• Title/Summary/Keyword: Na-Ca

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Evaluation of Groundwater Quality in Crystalline Bedrock Site for Disposal of Radioactive Waste (방사성폐기물 처분을 위한 결정질 기반암의 지하수 수질 평가)

  • Lee, Jeong-Hwan;Jung, Haeryong;Cheong, Jae-Yeol;Park, Joo-Wan;Yun, Si-Tae
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.12 no.4
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    • pp.275-286
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    • 2014
  • This study evaluated the evolution stage and origin of chemical components of 12 boreholes at crystalline bedrock using multivariate statistical and groundwater quality analyses. Groundwater types are mostly belonged to Na(Ca)-$HCO_3$ and Ca-$HCO_3$ types, indicating that directly reaction of cation exchange ($Ca^{2+}{\rightarrow}Na^+$) prevailed. The degree of groundwater evolution is included the range from low to intermediate stage based on field and laboratory analytical conditions. As a result of multivariate statistical analysis, a typical indicator of groundwater contamination, $NO_3$-, has the positive correlation with $Na^+$ and $Cl^-$. The origin of sea spary ($Cl^-$) has the positive correlation with $Na^+$, $SO{_4}^{2-}$, $Mg^{2+}$, and $K^+$, while not correlation with $Ca^{2+}$, $Fe^{2+}$, $HCO_3{^-}$, $F^-$, and $SiO_2$. The concentration of $Cl^-$ and $NO_3{^-}$ belongs to general quality of groundwater and not exceeds over the Korean standard for drinking water. And the negative values of saturation index of minerals are calculated with chemical components in groundwater. Therefore, most of chemical components of groundwater in the study area are originated from natural process between rock and groundwater, whereas some of components are derived from sea spary and anthropogenic sources related to agricultural activities.

Effect of First-Aid Drugs on Internal Contamination of Radiostrontium (방사성(放射性) 스트론듐의 체내오염(體內汚染)에 대한 응급처치제(應急處置劑)의 효과(效果))

  • Chung, In-Yong;Kim, Tae-Whan;Chin, Soo-Yil
    • Journal of Radiation Protection and Research
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    • v.14 no.1
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    • pp.16-23
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    • 1989
  • To obtain the basic data for protective roles and first-aid of radiation hazard, the present studies were carried out to evaluate the decontamination of radiostrontium by the First-Aid drugs. Each mouse was administered intraperitoneally dose of sodium alginate 5mg, $CaNa_3DTPA$ 8.4mg and saline 5ml following the internal contamination with 1 $\mu$Ci of strontium as $^{85}SrCl_2$. $^{85}Sr$ was determined by the radioactivity of body burden, urinary excretion, fecal excretion and organ distribution by Ge-detector and MCA. The results are summarized as follows. 1. Effective half life on whole body retention $^{85}Sr$ was determined at 33 hours. 2. The decontamination effect of First-Aid durgs on the body $^{85}Sr$ burden were increased $CaNa_3DTPA$ (4.7 times), sodium alginate (1.7 times) and saline (2.4 times) respectively. 3. Strontium were excreted through urine (35.4%), feces (64.4%) and other (0.2%). But on the $^{85}Sr$ excretion routes following First-Aid drugs treatment, strontium-85 mainly were excreted through urine after $CaNa_3DTPA$ and saline treatment, and was excreted through feces after sodium alginate treatment. 4. The organ distribution of strontium-85 is vertebra, femur, sternum and liver in order Finally, the extrapolations from these data to victims were suggested that the rapid administration of $CaNa_3DTPA$, sodium alginate and saline simultaneously were markedly increased the decontamination effects on the internal contamination of radiostrontium.

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Salts Requirement of Moderately Halophilic Bacterium, Kordia algicida gen. nov., sp. nov. (호염성세균, Kordia algicida gen. nov., sp. nov.의 염류요구특성)

  • Sohn Jae Hak
    • Korean Journal of Microbiology
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    • v.41 no.2
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    • pp.112-116
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    • 2005
  • Moderately halophilic bacterium, Kordia algicida gen. nov., sp. novo was isolated from seawater of Masan Bay, Korea, during algal blooming caused by Skeletonema costatum. This bacterium was grown on the ZoBell 2216e medium supplied aged seawater, but not grown the medium supplied $3\%$ NaCl. This bacterium showed absolute requirements for mono and divalent cations such as $Na^+,\;Mg^{2+}\;and\;Ca^{2+}$, since no growth was observed in the medium, which is not supplemented with one of $Na^+,\;Mg^{2+}\;and\;Ca^{2+}$ ions. In kinetic studies for three kinds of cation, Km values of $Na^+,\;Ca^{2+}\;and\;Mg^{2+}$ were determined to 0.202 M, 0.089 mM, and 0.189 mM, respectively. Also, $V_{max}({\mu}max)$ was 0.442 h, 0.411 hand 0.316 h. The bacterial cells were quickly lysed in the condition limited by the cations. This result should be suggested that Kordia algicida originated from marine.

Nutrient intake and Bone Minaral Density in Korean Premenopausal Women (폐경전 40대 한국 여성들의 영양 섭취 상태와 골밀도와의 관계)

  • 이종호;최미숙;백인경;문수재;임승길;안광진;이현철;송영득;허갑범
    • Journal of Nutrition and Health
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    • v.25 no.2
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    • pp.140-149
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    • 1992
  • It was hypothesized that variations within the range of usual calcium(Ca) and sodium(Na) intakes of Korean influence bone mineral density(BMD) in healthy premenopausal women The relationship of nutrient intake urinary excretion physical activity and circulating IGF-1 level with spine({{{{ { L}_{2 } }}}}-{{{{ { L}_{4 } }}}}) and femur BMD was determined in 47 normal premenpausal women. There was a positive relationship between BMD of the lumbar spine and body weight. The BMD of femoral neck was positively correlated with Ca and protein intakes from animal source and circulating IGF-1 level. There was a negative relationship between femur BMD and both Na intake and urinary excretion. The complex interrelations between femur BMD regression analysis, From this analysis. Ca intake from animal origin was the only significnat Premenopausal women of femur BMD. In the basis of femur BMD three groups were divided Premenopausal women of femur BMD$\leq$0.84g/cm2 showed depressed Ca intake of animal origin in later and early life and enhanced urinary Na excretion compared to women of femur study suggests that dietary Ca is a major constituent affecting femur BMD because of a decrease in net Ca absorption and an increase in urinary Ca loss.

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Addition Effects of Alkali Metal Oxide on Some Properties of Porous Glass-Ceramics in the $CaO-TiO_2-P_2O_5$ System ($CaO-TiO_2-P_2O_5$계 다공질 결정화 유리의 물성에 미치는 알카리 금속 산화물의 첨가효과)

  • 장순규;최세영
    • Journal of the Korean Ceramic Society
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    • v.31 no.11
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    • pp.1337-1345
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    • 1994
  • Glasses in the system of 45CaO-25TiO2-30P2O5 containing 1 mole% of M2O(M=Li, Na, K) were melted and crystallized. And their crystal phases were Ca3(PO4)2, CaTi4(PO4)6, and TiO2. Porous glass-ceramics with skeleton of two crystal phase CaTi4(PO4)6 and TiO2 were prepared by selective leaching of Ca3(PO4)2 with 0.1 N-HCl. Glass transition temperature(Tg) and crystallization temperature(Tc) were decreased by addition of 1 mole% alkali metal oxide. Pore size of porous glass-ceramics was increased with increasing heat treatment temperature and its dependence on heat treatment temperature was decreased with addition of Na2O and K2O. It was found that porous glass-ceramics of parent glass and containing 1mole% M2O(M=Li, Na, K) composition had maximum specific surface area, porosity and maximum of crystallzed phase by heat treatment at 80$0^{\circ}C$, 76$0^{\circ}C$, 78$0^{\circ}C$, 80$0^{\circ}C$ respectively.

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LIGHT DEPENDENT CHANNELS AND EXCHANGER IN THE INTERNAL LIMITING MEMBRANE OF VERTEBRATE EYE

  • Hyuk Jung;Kim, You-Young
    • Journal of Photoscience
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    • v.6 no.2
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    • pp.77-83
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    • 1999
  • Calcium has a variety of functions in neuron and muscle cells and blood clotting, especially in the visual system where dark adapted rods cotransport with Na$\^$+/ into the cell. An influx of Ca$\^$++/ flows out of the cell through the Na$\^$+/-Ca$\^$++/ exchanger. By using a modified Using chamber in order to bring in vivo environment close, we have known that Ca$\^$++/ blocks the activity of guanylate cyclase, in consequence, having an effect on the amplitude of electroretinogram (ERG). We have measured the Ca$\^$++/, K$\^$+/, and Na$\^$+/ concentration in dark and light adapted bullfrog's (Rana catesbeiana) vitreous humor. The calcium concentration of the light adapted bullfrog's vitreous humor was higher than that of the dark adapted bullfrog's vitreous humor This means that ion activity between the photoreceptor and vitreous humor side is light dependent and we have found that a Ca$\^$++/ channel and Ca$\^$++/K$\^$+/ exchanger exist in the vitreous humor side. Taken together permeability of Ca$\^$++/, K$\^$+/ and K$\^$+/ ion internal limiting membrane faced in the vitreous humor side has light-dependent activity during the illumination.

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Crystallization Mechanism of Slag-based Glass in $CaO-MgO-Al_2O_3-SiO_2(-Na_2O)$ System (Slag 위주의 $CaO-MgO-Al_2O_3-SiO_2(-Na_2O)$계 유리의 결정화 반응기구)

  • 장승현;정형진
    • Journal of the Korean Ceramic Society
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    • v.17 no.1
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    • pp.20-26
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    • 1980
  • The crystallization behaviors of slag-based glass in $CaO-MgO-Al_2O_3-SiO_2(-Na_2O)$ system have been studied. The mother glass containing 16.50 CaO, 7.50MgO, 19.70Al2O3, 50.80SiO3 and 2.09wt% $Na_2O$ was prepared by using Korean domestic raw materials such as granulated slag, serpentine, sea sand and etc. The glass-ceramics composed of major crystalline phase diopside was produced by the heat treatment in a temperature range from 850$^{\circ}$ to 9$25^{\circ}C$ for 0-6hr. The composition and morphology of diopside phase formed in the system were examined by X-ray diffraction analysis and electron microscopy. The kinetic measurements such as J.M. A plot and Arrhenius plot indicated that the process of nucleation of the initially formed diopside phase could be described from the view point of instantaneous nucleation. It was also demonstrated that the linear crystal growth of diopside phase was proceeded by short range diffusion of $Mg^{2+}$ and $Ca^{2+}$ ion. The microstructures of the resulting glass-ceramics were consisted of leafroidal shaped crystalline aggregations.

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Crystal Structures of Bromine Sorption Complexes of $Ca^{2+}$-Exchanged Zeolite A

  • 장세복;송성환;김양
    • Bulletin of the Korean Chemical Society
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    • v.16 no.12
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    • pp.1163-1167
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    • 1995
  • The structures of dehydrated Ca4Na4-A (a=12.243(1) Å) and of its bromine sorption complex (a=12.214(1) Å) have been determined by single crystal x-ray diffraction techniques in the cubic space groupPm&bar{3}m at 21(1) ℃. Both crystals were dehydrated at 360 ℃ and 2 X 10-3 Torr for 2 days and one crystal was treated with 180 Torr of bromine vapor at 24 ℃ for 1 h. The structures were refined to final error indices, R1=0.066 and R2=0.078 with 192 reflections and R1=0.109 and R2=0.093 with 100 reflections, respectively, for which I>3σ(I). In these structures, four Ca2+ and four Na+ ions are located on two different threefold axes associated with 6-ring oxygens, respectively. In Ca4Na4-A·6Br2, four Ca2+ ions are recessed 0.28(1) Å into the large cavity and four Na+ ions extend 0.63(1) Å into the sodalite unit. A total of six dibromine molecules are sorbed per unit cell. Each Br2 molecule approaches a framework oxide ion axially with O(1)-Br(1)=3.27(2) Å Br(1)-Br(2)=2.66(6) Å and O(1)-Br(1)-Br(2)=172(1)°, indicating a charge-transfer interaction.

Studies on Transport Mechanisms of Turtle Bladder I . Epithelium of Urinary Bladder (Turtle bladder의 수송기작(輸送機作)에 관한 연구 : I. 방광(膀胱)의 상피조직(上皮組織))

  • Jeon, Jin-Seok
    • Applied Microscopy
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    • v.19 no.2
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    • pp.119-137
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    • 1989
  • It has been shown in this and earlier investigation that the turtle bladder mucosa has three main cell types on their mucosal surface. They are the granular cells, ${\alpha}$ CA cells, and ${\beta}$ CA cells. The three major transport mechanisms that occurs in the turtle bladder are sodium reabsorption, proton secretion, and bicarbonate secretion. In the present work the trans-port mechanisms by bladder epithelial cells of freshwater turtle, Pseudemys scripta, are summarized as follows. 1. The granular cells play an important role in sodium transport, while the ${\alpha}$ and ${\beta}$ CA cells do not appear to play a determining role in sodium transport. 2. It appears that the active sodium transport in the granular cells occurs in two-step process, implying that first, sodium diffuses into the cells, followed by an energy-dependent efflux step, which is catalyzed by the ouabain-sensitive Na-K ATPase. 3. The ${\alpha}$ type of CA cells are responsible for the proton secretion using the proton pump on the apical plasma membrane, while the ${\beta}$ type of CA cells are believed to be responsible for bicarbonate secretion. 4. When looked at under freeze-fracture electron microscopy, the apical plasma membrane of ${\alpha}$ cells have a characteristic population of rod-shaped intramembranous particles which are believed to be components of the proton pumps. Conversely, ${\beta}$ type of CA cells show rod-shaped particles in their basolateral plasma membranes, which is consistent with the proton absorptive, bicarbonate secretory mechanism. 5. In the turtle bladder, the ${\alpha}$ and ${\beta}$ type of cells are believed to be both responsible for proton transport, but in opposite directions.

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Geochemical Characteristics of Geothermal Water and Groundwater in the Dongrae Hot-Spring Area (동래온천지역의 지열수와 지하수의 지화학적 특성)

  • Suck Jong Han;Se-Yeong Hamm;Ig Hwan Sung;Byeong Dae Lee;Byong Wook Cho;Myong Hee Cho
    • The Journal of Engineering Geology
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    • v.9 no.3
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    • pp.207-225
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    • 1999
  • Twenty water samples (eleven groundwater and nine geothermal water samples) were collected to elucidate hydrogeochemical characteristics of the groundwater and geothermal water in the Dongrae hot-spring area and its vicinity. Major and minor elements were analyzed for ground and geothermal water samples. Physicochemical properties of the groundwater and the geothermal water were examined and chemical composition of the two waters were compared. Factor and correlation analyses were carried out to simplify the physicochemical data into grouping some factors and to find interaction between them. The groundwaters belong to $Ca-HCO_3$ type, while the geothermal waters belong to Na-Cl type. The Na and Cl concentrations in the Dongrae hot-spring area are higher than those of other granite areas in South Korea. The Na/Cl weight ratio ranges from 0.7 to 1.3 for the geothermal waters. On the phase stability diagram groundwaters fall effectively in the field of stability of kaolinite, while geothermal waters fall in the stability field of microcline or kolinite depending on the chemical composition system. Based on the Na-K, Na-K-Ca and Na-K-Ca-Mg geothermometers, the geothermal reservoir is estimated to have equilibrium temperature between 115 and $145^{\circ}C$.

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