• 제목/요약/키워드: NaPl

검색결과 111건 처리시간 0.025초

화력발전소 바닥재로부터 합성된 제올라이트의 반응온도와 알칼리 농도에 따른 상변화에 대한 연구 (Synthesis of zeolite with reaction temperature and alkali concentration from coal bottom ash)

  • 전소연;한기천;안지환
    • 한국결정성장학회지
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    • 제14권5호
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    • pp.204-210
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    • 2004
  • 국내 화력발전소에서 배출되는 석탄회 중에서 비산재의 재활용률은 점점 증가하고 있으나, 바닥재는 현재 전량 매립되고 있는 실정이다. 이에 본 연구에서는 바닥재로부터 제올라이트를 합성함으로써 바닥재의 고부가가치 물질로의 전환 가능성을 알아보았다. 실험을 위해 분쇄한 바닥재를 반응온도$(80,{\;}120,{\;}150^{\circ}C)$ 및 NaOH농도(1~5M)를 변화시키면서 알칼리 수열합성법으로 반응시킨 결과, NaPl, hydrxoy-sodalite, tobermorite 등이 생성되었다. 특히, $120^{\circ}C$ 이하의 온도 및 2M이하의 NaOH농도에서 양이온교환능력이 우수한 것으로 알려진 NaPl이 높은 결정성을 갖는 것으로 나타났다.

송이로부터 골프장 농약 제거를 위한 합성 제올라이트의 개발 (Development of Synthetic Zeolites from Scoria for Pesticides Removal in the Golf Course)

  • 감상규;안병준;주창식;이민규
    • 한국환경과학회지
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    • 제10권6호
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    • pp.451-459
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    • 2001
  • Adsorption characteristics of triadimefon and diniconazole(pesticide) by natural zeolite($CLI_N$) and several synthetic zeolites were Investigated. The synthetic zeolites used En this study were as follows: Faujasite synthesized from coal fly ash($FAU_F$); Zeolite synthesized from the mixture of FAU and Na-Pl synthesized from the ratio of Cheju scoria 6 to coal fly ash 4 by weight($(FAU + Na-Pl)_{SF}$); waste fluid catalytic cracking catalyst($FCC_W$). The distribution coefficient, $K_D$ and Freundlich constant, $K_F$ decreased in the fellowing sequence : $FCC_W > FAU_F > (FAU + Na-Pl)_{SF} >CLI_N$ among the zeolites. The distribution coefficient and the adsorption capacity of $(FAU + Na-Pl)_{SF}$ for pesticides were 4.4 and 2.6 times higher for triamefon, and 2.0 and 2.4 times higher for diniconazole than those of $CLI_N$, respectively.

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$Na_2Se/NH_4OH $용액으로 처리된 GaAs 표면의 안정성 연구 (Investigation on the stability of $Na_2Se/NH_4OH $-treated GaAs surface)

  • 사승훈;강민구;박형호
    • 한국진공학회지
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    • 제7권1호
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    • pp.11-16
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    • 1998
  • 본 연구에서는 GaAs의 selenium보호막형성 효과를 관찰하기 위하여 $Na_2$Se/NH$_4$OH 용액을 제조하고 X-선 광전자 분광기(X-ray photoelectron spectroscopy)와 photoluminescence(PL)를 이용하여 표면처리된 GaAs의 처리직후 및 대기중 노출에 따른 화학적 결합특성 및 광학적 특성을 관찰하였다. 용액처리 직후, 표면에는 As-Se결합이 형성 되었으며 Se는 한가지 산화상태인 -2가로 존재함이 관찰되었다. 또한 세정처리후의 표면보 다 Se용액처리 이후에 PL의 피이크 세기가 크게 증가됨으로부터 Se 용액처리가 GaAs의 표면상태밀도를 효과적으로 감소시킬 수 있음을 확인할 수 있었다. 그러나 처리 직후 공기 중 노출없이 관찰한 GaAs표면에서 산화막이 국부적으로 관찰되었으며 이렇게 처리과정중 생성된 산화막은 대기중 노출에 따라 산화막 성장을 유도하고 표면처리 효과를 저하시키는 주요인으로 작용함을 알 수 있었다. 이는 Se용액처리된 GaAs표면의 PL강도가 대기중 노출 에 따라 감소하며 세정처리후 GaAs표면의 PL강도와 유사한 값을 나타냄으로 부터도 확인 할 수 있었다.

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Removal Characteristics of Heavy Metal by Na-P1 Zeolite Synthesized from Coal Fly Ash

  • Mingyu Lee;Don
    • 한국환경과학회지
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    • 제1권2호
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    • pp.167-175
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    • 1992
  • This study was conducted for an efficient utilization of waste fly ash obtained from the power plant. Fly ash was used for synthesizing zeolite. Na-Pl zeolite could be easily synthesized from waste fly ash and showed the potential to remove heavy metal ions. The synthetic zeolite showed good adsorption property for heavy metal much better than raw fly ash and natural zeolites. Na-Pl exhibited the high adsorption efficiency with a maximum value of 260 Pb mg/g and strong affinity for Pb2+ ion. The metal ion selectivity of Na-Pl was determined in a decreasing order : $Pb^{2+}$>$Cd^{2+}$>$Cu^{2+}$+>$Zn^{2+}$>$Fe^{3+}$

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제올라이트에 의한 농약의 흡착

  • 감상규;김길성;안병준;이민규
    • 한국지하수토양환경학회:학술대회논문집
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    • 한국지하수토양환경학회 2001년도 총회 및 춘계학술발표회
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    • pp.7-10
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    • 2001
  • Adsorption of the pesticides (phosphamidon, fenitrothion, triadimefon and diniconazole) in natural zeolite (CL $I_{N}$) and several synthetic zeolites was incestigated. The pesticides were not adsorbed on zeolites (Na-Pl, SOD, ANA, JBW and CAN) synthesized from Jeju scoria. The distribution coefficient ( $K_{D}$) and the Freundlich constant ( $K_{F}$) decreased in the following sequences. FC $C_{W}$ (waste catalytic cracking catalyst)>FA $U_{F}$ (FAU Synthesized from coal fly ash)>(FAU+Na-Pl)$_{SF}$ (the mixture of FAU and Na-Pl synthesized from the ratio of Jeju scoria 6 to coal fly ash 4 by weight)>CL $I_{N}$ among the zeolites; diniconazole>fenitrothion> triadimefon>phosphamidon. As the temperature was increased, the amount of pesticide adsorbed per unit mass of zeolite increased for FC $C_{W}$, FA $U_{F}$ and (FAU+Na-Pl)$_{SF}$ but it decreased for CL $I_{N}$, for all the pesticides used in this study. It was independent of pH for phosphamidon, fenitrothion and triadimefon, but decresed as pH was increased for all the zeolites used in this study.y.udy.y.y.y.y.y.y.

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RFID 기반 u-4PL 시스템 개발에 관한 연구 (Study on Development of u-4PL System based RFID)

  • 이종석;나형석;이창호
    • 대한안전경영과학회:학술대회논문집
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    • 대한안전경영과학회 2007년도 추계학술대회
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    • pp.181-191
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    • 2007
  • Logistics creates a boom in accordance with the recent new technique's development along with the recent RFID/USN of ubiquitous computing technique. The wave of 4PL(Fourth Party Logistics) that added the strategic consulting based on new IT techniques to logistics outsourcing through existing 3PL service with is a great issue. Moreover, the customer enterprises which contained manufacturers and distributors need the one stop service, therefore a method for effectively dealing with global logistics' environment changes is needed. Above all, a development of the 4PL system with RFID is very urgent. We developed the RFID u-4PL system progressed more than the present system, in which we applied many international standards. Finally, we constructed the web service based on Web 2.0 because of important condition of 4PL.

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RFID를 적용한 u-4PL 시스템 개발에 관한 연구 (Feasibility and Validity of u-4PL(Fourth Party Logistics) System with RFID)

  • 나형석;이종석;이창호
    • 대한안전경영과학회지
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    • 제9권5호
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    • pp.87-95
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    • 2007
  • Logistics creates a boom in accordance with the recent new technique's development along with the recent RFID/USN of ubiquitous computing technique. The wave of 4PL(Fourth Party Logistics) that added the strategic consulting based on new IT techniques to logistics outsourcing through existing 3PL service with is a great issue. Moreover, the customer enterprises which contained manufacturers and distributors need the one stop service, therefore a method for effectively dealing with global logistics' environment changes is needed. Above all, a development of the 4PL system with RFID is very urgent. We developed the RFID u-4PL system progressed more than the present system, in which we applied many international standards. Finally, we constructed the web service based on Web 2.0 because of important condition of 4PL.

항공물류에 적용한 u-4PL 시스템 개발 연구 (A Study on Development of u-4PL Based Air Cargo Logistics System)

  • 이광수;나형석;이종석;이두용;이창호
    • 대한안전경영과학회:학술대회논문집
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    • 대한안전경영과학회 2008년도 추계학술대회
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    • pp.579-582
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    • 2008
  • The wave of 4PL added to strategic consulting based on new IT techniques, for example RFID, with logistics outsourcing through existing 3PL service is a great issue. It is also worthy of notice that EPCglobal network strengthen the role of 4PL. In conclusion, the 4PL system based on EPCglobal network will result in a good success, so it will raise a prestige of air cargo in Korea to a higher position. This study deals with the new logistics system, air cargo logistics system based on u-4PL system, RFID and EPCglobal network, that will bring many advantages.

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