Development of Synthetic Zeolites from Scoria for Pesticides Removal in the Golf Course

송이로부터 골프장 농약 제거를 위한 합성 제올라이트의 개발

  • Published : 2001.12.01

Abstract

Adsorption characteristics of triadimefon and diniconazole(pesticide) by natural zeolite($CLI_N$) and several synthetic zeolites were Investigated. The synthetic zeolites used En this study were as follows: Faujasite synthesized from coal fly ash($FAU_F$); Zeolite synthesized from the mixture of FAU and Na-Pl synthesized from the ratio of Cheju scoria 6 to coal fly ash 4 by weight($(FAU + Na-Pl)_{SF}$); waste fluid catalytic cracking catalyst($FCC_W$). The distribution coefficient, $K_D$ and Freundlich constant, $K_F$ decreased in the fellowing sequence : $FCC_W > FAU_F > (FAU + Na-Pl)_{SF} >CLI_N$ among the zeolites. The distribution coefficient and the adsorption capacity of $(FAU + Na-Pl)_{SF}$ for pesticides were 4.4 and 2.6 times higher for triamefon, and 2.0 and 2.4 times higher for diniconazole than those of $CLI_N$, respectively.

Keywords

References

  1. U.S. Bur. of Mines Rept. of Invest. v.7744 Properties of Natural Zeolites Munson, R.A.
  2. Zeolite Molecular Sieves Breck, D.W.
  3. ACS Sym. Ser. v.40 no.144 Molecular Sieves Ⅱ Schwager, M.I.;H.G. Smolka;J.R. Katzer(ed.)
  4. Proc. 5th Intern. Conf. Zeolites Kuhl, G.H.;H.S. Sherry;L.V.C. Reeds(ed.)
  5. Natural Zeolites Mumpton, F.;L.B. Sand;F. Mumpton(eds.)
  6. Min. Eng. v.42 no.6 Heavy metal sorption with clinoptilolite zeolite: Alternatives for treating contaminated soil and water Leppert, D.
  7. Sep. Sci. Technol. v.25 no.13-15 Removal of heavy metals and other cations from wastewater using zeolites Zamzow, M.Z.;B.R. Eichbaum;K.R. Sandgren;D.E. Shanks
  8. Desalination v.83 no.1-3 Chromium removal from water by ion exchange using zeolite Pansini, M.;C. Colella;M. Degennaro
  9. J. Environ. Sci. Health v.27 no.7 Natural zeolites and their ion exchange behavior towards chromium Loizidow, M.;K.J. Haralambous;A. Loukatos;D. Dimitrakopoulou
  10. Zh. Vses. Khim. O-va v.24 no.1 Industrial and hygienic cleaning of gases by an adsorption method Kel'tsev. N.V.
  11. Inquinamento v.22 no.5 Utilization of natural zeolites for pollutant removal in gaseous effluents. 1. Sulfur dioxide adsorption on chabazite tuff Aiello, R.;C. Colella;A. Di Lorenzo
  12. Langmuir v.9 no.9 Removal of nitrogen monoxide on copper ion-exchaned zeolites by pressure swing adsorption Zhang, W.X.;H. Yahifo;N. Mizuno;J. Izumi;M. Iwamoto
  13. 산학연 공동기술개발 지역컨소시엄사업 기술개발보고서 송이로부터 골프장 농약 제거를 위한 최적의 합성 제올라이트의 개발 김상규;안병준;이민규;박광열
  14. Adsorption, Surface Area and Porosity(2nd ed.) Gregg, S.J.;K.S.W. Sing
  15. Methods of Soil Analysis (2nd ed.) Chemical and Microbiological Properties Page, A.L.
  16. Can. Jour. Soil Sci v.54 Adsorption studies with the acid and dimethylamine forms of 2,4-D and dicamba Grover, J.;A.E. Smith
  17. Soil Sci. Soc. Am. J. v.38 Picloram sorption by soils Farmer, W.J.;Y. Aochi
  18. J. Environ. Qual. v.18 Sorption desorption of dicamba and 3,6-dichlorosalicylic acid in soils Murray, M.R.;J.K. Hall
  19. 북제주군 지역 기생화산(오름)에 관한 학술조사 보고서 윤정수
  20. Soil Sci. Soc. Amer. Proc. v.35 A kinetic and equilibrium study of the adsorption of carbaryl and parathion upon organic matter surfaces Leenheer, J.A.;J.L. Ahlrichs
  21. Soil Sci. Soc. Am. J. v.41 Adsorption of parathion, fenitrothion, methyl parathion, aminoparathion and paraoxon by Na+, Ca2+, and Fe3+ montmorillonite suspensions Bowman, B.T.;W.W. Sans
  22. Soil Sci. v.150 no.6 Taboada and F. Sanchex Rasero, Adsorption of cyanazine on peat and montmorillonite clay surfaces Cancela, G. D.;E. P. Taboada;F. Sanchex-Rasero
  23. Soil Science. v.152 no.4 Relationship between the structure of organophosphorus pesticides and adsorption by soil components Sanchez-Martin, M.J.;M. Sanchez Camazano
  24. Wat. Res. v.32 no.9 Adsorptive characteristics of ionogenic aromatic pesticides in water on powderd acrivated carbon Hu, J.Y.;T. Aizawa;Y. Ookubo;T. Morita;Y. Magara
  25. Weed Science v.25 no.2 Sorption, movement, and dissipation of tebuthiuron in soils Chang, S.S.;J.F. Stritzke
  26. Soil Sci. Soc. Am. J. v.44 Carbaryl adsorption on calcium bentonite and soils Aly, M.I.;N. Bakry;F. Kishk;A.H. El-Sebae
  27. Weed Sci. v.35 Adsorption of celective grass herbicides by soils and sediments Rick, S.K.;F. W. Slife;W.L. Banwart
  28. Soil Sci. v.155 no.2 Interactions of alachlor with homoionic mont morillonites Bosetto, M.;P. Arfaioli;P. Fusi
  29. Proc. of the Fourth Japan-Korea Symposim on Separation Technology v.2 Adsorption of pesticides in water on activated carbon Cheong, Y.E.;Y. Sudo;J.E. Sohn;M. Suzuki
  30. Pesticide Sci. v.50 Adsorption, desorption and mobility of four commonly used pesticides in Malaysian agricultural soils Cheah, U.B.;R.C. Kirkwood;K.Y. Lum
  31. Colloids & Surfaces v.164 The adsorption of phosphamidon on the surface of styrene supported zirconium(IV) tungstophosphate: a thermodynamic study Niwas, R.;U. Gupta;A.A. Khan;K.G. Varshney