• Title/Summary/Keyword: Nano-alloy

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Synthesis of Pt/alloy Nanoparticles by Electrical Wire Explosion in Liquid Media and its Characteristics (액중 전기선 폭발 공정을 이용한 Pt/alloy 하이브리드 나노입자의 제조 및 그 특성)

  • Koo, Hye Young;Yun, Jung-Yeul;Yang, Sangsun;Lee, Hye-Moon
    • Particle and aerosol research
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    • v.8 no.2
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    • pp.83-88
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    • 2012
  • The electrical wire explosion process in liquid media is promising for nano-sized metal and/or alloy particles. The hybrid Pt/Fe-Cr-Al and Pt/Ni-Cr-Fe nanoparticles for exhaust emission control system are synthesized by electrical wire explosion process in liquid media. The alloy powders have spherical shape and nanometer size. According to the wire component, while Pt/Fe-Cr-Al nanoparticles are shown the well dispersed Pt on the Fe-Cr-Al core particle, Pt/Ni-Cr-Fe nanoparticles are shown the partially separated Pt on the Ni-Cr-Fe core particle. Morphologies and component of two kinds of hybrid nano catalyst particles were characterized by transmission electron microscope and energy dispersive X-ray spectroscopy analysis.

Electrochemical Characteristics of HA Film on the Ti Alloy Using Pulsed Laser Deposition

  • Jeong, Yong-Hoon;Shin, Seung-Pyo;Chung, Chae-Heon;Kim, Sang-Sub;Choe, Han-Cheol
    • Korean Journal of Metals and Materials
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    • v.50 no.5
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    • pp.395-400
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    • 2012
  • In this study, we have investigated the surface morphology of hydroxyapatite (HA) coated Ti alloy surface using pulsed laser plating. The HA (tooth ash) films were grown by pulsed KrF excimer laser, film surfaces were analyzed for topology, chemical composition, crystal structure and electrochemical behavior. The Ti-6Al-4V alloy showed ${\alpha}$ and ${\beta}$ phase, Cp-Ti showed ${\alpha}$ phase and the HA coated surface showed HA and Ti alloy peaks. The HA coating layer was formed with $1-2{\mu}m$ droplets and grain-like particles, particles which were smaller than the HA target particle, and the composition of the HA coatings were composed of Ca and P. From the electrochemical test, the pitting potential (1580 mV) of HA coated Ti-6Al-4V alloy was higher than those of Cp-Ti (1060 mV) and HA coated Cp-Ti (1350 mV). The HA coated samples showed a lower current density than non-HA coated samples, whereas, the polarization resistance of HA coated samples showed a high value compared to non-HA coated samples.

Comparison of HVOF Thermal Spray Coatings of T800 and WC-Co Powders

  • Cho, T.Y.;Yoon, J.H.;Kim, K.S.;Baek, N.K.;Song, K.O.;Youn, S.J.;Hwang, S.Y.;Chun, H.G.
    • Journal of Surface Science and Engineering
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    • v.39 no.6
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    • pp.295-301
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    • 2006
  • Hard chrome plating has been used in surface hard coating over 50 years both for applying hard coating and re-building of worn components. Hard chrome plating solution and mist pollute environment with very toxic $Cr^{6+}$(hex-Cr) known as carcinogen which causes lung cancer, High velocity oxy-fuel (HVOF) thermal spray coatings of WC base cermet and Co-alloy powders are the most promising candidates for the replacement of the traditional hard chrome plating. Surface properties, wear, and friction behaviors of micron size Co-alloy (T800) and micron size WC-l2Co (WC-Co) have been studied for the application as hard coatings. The temperature dependence of wear and friction behaviors of T800 and WC-Co have been investigated at the temperature of $25^{\circ}C$ and $538^{\circ}C$ for the application to high speed spindle.

Electrochemical Behavior of AZ31 Mg Alloy in Neutral Aqueous Solutions Containing Various Anions

  • Duyoung Kwon;Hien Van Pham;Pungkeun Song;Sungmo Moon
    • Journal of Electrochemical Science and Technology
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    • v.14 no.4
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    • pp.311-319
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    • 2023
  • This work was performed to characterize the electrochemical behavior of AZ31 Mg alloy in neutral aqueous solutions where Cl-, SO42-, PO43-, and F- ions were present and pH was adjusted to 6 to exclude the contribution of H+ and OH- ions. Open-circuit potential (OCP) transient, electrochemical impedance spectroscopy (EIS) and potnetiodynamic polarization curves were employed. The OCP value appeared to decrease in the order of F- > Cl- > SO42- > PO43- ions while corrosion current density increased in the same order. Electrochemical impedance spectroscopy (EIS) data showed two capacitive arcs in all the solutions and one more inductive arc appeared in PO43--containing solution. By fitting of two capacitive arcs, capacitance of dense film (Cdf), resistance of porous film (Rpf) and double layer capacitance (Cdl) and charge transfer resistance (Rct) beneath the porous films were obtained. A simplified model in which various thicknesses and coverages of dense and porous films are assumed to be present on the AZ31 Mg alloy surface, is suggested to explain the effects of four different anions on the electrochemical behavior of AZ31 Mg alloy.

Investigation on Age-hardening characteristic of thixo and rheocast by using Nano/Micro-probe Technology (나노/마이크로 프로브 기술을 통한 틱소/레오 캐스트의 시효경화 특성 조사)

  • Cho, S.H.;Lee, C.S.;Kang, C.G.
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2006.05a
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    • pp.322-325
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    • 2006
  • The nano/microstructure and mechanical properties of the eutectic regions in thixo and rheo cast A356 alloy parts were investigated using nano/micro-indentation and mechanical scratching, combined with optical microscopy and atomic force microscope (AFM).Most eutectic Si crystals in the A356 alloy showed a modified morphology as fine-fibers, however Si particles of network in eutectic region was formed quickly with aging time increase in thixo-cast. The aging responses of the eutectic regions in both the thixo and rheo cast A356 alloys aged at $150^{\circ}C$ for different times (0, 2, 4, 8, 10, 16, 24, 36, and 72 h) were investigated. Both Vickers hardness ($H_V$) and indentation ($H_{IT}$) test results showed almost the same trend of aging curves, the peak was obtained at the same aging time of 10 h.

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Improving the Thermal Stability of Ni-silicide using Ni-V on Boron Cluster Implanted Source/drain for Nano-scale CMOSFETs (나노급 CMOSFET을 위한 Boron Cluster(B18H22)가 이온 주입된(SOI 및 Bulk)기판에 Ni-V합금을 이용한 Ni-silicide의 열안정성 개선)

  • Li, Shu-Guang;Lee, Won-Jae;Zhang, Ying-Ying;Zhun, Zhong;Jung, Soon-Yen;Lee, Ga-Won;Wang, Jin-Suk;Lee, Hi-Deok
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.20 no.6
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    • pp.487-490
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    • 2007
  • In this paper, the formation and thermal stability characteristics of Ni silicide using Ni-V alloy on Boron cluster ($B_{18}H_{22}$) implanted bulk and SOI substrate were examined in comparison with pure Ni for nano-scale CMOSFET. The Ni silicide using Ni-V alloy on $B_{18}H_{22}$ implanted SOI substrate after high temperature post-silicidation annealing showed the lower sheet resistance, no agglomeration interface image and lower surface roughness than that using pure Ni. The thermal stability of Ni silicide was improved by using Ni-V alloy on $B_{18}H_{22}$ implanted SOI substrate.

Thermal Stability Improvement of Ni-silicide Using Ni-Co alloy for Nano-Scale CMOSFET Technology (나노급 CMOSFET을 윈한 Ni-Co 합금을 이용한 Ni-silicide의 열안정성 개선)

  • Park, Kee-Young;Zhang, Ying-Ying;Jung, Soon-Yen;Li, Shi-Guang;Zhun, Zhong;Lee, Ga-Won;Wang, Jin-Suk;Lee, Hi-Deok
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2007.06a
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    • pp.27-28
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    • 2007
  • In this paper, Ni-Co alloy was used for improvement of thermal stability of Ni silicide. The proposed Ni/Ni-Co structure exhibited wide temperature window of rapid thermal process. Sheet resistance as well as cross-sectional profile showed stable characteristics in spite of high temperature annealing up to $700^{\circ}C$ for 30min. Therefore, the proposed Ni/Ni-Co structure is highly promising for highly thermal immune Ni silicide for nano-scale CMOSFET technology.

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A Study on Deformation Behavior of the Grain-Size Controlled Rheology Material by Using Nanoindenter and AFM (나노인덴터와 원자력간 현미경을 이용한 결정립 제어 레오로지 소재의 변형거동에 관한 연구)

  • 윤성원;김정원;강충길
    • Transactions of Materials Processing
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    • v.13 no.4
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    • pp.374-381
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    • 2004
  • In this study, the deformation behavior of semi-solid Al-Si alloy was investigated by nanoindenter as a part of the research on the surface crack behavior in thixoformed automobile component. The microstructure of semi-solid Al-Si alloy consists of primary and eutectic regions. In eutectic regions the crack initiation begins with initial fracture of the eutectic silicon particles and inside other intermetallic phases. Nano-deformation characteristics in the eutectic and primary phase of semi-solid aluminium alloy were investigated through the nano-indentation experiments and the AFM observation. In addition, mechanical properties of each region were investigated and compared with each other.

Surface Characteristics of HA Coated Dental Implant Alloy by Sol-Gel Method (Sol-Gel법으로 HA코팅된 치과용 임플란트 합금의 표면특성)

  • Choe Han-Cheol;Ko Yeong-Mu
    • Journal of Surface Science and Engineering
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    • v.38 no.4
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    • pp.167-173
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    • 2005
  • Surface characteristics of HA(hydroxyapatite) coated dental implant alloy by Sol-Gel method were investigated using potentiostat, ICP, SEM, EDX, EPMA and surface roughness tester. Surface roughness of HA coated specimen by Sol-Gel showed higher than that of PVD coated specimen. Corrosion resistance increased in the order of $1\%$ lactic acid, artificial saliva, $0.5\%$ HCI and $0.9\%$ NaCl solution. Amount of Ca element release was higher than that of V and P in the $0.5\%$ HCI and $0.9\%$ NaCl solution.