• Title/Summary/Keyword: Nano-Sized Particles

Search Result 361, Processing Time 0.026 seconds

Effect of nano-sized powder addition on the microstructure and superconducting properties of the YBCO thin film. (나노분말 첨가에 따른 YBCO 초전도 박막의 미셀구조 및 초전도 특성변화 연구)

  • Park, Jin-A;Kim, Byung-Joo;Im, Sun-Won;Ahn, Ji-Hyun;Kim, Ho-Jin;Hong, Gye-Won;Lee, Hee-Gyun
    • Proceedings of the KIEE Conference
    • /
    • 2005.07c
    • /
    • pp.1998-2000
    • /
    • 2005
  • The effects of the addition of nanocrystalline Y2O3 powder on the microstructure and superconducting properties have been investigated in YBCO films prepared by TFA-MOD process. Precursor solution doped with extra $Y_2O_3$ Powder was prepared by adding $Y_2O_3$ powder into a stoichiometic precursor solution with a cation ratio of Y:Ba:Cu=1:2:3. Coating solutions with and without $Y_2O_3$ doping were coated on $LaAlO_3(100)$ single crystal by a dip coating method, cacination and conversion heat treatments were performed at the controlled atmosphere containing water vapor Current carry capacity(Jc) of YBCO film was enhanced about 50% by $Y_2O_3$ doping. It is thought that the enhancement of Jc is due to the better connectivity of YBCO grains and/or the flux pinning by the presence of nanocrystalline $Y_2O_3$ Particles embedded in YBCO grains.

  • PDF

Uniform PMMA-CH3NH3PbBr3 Nanoparticle Composite Film for Optoelectronic Application

  • Kirakosyan, Artavazd;Yun, Seokjin;Choi, Jihoon
    • Korean Journal of Materials Research
    • /
    • v.27 no.6
    • /
    • pp.307-311
    • /
    • 2017
  • Organometal halide perovskite materials, due to the tunability of their electronic and optical properties by control of composition and structure, have taken a position of significant importance in optoelectronic applications such as photovoltaic and lighting devices. Despite numerous studies on the structure - property relationship, however, practical application of these materials in electronic and optical devices is still limited by their processability during fabrication. Achieving nano-sized perovskite particles embedded in a polymer matrix with high loading density and outstanding photoluminescence performance is challenging. Here, we demonstrate that the careful control of nanoparticle formation and growth in the presence of poly(methyl methacrylate) results in perovskite nanoparticle - polymer nanocomposites with very good dispersion and photoluminescence. Furthermore, this approach is found to prevent further growth of perovskite nanoparticles, and thus results in a more uniform film, which enables fabrication using the perovskite nanoparticles.

An Experimental Study on the Drying and Curing Characteristics of Conductive metallic ink using Combined IR and Hot Air Type in the Roll-to-Roll System (R2R 공정에서 적외선가열과 열풍을 혼합한 건조방식에서 전도성 금속 잉크의 건조 및 큐어링 공정 특성에 관한 실험적 연구)

  • Kim, Young-Mo;Hong, Seung-Chan;Lee, Jai-Hyo
    • Journal of the Semiconductor & Display Technology
    • /
    • v.9 no.2
    • /
    • pp.73-78
    • /
    • 2010
  • This research is about the drying and curing characteristic of conductivity metallic ink on-line curing device in order to improve the curing time for productivity in RFID Gravure printing. The curing process is carried out to increase the electric conductivity after the metallic ink is printed on the substrate. The metal ink is composed of nano-sized silver or copper particles. In this research, the combined IR and Hot air curing system is used and its results is compared with those of oven, IR and Hot Air type respectively. Generally the curing time in the past is about 3 minutes. But the combined system (IR+Hot Air) in this research shows that curing time is less than 30 seconds. These results is much faster than those of other system. This study can be help to make Roll-to-Roll drying and curing process for mass and continuous production on-line.

Effects of binary conductive additives on electrochemical performance of a sheet-type composite cathode with different weight ratios of LiNi0.6Co0.2Mn0.2O2 in all-solid-state lithium batteries

  • Ann, Jiu;Choi, Sunho;Do, Jiyae;Lim, Seungwoo;Shin, Dongwook
    • Journal of Ceramic Processing Research
    • /
    • v.19 no.5
    • /
    • pp.413-418
    • /
    • 2018
  • All-solid-state lithium batteries (ASSBs) using inorganic sulfide-based solid electrolytes are considered prospective alternatives to existing liquid electrolyte-based batteries owing to benefits such as non-flammability. However, it is difficult to form a favorable solid-solid interface among electrode constituents because all the constituents are solid particles. It is important to form an effective electron conduction network in composite cathode while increasing utilization of active materials and not blocking the lithium ion path, resulting in excellent cell performance. In this study, a mixture of fibrous VGCF and spherical nano-sized Super P was used to improve rate performance by fabricating valid conduction paths in composite cathodes. Then, composite cathodes of ASSBs containing 70% and 80% active materials ($LiNi_{0.6}Co_{0.2}Mn_{0.2}O_2$) were prepared by a solution-based process to achieve uniform dispersion of the electrode components in the slurry. We investigated the influence of binary carbon additives in the cathode of all-solid-state batteries to improve rate performance by constructing an effective electron conduction network.

Formation of Antibacterial Film dried at Room Temperature using nano-sized TiO2 Particle (TiO2 나노 입자를 이용한 상온건조용 항균 코팅)

  • Choi, Young Jin;Kim, Donggyu;Kim, Insoo
    • Korean Journal of Metals and Materials
    • /
    • v.48 no.5
    • /
    • pp.401-409
    • /
    • 2010
  • This study was performed to develop an antibacterial film that can be dried at room temperature. A nanosized TiO$_2$ particle-dispersed solution was prepared by the hydrothermal treatment of peroxo-titanic acid at 160${^{\circ}C}$ for 4h. The binder was synthesized through the hydrolysis and condensation reactions of TEOS (10cc) and GPTS (3.5cc) in the mixture of H$_2$O (30cc) and EtOH (30cc). The synthesized binder was mixed with 0.1 M of TiO$_2$ solution in a volume ratio of binder/TiO$_2$ solution=0.25~0.5. The glass substrate was coated after using the dip coating method, which was then followed by drying for over 2h at room temperature. Although the TiO$_2$ particles did not chemically-bond to the binder, the coating layer strongly adhered to the substrate and displayed good antibacterial properties.

Compaction and Sintering Characteristics of High Energy Ball Milled Mn-Zn Ferrite Powders

  • Lee, Hyunseung;Rhee, Hoseong;Lee, Sangsoo;Chang, Si Young
    • Korean Journal of Materials Research
    • /
    • v.31 no.12
    • /
    • pp.677-681
    • /
    • 2021
  • The Mn-Zn ferrite powders were prepared by high energy ball milling, then compacted and sintered at various temperatures to assess their sintering behavior and magnetic properties. The initial ferrite powders were spherical in shape with the size of approximately 70 ㎛. After 3 h of ball milling at 300 rpm, aggregated powders ~230 nm in size and composed of ~15 nm nanoparticles were formed. The milled powders had a density of ~70 % when compacted at 490 MPa for 3 min. In the samples subsequently sintered at 1,273 K ~ 1,673 K for 3 h, the MnZnFe2O4 phase was detected. The density of the sintered samples had a tendency to increase with increasing sintering temperature up to 1,473 K, which produced the highest density of 98 %. On the other hand, the sample sintered at 1,373 K had the highest micro-hardness of approximately 610 Hv, which is due to much finer grains.

Formation of $ZrO_2$ nanodots for the enhanced flux pinning properties in high $T_c$ superconducting films (초전도 자속고정 특성 향상을 위한 $ZrO_2$ 나노점의 형성 연구)

  • Chung, Kook-Chae;Yoo, Jai-Moo;Kim, Young-Kuk;Lee, Hye-Moon;Wang, X.L.;Dou, S.X.
    • Progress in Superconductivity and Cryogenics
    • /
    • v.10 no.1
    • /
    • pp.15-18
    • /
    • 2008
  • To achieve high transport current without degradation under magnetic field, it is essential to artificially generate the pinning sites at which moving magnetic flux can be pinned. In this work, $ZrO_2$ nanodots were formed on the substrate surface using electro-spray deposition method. On top of the nanodots, the extended and effective pinning centers can be created. The positively charged Zr precursor solution was sprayed out from the needle using the corona discharge phenomena. Then, the sprayed precursor was deposited onto the negatively charged substrate surface followed by the heat treatment under the controlled atmosphere. Using the electrostatic force among the charged particles of precursor, evenly distributed and nano-sized dots were formed on the substrate surface. The size and density of the nanodots were studied by Atomic Force Microscopy. Also discussed are the effect of the deposition time and solution concentration on the size and density of the nanodot and processing variables in electro-spray method for the effective flux pinning centers in the superconducting films.

Trunk Injection of Citrus Trees with a Polymeric Nanobactericide Reduces Huanglongbing Severity Caused by Candidatus Liberibacter asiaticus

  • Ramiro Guerrero-Santos;Gabriela Cabrales-Orona;John Paul Delano-Frier;Judith Cabello-Romero;Jose Roman Torres-Lubian;Jose Humberto Valenzuela-Soto
    • The Plant Pathology Journal
    • /
    • v.40 no.2
    • /
    • pp.139-150
    • /
    • 2024
  • Huanglongbing (HLB) is a disease caused by the phloem-limited Candidatus Liberibacter asiaticus (CLas) that affects the citrus industry worldwide. To date, only indirect strategies have been implemented to eradicate HLB. Included among these is the population control of the psyllid vector (Diaphorina citri), which usually provides inconsistent results. Even though strategies for direct CLas suppression seem a priori more promising, only a handful of reports have been focused on a confrontation of the pathogen. Recent developments in polymer chemistry have allowed the design of polycationic self-assembled block copolymers with outstanding antibacterial capabilities. Here, we report the use of polymeric nano-sized bactericide particles (PNB) to control CLas directly in the phloem vasculature. The field experiments were performed in Rioverde, San Luis Potosí, and is one of the most important citrusproducing regions in Mexico. An average 52% reduction in the bacterial population was produced when PNB was injected directly into the trunk of 20 infected trees, although, in some cases, reduction levels reached 97%. These results position PNB as a novel and promising nanotechnological tool for citrus crop protection against CLas and other related pathogens.

A Fundamental Study on Nano-cement by Chemical Synthesis (화학적 방법에 의한 나노시멘트 개발에 관한 기초 연구)

  • Jo, Byung-Wan;Kang, Seok-Won;Yoon, Kwang-Won;Choi, Ji-Sun
    • Journal of the Korea Concrete Institute
    • /
    • v.21 no.6
    • /
    • pp.713-718
    • /
    • 2009
  • Advanced industries-IT, BT, NT and ET are rapidly developing in 21 century. And the cement industry is becoming the principal factor in air pollution because of the creation of $CO_2$ during manufacturing. Also, the cement industry will be faced with a crisis due to the exhaustion of natural resources. In this study, nano cement by Bottom-up method of a chemical synthesis was developed. The generation of $CO_2$ during the plasticization process of cement manufacturing was avoided. The purpose was to produce building materials that have both high strength and durability as the high value-added growth engine industry of the 21 century. The nano cement was developed using hydrothermal synthesis. This is a method of mixing after ripening, by manufacturing the high density gel and low gel, which does not require special test equipment or pressure conditions to produce. Particle size, SEM, EDX, and porosity tests were conducted. This study investigated the compressive strength of concrete with various compositions. Specimens were tested for compressive strength at 3, 7, 14 and 28 days. The medium-sized (50% by weight) cement particles created by chemical synthesis were less than 168 nm. The compressive strength of the mortar prepared using this cement was 53.9 MPa. But it was judged that succeeding study will be necessary for development of nano building materials with high ability and economical analysis.

Sol-gel Derived Nano-glass for Silicon Solar Cell Metallization (솔-젤법에 의해 제조된 실리콘 태양전지 전극형성용 나노 글래스)

  • Kang, Seong Gu;Lee, Chang Wan;Chung, Yoon Jang;Kim, Chang-Gyoun;Kim, Seongtak;Kim, Donghwan;Lee, Young Kuk
    • Current Photovoltaic Research
    • /
    • v.2 no.4
    • /
    • pp.173-176
    • /
    • 2014
  • We have investigated the seed layer formation of front side contact using the inkjet printing process. Conductive silver ink was printed on textured Si wafers with 80 nm thick $SiN_x$ anti reflection coating (ARC) layers and thickened by light induced plating (LIP). The inkjet printable sliver inks were specifically formulated for inkjet printing on these substrates. Also, a novel method to prepare nano-sized glass frits by the sol-gel process with particle sizes around 5 nm is presented. Furthermore, dispersion stability of the formulated ink was measured using a Turbiscan. By implementing these glass frits, it was found that a continuous and uniform seed layer with a line width of $40{\mu}m$ could be formed by a inkjet printing process. We also investigated the contact resistance between the front contact and emitter using the transfer length model (TLM). On an emitter with the sheet resistance of $60{\Omega}/sq$, a specific contact resistance (${\rho}_c$) below $10m{\Omega}{\cdot}cm^2$ could be achieved at a peak firing temperature around $700^{\circ}C$. In addition, the correlation between the contact resistance and interface microstructures were studied using scanning electron microscopy (SEM). We found that the added glass particles act as a very effective fire through agent, and Ag crystallites are formed along the interface glass layer.