• Title/Summary/Keyword: Nano-storage

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Electrical Characteristics of Engineered Tunnel Barrier using $SiO_2/HfO_2$ and $Al_2O_3/HfO_2$ stacks ($SiO_2/HfO_2$$Al_2O_3/HfO_2$를 이용한 Engineered Tunnel Barrier의 전기적 특성)

  • Kim, Kwan-Su;Park, Goon-Ho;Yoon, Jong-Won;Jung, Jong-Wan;Cho, Won-Ju
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2008.06a
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    • pp.127-128
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    • 2008
  • The electrical characteristics of VARIOT (variable oxide thickness) with various $HfO_2$ thicknesses on thin $SiO_2$ or $Al_2O_3$ layer were investigated. Especially, the charge trapping characteristics of $HfO_2$ layer were intensively studied. The thin $HfO_2$ layer has small charge trapping characteristics while the thick $HfO_2$ layer has large memory window. Therefore, the $HfO_2$ layer is superior material and can be applied to charge storage as well as tunneling barrier of the non-volatile memory applications.

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Graphene nanosheets encapsulated poorly soluble drugs with an enhanced dissolution rate

  • Shen, Shou-Cang;Ng, Wai Kiong;Letchmanan, Kumaran;Lim, Ron Tau Yee;Tan, Reginald Beng Hee
    • Carbon letters
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    • v.27
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    • pp.18-25
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    • 2018
  • In this study, graphene oxide(GO) was used as drug carriers to amorphize poorly watersoluble drugs via a co-spray drying process. Two poorly water-soluble drugs, fenofibrate and ibuprofen, were investigated. It was found that the drug molecules could be in the graphene nanosheets in amorphous or nano crystalline forms and thus have a significantly enhanced dissolution rate compared with the counterpart crystalline form. In addition, the dissolution of the amorphous drug enwrapped with the graphene oxide was higher than that of the amorphous drug in activated carbon (AC) even though the AC possessed a larger specific surface area than that of the graphene oxide. The amorphous formulations also remained stable under accelerated storage conditions ($40^{\circ}C$ and 75% relative humidity) for a study period of 14 months. Therefore, graphene oxide could be a potential drug carrier and amorphization agent for poorly water-soluble drugs to enhance their bioavailability.

Use of Red Algae Fiber as Reinforcement of Biocomposite (홍조류 섬유를 보강재로 사용한 바이오복합재료의 특성)

  • Lee, Min-Woo;Seo, Yung-Bum;Han, Seong-Ok
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.40 no.1
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    • pp.62-67
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    • 2008
  • Biocomposite was fabricated with biodegradable polymer and natural fiber that has potential to be used as replacement for glass fiber reinforced polymer composite with the benefits of low cost, low density, acceptable specific strength, biodegradability, etc. Until now, mostly natural cellulosic fibers on land have been used as reinforcement for biocomposite. The present study focused on investigating the fabrication and the characterization of biocomposite reinforced with red algae fibers from the sea. The bleached red algae fiber (BRAF) showed very similar crystallinity to the wood cellulose. It has high stability against thermal degradation (maximum thermal decomposition temperature of 359.3$^{\circ}C$) and thermal expansion. Biocomposites reinforced with BRAF have been fabricated by a compression molding method and their mechanical and thermal properties have been studied. The storage modulus and the thermomechanical stability of PBS (polybuthylenesuccinate) matrix are markedly improved by reinforcing with the BRAF. These results indicate that red algae fiber can be used as an excellent reinforcement of biocomposites, which are sometimes called as "green-composites" or "eco-composites".

Preliminary Study on Separation of Germanium and Gallium for Development of a 68Ge/68Ga Generator

  • Lee, Heung Nae;Kim, Sang Wook;Park, Jeong Hoon;Kim, Injong;Yang, Seung Dae;Hur, Min Goo
    • Journal of Radiation Industry
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    • v.5 no.2
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    • pp.101-106
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    • 2011
  • The separation of germanium and gallium ion with metal oxide was introduced into the development of $^{68}Ge/^{68}Ga$ generator. Germanium and gallium within mixed solution were respectively separated by using a liquid-liquid extraction and a column chromatographic method. The separation of Ge within high concentrated hydrochloric and sulfuric acid was conducted by the extraction to $CCl_4$ and the back-extraction to 0.05 M HCl. An optimum condition of the extraction by $CCl_4$ was in 5~7 M HCl and efficiency was around 80%. The gallium was selectively separated by using $Al_2O_3$ among metal oxides as sorbents from the mixed solution in 0.04~0.10 M HCl condition.

Molecular dynamics studies of interaction between hydrogenand carbon nano-carriers

  • Wang, Yun-Che;Wu, Chun-Yi;Chen, Chi;Yang, Ding-Shen
    • Coupled systems mechanics
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    • v.3 no.4
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    • pp.329-344
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    • 2014
  • In this work, quantum molecular dynamics simulations (QMD) are preformed to study the hydrogen molecules in three types of carbon nanostructures, $C_{60}$ fullerene, (5,5) and (9,0) carbon nanotubes and graphene layers. Interactions between hydrogen and the nanostructures is of importance to understand hydrogen storage for the development of hydrogen economy. The QMD method overcomes the difficulties with empirical interatomic potentials to model the interaction among hydrogen and carbon atoms in the confined geometry. In QMD, the interatomic forces are calculated by solving the Schrodinger's equation with the density functional theory (DFT) formulation, and the positions of the atomic nucleus are calculated with the Newton's second law in accordance with the Born-Oppenheimer approximation. It is found that the number of hydrogen atoms that is less than 58 can be stored in the $C_{60}$ fullerene. With larger carbon fullerenes, more hydrogen may be stored. For hydrogen molecules passing though the fullerene, a particular orientation is required to obtain least energy barrier. For carbon nanotubes and graphene, adsorption may adhere hydrogen atoms to carbon atoms. In addition, hydrogen molecules can also be stored inside the nanotubes or between the adjacent layers in graphite, multi-layer graphene.

The therapeutic potential of immune cell-derived exosomes as an alternative to adoptive cell transfer

  • Hong, Yeonsun;Kim, In-San
    • BMB Reports
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    • v.55 no.1
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    • pp.39-47
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    • 2022
  • Adoptive cell transfer (ACT), a form of cell-based immunotherapy that eliminates cancer by restoring and strengthening the body's immune system, has revolutionized cancer treatment. ACT entails intravenous transfer of either tumor-resident or peripheral blood-modified immune cells into cancer patients to mediate anti-tumor response. Although these immune cells control and eradicate cancer via enhanced cytotoxicity against specific tumor antigens, several side effects have been frequently reported in clinical trials. Recently, exosomes, potential cell-free therapeutics, have emerged as an alternative to cell-based immunotherapies, due to their higher stability under same storage condition, lower risk of GvHD and CRS, and higher resistance to immunosuppressive tumor microenvironment. Exosomes, which are nano-sized lipid vesicles, are secreted by living cells, including immune cells. Exosomes contain proteins, lipids, and nucleic acids, and the functional role of each exosome is determined by the specific cargo derived from parental cells. Exosomes derived from cytotoxic effectors including T cells and NK cells exert anti-tumor effects via proteins such as granzyme B and FasL. In this mini-review, we describe the current understanding of the ACT and immune cell-derived exosomes and discuss the limitations of ACT and the opportunities for immune cell-derived exosomes as immune therapies.

Facile Electrodeposition Technique for the Fabrication of MoP Cathode for Supercapacitor Application

  • Samanta, Prakas;Ghosh, Souvik;Murmu, Naresh Chandra;Lee, Joong Hee;Kuila, Tapas
    • Composites Research
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    • v.34 no.6
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    • pp.345-349
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    • 2021
  • The continued environmental pollution caused by fossil fuel consumption has prompted researchers around the world to develop environmentally friendly energy technologies. Electrochemical energy storage is the significant area of research in this development process, and the research significance of supercapacitors in this field is increasing. Herein, a simple electrodeposition synthetic route was explored to develop the MoP layered cathode material. The layered structure provided a highly ion-accessible surface for smooth and faster ion adsorption/desorption. After Fe was doped into MoP, the morphology of MoP changes and the electrochemical performance was significantly improved. Specific capacitance value of the binder-free FeMoP electrode was found to be 269 F g-1 at 2 A g-1 current density in 6 M aqueous KOH electrolyte. After adding Fe to MoP, an additional redox contribution was observed in the redox conversion from Fe3+ to Fe2+ redox pair, and the charge transfer kinetics of MoP was effectively improved. This research can provide guidance for the development of supercapacitor electrode materials through simple electrodeposition technology.

Preparation and Properties of Shape-Stabilized Phase Change Materials from UHMWPE and Paraffin Wax for Latent Heat Storage (파라핀과 초고분자량 폴리에틸렌으로 구성된 형태안정성 상 전이 물질의 제조 및 특성)

  • Lee, Hyun-Seok;Park, Jae-Hoon;Yim, Jong-Ha;Seo, Hye-Jin;Son, Tae-Won
    • Polymer(Korea)
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    • v.39 no.1
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    • pp.23-32
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    • 2015
  • Phase change materials based on ultra high molecular weight of polyethylene (UHMWPE) blended with paraffin wax (mp $65^{\circ}C$) were studied in this paper. In addition, this paper reviews recent studies on the preparation of shape stabilized phase change materials (SSPCM), such as SSPCM from UHMWPE and paraffin wax (mp $65^{\circ}C$), their basic properties and possible applications to latent heat storage. The preparation method was an absorption method. Also, SSPCM composites were prepared by using a hot press at $200^{\circ}C$ for 10 min. The analysis for the shape ability of SSPCM to improve heat efficiency was measured by FTIR, SEM, DSC, XRD, and ARES. UHMWPE composites with 30 wt% paraffin wax (mp $65^{\circ}C$) demonstrated less deterioration of physical property and effective thermal property compared with other conditions. As a result, these SSPCMs could be used for the heat storage and release materials for various products.

A Study on the Effects of Semi-Gel Electrolyte in Electricity Storage Battery (Semi-Gel 전해액이 전력저장용 배터리에 미치는 영향에 관한 연구)

  • Jeong, Soon-Wook;Ku, Bon-Keun
    • Journal of the Korean Applied Science and Technology
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    • v.29 no.2
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    • pp.193-198
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    • 2012
  • The following results are from the test of semi-gel electrolyte to store energy efficiently and use advanced VRLA batteries by photovoltaic and wind power generation. Semi-Gel electrolyte with Silica 5% became Gel after 1 and half hour. It shows it is the most suitable time that the electrolyte can be absorbed into the separator and active material of plate to be gel. The test also says that semi-gel electrolyte shows the much better performance for low-rate discharge and the liquid electrolyte is good for high-rate discharge because the reaction rate of gel electrolyte is slower than liquid one for high-rate discharge performance. The test with DOD10% and DOD100% says that 5% silica electrolyte shows much better performance for life efficiency than liquid one. Because semi-gel electrolyte increase the efficiency of gas recombination at the chemical reaction of VRLA battery and it makes minimizing the reduction of electrolyte. Using the 5% silica electrolyte in order to improve the stroage efficiency and life performance for photovoltic and wind power generation, it causes improving by 4.8% for DOD100% and 20% for DOD10%.

A Study on Physical Properties of N-Acyl Taurates and its Suitability of Personal Care Cleaner (N-Acyl Taurates의 물성 및 인체세정제의 적합성 연구)

  • Park Ji Na;Bae Jae Hem;Lim Ho
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.30 no.4 s.48
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    • pp.525-532
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    • 2004
  • N-acyl taurates are known as environmental-friendly and non-irritating to skin. In this study, the physicochemical properties of N-acyl taurates, which are amide-type anionic surfactants, were measured and also compared with sulfate-type anionic surfactants that show low biodegradability and are highly irritating to skin. The possibility of replacing the currently existing sulfate-type surfactants by N-acyl taurates was examined. Based on the experimental results, shampoos were formulated with these anionic surfactants and their stability and properties were measured. The possibility of application of amide-type surfactants to personal care cleaner was evaluated. Experimental results show that N-acyl taurates have various favorable aspects in making personal care cleanser: high viscosity, low surface tension, and low CMC values. These properties of N-acyl taurates generate nano-scale particles in emulsion, which is stable due to its high viscosity. This emulsion also has good cleaning ability with small amount of usage due to easy penetration into contaminants. Shampoo with N-methyl oleyl taurate showed high yield point and constant viscosity, and formed stable emulsion with nano- scale uniform particles. These results suggest that N-acyl taurates play an important role in making stable Interior structure in shampoo, and which improves the storage property.