• 제목/요약/키워드: Natural $^{15}N$

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농촌유역의 질소 오염원과 기여도 해석을 위한 $\delta^{15}$N 분석(지역환경 \circled1) ($\delta^{15}$N Analysis for Interpretation of Nitrogen pollution Source and Contribution in Agricultural Watersheds)

  • 홍영진;권순국
    • 한국농공학회:학술대회논문집
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    • 한국농공학회 2000년도 학술발표회 발표논문집
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    • pp.513-518
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    • 2000
  • It has been acknowledged that fertilizer, natural soil nitrogen and animal waste, municipal waste have different mass ratio of nitrogen which is presented as a symbol of $\delta^{15}$N. and that the values of $\delta^{15}$N for fertilizer and natural soil nitrogen and animal waste are placed less than +5$\textperthousand$ and higher than +10$\textperthousand$, respectively. thus, Nitrogen pollution sources and contribution can be interpreted in watershed through $\delta^{15}$N analysis and then, analysis is performed with Kjeldhl-Dumas method. In this study, The values of $\delta^{15}$N are between +1.46$\textperthousand$ and +8.97$\textperthousand$, and the nitrate concentration is placed less than 3.31mg/L and higher than 0.19mg/L, respectively. Thus, this watershed is noncontamination area at the present time. But as a result of $\delta^{15}$N, contribution of natural soil nitrogen be discovered in this watershed, presently.

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Identifying N sources that affect N uptake and assimilation in Vanda hybrid using 15N tracers

  • Panjama, Kanokwan;Ohyama, Takuji;Ohtake, Norikuni;Sato, Takashi;Potapohn, Nuttha;Sueyoshi, Kuni;Ruamrungsri, Soraya
    • Horticulture, Environment, and Biotechnology : HEB
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    • 제59권6호
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    • pp.805-813
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    • 2018
  • Vanda is an aerial tropical orchid native to Thailand and nitrogen (N) fertilizer is mainly used to promote its growth and quality. However, little is known about the characteristics of N absorption and assimilation in Vanda. The objective of this study was to determine the appropriate source of N for Vanda cultivation. In this experiment, shoots and roots of Vanda 'Ratchaburi Fuchs-Katsura' were sprayed weekly with 100 ml of $^{15}N$ tracer solution (1) 10 mM of $^{15}NO_3{^-}$, (2) 5 mM of $^{15}NO_3{^-}$ plus 5 mM of $NH_4{^+}$, (3) 5 mM of $NO_3{^-}$ plus 5 mM of $^{15}NH_4{^+}$ and (4) 10 mM of $^{15}NH_4{^+}$. The results indicated that plants fed with a combined N fertilizer gave the highest of $^{15}N$ use efficiency ( $^{15}NUE$) of about 21.8%, 30 days after the first feeding (DAF), compared with those fed sole sources of $^{15}NO_3{^-}$ (21.0%) and $^{15}NH_4{^+}$ (16.6%). However, a sole nitrate fertilizer or combination fertilizer did not significantly affect the total N and labelled N content. Alanine was a major amino acid found in leaves and roots at 7 DAF, whereas glutamine was mainly found in stems. At 30 DAF, tyrosine and alanine became major components in the leaves, and glutamine decreased in stems when plants were fed with a single $^{15}NH_4{^+}$ source.

산업용 질소발생기에 대한 청정소화설비로의 적용가능성에 관한 연구 (A Study on the Possibility of Application as a Natural Extinguishing System for $N_2$ Generator)

  • 서병택;장영근
    • 한국화재소방학회논문지
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    • 제24권2호
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    • pp.139-144
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    • 2010
  • 본 연구에서는 산업용으로 일반적으로 사용하고 있는 질소발생기를 사용하여 할론 계열의 소화약제를 대체할 청정소화설비로 적용할 수 있는지에 대한 소화성능 실험을 간단히 수행하였다. 산업용 질소발생기의 소화성능을 분석하기 위하여 간단한 방호구역을 제작하여 실제 질소발생기에서 발생하는 질소가스를방사하면서 방호구역 내의 산소농도 변화를 실험적으로 파악하였다. 실험결과, 현재 많이 사용하고 있는 질소발생기로 방호구역 $100m^3$에 대하여 질소가스를 $5m^3$/min로 방사하면 3분 이내에 방호구역 내의 산소 농도를 15% 이내로 낮추어 질식소화가 충분히 가능하다.

NMR을 이용한 천연 및 합성 다이아몬드의 특성 분석 연구 (Application of NMR on the Study of Natural and Synthetic Diamonds)

  • 김종랑;손수학;김종근;김정진;장윤득
    • 한국광물학회지
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    • 제20권2호
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    • pp.97-102
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    • 2007
  • 보석질 천연 다이아몬드와 합성 다이아몬드의 $^{15}N$$^{13}C$에 대하여 다양한 스핀 이완 시간과 반복 시간을 적용한 NMR 실험을 수행하였다. $^{13}C$에 대해서는 보석질 천연 다이아몬드는 실험 반복 시간이 30초에서 34.1 ppm의 미약한 신호를 얻었으며 합성 다이아몬드에서는 실험 반복 간격이 0.5초에서부터 34.2 ppm의 신호를 얻었으며 실험 반복 시간이 50초에서는 더 뚜렷한 34.7 ppm의 신호를 얻을 수 있었다. 천연 및 합성 다이아몬드의 극히 낮은 함량에 기인하여 $^{15}N$는 NMR 신호가 감지되지 않았다. 천연 다이아몬드와 합성 다이아몬드의 이완 시간과 불순물의 성분 함량은 서로 밀접한 관련성이 있음을 확인하였으나 $^{13}C$의 NMR 특성의 유사성으로 신호의 강약의 차이를 제외하고는 천연 혹은 합성 여부의 구별은 가능하지 않았다.

Electrocatalytic Reduction of Dioxygen at Glassy Carbon Electrodes with Irreversible Self-assembly of N-hexadecyl-N'-methyl Viologen

  • Lee, Chi-Woo;Jang, Jai-Man
    • Bulletin of the Korean Chemical Society
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    • 제15권7호
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    • pp.563-567
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    • 1994
  • The electroreduction of dioxygen at glassy carbon electrodes with irreversible self-assembly of N-hexadecyl-N'-methyl viologen $(C_{16}VC_1)$ proceeds at potentials more positive than those where the reduction occurs at bare electrodes. The electrocatalyzed reduction takes place at potentials well ahead of those where the catalyst is reduced in the absence of dioxygen and the limiting currents observed at rotating disk electrodes did not deviate from the thoretical Levich line up to 6400 rpm, indicating that the electrocatalysis is extremely rapid. The rate constant for the heterogeneous reaction between $C_{16}V^+C_1$ immobilized on the electrode surface and $O_2$ in solution was estimated to be ca. $10^8\;M^{-1}s^{-1}$. The half-wave potential of dioxygen reduction was independent of solution pH.