• Title/Summary/Keyword: Nano-Composites-Materials

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Superhydrophobic Engineered Surface Based on Nanohoneycomb Structures (나노허니컴 구조물을 이용한 산업용 극소수성 표면 제작)

  • Kim, Dong-Hyun;Park, Hyun-Chul;Lee, Kun-Hong;Hwang, Woon-Bong
    • Composites Research
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    • v.20 no.2
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    • pp.17-20
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    • 2007
  • Superhydrophobic polytetrafluoroethylene ($Teflon^{(R)}$, Dupont) sub-micro and nanostructures were fabricated by the dipping method, based on anodization process in oxalic acid. The polymer sticking phenomenon during the replication creates the sub-microstructures on the negative polytetrafluoroethylene nanostructure replica. This process gives a hierarchical structure with nanostructures on sub-microstructures, which looks like the same structures as lotus leaf and enables commercialization. The diameter and the height of the replicated nano pillars were 40 nm and 40 um respectively. The aspect ratio is approximately 1000. The fabricated surface has a semi-permanent superhydrophobicity, the apparent contact angle of the polytetrafluoroethylene sub-micro and nanostructures is about $160^{\circ}$, and the sliding angle is less than $1^{\circ}$.

Development of High-strength Polyethylene Terephthalate (PET) Sheet Through Low Melting Point Binder Compounding and Compression Process (저 융점 바인더 복합화 및 압착공정을 통한 고강도 폴리에틸렌 테레프탈레이트(PET) 시트 개발)

  • Moon, Jai Joung;Park, Ok-Kyung;Kim, Nam Hoon
    • Composites Research
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    • v.33 no.5
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    • pp.282-287
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    • 2020
  • In the present study, a high-strength polyethylene terephthalate (PET) sheet was fabricated through a densification process of low melting PET fiber (LMF) combined PET sheet. During the thermal heat treatment process of the combined LMF, individual PET fiber was connected, which in turn leads to the improvement of the interfacial bonding force between the fibers. Also, the densification of the PET sheet leads to reduce macrospore density and in return could enhance the binding force between the overlapped PET networks. Consequently, the asprepared LMF-PET sheet showed about 410% improved tensile strength and the same elongation compared to before compression. Besides, the enhanced bonding force can prevent the shrinkage of the PET fiber network and exhibited excellent dimensional stability.

Physical Test and Finite Element Analysis of Elastomer for Steel Rack Tube Forming (일체형 랙 튜브 성형을 위한 고 탄성체 물성시험과 유한요소 해석)

  • Woo, C.S.;Park, H.S.;Lee, G.A.
    • Elastomers and Composites
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    • v.43 no.3
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    • pp.173-182
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    • 2008
  • Rubber-pad forming process for materials such as metal in which portions of the die which act upon the material is composed of a natural or synthetic rubber or elastomer material. This makes the rubber pad forming process relatively cheap and flexible, high accuracy for small product series in particular. In this study, we carried out the physical test and finite element analysis of elastomer such as natural rubber and urethane for steel rack rube forming. The non-linear property of elastomer which are described as strain energy function are important parameter to design and evaluate of elastomer component. These are determined by material tests which are uni-axial tension and bi-axial tension. This study is concerned with simulation and investigation of the significant parameters associated with this process.

Study on the Determination of Fatigue Damage Parameter for Rubber Component under Multiaxial Loading (다축하중이 작용하는 방진고무부품 피로손상 파라미터 결정에 관한 연구)

  • Moon, Seong-In;Woo, Chang-Su;Kim, Wan-Doo
    • Elastomers and Composites
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    • v.47 no.3
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    • pp.194-200
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    • 2012
  • Rubber components have been widely used in automotive industry as anti-vibration components for many years. These subjected to fluctuating loads, often fail due to the nucleation and growth of defects or cracks. To prevent such failures, it is necessary to understand the fatigue failure mechanism for rubber materials and to evaluate the fatigue life for rubber components. The objective of this study is to develop the durability analysis process for vulcanized rubber components, which is applicable to predict fatigue life at initial product design step. The determination method of nonlinear material constants for FE analysis was proposed. In order to investigate the applicability of the commonly used damage parameters, fatigue tests and corresponding finite element analyses were carried out and strain energy density was proposed as the fatigue damage parameter for rubber components. The fatigue analysis for automotive rubber components was performed and the durability analysis process was reviewed.

Large Area Deposition of Biomimetic Polydopamine-Graphene Oxide Hybrids using Langmuir-Schaefer Technique (랭뮤어-쉐퍼 기법 이용 생체모사 폴리도파민-산화그래핀 복합체 대면적 적층 기법 연구)

  • Kim, Tae-Ho;Song, Seok Hyun;Jo, Kyung-Il;Koo, Jaseung
    • Journal of Adhesion and Interface
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    • v.20 no.3
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    • pp.110-115
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    • 2019
  • Graphene oxide has been gathering interests as a way to exfoliate graphene. Since the oxidation group of graphene oxide can hydrogen bond with various functional groups, tremendous efforts have been actively conducted to apply various applications. However, graphene oxide alone cannot substantially possess the mechanical properties required for the practical application. Therefore, in this study, polydopamine, which is a bio-mimetic mussel protein-inspired material, was combined with graphene oxide to form a large-area composite membrane at the liquid-gas interface. In addition, the morphology of the polydopamine-graphene oxide composite thin film was also controlled to obtain a composite membrane having a nano-wrinkle structure. It can be expected to be used in the next generation seawater desalination membranes or carbon composites because it can form mechanically superior and sophisticated nanostructures.

A Study on Mechanical Interfacial Properties of Copper-plated Carbon Fibers/Epoxy Resin Composites (구리도금된 탄소섬유/에폭시 수지 복합재료의 기계적 계면 특성에 관한 연구)

  • Hong, Myung-Sun;Bae, Kyong-Min;Choi, Woong-Ki;Lee, Hae-Seong;Park, Soo-Jin;An, Kay-Hyeok;Kim, Byung-Joo
    • Applied Chemistry for Engineering
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    • v.23 no.3
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    • pp.313-319
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    • 2012
  • In this work, the electroplating of copper was introduced on PAN-based carbon fibers for the enhancement of mechanical interfacial strength of carbon fibers-reinforced composites. The surface properties of carbon fibers were determined by scanning electron microscopy (SEM), X-ray photoelectron spectroscopy (XPS), X-ray diffraction (XRD), and contact angle measurements. Its mechanical interfacial properties of the composites were studied by interlaminar shear strength (ILSS) and critical stress intensity factor ($K_{IC}$). From the results, it was found that the mechanical interfacial properties of Cu-plated carbon fibers-reinforced composites (Cu-CFRPs) enhanced with increasing the Cu plating time, Cu content and COOH group up to Cu-CFRP-30. However, the mechanical interfacial properties of the Cu-CFRPs decreased dramatically in the excessively Cu-plated CFRPs sample. In conclusion, the presence of Cu particles on carbon fiber surfaces can be a key factor to determine the mechanical interfacial properties of the Cu-CFRPs, but the excessive Cu content can lead the failure due to the interfacial separation between fibers and matrices in this system.

Mechanical Properties and Consolidation of Ultra-Fine WC-10Co and WC-10Fe Hard Materials by Rapid Sintering Process (급속 소결 공정에 의한 초미립 WC-10Co와 WC-10Fe 초경재료 제조와 기계적 성질)

  • Jeong, In Kyoon;Park, Jung-Hwan;Doh, Jung-Mann;Kim, Ki-Youl;Woo, Kee-Do;Ko, In-Young;Shon, In-Jin
    • Korean Journal of Metals and Materials
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    • v.46 no.4
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    • pp.223-226
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    • 2008
  • The comparison of sintering behavior and mechanical properties of ultra-fine WC-10wt.%Co and WC-10wt.%Fe hard materials produced by high-frequency induction heated sintering (HFIHS) was accomplished using ultra fine powder of WC and binders(Co, Fe). The advantage of this process allows very quick densification to near theoretical density and prohibition of grain growth in nano-structured materials. Highly dense WC-10Co and WC-10Fe with a relative density of up to 99% could be obtained with simultaneous application of 60 MPa pressure and induced current within 1 minute without significant change in grain size. The hardness and fracture toughness of the dense WC-10Co and WC-10Fe composites produced by HFIHS were investigated.

Characteristics Analysis of Nano-composites Films Using Extruder (압출성형기를 이용한 나노복합재 필름의 특성 분석)

  • Kwon, Il-Jun;Park, Sung-Min;Yoo, Sung-Hun;Yeum, Jeong-Hyun
    • Textile Coloration and Finishing
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    • v.28 no.2
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    • pp.101-108
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    • 2016
  • Polypropylene(PP)/multiwalled carbon nanotubes(MWCNT) nanocomposites films and PP/poly(vinyl alcohol)/CNT nanocomposites films were prepared through melt mixing method by the extruder. The PP/CNT nanocomposites films, which contain CNT of a variable content, were prepared for the first time and research on a appropriate content of the CNT on the PP/CNT nanocomposites films was conducted. The effects of take-up speed of the extruder on the mechanical and chemical properties of the PP/CNT and PP/PVA/CNT nanocomposites film were studied. Field emission scanning electron microscope(FE-SEM) was used to examine the surface morphology and the DSC measurement and tensile test were conducted. It was found that the properties decreased when take-up speed was increased.

Effect of Sodium Lignosulfonate Treatment on the Dispersion of CaCO3 in CaCo3/Polypropylene Composite (Sodium Lignosulfonate 표면처리가 탄산칼슘/폴리프로필렌 복합체에서 탄산칼슘의 분산에 미치는 영향)

  • Song, Junyoung;Kwark, Young-Je;Jeong, Youngjin
    • Polymer(Korea)
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    • v.39 no.3
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    • pp.382-387
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    • 2015
  • The dispersion of calcium carbonate ($CaCO_3$) in polypropylene (PP) and the effect of $CaCO_3$ size on the crystallinity of PP were studied. Polymer composite usually suffers from the brittleness when reinforced with inorganic fillers. The problem is generally related to the size and dispersion of fillers. First, the dispersion was studied for the nanosize $CaCO_3$ with 15~40 nm average diameter. To enhance the dispersibility in PP, the surface of the $CaCO_3$ was treated with sodium lignosulfonate (SLS). $CaCO_3$/PP composites were prepared via melt compounding. The $CaCO_3$ coated with more than 3 wt% SLS was uniformly distributed within the PP matrix, while the uncoated $CaCO_3$ formed aggregated structures in the PP. Even with 30 wt%, the SLS-$CaCO_3$ was well dispersed in the PP matrix. Also, the transition enthalpy of $CaCO_3$/PP increased and the full-width of half maximum of the crystallization peak decreased regardless of SLS coating and size of $CaCO_3$. However, the crystallinity of PP was more influenced by nano $CaCO_3$. These results imply that the nano $CaCO_3$ coated with SLS may reduce the brittleness of polymer composites.

Microstructure, mechanical and electrical properties of core shell Ni-YSZ anode materials in Solid Oxide Fuel Cells (SOFC용 Anode 물질인 Ni/YSZ의 Core shell형성기구와 메카니즘과 전기화학적 특성)

  • Jung, Sunghun;Ji, Mijung;Kim, Eunkyung;Choi, Byunghyun
    • 한국신재생에너지학회:학술대회논문집
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    • 2011.11a
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    • pp.103.1-103.1
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    • 2011
  • 고체 산화물 연료전지(SOFC)는 크게 음극(anode), 양극(cathode), 전해질(electrolyte)로 구성되 있으며 연결자를 통해 직렬 또는 병렬로 연결된 형태로 발전장치 등에 활용되고 있다. 이중 연료의 산화반응을 담당하고 있는 연료전지의 음극으로 지금까지 Cobalt, Platinum, Palladium 등의 전이금속 또는 귀금속들이 사용되었지만 현재는 Nickel 또는 Nickel을 함유한 물질들 특히, Ni-YSZ 복합체가 주로 사용되고 있다. Ni-YSZ 복합체는 가격과 성능 등 여러가지 면에서 SOFC의 음극으로 사용하기에 가장 적합한 물질인데 특히 전지의 지지체 역할과 동시에 전극으로서의 역할도 병행해야하는 음극 지지형 SOFC의 경우 Ni-YSZ 복합체의 효용성을 더욱 커지게 된다. 본 연구에서는 SOFC의 음극물질로 가장 널리 쓰이고 있는 Ni-YSZ 복합체를 core shell 형태로 만들어 전도 path를 효율적으로 하고 그 특성을 최적화하기 위한 미세구조 및 소결 거동, 전기적 특성을 평가하였다.

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