• Proceedings of the Korean Vacuum Society Conference
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• 2012.08a
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• pp.441-442
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• 2012

SnNb2O6 nanoplates were prepared by a solvothermal synthesis with water and ethanol mixed solvent. For improvement of their properties, as-prepared SnNb2O6 nanoplates also were calcined. The prepared powder was characterized by X-ray diffraction (XRD), field emission scanning electron microscope (FESEM), Transmission electron microscope (TEM), UV-vis spectroscopy, Raman spectrometer, Brunauer-Emmett-Teller (BET). The calcined nanoplates have a smaller surface area than the as-prepared nanoplates have. Nevertheless, in the case of the optical absorption properties, the calcined nanoplates could absorb more photon energy, due to their smaller band gaps. The Raman analysis revealed that the Nb-O bond length in the calcined nanoplates was longer than that in the as-prepared nanoplate. The higher optical absorption capability of the calcined nanoplates was attributed to the local structure variation within them. Furthermore the high crystallinity of the calcined nanoplates is effective in improving the generation of charge carriers. So, It was found that the calcined nanoplates exhibited superior photocatalytic activity for the evolution of H2 from an aqueous methanol solution than the as-prepared nanoplates under UV and visible irradiation. Therefore, the enhanced photocatalytic activity of the calcined nanoplate powder for H2 evolution was mainly attributed to its high crystallinity and improved optical absorption property resulting from the variation of the crystal structure.

• Structural Engineering and Mechanics
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• v.89 no.6
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• pp.557-570
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• 2024

Due to interfacial ageing, chemical action and interfacial damage, the interface debonding may appear in the interfaces of composite laminates. Particularly, the laminates display a side-dependent effect at small scale. In this work, a three-dimensional (3D) and anisotropic thick nanoplate model is proposed to investigate the effects of imperfect interface and nonlocal parameter on the bending deformation, vibrational response and buckling stability of one-dimensional (1D) hexagonal quasicrystal (QC) layered nanoplates. By combining the linear spring model with the transferring matrix method, exact solutions of phonon and phason displacements, phonon and phason stresses of bending deformation, the natural frequencies of vibration and the critical buckling loads of 1D hexagonal QC layered nanoplates are derived with imperfect interfaces and nonlocal effects. Numerical examples are illustrated to demonstrate the effects of the imperfect interface parameter, aspect ratio, thickness, nonlocal parameter, and stacking sequence on the bending deformation, the vibrational response and the critical buckling load of 1D hexagonal QC layered nanoplate. The results indicate that both the interface debonding and nonlocal effect can reduce the stiffness and stability of layered nanoplates. Increasing thickness of QC coatings can enhance the stability of sandwich nanoplates with the perfect interfaces, while it can reduce first and then enhance the stability of sandwich nanoplates with the imperfect interfaces. The biaxial compression easily results in an instability of the QC layered nanoplates compared to uniaxial compression. QC material is suitable for surface layers in layered structures. The mechanical behavior of QC layered nanoplates can be optimized by imposing imperfect interfaces and controlling the stacking sequence artificially. The present solutions are helpful for the various numerical methods, thin nanoplate theories and the optimal design of QC nano-composites in engineering practice with interfacial debonding.

• Structural Engineering and Mechanics
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• v.64 no.6
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• pp.683-693
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• 2017

According to a generalized nonlocal strain gradient theory (NSGT), dynamic modeling and free vibrational analysis of nanoporous inhomogeneous nanoplates is presented. The present model incorporates two scale coefficients to examine vibration behavior of nanoplates much accurately. Porosity-dependent material properties of the nanoplate are defined via a modified power-law function. The nanoplate is resting on a viscoelastic substrate and is subjected to hygro-thermal environment and in-plane linearly varying mechanical loads. The governing equations and related classical and non-classical boundary conditions are derived based on Hamilton's principle. These equations are solved for hinged nanoplates via Galerkin's method. Obtained results show the importance of hygro-thermal loading, viscoelastic medium, in-plane bending load, gradient index, nonlocal parameter, strain gradient parameter and porosities on vibrational characteristics of size-dependent FG nanoplates.

• Bulletin of the Korean Chemical Society
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• v.34 no.2
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• pp.443-446
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• 2013

In this work, a novel strategy is provided to prepare silver nanoplates by a fibronectin (Fn) nanofibril template. First, Fn molecules were controlled to assemble into amyloid-like nanofibrils in highly concentrated ethanol aqueous solution. The resultant nanofibrils could serve as a soft template to direct the formation of silver nanoplates. It is worth noting that the silver nanoplates are excellent surface-enhanced Raman scattering (SERS) substrate with 4-aminothiophenol (4-ATP) molecule as a test probe. This high active SERS substrate can also be used to detect drug molecule, 2-thiouracil with high sensitivity.

• Applied Science and Convergence Technology
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• v.23 no.1
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• pp.48-53
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• 2014

We have formulated hexagonal-shaped gold nanoplates in a single-step for photothermal therapy that gold ions to gold particles using pyrenyl dextran as reducible stabilizer and template. They exhibit anisotropic structure with broad surface plasmon resonance (SPR) band into near-infrared (NIR) spectrum enabling photothermal therapy. These gold nanoplates are also confirmed biocompatibility and high uptake efficiency due to binding with dextran molecules on the surface of gold nanoplates and cells. From in vitro phtothermal ablation study under NIR laser, gold nanoplates have the potential to use as photothermal agents.

• Smart Structures and Systems
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• v.23 no.3
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• pp.215-225
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• 2019

In the present paper, the nonlocal strain gradient refined model is used to study the thermal stability of sandwich nanoplates integrated with piezoelectric layers for the first time. The influence of Kerr elastic foundation is also studied. The present model incorporates two small-scale coefficients to examine the size-dependent thermal stability response. Elastic properties of nanoplate made of functionally graded materials (FGMs) are supposed to vary through the thickness direction and are estimated employing a modified power-law rule in which the porosity with even type of distribution is approximated. The governing differential equations of embedded sandwich piezoelectric porous nanoplates under hygrothermal loading are derived through Hamilton's principle where the Galerkin method is applied to solve the stability problem of the nanoplates with simply-supported edges. It is indicated that the thermal stability characteristics of the porous nanoplates are obviously influenced by the porosity volume fraction and material variation, nonlocal parameter, strain gradient parameter, geometry of the nanoplate, external voltage, temperature and humidity variations, and elastic foundation parameters.

• Steel and Composite Structures
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• v.47 no.6
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• pp.795-811
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• 2023

When studying the resonance problem of nanoplates, the existing papers do not consider the influences of geometric nonlinearity and initial geometric imperfection, so this paper is to fill this gap. In this paper, based on the nonlocal strain gradient theory (NSGT), the nonlinear resonances of functionally graded (FG) nanoplates with initial geometric imperfection under different boundary conditions are established. In order to consider the small size effect of plates, nonlocal parameters and strain gradient parameters are introduced to expand the assumptions of the first-order shear deformation theory. Subsequently, the equations of motion are derived using the Euler-Lagrange principle and solved with the help of perturbation method. In addition, the effects of initial geometrical imperfection, functionally graded index, strain gradient parameter, nonlocal parameter and porosity on the nonlinear forced vibration behavior of nanoplates under different boundary conditions are discussed.

• Bulletin of the Korean Chemical Society
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• v.35 no.10
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• pp.2935-2940
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• 2014

Monodispersed $Bi_2O_2CO_3$ nanoplates with an average width of 320 nm and thicknesses of 50-90 nm were successfully synthesized by a simple solvothermal method in a mixture solution of polyethylene glycol and $H_2O$. The obtained nanoplates were characterized by means of XRD, FT-IR, SEM and TEM. The effect of surfactant sodium dodecyl benzene sulfonate on the morphology of $Bi_2O_2CO_3$ product was investigated. Under simulated solar light irradiation, $Bi_2O_2CO_3$ nanoplates exhibited superior photocatalytic activities towards the degradation of RhB as well as high chemical stability upon cycling photocatalytic test. The nanoplates also showed promising photodegradation ability for eliminating refractory pollutant of phenol. The excellent photocatalytic performance of $Bi_2O_2CO_3$ nanoplates as compared with P25-$TiO_2$ endows them as promising high efficiency photocatalysts.

• Steel and Composite Structures
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• v.45 no.6
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• pp.839-850
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• 2022

This paper presents an analytical solution to study the combined effect of non-local and stretching effect on the vibration of advanced functionally graded (FG) nanoplates. A new quasi-3D plate theory is presented; there are only five unknowns and any shear correction factor is used. A new displacement field with a new shear warping function is proposed. The equilibrium equations of the FG nanoplates are obtained using the Hamilton principle and solved numerically using the Navier technique. The material properties of functionally graded nanoplates are presumed to change according to the power-law distribution of ceramic and metal constituents. The numerical results of this work are compared with those of other published results to indicate the accuracy and convergence of this theory. Hence, a profound parameterstudy is also performed to show the influence of many parameters of the functionally graded nanoplates on the free vibration responses is investigated.

• Steel and Composite Structures
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• v.52 no.6
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• pp.621-626
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• 2024

The work researched the application of artificial intelligence to the design and analysis of advanced nanoplates, with a particular emphasis on size and surface effects. Employing an integrated theoretical framework, this study developed a more accurate model of complex nanoplate behavior. The following analysis considers nanoplates embedded in a Pasternak viscoelastic fractional foundation and represents the important step in understanding how nanoscale structures may respond under dynamic loads. Surface effects, significant for nanoscale, are included through the Gurtin-Murdoch theory in order to better describe the influence of surface stresses on the overall behavior of nanoplates. In the present analysis, the modified couple stress theory is utilized to capture the size-dependent behavior of nanoplates, while the Kelvin-Voigt model has been incorporated to realistically simulate the structural damping and energy dissipation. This paper will take a holistic approach in using sinusoidal shear deformation theory for the accurate replication of complex interactions within the nano-structure system. Addressing different aspectsof the dynamic behavior by considering the length scale parameter of the material, this work aims at establishing which one of the factors imposes the most influence on the nanostructure response. Besides, the surface stresses that become increasingly critical in nanoscale dimensions are considered in depth. AI algorithms subsequently improve the prediction of the mechanical response by incorporating other phenomena, including surface energy, material inhomogeneity, and size-dependent properties. In these AI- enhanced solutions, the improvement of precision becomes considerable compared to the classical solution methods and hence offers new insights into the mechanical performance of nanoplates when applied in nanotechnology and materials science.