• 제목/요약/키워드: Nano-bentonite

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개질된 벤토나이트가 혼입된 폴리비닐알코올/벤토나이트 나노복합 필름의 제조 및 특성분석 (Preparation and Characterization of Poly(vinyl alcohol)/bentonite Nanocomposites Films with Modified Bentonites)

  • 지병철;양성백;이정언;박재민;한명동;김의주;염정현
    • 한국염색가공학회지
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    • 제33권3호
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    • pp.161-167
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    • 2021
  • Polymer nanocomposite is considered a great alternative to solve the limitations that exist in a simple combination material, as well as to produce multifunctional and high-performance results. In this research, PVA/bentonite nanocomposite films were prepared based on the presence or absence of modification of nano-clay(bentonite) a SUPERGEL® product, modification conditions and content, and the structural variation of the prepared PVA/bentonite nanocomposite films were examined. The effect of variations in the internal structure of the nanocomposite on mechanical and thermal properties was investigated. As a result of evaluating the thermal characteristics of the PVA/bentonite nanocomposite film based on the concentration of the modified bentonite, it was verified that the thermal characteristics and stability were improved because of interaction between the polymer and the modified nano-clay.

벤토나이트를 활용한 산화마그네슘 경화체의 친환경성 및 열저항 특성 (Eco-Friendly and Thermal Conductivity Properties of Magnesium oxide Matrix Utilizing Bentonite)

  • 권오한;임현웅;이동훈;이상수
    • 한국건축시공학회:학술대회논문집
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    • 한국건축시공학회 2016년도 추계 학술논문 발표대회
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    • pp.64-65
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    • 2016
  • This study that prevent cancer using absorbent to inflow Radon gas in the room existing soil and rock is making board to absorb the Radon gas as a fundamental study. So, we use bentonite as a absorbent. So, we use bentonite as a absorbent. Bentonite is a 'clay mineral' composed to montmorillonite of main component that volcanic ash denatured to a clay mineral. Bentonite has fine microparticle of nano level, abundant mineral 66 of kinds, adsorbability, swelling, a positive ion(heavy metal adsorption reaction) as a bentonite's property. Using magnesia cement for oxide of magnesiuma and magnesium chloride as a main binder, we measure Radon gas absorbent efficiency and thermal conductivity.

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Enhancement and optimization of gamma radiation shielding by doped nano HgO into nanoscale bentonite

  • Allam, Elhassan A.;El-Sharkawy, Rehab M.;El-Taher, Atef;Shaaban, E.R.;RedaElsaman, RedaElsaman;Massoud, E. El Sayed;Mahmoud, Mohamed E.
    • Nuclear Engineering and Technology
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    • 제54권6호
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    • pp.2253-2261
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    • 2022
  • In this study, nano-scaled shielding materials were assembled and fabricated by doping different weight percentages of Nano-mercuric oxide (N-HgO) into Nano-Bentonite (N-Bent) based on using (100-x% N-Bent + x% N-HgO, x = 10, 20, 30, and 40 wt %). The fabricated N-HgO/N-Bent nanocomposites were characterized by FT-IR, XRD, and SEM and evaluated to evaluate their shielding properties toward gamma radiation by using four different γ-ray energies form three point sources; 356 keV from 133Ba, 662 keV from 137Cs as well as 1173, and 1332 keV from 60Co. The γ-rays mass attenuation coefficients were plotted as a function of the doped N-HgO concentrations into N-HgO/N-Bent nanocomposites. The computed values of mass attenuation coefficients (µm), effective atomic number (Zeff) and electron density (Nel) by the as-prepared samples were found to increase, while the half value layer (HVL) and mean free path (MFP) were identified to decrease upon increasing the N-HgO contents. It was concluded also that the increase in N-HgO concentration led to a direct increase in the mass attenuation coefficient from 0.10 to 0.17 cm2/g at 356 keV and from 0.08 to 0.09 cm2/g at 662 keV. However, a slight increase was observed in the identified mass attenuation coefficients at (1172 and 1332 keV).

Cultivable Microbial Diversity in Domestic Bentonites and Their Hydrolytic Enzyme Production

  • Seo, Dong-Ho;Cho, Eui-Sang;Hwang, Chi Young;Yoon, Deok Jun;Chun, Jeonghye;Jang, Yujin;Nam, Young-Do;Park, So-Lim;Lim, Seong-Il;Kim, Jae-Hwan;Seo, Myung-Ji
    • 한국미생물·생명공학회지
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    • 제47권1호
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    • pp.125-131
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    • 2019
  • We have isolated and identified 72 bacterial strains from four bentonite samples collected at the mining areas located in Gyeongsangbuk-do, Republic of Korea, and measured their hydrolytic enzyme (${\alpha}$-amylase, protease, and cellulase) activities to identify the isolates with industrial-use potential. Most of the isolates belonged to the Bacillaceae, with minor portions being from the Paenibacillaceae, Micrococcaceae, and Bacillales Family XII at the family level. Of the strains isolated, 33 had extracellular ${\alpha}$-amylase activity, 30 strains produced cellulase, and 35 strains produced protease. Strain MBLB1268, having the highest ${\alpha}$-amylase activity, was identified as Bacillus siamensis ($0.38{\pm}0.06U/ml$). Bacillus tequilensis MBLB1223, isolated from Byi33-b, showed the highest cellulase activity ($0.26{\pm} 0.04U/ml$), whereas Bacillus wiedmannii MBLB1197, isolated from Zdb130-b, exhibited the highest protease activity ($54.99{\pm}0.78U/ml$). These findings show that diverse bacteria of the Bacillaceae family adhere to and exist in bentonite and are potential sources of industrially useful hydrolytic enzymes.

국산 압축벤토나이트 완충재의 첨가제 혼합을 통한 열전도도 향상 (Increasing of Thermal Conductivity from Mixing of Additive on a Domestic Compacted Bentonite Buffer)

  • 이종표;최희주;최종원;이민수
    • 방사성폐기물학회지
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    • 제11권1호
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    • pp.11-21
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    • 2013
  • 현재 고준위 방사성 폐기물 심층 처분 시스템에서 기본 완충재 물질로서 건조밀도 1.6 g/$cm^3$의 경주산 칼슘 벤토나이트를 사용하고 있으나, 열전도도가 낮은 단점이 있다. 따라서 본 연구에서는 기준 완충재의 열전도율을 0.8 W/mK에서 1.0 W/mK로 향상시키기 위한 목적으로 다양한 첨가제를 다양한 혼합 방법을 통해 배합하고 열전도도를 측정하였다. 첨가제는 CNT(Cabon Nano Tube), Graphite, Alumina, CuO 및 $Fe_2O_3$ 등을 사용하였다. 혼합 방법의 경우, 핸드 믹서기를 통한 건식혼합, 습식 Milling 혼합, 건식 Ball Mill 혼합 등을 실시하였다. Ball Mill 혼합의 경우가 가장 균일하게 혼합되었기 때문에, 값의 편차가 가장 적었고 열전도도 증가율이 가장 좋았다. 지금까지 수행된 시험에서 소량의 고열전도 물질의 첨가로 경주산 칼슘 벤토나이트의 열전도도를 1.0 W/mK 수준으로 용이하게 증가시킬 수 있음을 실험적으로 확인할 수 있었다. 결론적으로, 본 연구에서 제시된 열전도 향상 방법은, 첨가제 혼합이 벤토나이트의 기본 성질인 팽윤압과 수리전도도에 미치는 영향까지 제시된다면, 국내 고준위폐기물 처분장의 개념 설계에 유용하게 활용될 수 있을 것으로 기대된다.

나노사이즈 탄산칼슘이 종이의 물리·광학적 특성에 미치는 영향 (Effects of Nano-sized Calcium Carbonate on Physical and Optical Properties of Paper)

  • 박정윤;이태주;김형진
    • 펄프종이기술
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    • 제46권4호
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    • pp.1-10
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    • 2014
  • In papermaking industry, inorganic fillers are widely used for the purpose of improving opacity, brightness, printability, uniformity and dimensional stability. They are also useful for production costs and energy savings. In the past, inorganic fillers in papermaking industry only focused on micro-scale but recently, new trials on nano-powdered technology are applying. Even nano-powdered fillers are rapidly utilized for improving the optical and surface properties in coating and surface sizing, there still have some problems in wet-end process due to poor dispersibility and retention. In this study, nano-particled calcium carbonate was produced by milling the PCC and its applicability between micro sized and nano sized calcium carbonated was compared in wet-end process, and finally the sheet properties were evaluated. Nano-PCC was not retained in sheet structure without applying retention system, but with retention system nano-powdered PCC was absorbed on fiber surface with expanding the fiber networks. The application of PAM-bentonite system has resulted in high ash retention and bulky structure for copier paper, and good optical properties in brightness and opacity. However, it required to solve the weakness of low tensile property due to interruption of hydrogen bonding by nano fillers.

Isolation and Characterization of Microbial Strains with Hydrolytic Enzyme Profile from Clay Minerals

  • Lee, Sulhee;Cho, Eui-Sang;Nam, Young-Do;Park, So-Lim;Lim, Seong-Il;Seo, Dong-Ho;Kim, Jae-Hwan;Seo, Myung-Ji
    • 한국미생물·생명공학회지
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    • 제48권1호
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    • pp.64-71
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    • 2020
  • A total of 262 bacterial strains were isolated from clay minerals, bentonite and zeolite, in Gyeongsangbukdo, Republic of Korea, and their hydrolytic enzyme activities were analyzed. Most of the isolated strains belonged to Micrococcales and Bacillales order. Of strains, 96 strains produced α-amylase activity, 42 strains showed cellulase activity, 111 strains had pectinase activity, and 70 strains showed protease activity. Among them, 177 isolates exhibited one or more of the hydrolytic enzyme activities and in particular Bacillus cereus MBLB1321, B. albus MBLB1326 and KIGAM017, B. mobilis MBLB1328, MBLB1329 and MBLB1330 showed all of the enzyme activities. These results demonstrate the diversity of functional Bacillus species in clay minerals as vital sources for the discovery of industrially valuable hydrolytic enzymes, which have a great commercial prospect in various bio-industrial applications.

Experimental study on nano silica modified cement base grouting reinforcement materials

  • Zhou, Fei;Sun, Wenbin;Shao, Jianli;Kong, Lingjun;Geng, Xueyu
    • Geomechanics and Engineering
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    • 제20권1호
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    • pp.67-73
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    • 2020
  • With the increasing number of underground projects, the problem of rock-water coupling catastrophe has increasingly become the focus of safety. Grouting reinforcement is gradually applied in subway, tunnel, bridge reinforcement, coal mine floor and other construction projects. At present, cement-based grouting materials are easy to shrink and have low strength after solidification. In order to overcome the special problems of high water pressure and high in-situ stress in deep part and improve the reinforcement effect. In view of the mining conditions of deep surrounding rock, a new type of cement-based reinforcement material was developed. We analyses the principle and main indexes of floor strengthening, and tests and optimizes the indexes and proportions of the two materials through laboratory tests. Then, observes and compares the microstructures of the optimized floor strengthening materials with those of the traditional strengthening materials through scanning electron microscopy. The test results show that 42.5 Portland cement-based grouting reinforcement material has the advantages of slight expansion, anti-dry-shrinkage, high compressive strength and high density when the water-cement ratio is 0.4, the content of bentonite is 4%, and the content of Nano Silica is 2.5%. The reinforcement effect is better than other traditional grouting reinforcement materials.