• 제목/요약/키워드: Nano-material

검색결과 2,414건 처리시간 0.027초

열분해와 Hot Injection법을 이용한 CoSb3 나노분말합성 (Thermal Decomposition Synthesis of CoSb3 Nanoparticle by Hot Injection Method)

  • 김민숙;안종필;김경자;박주석;김경훈;김형순
    • 한국세라믹학회지
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    • 제50권6호
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    • pp.476-479
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    • 2013
  • $CoSb_3$ with its high electrical conductivity, Seebeck coefficient and rather low thermal conductivity is quite a promising material for thermoelectric conversion applications. A potentially high figure of merit (ZT) can be achieved by a nanostructure evolution of thermoelectric materials. In this work, $CoSb_3$ nanoparticles were synthesized through a thermal decomposition method in cooperation with a hot injection technique. Nano-sized $CoSb_3$ particles were obtained through the thermal decomposition reaction between the pre-heated cobalt-oleate at $320^{\circ}C$ and the injected antimony oleate with room temperature. The results showed that the particle size was increased with increasing synthesis temperature and the crystallinity of particles was improved with temperature but the decomposition of $CoSb_3$ was observed at $320^{\circ}C$. The $CoSb_3$ particles synthesized at $300^{\circ}C$ showed a high purity and an homogeneous shape with average particle size of 26 nm.

평균입도 30 nm 이하의 산화 팔라듐(PdO) 분체의 분무열분해공정에 의한 제조기술 개발 (Preparation of Nanosized Palladium Oxide Powder with Average Particle Size Below 30 nm by Spray Pyrolysis Process)

  • 김동희;유재근
    • 자원리싸이클링
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    • 제27권2호
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    • pp.32-37
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    • 2018
  • 본 연구는 금속 팔라듐 및 산화 팔라듐의 재활용을 위한 전 단계 연구로 수행되었다. 본 연구에서는 산화 팔라듐(PdO)의 형성을 위한 열역학적 수식들을 확립하였다. 또한 고상의 염화 팔라듐($PdCl_2$)을 염산 용액에 용해시킨 염화 팔라듐 용액을 원료용액으로 사용하였다. 이 원료 용액으로부터 분무열분해 공정에 의하여 평균입도 30 nm 이하의 산화 팔라듐 분체를 제조하였다. XRD 분석 결과 생성된 분체는 오직 PdO 상이었으며 TEM 분석결과 형성된 나노 PdO 입자들은 단결정 상임을 확인하였다. 또한 생성된 PdO 분말의 비표면적은 약 $32m^2/g$이었다.

RF Characteristics of Open Stubs on PES Substrate for Application to Capacitive Matching Components on Flexible MMIC

  • Yun, Young;Jeong, Jang-Hyeon;Kim, Hong-Seung;Jang, Nak-Won
    • Transactions on Electrical and Electronic Materials
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    • 제16권3호
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    • pp.142-145
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    • 2015
  • In this work, open stubs were fabricated on a polyether sulfone (PES) substrate, and their basic radio frequency (RF) characteristics were investigated for application to RF matching components of a flexible monolithic microwave integrated circuit (MMIC). According to the results, an open stub employing coplanar waveguide (OSCPW) on PES exhibited much lower loss than that on silicon substrate. The OSCPW with a length of $500{\mu}m$ on PES showed capacitance values of 0.031 ~ 0.044 pF from 0.5 to 50 GHz. For application to a relatively high-value capacitive matching, an open stub employing a fishbone-type transmission line (OSFTTL) was fabricated on PES, and its characteristics were investigated. The OSFTTL showed much higher capacitance values than the OSCPW due to the high effective permittivity value. Specifically, the OSFTTL on PES showed capacitance values of 0.066 ~ 0.24 pF from 0.5 to 50 GHz, which are higher than those for the open stub on silicon substrate. The above results indicate that the OSCPW and OSFTTL on PES can be effectively used for application to low/high-value capacitive matching components on microwave and millimeter wave flexible MMIC. To the best of the authors' knowledge, this work is the first report of the investigation of RF capacitive matching components on PES substrate.

The Effect of a Sol-gel Formed TiO2 Blocking Layer on the Efficiency of Dye-sensitized Solar Cells

  • Cho, Tae-Yeon;Yoon, Soon-Gil;Sekhon, S.S.;Kang, Man-Gu;Han, Chi-Hwan
    • Bulletin of the Korean Chemical Society
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    • 제32권10호
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    • pp.3629-3633
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    • 2011
  • The effect of a dense $TiO_2$ blocking layer prepared using the sol-gel method on the performance of dye-sensitized solar cells was studied. The blocking layer formed directly on the working electrode, separated it from the electrolyte, and prevented the back transfer of electrons from the electrode to the electrolyte. The dyesensitized solar cells were prepared with a working electrode of fluorine-doped tin oxide glass coated with a blocking layer of dense $TiO_2$, a dye-attached mesoporous $TiO_2$ film, and a nano-gel electrolyte, and a counter electrode of Pt-deposited FTO glass. The gel processing conditions and heat treatment temperature for blocking layer formation affected the morphology and performance of the cells, and their optimal values were determined. The introduction of the blocking layer increased the conversion efficiency of the cell by 7.37% for the cell without a blocking layer to 8.55% for the cell with a dense $TiO_2$ blocking layer, under standard illumination conditions. The short-circuit current density ($J_{sc}$) and open-circuit voltage ($V_{oc}$) also were increased by the addition of a dense $TiO_2$ blocking layer.

고효율 전자파 차폐를 위한 이종금속 코팅 탄소섬유 개발 (Development of Hybrid Metals Coated Carbon Fibers for High-Efficient Electromagnetic Interference Shielding)

  • 문재정;박옥경;이중희
    • Composites Research
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    • 제33권4호
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    • pp.191-197
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    • 2020
  • 본 연구에서는 향상된 내구성을 가진 고효율 전자파차폐용 랜덤배향 시트 소재를 개발하기 위해 구리(Copper: Cu)와 니켈 (Nickel: Ni)이 코팅된 탄소섬유(Carbon fiber: CF)와 같은 하이브리드 소재를 습식공정을 통해 제조 하였다. 제조된 시트 소재는 69.4~93.0 dB의 높은 전자파 차폐효율을 보여주었다. 또한 하이브리드 금속으로 코팅된 Ni-Cu/CFs 시트는 Ni표면의 유효한 부식저항성과 기계적 저항성 때문에 가혹한 화학적/열적 환경하에서 매우 우수한 내구성을 보여주었다. 이와 관련하여 Ni-Cu/CF 시트는 Cu/CF 시트와 비교하여 1.7배 긴 수명을 가지는 것을 확인하였다.

레이저빔을 이용한 솔더범프 적층 공정 (Solder Bump Deposition Using a Laser Beam)

  • 최원석;김재운;김종형;김주한
    • 대한기계학회논문집A
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    • 제36권1호
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    • pp.37-42
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    • 2012
  • LIFT(Laser-Induced-Forward-Transfer) 공정은 선택적으로 마이크로 크기의 물질을 이동시키는데 사용할 수 있는 레이저 공정이다. 본 연구에서 이 공정은 전자부품의 마이크로 시스템 패키징을 위한 솔더볼의 적층을 위해 적용되었다. 레이저 펄스에 의해 국부적으로 녹은 솔더 페이스트는 단단한 기저부분에 이동적층되었다. 솔더 크림층을 지닌 박판유리플레이트가 도우너 필름으로 사용되었고 1070nm 파장의 IR 레이저 펄스를 조사하여 리셉터에 마이크로 솔더를 이동적층하였다. 물질 및 에너지 평형 방정식 등이 솔더 페이스 드롭의 모양과 온도 분포를 분석하기 위해 적용되었다. 실제 실험에서 얻어진 이동적층된 솔더 범프는 30~40 ${\mu}m$ 의 직경과 50 ${\mu}m$ 의 두께를 가진 것으로 측정되었다. 본 공정의 한계 및 적용에 대해서도 논의한다.

DEA를 활용한 R&D 프로젝트의 효율성 비교 : 산업기술사업을 중심으로 (Comparing Efficiencies of R&D Projects Using DEA : Focused on Industrial Technology Program)

  • 김흥규;강원진;배진희
    • 산업경영시스템학회지
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    • 제38권3호
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    • pp.29-38
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    • 2015
  • In this paper, scale efficiencies and relative efficiencies of R&D projects in Industrial Technology Program, sponsored by Ministry of Trade, Industry and Energy, Korea, are calculated and compared. For the process, various DEA (Data Envelopment Analysis) models are adopted as major techniques. For DEA, two stage input oriented models are utilized for calculating the efficiencies. Next, the calculated efficiencies are grouped according to their subprograms (Industrial Material, IT Fusion, Nano Fusion, Energy Resources, and Resources Technology) and recipient types (Public Enterprise, Large Enterprise, Medium Enterprise, Small Enterprise, Lab., Univ., and etc.) respectively. Then various subprograms and recipient types are compared in terms of scale efficiencies (CCR models) and relative efficiencies (BCC models). In addition, the correlation between the 1st stage relative efficiencies and the 2nd stage relative efficiencies is calculated, from which the causal relationship between them can be inferred. Statistical analysis shows that the amount of input, in general, should increase in order to be scale efficient (CCR models) regardless of the subprograms and recipient types, that the 1st and 2nd stage relative efficiencies are different in terms of the programs and recipient types (BCC models), and that there is no significant correlation between the 1st stage relative efficiencies and the 2nd stage relative efficiencies. However, the results should be used only as reference because the goal each and every subprogram has is different and the situation each and every recipient type faces is different. In addition, the causal link between the 1st stage relative efficiencies and the 2nd relative efficiencies is not considered, which, in turn, is the limitation of this paper.

Non-uniform Distribution of Magnetic Fluid in Multistage Magnetic Fluid Seals

  • Zhongzhong, Wang;Decai, Li;Jing, Zhou
    • Journal of Magnetics
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    • 제22권2호
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    • pp.299-305
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    • 2017
  • Magnetic fluid, a new type of magnetic material, is a colloidal liquid constituted of nano-scale ferromagnetic particles suspended in carrier fluid. Magnetic fluid sealing is one of the most successful applications of magnetic fluid. As a new type of seal offering the advantages of no leakage, long life and high reliability, the magnetic fluid seal has been widely utilized under vacuum- and low-pressure-differential conditions. In practical applications, for improved pressure capacity, a multistage sealing structure is always used. However, in engineering applications, a uniform distribution of magnetic fluid under each tooth often cannot be achieved, which problem weakens the overall pressure capacity of the seals. In order to improve the pressure capacity of magnetic fluid seals and broaden their applications, the present study theoretically and experimentally analyzed the degree of non-uniform distribution of multistage magnetic fluid seals. A mathematical model reflecting the relationship between the pressure capacity and the distribution of magnetic fluid under a single tooth was constructed, and a formula showing the relationship between the volume of magnetic fluid and its contact width with the shaft was derived. Furthermore, the relationship of magnetic fluid volume to capacity was analyzed. Thereby, the causes of non-uniform distribution could be verified: injection of magnetic fluid; the assembly of magnetic fluid seals; the change of magnetic fluid silhouette under pressure loading; the magnetic fluid sealing mechanism of pressure transmission, and seal failure. In consideration of these causes, methods to improve the pressure capacity of magnetic fluid seals was devised (and is herein proposed).

고무 복합재료의 압저항 효과 (Rubber Composites with Piezoresistive Effects)

  • 정준호;윤주호;김일;심상은
    • Elastomers and Composites
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    • 제48권1호
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    • pp.76-84
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    • 2013
  • 압저항 효과(piezoresistive effect)는 가해진 외부 압력이나 힘에 의해 전기적 저항이 변하는 것을 말한다. 이러한 압저항 효과는 압력, 진동, 가속 등을 탐지하는 센서에 많이 이용되고 있다. 압저항 효과를 갖는 재료가 많지만 그 중에서도 특히, 전도성 충전제를 첨가한 고무 복합체는 충전제의 종류, 입자 크기, 입자 모양, 입자 종횡비(aspect ratio), 그리고 입자의 양 등을 조절하여 다양한 압력 범위에서의 압저항 효과를 발현할 수 있고, 고무를 기질로 사용함으로써 복합체에 탄성과 유연성을 줄 수 있기 때문에 많은 관심을 받고 있다. 본 논문에서는 압저항 효과의 기본원리 및 다양한 고무 복합체의 압저항 효과에 대해 알아본다.

Comparion of stability in titanium implants with different surface topographies in dogs

  • Kim, Nam-Sook;Vang, Mong-Sook;Yang, Hong-So;Park, Sang-Won;Park, Ha-Ok;Lim, Hyun-Pil
    • The Journal of Advanced Prosthodontics
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    • 제1권1호
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    • pp.47-55
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    • 2009
  • STATEMENT OF PROBLEM. A few of studies which compared and continuously measured the stability of various surface treated implants in the same individual had been performed. PURPOSE. We aim to find the clinical significance of surface treatments by observing the differences in the stabilization stages of implant stability. MATERIAL AND METHODS. Eight different surface topographies of dental implants were especially designed for the present study. Machined surface implants were used as a control group. 4 nano-treated surface implants(20 nm $TiO_2$ coating surface, heat-treated 80 nm $TiO_2$ coating surface, CaP coating surface, heat treated CaP coating surface) and 3 micro-treated surface implants [resorbable blast media(RBM) surface, sandblast and acid-etched(SAE) surface, anodized RBM surface] were used as experiment groups. All 24 implants were placed in 3 adult dogs. $Periotest^{(R)}$ & ISQ values measured for 8 weeks and all animals were sacrificed at 8 weeks after surgery. Then the histological analyses were done. RESULTS. In PTV, all implants were stabilized except 1 failed implants. In ISQ values, The lowest stability was observed at different times for each individual. The ISQ values were showed increased tendency after 5 weeks in every groups. After 4 to 5 weeks, the values were stabilized. There was no statistical correlation between the ISQ values and PTV. In the histological findings, the bone formation was observed to be adequate in general and no differences among the 8 surface treated implants. CONCLUSIONS. In this study, the difference in the stability of the implants was determined not by the differences in the surface treatment but by the individual specificity.