• Korean Journal of Materials Research
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• v.2 no.5
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• pp.330-336
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• 1992

Four distinctive hot pressed and heat treated S${i_3}{N_4}$ceramics, S${i_3}{N_4}$-8%${Y_2}{O_3}$, S${i_3}{N_4}$-6% ${Y_2}{O_3}$-2% $A{l_2}{O_3}$, S${i_3}{N_4}$-4% ${Y_2}{O_3}$-3% $A{l_2}{O_3}$, 그리고 S${i_3}{N_4}$-1% MgO-1% Si$O_2$(in wt%), were prepared and characterized by X-ray diffraction, scanning electron microscopy, image analysis and mechanical tests. The fracture toughness of S${i_3}{N_4}$-8% ${Y_2}{O_3}$specimens containing large elongated grains showed the highest value of about 9.8MPa$m^{1/2}$. Two out of four S${i_3}{N_4}$, ceramics(S${i_3}{N_4}$-6% ${Y_2}{O_3}$-2% $A{l_2}{O_3}$and S${i_3}{N_4}$-4% ${Y_2}{O_3}$-3% $A{l_2}{O_3}$) heat treated at 200 $0^{\circ}C$retained the fracture strength of over 900MPa and fracture toughness of over 8.0MPa$m^{1/2}$. Large ${\beta}$-S${i_3}{N_4}$grains having a diameter larger than 1${\mu}$m appeared to contribute to increase in fracture toughness.

• Korean journal of applied entomology
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• v.59 no.3
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• pp.243-250
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• 2020

Two meridic diets, N4 and N6, containing pinto bean, wheat germ, soybean, whole milk and sucrose as main nutrients were developed for rearing Spodoptera frugiperda (Noctuidae) larvae. Six larval instars were observed when neonate larvae were individually raised on these diets in small petri-dishes (ø 50 × 10 mm, 19.6 ㎤) at 25℃ and 15:9 h (light:dark) photoperiod. The average pupation rate of 97.8% on the N4 diet was significantly higher than the rate of 85.6% on N6 diet. The emergence rates were 92.0% on N4 diet and 93.5% on N6 diet, with a non-significant difference. The larval periods were 17.9 and 17.7 days for females, and 18.7 and 18.5 days for males, for N4 and N6 diets, respectively, with non-significant differences between diets and sexes. The pupal periods on both diets were identical (11.1 days for females and 12.8 days for males), despite differences between sexes. The pupal weights of both sexes on N4 diet were identical with a value of 257 mg, whereas those on N6 diet were 256 and 263 mg for females and males, respectively, with a non-significant difference. The longevity of female adults that emerged on N6 diet was 13.8 days and longer than 8.6 days on N4 diet. The pre-oviposition periods were 5.0 and 4.2 days on the N4 and N6 diets, respectively, with a non-significant difference, however, the oviposition period of 6.5 days on N6 diet was longer than the period of 3.9 days on N4 diet. The effective fecundity on N6 diet was 1,392 eggs (maximum 1,776) and was higher than that of 942 eggs (maximum 1,694) on N4 diet, with a non-significant difference. The egg hatching rates on N4 and N6 diets were 79.2 and 79.8%, and egg periods were 3.0 and 2.9 days, respectively, with non-significant differences.

• Bulletin of the Korean Chemical Society
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• v.13 no.6
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• pp.676-680
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• 1992

Irradiation of N-t-butyl-N-chloro-3-phenylpropanesulfonamide (1a) in benzene at $20^{\circ}C$ using 450 W high pressure mercury arc lamp in the presence of oxygen affored N-t-butyl-3-phenylpropanesulfonamide (2), N-t-butyl-3-chloro-3-phenylpropanesulfonamide (3), and N-t-butyl-3-oxo-3-phenylpropanesulfonamide (4). Similarly, N-t-butyl-4- (5), N-t-butyl-4-chloro-4- (6), and N-t-butyl-4-phenylbutanesulfonamides (7) were obtained from N-t-butyl-N-chloro-4-phenylbutanesulfonamide (1b). However, irradiation of N-t-butyl-N-chloro-5-phenylpentanesulfonamide (1c) under the same conditions gave complex mixtures. These results indicate that sulfonamidyl radical generated from each of 1a and 1b can abstract intramolecularly a hydrogen atom from the benzylic position only by forming six and seven-membered transition states, respectively.

• Journal of Bio-Environment Control
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• v.3 no.2
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• pp.99-105
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• 1994

The objective of this study was conducted for elucidation of effects of the NO$_3$$^{[-10]}$ -N. NH$_4$$^{+}$-N ratio in the nutrient solution on the growth and quality of welsh onion(Allium fistulosum L.). The pH of nutrient solution increased in NO$_3$$^{[-10]}$ -N : NH$_4$$^{+}$-N ratio of 9 : 1 treatment, decreased in 1 : 1, 1 : 3 treatment, but was stable in 3 : 1 treatment during cultivation. The apparent growth of welsh onion was best in the treatment of 9 : 1(NO$_3$$^{[-10]}$ -N : NH$_4$$^{+}$-N ratio), however the treatment of 1 : 3 resulted in poor growth. The NO$_3$$^{[-10]}$ -N content of the plants increased in proportion to that content of nutrient solution. Pyruvic acid content of welsh onion was highest at 9 : 1, 3 : 1 treatment, and lowest at 1 : 3 treatment.tment.

• Membrane Journal
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• v.24 no.6
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• pp.423-430
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• 2014

PTMSP/LDH composite membranes were prepared by adding 0, 1, 3, and 5 wt% LDH contents to PTMSP. The gas permeability and selectivity for $H_2$, $N_2$, $CH_4$, $C_3H_8$, $n-C_4H_{10}$ were investigated as a function of LDH content. As LDH content of PTMSP/LDH composite membranes increased to 5 wt%, the gas permeability for $H_2$ and $N_2$ gradually decreased, while $n-C_4H_{10}$ permeability rapidly increased. The gas permeability for $CH_4$ and $C_3H_8$ was found to decrease for the membranes with LDH content range of 0~3 wt%, however increase in the range of 3~5 wt%. As LDH content of PTMSP/LDH composite membranes increased to 5 wt%, the selectivity of membranes gradually increased for $H_2$, $N_2$, $CH_4$, $C_3H_8$, $n-C_4H_{10}$ over $H_2$, $N_2$. However the selectivity for $C_3H_8$ and $n-C_4H_{10}$ over $CH_4$ increased in the range of LDH content 0~3 wt% but decreased in the range of 3~5 wt%. The $CH_4$ and $n-C_4H_{10}$ selectivity over $H_2$ and $N_2$ increased as $CH_4$ and $n-C_4H_{10}$ permeability increased. The $n-C_4H_{10}$ selectivity over $CH_4$ increased with increasing $n-C_4H_{10}$ permeability up to 182,000 barrer and decreased above 182,000 barrer of $n-C_4H_{10}$ permeability. The $C_3H_8$ selectivity over $H_2$ and $N_2$ was found to decrease as the $C_3H_8$ permeability increased from 46,000 to 50,000 barrer, but to increase with increasing permeability from 50,000 to 52,300 barrer and decrease again with increasing permeability from 52,300 to 60,000 barrer. The $C_3H_8$ selectivity over $CH_4$ was found to decrease with increasing $C_3H_8$ permeability up to 52,300 barrer but increase above 52,300 barrer.

• Journal of the Korean Chemical Society
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• v.15 no.5
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• pp.228-235
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• 1971

The solubilities of n-butyl bromide in nitrobenzene and in 1,2,4-trichlorobenzene have been measured at $19^{\circ},\;25^{\circ},\;and\;40^{\circ}C$ in the presence and absence of gallium bromide. When gallium bromide does not exist in the system, the solubility of n-butyl bromide in nitrobenzene is greater than in 1,2,4-trichlorobenzene, indicating a stronger interaction of n-butyl bromide with nitrobenzene than with 1,2,4-trichlorobenzene. In the presence of gallium bromide, complex of n-butyl bromide with gallium bromide, 1:1 complex, $n-C_4H_9Br{\cdot}GaBr_3$, is formed in the solution. The instability constant K of the complex was evaluated. $n-C_4H_9Br{\cdot}GaBr_3{\rightleftharpoons}n-C_4H_9Br+\frac{1}{2}Ga_2Br_6$ The changes of enthalpy, free energy and entropy for the dissociation of the complex were also calculated.

• Applied Chemistry for Engineering
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• v.22 no.4
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• pp.348-352
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• 2011

In this research, we have synthesized new pendant-type polyurethane polymers by introducing various chromophores with stilbene derivatives in the side-chain of the polymer backbone. The Stilbene monomers, N,N-bis(2-hydroxyethyl) amino-4'-cyanostilbene, N,N-bis(2-hydroxyethyl)amino-4'-methoxy stilbene, N,N-bis(2-hydroxyethyl)amino-4'-acetylstilbene, and N,N-bis(2-hydroxyethyl) amino stilbene, were synthesized by Wittig reaction. Another stilbene monomer, N,N-bis(2-hydroxyethyl)amino-4'-nitrostilbene, was synthesized by Knoevenagel condensation. By the measurement of UV-Vis absorption and Photoluminescence (PL) spectrum, we found that introduction of the electron-withdrawing group as a substituent shifts both UV-Vis and PL spectra to longer wavelength, and the introduction of the electron-donating group results in blue-shift of the spectrum. In case of polymer with $NO_2$ group as a substituent, PL is quenched.

• Journal of the Korean Chemical Society
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• v.35 no.6
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• pp.707-712
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• 1991

N'-phenyl-N-(2-chloroethyl)-N-aminourea has been prepared from N'-phenyl-N-(2-chloroethyl)-N-nitrosourea by means of the electrochemical reduction with the mercury pool electrolytic cell. In order to find out the optimum condition of the reaction, the voltammetric behaviors for N'-aryl-N-(2-chloroethyl)-N-nitrosourea derivatives have been investigated by the cyclic voltammetry and polarography. The peak potentials was shifted to the negative direction as the pH value of the solution decrease. The substituent effects of phenyl ring on the peak potential were not observed in this case. (5:3) EtOH/4 N-HCl mixed solution was employed for the electrolysis. The applied potential was -0.7 V vs. Ag/AgCl/4 N-HCl electrode. The number of electrons participated to the reduction process was 4, respectively. The product was identified by FT-IR, NMR, mass and/or elemental analysis data.

• Honam Mathematical Journal
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• v.44 no.1
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• pp.135-145
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• 2022

This paper aims to investigate characterizations on parameters k₁, k₂, k₃, k₄, k₅, l₁, l₂, l₃, and l₄ to find relation between the class of 𝓗(k, l, m, n, o) hypergeometric functions defined by $$5_F_4\[{\array{k_1,\;k_2,\;k_3,\;k_4,\;k_5\\l_1,\;l_2,\;l_3,\;l_4}}\;:\;z\]=\sum\limits_{n=2}^{\infty}\frac{(k_1)_n(k_2)_n(k_3)_n(k_4)_n(k_5)_n}{(l_1)_n(l_2)_n(l_3)_n(l_4)_n(1)_n}z^n$$. We need to find k, l, m and n that lead to the necessary and sufficient condition for the function zF([W]), G = z(2 - F([W])) and $H_1[W]=z^2{\frac{d}{dz}}(ln(z)-h(z))$ to be in 𝓢^*(2^-r), r is a positive integer in the open unit disc 𝒟 = {z : |z| < 1, z ∈ ℂ} with $$h(z)=\sum\limits_{n=0}^{\infty}\frac{(k)_n(l)_n(m)_n(n)_n(1+\frac{k}{2})_n}{(\frac{k}{2})_n(1+k-l)_n(1+k-m)_n(1+k-n)_nn(1)_n}z^n$$ and $$[W]=\[{\array{k,\;1+{\frac{k}{2}},\;l,\;m,\;n\\{\frac{k}{2}},\;1+k-l,\;1+k-m,\;1+k-n}}\;:\;z\]$$.

• Applied Chemistry for Engineering
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• v.8 no.6
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• pp.1054-1057
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• 1997

Four kinds of N,N'-bisacrylamide derivatives were synthesized by Scotten-Baumann reaction from acryloyl chloride and several diamines in the presence of triethylamine, and their chemical structures were identified by IR, $^1H-NMR$, and elemental analysis. The yields of the synthesized N,N'- hexamethylenebisacrylamide and N,N'-dodecamethylenebisacrylamide were 56.0% and 70.4%, respectively, and were increased with the increased number of methylene group in the dimines. The yields of the synthesized N,N'-1,4-phenylenebisacrylamide and N,N'-2,6-pyridinebisacrylamide were 80.3% and 83.1%, respectively, which were higher than those of the alkylenebisacrylamide derivatives. The synthesized N,N'-bisacrylamide derivatives can be used to prepare various crosslinked polymers.