• 한국연소학회:학술대회논문집
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• 2001.11a
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• pp.42-50
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• 2001

An experimental study has been carried on high-preheated temperature air combustion. Because the flames with high-preheated temperature air combustion were much more stable and homogeneous(both temporally and spatially) as compared to the room-temperature combustion air. The global flame feature showed range of flame colors (yellow, blue, blurish-green) over the range of conditions. Low level of NOx along with low level of CO have been obtained under high-preheated air combustion conditions. The thermal and chemical behavior of high-preheated air combustion flames depends on preheated temperature and oxygen concentration air.

• Journal of Environmental Science International
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• v.27 no.10
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• pp.809-820
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• 2018

DeNOx experiments for the effects of hydrocarbon additives on diesel SNCR process were conducted under oxidizing diesel exhaust conditions. A diesel-fueled combustion system was set up to simulate the actual cylinder and head, exhaust pipe and combustion products, where the reducing agent $NH_3$ and $C_2H_6/diesel$ fuel additives were separately or simultaneously injected into the exhaust pipe, used as the SNCR flow reactor. A wide range of air/fuel ratios (A/F=20~40) were maintained, based on engine speeds where an initial NOx level was 530 ppm and the molar ratios (${\beta}=NH_3/NOx$) ranged between 1.0~2.0, together with adjusting the amounts of hydrocarbon additives. Temperature windows were normally formed in the range of 1200~1350K, which were shifted downwards by 50~100K with injecting $C_2H_6/diesel$ fuel additives. About 50~68% NOx reduction was possible with the above molar ratios (${\beta}$) at the optimum flow #1 ($T_{in}=1260K$). Injecting a small amount of $C_2H_6$ or diesel fuel (${\gamma}=hydrocarbon/NOx$) gave the promising results, particularly in the lower exhaust temperatures, by contributing to the sufficient production of active radicals ($OH/O/HO_2/H$) for NOx reduction. Unfortunately, the addition of hydrocarbons increased the concentrations of byproducts such as CO, UHC, $N_2O$ and $NO_2$, and their emission levels are discussed. Among them, Injecting diesel fuel together with the primary reductant seems to be more encouraging for practical reason and could be suggested as an alternative SNCR DeNOx strategy under diesel exhaust systems, following further optimization of chemicals used for lower emission levels of byproducts.

• Journal of Animal Science and Technology
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• v.50 no.4
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• pp.561-572
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• 2008

Responses of real-time control parameters, such as ORP, DO and pH, to the conditions of biological animal wastewater treatment process were examined to evaluate the stability of real-time control using each parameter. Also an optimum index for supplemental carbon source addition based on NOx-N level was determined under a consideration of denitrification rate by endogenous respiration of microorganism and residual organic matter in liquor. Experiment was performed with lab-scale sequencing batch reactor(SBR) and working volume of the process was 45L. The distinctive nitrogen break point(NBP) on ORP-and DO-time profiles, which mean the termination of nitrification, started disappearing with the maintenance of low NH4-N loading rate. Also the NBP on ORP-and DO-time profiles was no longer observed when high NOx-N was loaded into the reactor, and the sensitivity of ORP became dull with the increase of NOx-N level. However, the distinctive NBP was constantly occurred on pH(mV)-time profile, maintaining unique profile patterns. This stable occurrence of NBP on pH(mV)-time profile was lasted even at very high NOx-N:NH4-N ratio(over 80:1) in reactor, and the specific point could be easily detected by tracking moving slope change(MSC) of the curve. Revelation of NBP on pH(mV)-time profile and recognition of the realtime control point using MSC were stable at a condition of over 300mg/L NOx-N level in reactor. The occurrence of distinctive NBP was persistent on pH(mV)-time profile even at a level of 10,000mg/L STOC(soluble total organic carbon) and the recognition of NBP was feasible by tracing MSC, but that point on ORP and DO-time profiles began to disappear with the increase of STOC level in reactor. The denitrfication rate by endogenous respiration and residual organic matter was about 0.4mg/L.hr., and it was found that 0.83 would be accepted as an index for supplemental carbon source addition when 0.1 of safety factor was applied.

• 한국연소학회:학술대회논문집
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• 2012.04a
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• pp.289-291
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• 2012

The present study numerically investigate detailed flame structure of the Syngas diffusion flames. In order to realistically represent the turbulence-chemistry interaction and the spatial inhomogeneity of scalar dissipation rate, the Eulerian Particle Flamelet Model(EPFM) with multiple flamelets has been applied to simulate the combustion processes and NOx formation in the syngas turbulent nonpremixed flames. And level-set approach is also utilized to account for the partially premixing effect at fuel and oxidizer injector in KEPRI nonpremixed combustor. Based on numerical results, the detailed discussion has been made for the precise structure and NOx formation characteristics of the turbulent syngas nonpremixed flames.

• Journal of the Korean Society of Combustion
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• v.8 no.1
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• pp.25-35
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• 2003

The objective of this research is to determine generally applicable design principles for the development of internally staged combustion devices. Utilizing a triple annulus combustor, the detailed combustion characteristics are studied. For this triple air staged combustor, the angular momentum weighted by it#s swirl number and air distribution ratio was observed to be the critical criteria of NOx emission. An internal recirculation zone which develops on the centerline of the flame immediately downstream of the burner entraps the fuel into a fuel rich eddy. Then sufficient heat must be transferred from the flame via radiation to the chamber heat transfer surfaces, such that the peak flame temperatures are suppressed when the second air is introduced. It is experimentally found out that the total NOx emission level in this type of burner is below 50ppm(3% Ref. O2) at optimum operating conditions.

• Journal of the Korean Society of Combustion
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• v.13 no.1
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• pp.1-9
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• 2008

Emission characteristics of NOx and CO with heat loss under high efficiency combustion conditions of $CH_4$/Air prmixed flame were examined numerically using detailed-kinetic chemistry. The one-dimensional combustor length was fixed 5cm, and the equivalence ratio was varied from 0.75 to 0.95. To consider the effects of heat loss on NOx and CO formation, the radiative heat loss rate and combined heat loss rate of conductive and convective heat transfer are included. The following conclusions were drawn. In order to reduce the NOx and CO emission level simultaneously, the temperature of product gases must be reduced under 1,800K as soon as possible but kept over 1,300K during the residence time which is needed to converge CO to $CO_2$.

• 유체기계공업학회:학술대회논문집
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• 2006.08a
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• pp.569-572
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• 2006

In present study, the influence of changing combustor pressure on flame stabilization and nitrogen oxide (NOX) emission in the swirl flame with secondary fuel injection was investigated. The combustor pressure was controlled by suction at combustor exit. Pressure index ($P^*=Pabs/Patm$), where Pabs and Patm indicated the absolute pressure and atmosphere pressure, was controlled in the range of 0.7~1.15 for each equivalence ratio conditions. It could be observed that flame stable region became narrower with decreasing equivalence ratio and pressure index. In this combustion system, stable flames were formed until $P^*=\;0.7$. Emission index decreased with decreasing pressure index for overall equivalence ratio conditions and NOx reduction rates were almost identical for $P^*<1$ regardless of equivalence ratio though EINOx values showed different level with change of equivalence ratio for $P^*{\geq}1$. It is also observed that EINOx decreased with increasing secondary fuel injection ratio. Emission index of nitric oxide was controllable by adjusting the changing combustor pressure and injecting secondary fuel and this NOx reduction technology is applicable to industrial furnaces and air conditioning system.

• 한국연소학회:학술대회논문집
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• 2003.05a
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• pp.295-300
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• 2003

In Korea, the emission standards for air pollutants will be more tighten from Jan. 2005. Especially, the new emission standards is focused on the nitrogen oxide. From this trend of standards, nitrogen oxide emission is hot issue in energy fields. Also, we have a new environmental problem, the carbon dioxide emission, which are related to the global warming. To solve the environmental problems, we must define the situation of clean-up technologies level in Korea and decide the direction of R&D for flue gas cleaning technologies. Now, this paper discus briefly on the De-NOx R&D activities and the large scale testing facility for flue gas clean-up technologies in Korea Institute of Energy Research. These discussions are contribute to the increasing of the R&D activities for flue gas clean-up technologies in Korea.

• Proceedings of the IEEK Conference
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• 1998.10a
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• pp.601-604
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• 1998

NOX detecting gas sensors using TiO2 doped tungsten oxide semiconductor were prepared and their electrical and sensing characteristics have been investigated. In normal air condition, the sensors of WO3, TiO2 doped WO3 show grain boundary heights of 0.34 eV, 0.25 eV, respectively. The grain boundary barrier energy variation was increased by doping TiO2 into large variation of resistance to NOX gases. And doping the TiO2 4 wt.%, the particle size of WO3 polycrystal films showed higher sensitivity and better sorption characteristics to NOX gas than the pure WO3 films material in air at operating temperature of $350^{\circ}C.$ The TiO2 doped WO3 semiconductor gas sensor shows nano-sized particle size and good sensitivity to sub-ppm concentration of NOX.

• Journal of the Korean Society of Safety
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• v.5 no.2
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• pp.40-49
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• 1990

For the determination of polluant NOx in ambient air, nitrate ion-selective electrode(ISE) was made. To comparison of NOx in each method, the nitrate-ISE, NEBA, Orion electrode were used to determinee NOx in ambient air. In this work, the concentration of NOx in ambient air was average 0.06ppm. The results were good agreement with those obtained by each method within a relative error of 3％, Absorbing efficiency of nitrogen oxides in ambient air was good for Alkali solution. The determination of nitrogen oxides in ambient air using the Aliquat 336N-PVC membrane electrode was one of the useful method. The best characteristics of the Aliquat 336N-PVC me,mbrane electrode were obtained with the ion-exchanger concentration level of 6.5-9.1 percent by weight. The optimal membrane composition, was 9.09wt.％ of ion-exchanger, 30.95wt.％ of PVC, 60.6wt.％ of plasticizer (DBP), and 0.5mm of thickness. Under the above condition, the electrode approached the Nernstian slope most closely, and the linear response ranges produced the best results.