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Effect of Carbon Support (CNTs) on Pt/Au/TiO2 Catalyst Preparation and Characterization for Direct Methanol Fuel Cell (DMFC)

탄소 담지체(CNTs)에 따른 직접메탄올연료전지용 Pt/Au/TiO2 촉매 제조와 평가

  • Published : 2009.08.28

Abstract

The synthesis and characterization of catalysts supported on multi-walled carbon nanotubes (CNTs). $Pt/Au/TiO_2$ is added to a CNTs(cabon nano tube) carbon support to improve the performance of a direct methanol fuel cell. XRD and SEM showed that uniform anatase $TiO_2$ and Pt/Au particles were about 200 nm and 20${\sim}$25 nm in diameter. The composite catalyst activities were measured by cyclic voltammetry (CV), demonstrating that it is more promising for use in fuel cells.

MWNT(CNTs)를 지지체로 촉매를 합성하고 특성평가를 진행하였다. $Pt/Au/TiO_2$는 CNTs(cabon 나노 튜브) 탄소 지지체에 첨가되어 직접 메탄올 연료 전지의 성능을 개선하였다. XRD와 SEM을 통해 아나타제 $TiO_2$와 Pt/Au를 확인하였고 각각의 입자 사이즈는 200 nm와 20${\sim}$25 nm 이다. 혼성 촉매의 활성은 CV를 통해 측정되었으며 제조된 촉매는 연료전지 이용에 유망하다.

Keywords

References

  1. H. Chang, J. R Kim, J. H Cho, H. K Kim, and K. H Choi - Sokid state Ionics, 148, 601 (2000)
  2. K. Scott, W. M. Taama, and P. Argyropoulos - J. Power Sources, 79, 43 (1999) https://doi.org/10.1016/S0378-7753(98)00198-0
  3. H. Dohle, H. Schmitz, T. Bewer, J. Mergel, and D. Stolten - J. Power Sources, 106, 313 (2002) https://doi.org/10.1016/S0378-7753(01)01064-3
  4. X. Ren, P. Zelenay, S. Thomas, J. Davey, and S. Gottesfeld - J. Power Sources, 86, 111 (2000) https://doi.org/10.1016/S0378-7753(99)00407-3
  5. R. Dillon, S. Srinivasan, A.S. Arico, and V. Antonucci - J. Power Sources, 127, 112 (2004) https://doi.org/10.1016/j.jpowsour.2003.09.032
  6. P. J. Britto, K. S. V. Santhanam, and P. M. Ajayan - Bioelectrochem. Bioenerg, 41, 121 (1996) https://doi.org/10.1016/0302-4598(96)05078-7
  7. E. Pennisi - Sci. News, 142, 36 (1992)
  8. A. V. Ellis, K. Vijayamohanan, R. Goswami, N. Chakrapani, L. S. Ramanathan, P. M. Ajayan, and G. Ramanath - Nano Lett. 3, 279 (2003) https://doi.org/10.1021/nl025824o
  9. Huanqiao Song, Xinping Qiu, Fushen Li - Electrochemical Acta, 53, 3708 (2008) https://doi.org/10.1016/j.electacta.2007.11.080
  10. Dao-Jun Guo, Xin-Ping Qiu, Li-Quan Chen, and Wen- Tao Zhu - Journal of Cabon, 47, 1680 (2009)
  11. Sakae Takenaka, Toshiyuki Iguchi, Eishi Tanabe, Hideki Matsune, Masajiro Kishida - Journal of Cabon, 47, 1251 (2009) https://doi.org/10.1016/j.carbon.2008.12.051
  12. Hyun-Jong Kim, Do-Young Kim, Haksoo Han, and Yong-Gun Shul - Jourmal of Power Source, 159, 484 (2006) https://doi.org/10.1016/j.jpowsour.2005.10.101
  13. Vaithilingam Selvaraj, Mari Vinoba, Muthukaruppan Alagar - Journal of Colloid and Interface Science, 322, 537 (2008) https://doi.org/10.1016/j.jcis.2008.02.069
  14. S. Wang, G. Sun, G.Wang, Z. Zhou, X. Zhao, H. Sun, X. Fan, B.Yi, and Q. Xin, - Electrochemical and Solid State Letters, 8, 1007 (2005)