• Journal of the Mineralogical Society of Korea
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• v.15 no.4
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• pp.243-257
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• 2002

Ca-type and Na-type bentonites show the great difference of some physicochemical properties. Na exchanged bentonite is mainly used for the foundry and construction materials in domestic utilization. This study tries to identify in detail the differences of some physicochemical properties and thermal properties between Ca-type and Na-type bentonites. Also the adsorption behavior and interlayer expansion for the HDTMA (Hexadecyltrimethylammonium) exchanged and CP (Cetylprydinium) exchanged Ca-type and Na-type bentonites were compared. Na-type bentonite shows the strong alkaline property, high viscosity and swelling compared to Ca-type bentonite. However, two types are very similar for the cation exchange capacity and MB (Methylene Blue) adsorption. The decomposition of adsorbed and interlayer water of Na-type bentonite is caused in the lower temperature than Ca-type bentonite. And Ca-type bentonite shows the decomposition of structural water in the lower temperature than Na-type bentonite. The interlayer expansion of montmorillonite resulted to the intercalation of HDTMA and CP into bentonite is so strongly caused from 12～15 $\AA$ to $40\AA$ (basal spacing). HDTMA-bentonite is almost expanded to $37～38\AA$ when 200% CEC equivalent amount of HDTMA is added, and CP-bentonite is fullly expanded to 40 $\AA$ in the 140% CEC equivalent amount of CP It means that CP causes the stronger interlayer expansion of montmorillonite and easier adsorption than HDTMA. Adsorption behaviors of CP into bentonite is so stable and continuously sorbed in the proportion to the treatment of amount until 200% of the CEC equivalents. CP-bentonite shows the same adsorption behavior regardless of Ca-type or Na-type montmorillonite.

• Korean Journal of Optics and Photonics
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• v.34 no.6
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• pp.248-260
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• 2023

A 0.5-numerical-aperture (NA) refractive-reflective objective, composed of a low-NA refractive and a reflective focal reducer, is designed. A 0.25-NA Lister objective is used for the refractive. A two-spherical-mirror system, corrected for spherical aberration, coma, and astigmatism is used for the reflective focal reducer. In spite of high NA, the refractive-reflective objective has an 18-mm working distance and improved imaging performance, compared to the 0.25-NA Lister objective.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 2004.04a
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• pp.384-387
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• 2004

강원도 지역 탄산수에 대해 혼합에 의한 용존 희유원소의 거동특성 및 탄산염 침전물 형성에 따른 REE 분별작용을 살펴보았다. 탄산수들은 화학적으로 $Na-HCO_3형,\; Ca-Na-HCO_3형\; 및\; Ca-HCO_3$형으로 구분되며, 동위원소조성도 유형에 따라 명확히 구분되는 특징을 보인다. 지화학 및 동위원소 자료의 해석 결과, $Na-HCO_$형 탄산수는 지하심부에서 심부 기원 $CO_2$의 공급에 의해 형성된 반면, 다른 두 유형의 탄산수들은 $Na-HCO_$ 형 탄산수와 천부지하수 간의 혼합에 의해 생성되었음을 지시하였다. 탄산수 내 용존 REE 함량은 물 유형에 따라 변화하지만, ∑REE 함량은 TDS, pH, alkalinity, $\delta^{18}O$$\delta^{18}O$ 및 tritium 함량과 좋은 상관성을 보여주어, 천부 지하수와의 혼합된 특징을 나타내었다. Na-HCO$_3$형 탄산수의 용존 REE 패턴은 강한 HREE 부화를 보여주어 이른바 'S-shape'을 나타내는 반면, $Na-HCO_$ 형은 분산되어 있으며 LREE 부화를 보여주었다. $Ca-Na-HCO_3$형은 약한 HREE 분화 패턴을 보여주었다. 탄산수로부터 침전된 침전물과 침전물을 제거한 잔류물의 REE 패턴은 원 탄산수와 거의 유사한 형태를 보여주어, 탄산염 침전물과 잔류물 간의 REE 분별작용은 일어나지 않았음을 나타낸다.지 않았음을 나타낸다.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 2003.09a
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• pp.520-523
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• 2003

강원도 지역의 대표적인 탄산용출수에 대한 수리지구화학적 연구를 통하여 심부 지열 저장지의 온도와 심부환경을 추정하였다. 탄산용출수는 공통적으로 약산성의 pH와 높은 이온함량으로 특징되지만, 화학적으로는 Na-HCO$_3$형, Ca-Na-HCO$_3$형, 그리고 Ca-HCO$_3$형으로 뚜렷이 구분된다. 심부에서 생성된 탄산용출수가 지표로 상승하는 도중에 수반된 지표수 혼합차이로 인해 이런 화학조성의 차이가 유발된 것으로 판단된다. Na-HCO$_3$형 탄산수는 화학 조성상 ‘mature water’의 특징을 보여주는 반면, 다른 두 유형의 탄산수들은 ‘immature water’에 해당하였다. Na-HCO$_3$ 형 탄산수에 대하여 실리카, Na-K 및 Na-K-Ca 지온계를 적용한 결과, 약 l15-157도의 심부저장지 온도가 산출되었으며, 이 결과는 다성분 평형계를 이용한 추정 온도 (약 140-160도)와도 잘 일치하였다. 반면, Ca-HCO$_3$ 형 탄산수들은 지표수와의 혼합 때문에 상대적으로 낮고 넓은 범위의 추정 온도 (약 60-130도)를 나타내었다. 따라서 연구지역 내 탄산용출수의 심부저장지 온도는 Na-HCO$_3$형에 대해서만 타당하게 적용될 수 있으며, 약 140-160도일 것으로 추정된다.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2012.05a
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• pp.149-152
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• 2012

This paper describes the study of integrated hydrogen supply system for environment friendly propulsion systems of fuel-cell UAV. Diluted hydrochloric acid was used for direct-decomposing solid-state $NaBH_4$ and generating hydrogen. Self-hydrogen pressurized reactor and pressure regulator was introduced for stable hydrogen supply. Prototype of integrated hydrogen supply systems using the solid-state $NaBH_4$ direct-decomposition was designed for performance evaluation and concept demonstration.

• Applied Biological Chemistry
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• v.9
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• pp.153-159
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• 1968

In this paper the auther investigated the chemical properties, process of humification and type of humic acid in soils which were reclaimed by farming for cultivation in Kangwondo. The results obtained in this studies were summarized as follows: 1. General chemical components of these soil were similar to the ordinary soil but C.E.C. and humus contents were found much more 2. Humic acid and fulvic acid which were extracted with NaOH from soil were greater than those of Na-pyrophosphate(Na-p.) and NaF. Hmus contents and PQ% were increased much more in the upper layer than in the lower layer. 3. Degree of humification of humic acid extracted with NaOH. was very similar to those extracted with Na-pyrophosphate. Humification degree of humic acid extracted with NaF was lower than humic acid which were extracted with NaOH and Na-pyrophosphate. But humification degree of humic acid extracted with NaOH was similar to that with Na-pyrophosphate. Humic acid in B soil and the upper layer was higher than A, C soil and the lower layer of soil, in humification degree. 4. Humic acids extracted with NaOH and Na-pyrophosphate from soil were fractionated by Mg into two parts ${\alpha}$ type and ${\beta}$ type humic acid. Humic acids of ${\alpha}$ and ${\beta}$ type extracted with NaOH were higher than these of Na-pyrophosphate in humification degree. In this soil the humification degree of humic acid was not changed during the period of cultivation. 5. ${\alpha}$, ${\beta}$ type humic acid extracted with NaOH were very similar to the humic acid extracted with Na-pyrophosphate in shapes of absorption curves.

• Journal of the Korean Chemical Society
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• v.30 no.5
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• pp.488-492
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• 1986

The $Ca^{++}$ and $Mg^{++}$ released during Ca, Mg-Na exchange on Kampo 78 montmorillonite which was treated with various concentrations of NaCl solution, were measured with EDTA titration metbod in the leaching solutions. Lanthanide montmorillonite was prepared with various neutral lanthanide ions from sodium montmorillonite in which the exchangeable ions are displaced from the exchanger, such as the displacement of $Na^+$ by $Ln^{3+}$ ions, Cation exchange capacity (CEC) is determined on remaining lanthanides in the leaching solutions with E. D. T. A titration method. As a results of this study, there were no difference of C. E. C in series of lanthanide contraction, but C. E. C depends on charge density of montmorillonite. When we conformed the structure of Ln-montmorillonite by X-ray diffraction. It was found that there was much difference of pattern between Na-montmorillonite and Ln-montmorillonite.

• Korean Journal of Optics and Photonics
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• v.12 no.4
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• pp.320-326
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• 2001

In this paper, we have fabricated asymmetric Y-branch optical power splitters with various optical power splitting ratios by changing the width of one of the output waveguides using $Ag^+-Na^+$ ion change method in BK7 glass. The transmission characteristics of asymmetric Y-branch optical power splitters with different output waveguide width have been investigated using the finitedifference beam propagation method (FD-BPM). We have found the index of the channel waveguide formed by Ag+-Na+ ion change method in BK7 glass and have fabricated channel waveguides to examine the transmission characteristics of channel waveguide. And we have fabricated asymmetric Y-branch optical power splitters with output waveguide width from TEX>$4{\mu}m$ to $6{\mu}m$. /TEX>.

• Applied Chemistry for Engineering
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• v.21 no.3
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• pp.301-305
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• 2010

In this study, the alkaline degreasing agent was developed for electroplating pretreatment process, and the efficiency and the durability was predicted. The alkaline deeping degreasing agent was prepared by blending sodium hydroxide (NaOH), sodium carbonate ($Na_2CO_3$), sodium silicate ($Na_2SiO_3$), and sodium lauric sulfate (SLS). The performance tests of the degreasing agent were evaluated in the $40{\sim}50^{\circ}C$ of the degreasing temperature and 30~40 min of the degreasing time. The efficiency and durability of the prepared degreasing agent were tested by the waterdrop formation test and Hull-cell plating test. The optimum ratio of alkaline degreasing agent was NaOH (30 g/L) + SLS (6.0 g/L) + $Na_2SiO_3$ (2.0 g/L) + $Na_2CO_3$ (40 g/L). Also, the optimum degreasing conditions were $50^{\circ}C$ of the degreasing temperature and 35 min of the degreasing time.

• Journal of the Korean Society of Groundwater Environment
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• v.7 no.2
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• pp.73-88
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• 2000

The geochemistry of the $CO_2$-rich waters ($Pco_2\leq$about 1 atm) in NE part of the Kangwon province was investigated. The $CO_2$-rich waters can be divided to three types based on chemical compositions: Na-$HCO_3$, Ca-Na-$HCO_3$and Ca-$HCO_3$types. The water chemistry indicates that these type waters were evolved through reaction with host rocks by supply of deep-seated $CO_2$during deep circulation, and their geochemical environments in depth might have been different each other. The dissolution process of plagioclase is important in water/granite interactions and its solubility change according to reaction temperature played an important role in the determination of chemical compositions. The higher reaction temperature coincides with the lower different in solubility between albite and anorthite. It means that calcium is mainly released to the water in the lower temperature, whereas sodium in the higher temperature due to high Na/Ca ratio in plagioclase. The application of various chemical geothermometries on the $CO_2$-rich waters shows that the calculated reservoir temperature of Na-$HCO_3$type (about 15$0^{\circ}C$) is higher than those of Ca-$HCO_3$type. Therefore, we now interpret the recognized chemical difference was mainly due to the difference of reaction temperature. Considering normal thermal gradient, we can understand that the Na-$HCO_3$type was evolved from deeper crustal depth than the Ca-$HCO_3$type.