• Journal of ILASS-Korea
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• v.6 no.3
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• pp.8-16
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• 2001

The present study is focused on modeling the transient behavior of the local flame structure which is especially important for slow reaction processes, such as NOx formation in the radiating flame field. The unsteady flamelet model recently developed has been applied to analyze a steady, turbulent jet flame. Numerical results are compared with experimental data and numerical results of the conventional steady flamelet model. The numerical result reveals that the unsteady flamelet model correctly predicts the nonequilibrium effect upsteam and the subsequent decay of the superequilibrium radical concentrations further downstream.

• Proceedings of the Korean Institute of IIIuminating and Electrical Installation Engineers Conference
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• 1999.11a
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• pp.95-98
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• 1999

This paper describes preliminary discussions on spatial distribution of NO density, which is mostly contained in simulated NOX exhaust, between a wire-cylinder geometry discharge gaps by using Laser Induced Fluorescence(LIF) Spectroscopy. Spatial distribution of NO density will be measured with varying NO concentrations from 166 to 644[ppm] and diameters of central electrode from 6 to 10mm. Pulsed Nd:YAG laser, Optical Parametric Oscillator(OPO), and Frequency Doubler are used to excite NO molecules to their excited state.

• Journal of the korean Society of Automotive Engineers
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• v.15 no.2
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• pp.44-52
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• 1993

In this study, the characteristics of decreasing exhaust gas of diesel engine was examined in dual fuel method by using commertial LPG for automotive. LPG was supplied to engine intake port by fumigation method and flow rate was controlled by using the needle valve. LPG supply ratios were 0, 20, 30% of total fuel amount to be supplied to engine by mass base. We investigated the effect of LPG supply ratio on exhaust gas concentrations related to excess air ratio and engine load at 1600, 1800, 2000 rpm. Soot concentration decreased about 30% in proportion to the increase of the LPG supply ratio. NOx concentration decreased in proportion to the increase of the LPG than diesel only and the increase rate was higher at low engine load. BSFC(Brake specific fuel consumption) was lower in proportion to the increase of the LPG supply ratio at high engine load and to the decrease of LPG supply ratio at low engine load.

• Journal of the Korean Society of Industry Convergence
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• v.8 no.1
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• pp.19-23
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• 2005

This study was performed to find out performance characteristics and develop LNG engine. this system was designed and manufactured by modification of a diesel using the LNgas. The engine was manufactured to be able to change the compression ratio by changing thickness of the gasket. The results are summarized brake power and torque of the engine increased when compression ratio of the engine increased. The engine output showed more power with gasoline by 5-10% then LNG under compression ratio of 9.5.and maximum brake thermal effeiency was noted when air-fuel ratio was 15.5. The concentrations of NOx, CO and HC in the exhaust gas showed lower values with the engine fueled LNG then gasoline.

• Transactions of the Korean Society of Automotive Engineers
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• v.18 no.4
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• pp.48-53
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• 2010

Roadside measurement of ultrafine particles, black carbon, and NOx was carried out to investigate air pollution at a junction area contaminated with vehicle emissions in Seoul from March 19 to 23, 2007. Diurnal variation of ultrafine particles, black carbon, and $NO_x$ concentrations at a roadside showed minimum at around 2-4 a.m. and two peak modes during the morning and evening rush hours. Since these pollutants might be mainly emitted from vehicles, the roadside was highly contaminated with vehicles.

• Proceedings of the Korea Air Pollution Research Association Conference
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• 2002.11a
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• pp.298-299
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• 2002

산업의 발전과 인구의 과밀, 자동차의 증가는 오염물질의 배출을 크게 증가시켰지만 최근 관련 규제의 강화로 각 도시의 대기질은 많이 개선되어 왔다. 그러나 대기중으로 배출되는 오염물은 여전히 선진국에 비하면 기준치를 훨씬 넘는 높은 수준이다. (김우규 등, 1995) 우리나라에서 미세먼지와 SO$_2$, NOX, CO, VOC 등 대기오염물질로 인한 사회적 피해 비용이 1999년 기준 연간 최저 32조원에서 최고 60조원으로 평균 45조원에 달하는 것으로 나타났고, 이 중에 입자상 오염물질은 6조에서 18조원까지의 재산상 피해를 입히는 것으로 나타났다. (중략)

• Journal of the Korean Society of Combustion
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• v.22 no.1
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• pp.23-31
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• 2017

Large-scale fuel tanks emit massive amount of hardly-combustible VOC mixtures which are light hydrocarbon species in dilution with nitrogen and carbon dioxide. We have developed a lab-scale burner to combust those VOC mixtures by use of a turbulent partially-premixed flame as a pilot flame. For a higher HC treatment ratio, the mixture gases were reformed by a rotating arc plasma device. The results showed that the nitrogen mole fraction and the injecting speed of the VOC mixture influence on the performance of the burner. It was also found that the size of the pilot flame and the power supplied to the plasma device determine the overall HC treatment ratio and the concentrations of CO and NOx in the exhaust gas.

• Bulletin of the Korean Chemical Society
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• v.13 no.1
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• pp.37-41
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• 1992

The reactions of nitrous acid with hydrogen peroxide in acidic aqueous solution in the presence of several added anions have been studied at $0^{\circ}C$ and pH 2-4 to investigate the nucleophilic catalysis of these anions. From the dependence of reaction rates on the anion concentrations, significant catalytic effects were found for $Cl^-,\;Br^-,\;SCN^-$, in order of effect $SCN^-\;{\approx}\;Br^->Cl^-$, while no observable effect was found for ${ClO_4}^-$ and ${NO_3}^-$. These results support O-nitrosation reaction is the rate-determining step and NOX formed in the presence of an anion ($X^-$) also acts as a nitrosating agent and accelerates the overall reaction rate. The order of reactivity was found to be NOCl>NOBr>NOSCN, which is consistent with the results of N-nitrosation and S-nitrosation reactions.

• Journal of Environmental Science International
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• v.25 no.1
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• pp.85-97
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• 2016

A comparison of ozone simulations in the seoul metropolitan region (SMR) using the community multiscale air quality (CMAQ) model with SAPRC99 and CB05 chemical mechanisms (i.e. EXP-SP99 and EXP-CB05) has been conducted during four seasons of 2012. The model results showed that the differences in average ozone concentrations between the EXP-SP99 and EXP-CB05 were found to be large in summer, but very small in the other seasons. This can be attributed that the SAPRC99 tends to produce more ozone than the CB05 in urban area like the SMR with low VOC/NOx ratio under high ozone conditions. Through quantitative comparison between two mechanisms for the summer, it was found that the average ozone concentrations from the EXP-SP99 were about 3 ppb higher than those from the EXP-CB05 and agreed well with the observations. Horizontal differences in ozone concentrations between SAPRC99 and CB05 showed that significant differences were found in southern part of the SMR and over the sea near the coast in summer.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.10 no.12
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• pp.3761-3767
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• 2009

This study was investigated to determine the combustion characteristics, decomposition efficiency, and the flue gas concentrations after combustion in the high temperature reactor($1,250{\sim}1,400^{\circ}C$, 1 atm) for the liquid wastes(waste oil and waste solvent) generated from the industrial complex. The concentration of nitrogen oxide(NOx) is decreased and the synthetic gas is increased when the mass ratio of $O_2$/waste is about 1.53 because the reaction condition was changed to reduction state. And BTEXs(benzene, toluene, ethylbenzene, xylene) are decomposed more than 99.99%. If the highly concentrated liquid waste (waste oil and waste solvent) is treated under the operating conditions suggested by this study, our treatment method for the liquid waste was found to be proper because of the contaminants emission concentration is very low. In addition, the synthetic gas after combustion can be used as an alternative fuel.