• Title/Summary/Keyword: N_2gas

Search Result 3,470, Processing Time 0.042 seconds

Empirical Analysis on Determinants of Air Pollution in China (중국의 대기오염 배출 결정요인에 대한 경험적 분석)

  • Li, Dmitriy D.;Wang, Wen;Bae, Jeong Hwan
    • Environmental and Resource Economics Review
    • /
    • v.29 no.1
    • /
    • pp.23-45
    • /
    • 2020
  • The rapid economic growth has brought tremendous pressure on the environment and caused severe air pollution in China. This study empirically examines causes of air pollution in China. Panel-corrected standard errors procedure (PCSE) was used to analyze major determinants of increasing or reducing emissions of sulfur dioxide (SO2) and nitrogen oxides (NOX) in 30 Chinese provinces. The estimation results show that SO2 emission is mitigated as per capita regional GDP increases, but the relation between emission of NOX and per capita regional GDP is found to have an inverse N-shaped curve, which implies that emission of NOX is ultimately expected to decline with economic growth. As for increasing factors of air pollutants, electricity consumption is a significant common source of SO2 and NOX emissions. Moreover, the results show that increment of coal consumption significantly affects emission of SO2 while increase of natural gas consumption reduce emission of SO2. On the other side, investment in energy industry, and investment on treatment of waste gases are determinants of mitigating emissions of SO2, but have no impact on NOX. Consumption of diesel, truck ratio and number of vehicles increase emission of NOX. Meanwhile, higher precipitation rate is a common determinant of mitigating emissions of SO2 and NOX. Policy implications are suggested in the conclusion.

Effect of γ-Irradiation on the Volatile Organic Compounds from Leek (Allium tuberosum R.) (부추(Allium tuberosum R.)의 감마선 조사에 의한 휘발성 유기화합물의 성분 변화)

  • Han, Byung-Jae;Yang, Sook-Young;Kim, Jun-Hyoung;Shim, Sung-Lye;Gyawali Rajendra;Lee, Sung-Jin;Kim, Kyong-Su
    • Journal of the Korean Society of Food Science and Nutrition
    • /
    • v.34 no.4
    • /
    • pp.513-518
    • /
    • 2005
  • Volatile compounds of $\gamma-irradiation$ leeks (Aillum tuberosum R.) were isolated by simultaneous steam distillation and extraction method (SDE) and analyzed by gas chromatography/mass spectrometry (GC/MS) along with the non-irradiated sample. Leeks were irradiated at dose of 20 kGy and non-irradiated samples were considered as control sample. 56 and 54 compounds were identified in non-irradiated and irradiated samples, respectively. These components included the functional groups; alcohols, aldehydes, esters, ketones, N- and S-containing compounds. S-containing compounds such as dimethyl trisulfide, methyl-(Z)-l-proenyl trisulfide, dimethyl disulfide, 3-ethyl-l,2-dithi-5-ene and methyl allyl disulfide were the major compounds. Methyl-(Z)-l-propenyl trisulfide, diallyl trisulfide, (E)-2-hexanal and 3-ethyl-l,2-dithi-5-ene were clearly decreased by the $\gamma-irradiation$, but dimethyl disulfide, diallyl sulfide, allyl methyl sulfide and pyridine were increased by the $\gamma-irradiation$.

Bending Strength Properties of SiC Ceramics at Different Roughness Values of Polishing Plates (연마판의 거칠기에 따르는 SiC 세라믹스의 굽힘강도 특성)

  • Nam, Ki-Woo;Kim, Eun-Sun
    • Transactions of the Korean Society of Mechanical Engineers A
    • /
    • v.35 no.7
    • /
    • pp.779-784
    • /
    • 2011
  • This study was carried out on the crack healing of three types of SiC ceramics based on a $SiO_2$ additive, taking into account the roughness of the polishing plate used for polishing the specimens. The mixtures were subsequently hot-pressed in $N_2$ gas for one hour under 35 MPa at 2053 K. In these specimens, the optimized crack-healing condition was 1373 K for one hour in air. The crack-healing material of the cracked part was the glassy phase of $SiO_2$ that was formed by the oxidation of SiC. In the optimum healing condition, the bending strength of non-polished SiC ceramics was not completely recovered. However, the bending strength of the SAY specimen was excellent, considering the economic aspects of SAY, SAYS-1, and SAYS-2. The SAY specimen is definitely superior to the others after an hour of heat treatment. There was a decrease in the number and size of defects in the specimen polished by using a $125-{\mu}m$ polishing plate; however, the micro-surface defects were not completely repaired. The specimen polished by using a 40-${\mu}m$ polishing plate showed little voids or surface defects after an hour of heat treatment. The bending strength of the specimen mirror-polished by using a 6-${\mu}m$ polishing plate was completely recovered.

Discrimination of the geographical origin of commercial sesame oils using fatty acids composition combined with linear discriminant analysis (지방산 조성과 선형판별분석을 활용한 유통판매 참기름의 원산지 판별)

  • Kim, Nam-Hoon;Choi, Chae-man;Lee, Young-Ju;Kim, Na-Young;Hong, Mi-Sun;Yu, In-Sil
    • Analytical Science and Technology
    • /
    • v.34 no.3
    • /
    • pp.134-141
    • /
    • 2021
  • In this study, the fatty acid (FA) composition of commercial sesame oils (n = 62) was investigated using gas chromatography with flame ionization detector (GC-FID). Multivariate statistical techniques, including principal component analysis (PCA) and linear discriminant analysis (LDA), were applied to the chromatographic data of the FAs to discriminate the geographical origin of sesame oils. A statistically significant difference was observed in the content of C16:0, C18:0, C18:1, and C18:2 between domestic and imported sesame oils. A satisfactory recovery rate of 82.8-100.2 % was achieved for C16:0, C18:0, C18:1, C18:2, and C18:3. The correlation of C16:0, C18:1, and C18:2 in domestic sesame oils showed opposite trends compared to imported oils. The PCA plot demonstrated that sesame oils were clustered in distinct groups according to their origin. LDA was used to predict sesame oil samples in one of the two groups. C16:0 (Wilks λ = 0.361) and C18:1 (Wilks λ = 0.637) demonstrated the highest discriminant power for classifying the origin of the samples. The correct prediction rates were 88.9 % and 100 % for the domestic and imported samples, respectively. Further, 60 of the 62 sesame oil samples (96.8 %) were correctly classified, indicating that this approach can be used as a valuable tool to predict and classify the geographical origin of sesame oils.

The Effect of Epigallocatechin-3-gallate on HIF-1 α and VEGF in Human Lung Cancer Cell Line (비소세포폐암주에서 저산소상태에 의해 유발된 HIFa-1 α와 VEGF의 발현증가에 미치는 Epigallocatechin-3-gallate의 억제 효과)

  • Song, Joo Han;Jeon, Eun Joo;Kwak, Hee Won;Lee, Hye Min;Cho, Sung Gun;Kang, Hyung Koo;Park, Sung Woon;Lee, Jae Hee;Lee, Byung Ook;Jung, Jae Woo;Choi, Jae Cheol;Shin, Jong Wook;Kim, Ki Jeong;Kim, Jae-Yeol;Park, In Won;Choi, Byoung Whui
    • Tuberculosis and Respiratory Diseases
    • /
    • v.66 no.3
    • /
    • pp.178-185
    • /
    • 2009
  • Background: Epigallocatechin-3-gallate (EGCG) is the major catechin in green tea, and has shown antiproliferative, antiangiogenic, antimetastatic and cell cycle pertubation activity in various tumor models. Hypoxia can be induced because angiogenesis is insufficient for highly proliferating cancer. Hypoxia-inducible factor-1$\alpha$ (HIF-1$\alpha$) and its downstream target, vascular endothelial growth factor (VEGF), are important for angiogenesis, tumor growth and metastasis. The aim of this study was to determine how hypoxia could cause changes in the cellular phenomena and microenvironment in a non-small cell culture system and to examine the effects of EGCG on a HIF-1$\alpha$ and VEGF in A549 cell line. Methods: A549 cells, a non-small cell lung cancer cell line, were cultured with DMEM and 10% fetal bovine serum. A decrease in oxygen tension was induced using a hypoxia microchamber and a $CO_2-N_2$ gas mixture. Gas analysis and a MTT assay were performed. The A549 cells were treated with EGCG (0, 12.5, 25, 50 ${\mu}mol/L$), and then examined by real-time-PCR analysis of HIF-1$\alpha$, VEGF, and $\beta$-actin mRNA. Results: Hypoxia reduced the proliferation of A549 cells from normoxic conditions. EGCG inhibited HIF-1$\alpha$ transcription in A549 cells in a dose-dependent manner. Compared to HIF-1$\alpha$, VEGF was not inhibited by EGCG. Conclusion: HIF-1$\alpha$ can be inhibited by EGCG. This suggests that targeting HIF-1$\alpha$ with a EGCG treatment may have therapeutic potential in non-small cell lung cancers.

Studies on the storage of fresh fruits and vegetables by plastic coating (1) on Rall's Janet Apple- (Plastic Coating에 의(依)한 청과물저장연구(靑果物貯藏硏究) (제1보(第1報)) -사과(국광(國光))에 대(對)하여-)

  • Park, Nou-Pung
    • Applied Biological Chemistry
    • /
    • v.12
    • /
    • pp.89-97
    • /
    • 1969
  • These studies were made on coating of fresh fruits and vegetables with PVC under view on preservation of fresh fruits and vegetables due to restrain water evaporation of them and control gas metabolisms. The results obtained, as selection of PVC materials availble for preservation of them, procedure of the coating, useful organic solvents, concentration of PVC solution and the time of dipping, and effects of the preservation of them, were summarized as follows: 1) PVC powder 222 and PVC powder 443 were surveyed as suitable materials for coating apple, and later was excellent in lustrous aspect. 2) The coating procedure which dipt into PVC solution was suitable to treat much within a short space of time, and using of ventillator accelerate rather evaporation of the organic solvent. 3) Aceton and methyethylketon as solvent of the PVC were, in purpose of storage only, avaible, while aceton was, in view ef taste, better. 4) 10% of the PVC solutions were better to preserve the freshness of apple and 5, 4, 1 and 0.5% of them in order were gradually decreased in preservability, and 15% of them as high concentration were looked like fermentation in one week after the coating. 5) The dipping time was also better n minute than 10 seconds in a preservation but 1-2 minutes could be applied owing to be not affected of the taste due to coating. 6) The freshness of treatment groups were extend about 48 days after coating in room temperature but control lost market value with 12 days. 7) Weight of control was decreased to 10-13% but treatment which was dipped into 10% of coating solution for one minute was decreased to 3.5-4.6% and treatment for four minutes was did to 2.9-3.0%. 8) Change in respiration was less is treatment groups than control in exhaustion of $CO_2$, and water soluble sugar, reduced sugar and pH were not changed almost due to coating. 9) Pannel discussion of the taste was indicated that control was better than treatments soon after coating, but treatments were rather than control last period of storage and treatment with aceton solvent specially was better than others.

  • PDF

Effects of Dicarboxylic Acid as an Alternative to Antibiotic on in vitro Rumen Parameters, Milk yield and Milk Compositions in Lactating Cows (항생제 대체제로서 Dicarboxylic Acid 급여가 in vitro 반추위 발효성상, 착유우의 유량 및 유성분에 미치는 영향)

  • Nam, In-Sik;Ahn, Yong-Dae;Jeong, Ki-Hwan;Ahn, Jong-Ho
    • Korean Journal of Organic Agriculture
    • /
    • v.24 no.3
    • /
    • pp.453-463
    • /
    • 2016
  • This study was undertaken to investigate the effects of dicarboxylic acid supplementation, as replacement antibiotics, of on in vitro ruminal parameters and milk yield and milk composition in lactating cows. in vitro treatments were 1) Con (4 g of basal diet), 2) CM (4 g of basal diet + 0.05 ml of monensin), 3) CR (4 g of basal diet + 0.1 ml of dicarboxylic acid) and in vivo treatments were 1) Con (25 kg of basal diet/head/day), and 2) CR (25 kg of basal diet + 5 g of dicarboxylic acid/head/day), respectively. A total 10 lactating dairy cows ($649{\pm}19kg$ average body weight, $99{\pm}65$ average milking days) were divided in to two groups according to mean milk yield and number of days of postpartum. The cows fed a basal diet during adaptation (2 wk) and experimental diets during the treatment periods (4 wk). In the first in vitro experiment, there were no statistical differences between treatments in pH, gas production, and ammonia-N and lactic acid concentration during incubation. However, dry matter digestibility was significantly higher in CR treatment compared to control or CM treatment (P<0.05). Total VFA was tended to higher in CR treatment than those of control and CM treatment (P>0.05). In the second experiment, milk yield was significantly higher in treatment (40.39 kg) compared to control (35.19 kg), (P<0.05). Milk composition and MUN were not changed by dietary supplementing dicarboxylic acid. Therefore the present results reporting that supplementation of dicarboxylic acid might enhance the stabilization of ruminal fermentation and increase the milk yield of lactating cows.

Real-time Monitoring of Ammonia and Hydrogen Sulfide According to Workplace at Swine Farms (양돈장 작업장소별 암모니아 및 황화수소의 실시간 모니터링)

  • Park, Jihoon;Kang, Taesun;Seok, Jiwon;Jin, Suhyun;Heo, Yong;Kim, Kyungran;Lee, Kyungsuk;Yoon, Chungsik
    • Journal of Korean Society of Occupational and Environmental Hygiene
    • /
    • v.23 no.4
    • /
    • pp.402-411
    • /
    • 2013
  • Objectives: This study aims to assess the concentrations of ammonia and hydrogen sulfide according to task unit area at swine farms. Methods: A total of six swine farms were selected for this study. Ammonia and hydrogen sulfide were monitored using a real-time multi-gas monitor which could sample the gases simultaneously. The sampling was done in the pig building, manure storage facility and composting facility of each farm. Results: The concentration of ammonia in the pig buildings(GM 22.6 ppm, GSD 2.3) was significantly higher(p<0.0001) than in the manure storage facilities(GM 10.4 ppm, GSD 2.7) and composting facilities(GM 8.6 ppm, GSD 2.8). The concentration of hydrogen sulfide in the manure storage facilities(GM 9.8 ppm, GSD 3.2) was higher(p<0.0001) than in the pig buildings(GM 2.3 ppm, GSD 2.3) and composting facilities(GM 1.9 ppm, GSD 2.5). In particular, the levels of hydrogen sulfide in the confined manure storage facilities were higher than those in open-type facilities and the peak concentration(98 ppm) in the confined facilities was approximate to 100 ppm, at the value of Immediately Dangerous to Life or Health(IDLH). Conclusions: Suffocation accidents caused by hazardous gases at a swine farm have occurred annually. Real-time monitoring of the hazards should be done in order to protect farm workers and livestock from the sudden accidents.

A Study on Characteristics of HI Decomposition Using Pt Catalysts on ZrO2-SiO2 Mixed Oxide (ZrO2-SiO2 복합산화물에 담지된 백금 촉매의 요오드화수소 분해 특성 연구)

  • Ko, Yunki;Park, Eunjung;Bae, Kikwang;Park, Chusik;Kang, Kyoungsoo;Cho, Wonchul;Jeong, Seonguk;Kim, Changhee;Kim, Young Ho
    • Journal of Hydrogen and New Energy
    • /
    • v.24 no.5
    • /
    • pp.359-366
    • /
    • 2013
  • This work is investigated for the catalytic decomposition of hydrogen iodide (HI). Platinum was used as active material by loading on $ZrO_2-SiO_2$ mixed oxide in HI decomposition reaction. To obtain high and stable conversion of hydrogen iodide in severe condition, it was required to improve catalytic activity. For this reason, a method increasing dispersion of platinum was proposed in this study. In order to get high dispersion of platinum, zirconia was incorporated in silica by sol-gel synthesis. Incorporating zirconia influence increasing platinum dispersion and BET surface area as well as decreasing deactivation of catalysts. It should be able to stably product hydrogen for a long time because of inhibitive deactivation. HI decomposition reaction was carried out under the condition of $450^{\circ}C$ and 1 atm in a fixed bed reactor. Catalysts analysis methods such as $N_2$ adsorption/desorption analysis, X-ray diffraction, X-ray fluorescence, ICP-AES and CO gas chemisorption were used to measurement of their physico-chemical properties.

Steam Gasification Characteristics of Wood Pellet (우드펠릿의 스팀가스화 특성)

  • Hwang, Hoon;Lee, Moon-Won;Choi, Sun-Yong;Kim, Lae-Hyun
    • Journal of Energy Engineering
    • /
    • v.19 no.4
    • /
    • pp.215-220
    • /
    • 2010
  • Hydrogen is a clean and efficient energy source and is expected to take an important role in future energy demand. A possibly good route to produce hydrogen is by using biomass and organic wastes as a source through thermo-chemical conversion technology. In this study, pyrolysis of wood Pellet(Oregon pine) has been carried out in batch type fixed-bed reactor in $N_2$ atmosphere during 20 minutes to determine the optimum hydrogen generating conditions. At the influence of temperature, hydrogen yield was increased with increasing temperature. For the influence of Steam/Biomass Ratio(SBR), hydrogen yield was increased by steam addition at low temperature condition. However, effect of steam addition was insignificant over at SBR = 1. The hydrogen yield was increased with increasing SBR at high temperature condition. From result of $H_2$/CO and $H_2/CH_4$ ratio, dominant reaction was steam reforming in this experimental condition. The optimum condition for hydrogen production was determined as follows: $H_2$ yield = 38.3 vol.% (56.01 L/min kg) at $900^{\circ}C$, SBR=3.