• Title/Summary/Keyword: Na content

Search Result 3,063, Processing Time 0.032 seconds

Relationships between dielectric properties and characteristics of impregnated and activated samples of potassium carbonate-and sodium hydroxide-modified palm kernel shell for microwave- assisted activation

  • Alias, Norulaina;Zaini, Muhammad Abbas Ahmad;Kamaruddin, Mohd Johari
    • Carbon letters
    • /
    • v.24
    • /
    • pp.62-72
    • /
    • 2017
  • The aim of this work was to evaluate the dielectric properties of impregnated and activated palm kernel shells (PKSs) samples using two activating agents, potassium carbonate ($K_2CO_3$) and sodium hydroxide (NaOH), at three impregnation ratios. The materials were characterized by moisture content, carbon content, ash content, thermal profile and functional groups. The dielectric properties were examined using an open-ended coaxial probe method at various microwave frequencies (1-6 GHz) and temperatures (25, 35, and $45^{\circ}C$). The results show that the dielectric properties varied with frequency, temperature, moisture content, carbon content and mass ratio of the ionic solids. PKSK1.75 (PKS impregnated with $K_2CO_3$ at a mass ratio of 1.75) and PKSN1.5 (PKS impregnated with NaOH at a mass ratio of 1.5) exhibited a high loss tangent ($tan{\delta}$) indicating the effectiveness of these materials to be heated by microwaves. $K_2CO_3$ and NaOH can act as a microwave absorber to enhance the efficiency of microwave heating for low loss PKSs. Materials with a high moisture content exhibit a high loss tangent but low penetration depth. The interplay of multiple operating frequencies is suggested to promote better microwave heating by considering the changes in the materials characteristics.

Some Factors Effect on the Detergency of Triglyceride (Triglyceride의 세척성에 영향을 미치는 몇가지 요인)

  • Lee Mee Sik;Kim Sung Reon
    • Journal of the Korean Society of Clothing and Textiles
    • /
    • v.5 no.1
    • /
    • pp.15-21
    • /
    • 1981
  • The effect of fatty acid content in oily soil and conditions of washing on the removal of triglyceride have been studied. Cotton lawn was soiled with the four-component soil-tripalmitin, palmitic acid, dodecyl alcohol and dodecane-and washed in constant temperature waterbath shaker. The detergency was estimated by analysis of triglyceride labelled carbon-14 on fabrics before and after washing by means of liquid scintillation counting. It was shown that the detergency of triglyceride washed with the nonionic, nonylphenol poly (10)-ethylene oxide and soap was increased steadily with increasing temperature, whereas with the anionics Na-DBS and SLS, the detergency was rather decreased when the temperature was elevated above $40^{\circ}C$. To investigate the effects of free fatty acid content in soil on the removal of triglyceride, the fabrics were soiled altering palmitic acid content, and then washed. From the results, the detergency of triglyceride was developed with increasing free fatty acid content. With soils containing less than $30\%$ of free fatty acid, of the three detergents tested, the nonionic was by far the most effective soil removal. Soap was intermediate and the synthetic anionic was the poorest. With soil containing $45\%$ of free fatty acid, soap was the most effective soil removal. When NaOH was added to detergent solution. the detergency of triglyceride was improved without regard to detergents. The optimum alkalinity was obtained according to free fatty acid content. And the alkalinity changed to low NaOH concentration with increasing free fatty acid content. From the results mentioned above, it could be concluded that the major removal mechanisms of triglyceride containing oily soil were mesomorphic phase formation, solubilization and soap forma-tion when alkali was added in detergent solution.

  • PDF

The Effects of Dietary Supplementation of Feather Meal Digests on the Performances and Muscular Taurine Contents in Broiler Chickens (육계 사료내 우모 Digest 첨가시 생산성과 계육내 Taurine 함량에 미치는 영향)

  • Lee, S.M.;Lim, H.S.;Kim, W.Y.;Paik, I.K.
    • Journal of Animal Science and Technology
    • /
    • v.46 no.5
    • /
    • pp.753-762
    • /
    • 2004
  • its digests on the performance of broiler chicks and taurine content in broiler meat. A total of 100 broiler chickens were assigned to five dietary treatments; Control, PM diet(FM), NaOH treated FM diet(NaOH-FM), HN03 treated FM diet(HN03 - FM) and 0.5% synthetic taurine supplemented diet(Taurine). Treated diets were supplemented with FM or FM digests at the level of 5% to the control diet Treated diets were fed during the last 3wks of 6wks feeding. During the finisher period, weight gain of chicks fed FM treatments tended to decrease in general. Feed intakes of FM and Taurine were significantly lower than the control but were not significantly different from NaOH - FM or HN03- PM. Feed conversion rate(feed intake/gain) of NaOH-FM was significantly higher than those of FM and HNOJ - FM but not different from those of the control and Taurine. Taurine content of the control was highest in heart muscle(1482 J1.g/g) followed by leg muscle(778f.lg/g) and breast muscle(79 J1.g/g). Taurine contents of leg and breast muscle were significantly(P< 0.01) affected by treatments but that of heart muscle was not. Taurine content of Taurine treatments was highest in both leg and breast muscle. Taurine content of leg muscle was increased 170"10 by Taurine supplementation, 123% by FM supplementation, 122% by NaOH - FM supplementation and 63% by HNOJ- FM supplementation compared with control. Taurine content of breast muscle of Taurine treatment was 246% higher than the control, but other treatments were not different from the control. In conclusion, supplementation of feather meal at 5% level of broiler diet can enrich taurine content of leg muscle. Chemical treatments of FM were not effective in improving taurine enrichment of broiler meat.

Effect of High Concentrations of Sodium or Chloride Salts in Soil on the Growth of and Mineral Uptake by Tomatoes (토양에의 고농도 Na 및 Cl 염류가 토마토의 생육 및 무기성분 흡수에 미치는 영향)

  • 강경희;권기범;최영하;김회태;이한철
    • Journal of Bio-Environment Control
    • /
    • v.11 no.3
    • /
    • pp.121-126
    • /
    • 2002
  • This study was conducted to investigate the effect of high concentration of sodium salts and chlorides in soil on the growth of tomato and the uptake of minerals. The growth inhibition rates of plant height and dry weight were different depending on salts, but they were not related to the electric conductivities (EC) and acidities (pH) in the soil solution. The orders of growth inhibition were Cl, SO$_4$, CO$_3$, PO$_4$>NO$_3$ in the sodium salts series, and Na, K, Mg, NH$_4$>Ca in the chlorides. The growth inhibition rates of the sodium salts series tended to be larger than those of the chloride series. Yield was lower 30%~10% in the sodium salt and chloride series than in the control. Chlorophyll content, photosynthetic rate and stomatal conductance were lower in the sodium salts and chloride series than in the control. Mineral concentration was lower in sodium salts and chlorides than in control. The nitrate absorption was inhibited in all salts except for NaNO$_3$ and NH$_4$Cl, and specially in NaCl and Na$_2$SO$_4$ treatments of the sodium salts and in KCl treatment of chloride series. K concentration was reduced NaCl and Na$_2$SO$_4$ treatments compared with the other salts. In the sodium salt series, calcium and magnesium concentration were decreased antagonistically when sodium concentration was increased.

Separation of $H_2$ and $N_2$ Gases by PTMSP-NaY Zeolite Composite Membranes (PTMSP-NaY Zeolite 복합막에 의한 수소-질소 기체 분리에 관한 연구)

  • Kim, Ok-Su;Hong, Se Ryeong
    • Membrane Journal
    • /
    • v.24 no.4
    • /
    • pp.285-291
    • /
    • 2014
  • The PTMSP[Poly(1-trimethylsilyl-1-propyne)]-NaY zeolite composite membranes were prepared by adding 0~50 wt% NaY zeolite to PTMSP. In order to investigate the characteristics of these membranes, we used the analytical methods such as FT-IR, $^1H$-NMR, GPC, DSC, TGA, and SEM. Gas permeation experiments were carried out at $23{\sim}26^{\circ}C$, $2kgf/cm^2$, and the permselectivity of $H_2$ and $N_2$ gases through the composite membranes was studied as a function of the NaY zeolite contents. According to TGA measurements, when NaY zeolite was inserted within the PTMSP, thermal stability of PTMSP was enhanced. Based on SEM observation, NaY zeolite was dispersed in the PTMSP-NaY zeolite composite membrane with a size of $1.5{\mu}m$. The permeability of $H_2$ and $N_2$ through the PTMSP-NaY zeolite composite membranes increased as NaY zeolite content increased. On the contrary, the selectivity($H_2/N_2$) of the PTMSP-NaY zeolite composite membranes decreased as zeolite content increased.

Variation of Critical Chloride Content of Rebar Embedded in Concrete with Admixture (혼화재 혼입에 따른 콘크리트에 매립된 철근의 부식 임계 염화물량의 변화)

  • Park, Jang-Hyun;Lee, Yun-Su;Lee, Han-Seung
    • Journal of the Korea Institute of Building Construction
    • /
    • v.19 no.6
    • /
    • pp.511-520
    • /
    • 2019
  • The critical chloride content of rebar embedded in concrete was experimentally evaluated according to the admixture replacement ratio and admixture type. Four types of reinforced concrete were mixed OPC 100%, OPC 70% + GGBFS 30%, OPC 40% + GGBFS 60%, and OPC 40% + GGBFS 40% + FA 20%. NaCl solution was supplied to the specimens, and the open circuit potential of the embedded rebar was monitored. The specimens determined to initiate corrosion were cut at intervals of 5mm from the NaCl solution supply surface and conducted to chlorine ion profile. Corrosion initiation time of rebar embedded in concrete was delayed as the admixture replacement ratio increased. Looking at the critical chloride content of the types of reinforced concrete, it was highest in OPC 1.46kg/㎥, followed in order by S30 0.98kg/㎥, TBC 0.74kg/㎥, and S60 0.71kg/㎥.

Removal of Chlorine from Fly Ash in Municipal Solid Waste Incineration Ash by Water Washing (수세에 의한 생활폐기물 소각재 중 비산재로부터 염소성분의 제거)

  • 안지환;한기천;김형석
    • Resources Recycling
    • /
    • v.10 no.5
    • /
    • pp.36-43
    • /
    • 2001
  • The chlorine component in fly ash from municipal solid waste incineration ash was removed by water washing for the purpose of recycling fly ash as a raw material of ordinary portland cement. The samples were a different kind of 리y ashes using $Ca(OH)_2$and NaOH as media of wet scrubber for flue gas cleaning. The content of soluble salts of fly ash using $Ca(OH)_2$and NaOH was 32.8%, 50.1% and the content of chlorine component, 22.9% and 26.0% respectively, which was KCl, NaCl, CaC1OH mainly. When each fly ash was washed using water under conditions of a agitation speed of 300 rpm, a liquid to solid ratio of 10, most soluble salts in fly ash were dissolved within 30 minutes and the content of chlorine component in ash was diminished to the content of 4.4%, 2.O% at $20^{\circ}C$ and 1.7%, 0.8% at $50^{\circ}C$ respectively. And the main compound of residual chlorine component in ash after water washing was friedel`s salt ($3CaO.A1_2$$O_3$.$CaCl_2$.$10H2$O). From analysis results of water quality for wastewater by water washing, the components exceeding discharged wastewater standard were only Pb and Cd. But As pH was controlled to 10 with addition of $CO_2$(g) or $Na_2$$_CO3$in water, the concentration of heavy metals such as Pb and Cd was also under discharged wastewater standard.

  • PDF

Alkali activated ceramic waste with or without two different calcium sources

  • Zedan, Sayieda R.;Mohamed, Maha R.;Ahmed, Doaa A.;Mohammed, Aya H.
    • Advances in materials Research
    • /
    • v.4 no.3
    • /
    • pp.133-144
    • /
    • 2015
  • The aim of this investigation is to prepare geopolymer resin by alkali activation of ceramic waste (AACW) with different sodium hydroxide (NaOH) and liquid sodium silicate (LSS) concentrations. In order to prepare geopolymer cement, AACW was replaced by 10 and 30 % by weight (wt.,) of concrete waste (CoW) as well as 10 and 30 wt., % ground granulated blast-furnace slag (GGBFS). The results showed that, the compressive strength of AACW increases with the increase of activator content up to 15:15 wt., % NaOH: LSS. All AACW hardened specimens activated by 3:3 (MC6), 6:6 (MC12), 12:12 (MC24) and 15:15 wt., % (MC30) NaOH: LSS destroyed when cured in water for 24h. The MC18 mix showed higher resistivity to water curing. The results also showed that, the replacement of AACW containing 9:9 wt., % NaOH: LSS (MC18) by 10 (MCCo10) and 30 (MCCo30) wt., % CoWdecreased the compressive strength at all ages of curing. In contrast, the MCCo10 mix showed the lower chemically combined water content compared to MC18 mix. The MCCo30 mix showed the higher chemically combined water content compared to MC18 and MCCo10 mixes. The compressive strength and chemically combined water of all AACWmixes containing GGBFS (MCS10 and MCS30) were higher than those of AACWwith no GGBFS (MC18). As the amount of GGBFS content increases the chemically combined water increases. The x-ray diffraction (XRD) proved that as the amount of CoWcontent increases, the degree of crystallinity increases. Conversely, the replacement of AACW by GGBFS leads to increase the amorphiticity character. The infrared spectroscopy (FTIR) confirms the higher reactivity of GGBFS compared to CoW as a result of successive hydration products formation, enhancing the compaction of microstructure as observed in scanning electron microscopy (SEM).

A Study on the Mineral Contents of Dolwoe Tea(Gynostemma pentaphyllum Makino) (돌외차(Gynostemma pentaphyllum Makino)의 무기성분에 관한 연구)

  • Park, Young-Hee;Hong, Youn-Ho;Park, Won-Ki
    • Journal of the Korean Society of Food Science and Nutrition
    • /
    • v.16 no.2
    • /
    • pp.105-109
    • /
    • 1987
  • The mineral content of Dolowe, which were prepared in the laboratory and marketed Korean products of Dolwoe, Japanese product of Dolwoe and Korean-roasted products of Dolwoe were analysed and compared. Dolwoe-leaf tea had high mineral content of Ca, Mg, Mn and Cu, while Dolwone-stem tea had high mineral content of K, Na and Fe. Especially in the ash of Dolwoe-stem tea showed the highest mineral content of K (33.4%) Dolwoe teas were extracted for 5 minutes as ratio of $1,000m{\ell}$ boiling water to 4g Dolwoe tea (250: 1, v/w). Comparing the ratio of extraction of minerals in Dolwoe tea made by us and marketed Dolwoe products, K was the most abundant element of all extractions with the rate of $83.2%{\sim}96.3%$ followed by Mg with $44.8%{\sim}62.2%$, Ca with $23.1%{\sim}64.4%$ and Na with $6.3%{\sim}55.6%$. On the other hand Mn, Fe and Cu were extracted in extremely small quantities.

  • PDF

Electrochemical Desalination of a 50% w/w Sodium Hydroxide Solution, a Pharmaceutical Sterilization Agent

  • Jaehong Lee;Ji-hyun Yang;Eugene Huh;Sewon Park;Bonmoo Koo;Ik-Sung Ahn
    • Journal of Electrochemical Science and Technology
    • /
    • v.14 no.1
    • /
    • pp.59-65
    • /
    • 2023
  • Sodium hydroxide solutions are often employed as sterilization agents in the pharmaceutical industry. Here, the chloride content is considered as a critical impurity. In this study, an electrochemical method was developed to remove chloride ions (Cl-) through the oxidative deposition of AgCl on a Ag anode. The Cl- content in the commercially available 50% w/w NaOH solution employed was approximately 100 mg Cl-/kg NaOH. As the OH- content is approximately 18,000 times higher than the Cl- content, the formation of AgCl may be expected to be thermodynamically less favorable than the formation of Ag2O. However, activation energies for AgCl and Ag2O formation have been reported to be approximately 3.8 and 31.2 kJ/mol, respectively, and indicate that AgCl formation is favored. AgCl can be selectively produced by controlling the anode potential. Here, the Cl- concentration was reduced to less than 50 mg Cl-/kg NaOH when an anode potential of 0.18 or 0.19 V vs. Hg/HgO (reference electrode) was applied for one hour at 50℃. XRD analysis and visual monitoring of the Ag anode confirmed the oxidative deposition of AgCl on the anode surface as well as the electrochemical desalination of the concentrated NaOH solution.