Macromolecular Research

The Polymer Society of Korea (한국고분자학회)
권호 표지

Fabrication and Characterization of Polystyrene/Gold Nanoparticle Composite Nanofibers

  • Kim, Jung-Kil (Department of Fiber and Polymer Engineering, Hanyang University) ;
  • Ahn, Hee-Joon (Department of Fiber and Polymer Engineering, Hanyang University)
  • Published : 2008.02.29
Download PDF
⟨ Previous Next ⟩

Abstract

Polystyrene/gold nanoparticle (PS/AuNP) composite fibers were fabricated using an electrospinning technique. Transmission electron microscopy (TEM) showed that the diameters of the naphthalenethiol-capped gold nanoparticles (prior to incorporation into the PS fibers) ranged from 2 to 5 nm. UV-vis spectroscopy revealed the surface plasmon peaks of the gold nanoparticles centered at approximately 512 nm, indicating that nano-sized Au particles are well-dispersed in solution. This was consistent with the TEM observations. The electrospun nanofibers of PS/AuNP composites were approximately 60-3,000 nm in diameter. The surface morphology of the PS/AuNP composite and the dispersability of the Au nanoparticles inside of PS after electrospinning process were investigated by SEM and TEM. The thermal behavior of the pure PS and PS/AuNP nanocomposites and fibers were examined by DSC.

Keywords

References

  1. U. Heiz and U. Landman, Nanocatalysis, Springer, Berlin, 2007
  2. K. H. A. Lau, W. Knoll, and D. H. Kim, Macromol. Res., 15, 211 (2007) https://doi.org/10.1007/BF03218777
  3. G. I. Frolov, Tech. Phys., 46, 1537 (2001) https://doi.org/10.1134/1.1340876
  4. G. Shemer and G. Markovich, J. Phys. Chem. B, 106, 9195 (2002) https://doi.org/10.1021/jp022095s
  5. O. A. Aktsipetrov, Coll. Surf. A, 202, 165 (2002)
  6. J. L. MenZndez, B. Besc-s, G. Armelles, R. Serna, J. Gonzalo, R. Doole, A. K. Petford-Long, and M. I. Alonso, Phys. Rev. B, 65, 205413 (2002)
  7. A. B. Kharitonov, A. N. Shipway, and I. Willner, Anal. Chem., 71, 5441, (1999)
  8. A. B. Kharitonov, A. N. Shipway, E. Katz, and I. Willner, Rev. Anal. Chem., 18, 255, (1999)
  9. V. Pardo-Yissar, R. Gabai, A. N. Shipway, T. Bourenko, and I. Willner, Adv. Mater., 13, 1320, (2001)
  10. A. K. Boal and V. M. Rotello, J. Am. Chem. Soc., 124, 5019 (2002)
  11. A. K. Boal and V. M. Rotello, J. Am. Chem. Soc., 122, 734 (2000)
  12. S.-D. Oh, B.-S. Byun, S. Lee, and S. H. Choi, Macromol. Res., 14, 194 (2006) https://doi.org/10.1007/BF03218508
  13. S.-D. Oh, B.-S. Byun, S. Lee, S. H. Choi, M. I. Kim, and H. J. Park, Macromol. Res., 15, 285 (2007) https://doi.org/10.1007/BF03218789
  14. Z. Lin, B. Gilbert, Q. Liu, G. Ren, and F. Huang, J. Am. Chem. Soc., 128, 6126 (2006) https://doi.org/10.1021/ja054700l
  15. G. Schmid, B. Morun, and J. -O. Malm, Angew. Chem. Int. Ed. Engl., 28, 778 (1989)
  16. S. V. Manorama, K. M. Reddy, C. V. G. Reddy, S. Narayanan, P. R. Paja, and P. R. Chatterji, J. Phys. Chem. Solids, 63, 135 (2002)
  17. Y. Zhou, H. Itoh, T. Uemura, K. Naka, and Y. Chujo, Langmuir, 18, 5287 (2002)
  18. C. Park, M. Rhue, J. Lim, and C. Kim, Macromol. Res., 15, 39 (2007) https://doi.org/10.1007/BF03218750
  19. K. J. Klabunde, J. Habdas, and G. Crdenas-Trivi-o, Chem. Mater., 1, 481 (1989)
  20. M. S. El-Shall and W. Slack, Macromolecules, 28, 8456 (1995)
  21. L. Quaroni and G. Chumanov, J. Am. Chem. Soc., 121, 10642 (1999)
  22. C. Johans, J. Clohessy, S. Fantini, K. Kontturi, and V. J. Cunnane, Electrochem. Commun., 4, 227 (2002)
  23. T. K. Sarma, D. Chowdhury, A. Paul, and A. Chattopadhyay, Chem. Commun., 1048 (2002)
  24. L. Nicolais and G. Carotenuto, Metal-polymer nanocomposites, Wiley, New Jersey, 2005.
  25. D. I. Cha, K. W. Kim, G. H. Chu, H. Y. Kim, K. H. Lee, and N. Bhattarai, Macromol. Res., 14, 331 (2006) https://doi.org/10.1007/BF03219090
  26. K. Park, H. J. Jung, J. J. Kim, K.-D. Ahn, D. K. Han, and Y. M. Ju, Macromol. Res., 14, 552 (2006) https://doi.org/10.1007/BF03218723
  27. Y. H. Jung, H. Y. Kim, D. R. Lee, S. Y. Park, and M. S. Khil, Macromol. Res., 13, 385 (2005)
  28. Z.-M. Auang, Y.-Z. Zhang, M. Kotaki, and S. Ramakrishna, Composites Sci. Tech., 63, 2223 (2003)
  29. W. K. Son, J. H. Youk, T. S. Lee, and W. H. Park, Macromol. Rapid Commun., 25, 1632 (2004)
  30. H. Park, K. Y. Lee, S. J. Lee, K. E. Park, and W. H. Park, Macromol. Res., 15, 238 (2007) https://doi.org/10.1007/BF03218782
  31. Q. L. Feng, J. Wu, G. Q. Chen, F. Z. Cui, T. N. Kim, and J. O. Kim, J. Biomed. Mater. Res., 52, 662 (2000)
  32. G.-M. Kim, A. Wutzler, H.-J. Radusch, G. H. Michler, P. Simon, R. A. Sperling, and W. J. Parak, Chem. Mater., 17, 4949 (2005)
  33. J. Bai, Y. Li, S. Yang, J. Du, S. Wang, J. Zheng, Y. Wang, Q. Yang, X. Chen, and X. Jing, Solid State Commun., 141, 292 (2007)
  34. Y. Wang, Y. Li, G. Sun, G. Zhang, H. Liu, J. Du, S. Yang, J. Bai, and Q. Yang, J. Appl. Polym. Sci., 105, 3618 (2007)
  35. M. Brust, M. Walker, D. Bethell, D. J. Schiffrin, and R. Whyman, J. Chem. Soc., Chem. Commun., 801 (1994)
  36. P. Mulvaney, Langmuir, 12, 788 (1996)
  37. W. K. Son, J. H. Youk, T. S. Lee, and W. H. Park, Polymer, 45, 2959 (2004)
  38. L. Balan and D. Burget, Eur. Polym. J., 42, 3180 (2006)