. The effect of alum after-treatment on color difference were highest in onion dyeing. The dyeabilities of both P-O and O-P were higher than persimmom juice dyeing and onion dyeing. The dyeabilities of P+O was lower than persimmom juice dyeing and onion dyeing. The value of color difference of alum-treated fabric was the highest. The color difference of P-O and O-P caused from 2 to 4 hours of uv-irradiation were lower than those of persimmon juice dyed fabrics. Onion skin extract could prevent the color-change of persimmon juice dyed fabrics in mixed dyeing. The color difference of PU-O was higher than the P-O.

• 한국의상디자인학회지
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• 제19권1호
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• pp.135-145
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• 2017

In order to analysis on color difference of yellow natural dyes, I have dyed cellulose and protein fabrics. The results of experiment have been analysed by wavelength of maximum absorption, amounts of dye uptake, color difference, Hunter's value and Munsell's value. The results from these analyses are as follows : Bud of pagoda tree, Amur cork, and Curcuma showed greenish yellow color, Gardenia Jasminoides showed reddish yellow color. Barberry root showed reddish yellow color with post-mordanting method on cellulose fabric. Moreover, Dupioni silk was dyed in reddish yellow color by Barberry root and Rhubarb. In addition to Chroma index, Gardenia Jasminoides and Curcuma showed clear color overall. However, dyeing rayon and silk by Barberry root, and dyeing silk by Rhubarb showed clear color. Comparing all the results to actual dyed materials, Bud of pagoda tree had small dye uptake, and both ${\Delta}a$ and ${\Delta}b$ value were short which can't recognized the yellow color easily. Dye uptake of Amur cork and Gardenia Jasminoides was small just like Bud of pagoda tree. However, ${\Delta}b$ value order was Gardenia Jasminoides>Amur cork>Bud of pagoda tree. Therefore, Gardenia Jasminoides recognized reddish yellow because of big value of red color and yellow color. In case of Barberry root and Rhubarb which have larger dye uptake, Baberry root recognized yellow color on rayon only, and couldn't recognized yellow color on bleached cotton fabric, ramie, silk, and dupioni silk. Rhubarb recognized yellow color on rayon with pre-mordanting method only, but recognized silk and dupioni silk as brown like color. Moreover, we could not analyze color by dye uptake, Lab, and H(v/c) for Barberry root and Rhubarb. As a result, I think we need to attach color table for the research paper which handled the color of dyeing materials.

• 자연과학논문집
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• 제11권1호
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• pp.151-157
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• 1999

승화성이 우수한 분산염료를 사용하여 면포에 대한 열 전사 염색성의 최적조건을 알아보기 위하여 온도, 시간, 농도에 따른 전사 염색에 대하여 연구하였다. 이 최적조건에 따라 팽윤제를 첨가한 후의 열 전사 염색성과 전 처리된 면포의 열 전사 염색성 및 분자량에 따른 열 전사 염색성을 검토하였으며, 세탁견뢰도와 일광견뢰도를 측정하여 열 전사날염에 대한 염색견뢰도를 측정하였다. 분산염료를 사용하여 면포에 대한 열 전사날염의 최적조건은 염료용액의 농도는 5%로, 처리온도가 $200^{\circ}C$, 처리시간은 3분에서 열 전사 염색성이 우수하였다. 면포에 대한 전처리의 시간이 길어질수록 열 전사 염색성이 향상되었으며, 팽윤제로는 Glycerin이 우수하였고, 혼합처리보다는 전처리가 열 전사 염색성이 우수하였다. 분자량에 따른 열 전사 염색성은 혼합처리의 경우 분자량이 작을수록 열 전사 염색성이 향상되었으며, 분자량이 커짐에 따라 열 전사 염색성이 나빠짐을 나타내었다. 그러나 전처리의 경우는 분자량에 큰 영향을 받지 않음을 나타내었다. 열 전사 날염된 면포의 세탁견뢰도는 염료의 분자량이 작은 것이 우수하였고, 일광견뢰도는 염료의 분자량이 큰 것이 보다 우수한 견뢰성을 나타내었다.