• Title/Summary/Keyword: Nano-Sized Particles

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Mossbauer Study of nano-sized (Li_{0.5x}Fe_{0.5x}Zn_{1-x})Fe_2O_4$ particles

  • J. C. Sur;Kim, T. S.;T. Y. Ha;Lee, J. K.;S. H. Gee;Y. K. Hong;Park, M. H.;D. W. Erickson;P. J. Lamb
    • Proceedings of the Korean Magnestics Society Conference
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    • 2002.12a
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    • pp.92-93
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    • 2002
  • The substituted lithium ferrites combine useful ferromagnetic properties with high Curie temperature ranging from 55$0^{\circ}C$ to 85$0^{\circ}C$, [1] high saturation magnetization, [2] and low microwave dielectric loss.[3] Saturation magnetization of (Z $n_{1-x}$ F $e_{x}$)A[L $i_{0.5x}$F $e_{ 2-0.5x}$]$_{B}$ $O_4$ increased with zinc concentration, followed by a decrease at x = 0.7.[4] This is attributed to a dilution of the A-site with zinc which initially causes an increase in saturation magnetization due to the dominance of the B-site. (omitted)d))d)d))

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A Study of Reduced and Carburized Reactions in Dry-milled $WO_3+Co_3O_4+C$ Mixed Powders with Different Carbon Content

  • Im, Hoo-Soon;Lee, Wan-Jae
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09a
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    • pp.648-649
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    • 2006
  • The dry-milling technique was used for mixing and crushing oxides and graphite powders. The ratio of ball-to-powder was 30:1 and argon gas was filled in jar. The excess carbon was $10{\sim}20wt%$ of the stoichiometric amount. The dry-milling was carried for 20 hours. The mixed powders were reduced and carburized at $900{\sim}980^{\circ}C$ for 3 hours flowing Ar gas in tube furnace. The dry-milled powders showed the wide diffraction patterns of X-ray. The reactions of reduction and carburization were completed in 3 hours at $980^{\circ}C$. After the reactions, the mean size of WC particles was about 200 nm. The content of free carbon in WC/Co mixed powders was less as the reaction temperature increased.

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Characteristics of Porous YAG Powders Fabricated by PVA Polymer Solution Technique

  • Lee, S.J.;Shin, P.W.;Kim, J.W.;Chun, S.Y.
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09a
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    • pp.438-439
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    • 2006
  • Pure and stable YAG $(Y_3Al_5O_{12})$ powders were synthesized by a PVA (polyvinyl alcohol) polymer solution technique. PVA was used as an organic carrier for the precursor ceramic gel. The precursor gels were crystallized to YAG at relatively a low temperature of $900\;^{\circ}C$. The synthesized powders, which have nano-sized primary particles, were soft and porous, and the porous powders were ground to sub-micron size by a simple ball milling process. The ball-milled powders were densified to 94% relative density at $1500\;^{\circ}C$ for 1h. In this study, the characteristics of the synthesized YAG powders were examined.

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Fabrication and Characterization of Polystyrene/Gold Nanoparticle Composite Nanofibers

  • Kim, Jung-Kil;Ahn, Hee-Joon
    • Macromolecular Research
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    • v.16 no.2
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    • pp.163-168
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    • 2008
  • Polystyrene/gold nanoparticle (PS/AuNP) composite fibers were fabricated using an electrospinning technique. Transmission electron microscopy (TEM) showed that the diameters of the naphthalenethiol-capped gold nanoparticles (prior to incorporation into the PS fibers) ranged from 2 to 5 nm. UV-vis spectroscopy revealed the surface plasmon peaks of the gold nanoparticles centered at approximately 512 nm, indicating that nano-sized Au particles are well-dispersed in solution. This was consistent with the TEM observations. The electrospun nanofibers of PS/AuNP composites were approximately 60-3,000 nm in diameter. The surface morphology of the PS/AuNP composite and the dispersability of the Au nanoparticles inside of PS after electrospinning process were investigated by SEM and TEM. The thermal behavior of the pure PS and PS/AuNP nanocomposites and fibers were examined by DSC.

Transparent Nano-floating Gate Memory Using Self-Assembled Bismuth Nanocrystals in $Bi_2Mg_{2/3}Nb_{4/3}O_7$ (BMN) Pyrochlore Thin Films

  • Jeong, Hyeon-Jun;Song, Hyeon-A;Yang, Seung-Dong;Lee, Ga-Won;Yun, Sun-Gil
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2011.10a
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    • pp.20.1-20.1
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    • 2011
  • The nano-sized quantum structure has been an attractive candidate for investigations of the fundamental physical properties and potential applications of next-generation electronic devices. Metal nano-particles form deep quantum wells between control and tunnel oxides due to a difference in work functions. The charge storage capacity of nanoparticles has led to their use in the development of nano-floating gate memory (NFGM) devices. When compared with conventional floating gate memory devices, NFGM devices offer a number of advantages that have attracted a great deal of attention: a greater inherent scalability, better endurance, a faster write/erase speed, and more processes that are compatible with conventional silicon processes. To improve the performance of NFGM, metal nanocrystals such as Au, Ag, Ni Pt, and W have been proposed due to superior density, a strong coupling with the conduction channel, a wide range of work function selectivity, and a small energy perturbation. In the present study, bismuth metal nanocrystals were self-assembled within high-k $Bi_2Mg_{2/3}Nb_{4/3}O_7$ (BMN) films grown at room temperature in Ar ambient via radio-frequency magnetron sputtering. The work function of the bismuth metal nanocrystals (4.34 eV) was important for nanocrystal-based nonvolatile memory (NVM) applications. If transparent NFGM devices can be integrated with transparent solar cells, non-volatile memory fields will open a new platform for flexible electron devices.

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Mechanical Properties of Synthesized Nano Laminating $Ti_3SiC_2$ by Reaction Press Sintering (반응 가압 소결 방법으로 합성된 nano laminating $Ti_3SiC_2$의 기계적 특성)

  • 황성식;박상환;김찬묵
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2003.06a
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    • pp.396-400
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    • 2003
  • A new synthesis process for nano laminating Ti$_3$SiC$_2$ has been developed using TiCx (x=0.67) and Si powder as starting materials by a reaction hot pressing. Bulk Ti$_3$SiC$_2$ was fabricated using a green body consisting of TiCx and Si by a hot pressing under the pressures of 25 MPa at 1420-1550 $^{\circ}C$ for 90 min. The synthesized Ti$_3$SiC$_2$ was consisting of only TiCx and Ti$_3$SiC$_2$. The relative density of sintered bulk Ti$_3$SiC$_2$ was increased as the hot pressing temperature was increased, which was mainly due to the increase in TiCx contents in synthesized Ti$_3$SiC$_2$. The synthesized Ti$_3$SiC$_2$ bulk was consisted of nano sized lamella structure of 20-100 nm in thickness. It was found that TiCx particles in Ti$_3$SiC$_2$ would increase the 3-point bending strength of synthesized Ti$_3$SiC$_2$ bulk. The maximum 3-P. bending strength of synthesized Ti$_3$SiC$_2$ bulk was more than 800 MPa. The Vickers hardness of synthesized Ti$_3$SiC$_2$bulk was as low as 5 Gpa, which was decreased with the indentation load. The quasi-plastic deformation behaviors were observed around indentation mark on Ti$_3$SiC$_2$.

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Silver Contamination in Drinking Water of Gyeongbuk Area in Korea (경북 지역 먹는 물의 은 검출 특성)

  • Lee, Hea Geun;Kim, Jeong Jin;Kim, Young Hun
    • Korean Journal of Mineralogy and Petrology
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    • v.33 no.3
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    • pp.233-242
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    • 2020
  • As studies and developments of nano-material increase, the release of the nano-sized material to water environment increase. Especially, silver nanoparticles have been found as dissolved and particulate state since nano-silver particle have been intensively used in industrial and our living environment due to the anti-bacterial effect of the nano-particles. The silver nano-particles and silver ion gives adverse effect on ecology and US-EPA set a secondary drinking water standards as 0.1 mg/L. Current study focused on the analysis of silver in groundwater, small scale water supply systems in Gyeongbook area. The results have been compared with the secondary drinking water standards and discussed at the point of characteristics of the local area and purpose of use of the water sample. Among the total of 298 samples, 2 samples exceed the secondary drinking water standards of EPA, 0.64% rate. Community drinking water and simplified water service showed relatively high detection rate and groundwater gave relatively higher concentration of silver indicating anthropogenic source and natural source could contribute simultaneously on groundwater.

Development and Prospect of Emulsion Technology in Cosmetics (화장품에서 유화기술의 발전 및 전망)

  • Kyong, Kee-Yeol;Lee, Cheon-Koo
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.32 no.4 s.59
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    • pp.209-217
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    • 2006
  • Emulsion is a dispersion system among liquids which are not miscible together. There are numerous cosmetic raw materials which have different physicochemical properties. Therefore, emulsion technology is very useful in cosmetics. With the development of emulsifier, several emulsification technologies have been developed. Since HLB method by Griffin in 1950's, PIT method, gel method, and D-phase methods, etc, have been developed. Recently, the application of natural emulsifier and polymeric emulsifier increases in cosmetics in order to achieve enhanced safety and biocompatibility. Besides nano-emulsion, multiple-emulsion, liquid crystal emulsion, and Pickering emulsion have been developed and applied as means of differentiating appearance and texture of products and achieving enhanced delivery of active ingredients. Meanwhile, the application studies of nano-dispersed structural system such as liposome or cubosome are on progress. Liposome is a bi- or multi-lamella layer dispersion system composed of amhiphilic molecules - phospholipids which are main components of plasma membrane. Cubosome also is a nano-sized dispersion system composed of a specific molecule like glyceryl monoloeate derived from natural products. And it has a cubic bicontinuous structure in water due to its unique molecular structure. Incorporating compounds (active materials) into such nano-particles can increase biocompatibility and delivery efficiency of target compounds. Manufacturing process and application of cosmetic emulsions and nano-particles are briefly introduced in this paper.

Poly(phenanthrenequinone)-Poly(acrylic acid) Composite as a Conductive Polymer Binder for Submicrometer-Sized Silicon Negative Electrodes (서브마이크로미터 크기의 실리콘 음극용 폴리페난트렌퀴논-폴리아크릴산 전도성 고분자 복합 바인더)

  • Kim, Sang-Mo;Lee, Byeongil;Lee, Jae Gil;Lee, Jeong Beom;Ryu, Ji Heon;Kim, Hyung-Tae;Kim, Young Gyu;Oh, Seung M.
    • Journal of the Korean Electrochemical Society
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    • v.19 no.3
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    • pp.87-94
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    • 2016
  • In order to improve performances of submicrometer-sized Si negative electrode which shows larger volumetric change than nano-sized Si, composite binders are introduced by blending between poly(phenanthrenequinone) (PPQ) conductive polymer binder and poly(acrylic acid) (PAA) having good adhesion strength due to its carboxyl functional group. Blending between PPQ and PAA shows an effect that the adhesion strength of the Si electrode with the composite conductive binder is greatly improved after blending and this makes its better stable cycle performance. Blending ratios between PPQ and PAA in this work are 2:1, 1:1, 1:2 (by weight) and the best capacity retention at 50th cycle is observed in the electrode with the blending ratio 2:1 (named QA21). This is because that PPQ plays a role of conductive carbon among the Si particles or between Si particles and Cu current collector and PAA binds effectively the particles and the current collector. According to this synergetic effect, the internal resistance of the Si electrode with the blending ratio 2:1 is the smallest value. In addition, the Si electrode with PPQ-PAA composite binder shows the better stable cycle performance than the electrode with conventional super-P conductive carbon (20 wt.%).

Low temperature synthesis of ZnO nanopowders by the polymerized complex method (착체중합법을 이용한 ZnO 나노분말의 저온합성)

  • 권용재;김경훈;임창성;심광보
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.12 no.5
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    • pp.229-233
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    • 2002
  • Nano-sized ZnO particles were successfully synthesized at low temperatures by a polymerized complex method via an organochemical route. The polymeric precursors could be prepared using Zn nitrate hexahydrate and a mixed solution of citric acid and ethylene glycol as a chelating agent and a reaction medium. The polymeric precursors were calcined at temperatures from 300 to $700^{\circ}C$ for 3 h, and evaluated for degree of crystallization process, thermal decomposition, surface morphology and crystallite size. The thermal decomposition and crystallization process were analyzed by TG-DTA, FI-IR and XRD. The morphology and crystallite size of the calcined particles were evaluated by scanning electron microscopy (SEM), transmittance electron microscopy (TEM) and Scherrer's equation. Crystallization of the ZnO particles was detected at $300^{\circ}C$ and entirely completed above $400^{\circ}C$. Particles calcined between 400 and $700^{\circ}C$ showed a uniform size distribution with a round shape. The average particle sizes calcined at $400^{\circ}C$ for 3 hour were 30~40nm showing an ordinary tendency to increase with the temperatures.