• Title/Summary/Keyword: Nano-tube

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Nitrogen Effect on Vertically Aligned CNT Growth (수직배향 CNT의 성장에 미치는 질소의 영향)

  • 김태영;오규환;정민재;이승철;이광렬
    • Journal of the Korean Vacuum Society
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    • v.12 no.1
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    • pp.70-77
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    • 2003
  • It is well Down that the growth of carbon nanotubes (CNTs) by chemical vapor deposition (CVD) using a transition metal catalyst is greatly enhanced in a nitrogen environment. We show here that the enhanced growth is closely related to the activated nitrogen and it's incorporation into the CNT wall and cap during growth. This behavior is consistent with theoretical calculations of CNx thin films, showing that nitrogen incorporation to the graphitic basal plane reduces the elastic strain energy for curving the graphitic layer. Enhanced CNT growth by nitrogen incorporation is thus due to a decrease in the activation energies required for nucleation and growth of the tubular graphitic layer.

Fabrication of AZ31/CNT Surface Composite by Friction Stir Processing (마찰교반공정에 의한 AZ31/CNT 표면 복합재료 제조)

  • Kim, Jae-Yeon;Lee, Seung-Mi;Hwang, Jung-Woo;Byeon, Jai-Won
    • Journal of the Korean Society for Heat Treatment
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    • v.28 no.6
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    • pp.315-321
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    • 2015
  • Friction stir processing (FSP) was applied to fabricate AZ31/CNT (Carbon Nano Tube) surface composite for improvement of surface hardness of AZ31 Mg-based alloy. The effects of traverse speed of rotating tool and volume fraction of CNT (i.e., groove depth of 3 mm and 4 mm) on the soundness and hardness of the composite layer were investigated. Multi-walled CNTs were fully filled in a machined groove and stirring tool was rotated at the speed of 1400 rpm. Only under the tool traverse speed of 25 mm/min for the specimen with a groove depth of 3 mm, surface composite layer with no defect was successfully produced. Increased hardness of about 35% was observed in the composite layer.

Biological Assay of Mercury and Cadmium Ions Using DNA Immobilized on a Nanotube Paste Electrodes

  • Ly, Suw-Young;Lee, Chang-Hyun;Jung, Hong-Rak;Park, Kwang-Ho;Park, Yong-Keun;Suk, Hong-Woo
    • Journal of the Korean Applied Science and Technology
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    • v.29 no.2
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    • pp.302-310
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    • 2012
  • Bio assay of mercury and cadmium ions were searched using voltammetric analysis using DNA doped carbon nanotube paste electrodes (DCP). The square-wave stripping voltammetryic optimized results indicated working ranges of 1-10.0 $ngL^{-1}$ and 20-100 $ugL^{-1}$, Hg(II) Cd(II) within an accumulation time of 120 seconds, in 0.1-M phosphate buffer solutions of pH 6.3. The relative standard deviations of 5 $ngL^{-1}$ Hg(II) and Cd(II) that observed were 0.14 and 0.22% (n=12), respectively, using optimum conditions. The low detection limit (S/N) was pegged at 0.1 $ngL^{-1}$ ($4.9{\times}10^{-11}M$) Hg(II) and 0.2 $ngL^{-1}$ ($1.77{\times}10^{-10}M$) Cd(II). The developed methods can be applied to assays in biological fish kidneys and water samples.

A gas display device with electron emitter

  • Son, Seung-Hyun;Nam, Mun-Ho;Kim, Jung-Min;Cho, Sung-Hee;Jang, Sang-Hun;Kim, Gi-Young;Han, In-Su;Kim, Dae-Hyun;Cho, Young-Mi;Kim, Chang-Wook;Park, Hyoung-Bin
    • 한국정보디스플레이학회:학술대회논문집
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    • 2007.08b
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    • pp.1253-1256
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    • 2007
  • A display device combining plasma display panel (PDP) and field emission display (FED) is proposed to achieve high luminous efficiency. The device can avoid the main energy loss channels of both PDP (ion loss) and FED (low CL efficiency). $2{\sim}6$”-diagonal test panels with carbon nano-tube (CNT) electron emitter and Xenon ambient gas showed the luminous efficiency of 4.14lm/W and brightness of $263cd/m^2$ at 35V (1kHz, 1% duty), indicating that it is a good candidate for the low voltage driven, highly efficient next generation display.

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Effect of Carbon Support (CNTs) on Pt/Au/TiO2 Catalyst Preparation and Characterization for Direct Methanol Fuel Cell (DMFC) (탄소 담지체(CNTs)에 따른 직접메탄올연료전지용 Pt/Au/TiO2 촉매 제조와 평가)

  • You, Sun-Kyung;Kim, Han-Joo;Kim, Tae-Il;Kang, Kyung-Suk;Park, Soo-Gil
    • Journal of the Korean Electrochemical Society
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    • v.12 no.3
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    • pp.282-286
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    • 2009
  • The synthesis and characterization of catalysts supported on multi-walled carbon nanotubes (CNTs). $Pt/Au/TiO_2$ is added to a CNTs(cabon nano tube) carbon support to improve the performance of a direct methanol fuel cell. XRD and SEM showed that uniform anatase $TiO_2$ and Pt/Au particles were about 200 nm and 20${\sim}$25 nm in diameter. The composite catalyst activities were measured by cyclic voltammetry (CV), demonstrating that it is more promising for use in fuel cells.

Vibration of SWCNTs: Consistency and behavior of polynomial law index with Galerkin's model

  • Khadimallah, Mohamed A.;Hussain, Muzamal;Khedher, Khaled Mohamed;Bouzgarrou, Souhail Mohamed;Al Naim, Abdullah F.;Naeem, Muhammad Nawaz;Taj, Muhammad;Iqbal, Zafar;Tounsi, Abdelouahed
    • Advances in nano research
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    • v.9 no.4
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    • pp.251-261
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    • 2020
  • In this article, vibration attributes of single walled carbon nanotubes based on Galerkin's method have been investigated. The influence of power law index subjected to different end supports has been overtly examined. Application of the Hamilton's variational principal leads to the formation of partial differential equations. The effects of different physical and material parameters on the fundamental frequencies are investigated for armchair and zigzag carbon nanotubes with clamped-clamped, simply supported and clamped-free boundary conditions. By using volume fraction for power law index, the fundamental natural frequency spectra for two forms of Single-Walled Carbon Nanotubes (SWCNTs) are calculated. The influence of frequencies against length-to-diameter ratios with varying power law index are investigated in detail for these tubes. MATLAB software package has been utilized for extracting tube frequency spectra. The obtained results are confirmed by comparing with available literature.

Control of Nanospacing in TiO2 Nanowire Array Using Electron Beam Lithography

  • Yun, Young-Shik;Yeo, Jong-Souk
    • Proceedings of the Korean Vacuum Society Conference
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    • 2014.02a
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    • pp.430.1-430.1
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    • 2014
  • According to advanced nanotechnology in the field of biomedical engineering, many studies of the interaction between topography of surfaces and cellular responses have been focused on nanostructure. In order to investigate this interaction, it is essential to make well-controlled nanostructures. Electron beam lithography (EBL) have been considered the most typical processes to fabricate and control nano-scale patterns. In this work, $TiO_2$ nanowire array was fabricated with hybrid process (top-down and bottom-up processes). Nanodot arrays were patterned on the substrate by EBL process (top-down). In order to control the spacing between nanodots, we optimized the EBL process using Poly(methyl methacrylate) (PMMA) as an electron beam resist. Metal lift-off was used to transfer the spacing-controlled nanodots as a seed pattern of $TiO_2$ nanowire array. Au or Sn nanodots which play an important role for catalyst using Vapor-Liquid-Solid (VLS) method were patterned on the substrate through the lift-off process. Then, the sample was placed in the tube furnace and heated at the synthesis temperature. After heat treatment, $TiO_2$ nanowire array was fabricated from the nanodots through VLS method (bottom-up). These results of spacing-controlled nanowire arrays will be used to study the interaction between nanostructures and cellular responses in our next steps.

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Evaluation of Life Span for Al2O3 Nano Tube Formed by Anodizing with Current Density

  • Lee, Seung-Jun;Kim, Seong-Jong
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2017.05a
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    • pp.148-148
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    • 2017
  • Surface modification is a type of mechanical manipulation skills to achieve extensive aims including corrosion control, exterior appearance, abrasion resistance, electrical insulation and electrical conductivity of substrate materials by generating a protective surface using electrical, physical and chemical treatment on the surface of parts made from metallic materials. Such surface modification includes plating, anodizing, chemical conversion treatment, painting, lining, coating and surface hardening; this study conducted cavitation experiment to assess improvement of durability using anodizing. In order to observe surface characteristics with applied current density, the electrolyte temperature, concentration was maintained at constant condition. To prevent hindrance of stable growth of oxide layer due to local temperature increase during the experiment, stirring was maintained at constant speed. In addition, using galvanostatic method, it was maintained at processing time of 40minutes for 10 to $30mA/cm^2$. The cavitation experiment was carried out with an ultra sonic vibratory apparatus using piezo-electric effect with modified ASTM-G32. The peak-to-peak amplitude was $30{\mu}m$ and the distance between the horn tip and specimen was 1mm. The specimen after the experiment was cleaned in an ultrasonic bath, dried in a vacuum oven for more than 24 hours, and weighed with an electric balance. The surface damage morphology was observed with 3D analysis microscope. As a result of the study, differences were observed surface hardness and anti-cavitation characteristics depending on the development of oxide film with the anodizing process time.

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Mechanical and Magnetic Properties Variation of YBCO Superconductors with Resin and Ag Impregnation (Resin, Ag를 첨가한 YBCO 초전도체의 기계, 자기적 특성 변화)

  • Lee, N.I.;Jang, G.E.;Kim, C.J.;Jung, S.Y.;Han, Y.H.;Sung, T.H.
    • Progress in Superconductivity
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    • v.8 no.1
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    • pp.119-121
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    • 2006
  • We studied the mechanical and magnetic properties of Y-Ba-Cu-O superconductor with and without resin and Ag impregnation. Bulk YBCO superconductor was manufactured with the top-seeded melt-growth method. Typical sample of 40mm X 20mm X 3mm was made and then 8 holes with 0.5mm diameter were drilled arbitrally. Epoxy resin and $AgNO_3$ were systematically added into the holes to compare the mechanical and magnetic properties of YBCO superconductor before and after reinforcement of resin and Ag. Based on the result of 3 point bending, bending strength increased with increasing amounts of resin and carbon nano-tube. However, it was found that the levitation force decreased after making hole, compared with virgin sample without hole.

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Theoretical impact of Kelvin's theory for vibration of double walled carbon nanotubes

  • Hussain, Muzamal;Naeem, Muhammad N.;Asghar, Sehar;Tounsi, Abdelouahed
    • Advances in nano research
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    • v.8 no.4
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    • pp.307-322
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    • 2020
  • In this article, free vibration of double-walled carbon nanotubes (DWNT) based on nonlocal Kelvin's model have been investigated. For this purpose, a nonlocal Kelvin's model is established to observe the small scale effect. The wave propagation is employed to frame the governing equations as eigenvalue system. The influence of nonlocal parameter subjected to different end supports has been overtly examined. The new set of inner and outer tubes radii investigated in detail against aspect ratio. The influence of boundary conditions via nonlocal parameter is shown graphically. Due to small scale effect fundamental frequency ratio decreases as length to diameter ratio increases. Small scale effect becomes negligible on all end supports for the higher values of aspect ratio. With the smaller inner tube radius double-walled CNT behaves more sensitive towards nonlocal parameter. The results generated furnish the evidence regarding applicability of nonlocal model and also verified by earlier published literature.