• 한국연소학회:학술대회논문집
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• 1998.10a
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• pp.165-170
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• 1998

Turbulent nonpremixed $H_2$-air jet flames are numerically investigated using the joint PDF model. The reaction progress variable is derived by assuming the radicals 0, H, and OH to be in partial equilibrium and additional species $HO_2$ and $H_2O_2$ in steady state. The model is extended to npnadiabatic flame by introducing additional variable for the transport of enthalpy and radiative source term is calculated using a local, geometry independent model. In terms of flame structure and NO formation, the predicted results are favorably agreed with experimental data. The effects of nonequilibrium chemistry and radiative heat loss on the thermal NO formation are discussed in detail.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.36 no.1
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• pp.103-110
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• 2012

The flow field, fuel-air mixing, and behaviors of turbulent flames have been investigated using the large eddy simulation (LES) numerical technique in a premixed swirl combustor equipped with EV double cone burners. Recirculation zones are generated by the swirl burner, and lean premixed flames are formed within a distance of 0.2 m from the tip of the burner. NOx emission of 0.46 ppm is predicted at 1 atm and an air/fuel ratio of 38.7. However, most of the CO generated in a flame front continues to be oxidized as it moves toward the exit, and CO emission of 5.45 ppm is predicted at the exit. The NOx emission can be reduced by decreasing the pressure and air/fuel ratio. The characteristics of NOx emission have been investigated through RANS simulations for various fuel injection types, and it is found thereby that five-lance-hole injection produces the lowest NOx emission rate.

• Journal of Energy Engineering
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• v.12 no.4
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• pp.320-327
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• 2003

A CFD (Computational fluid Dynamics) research is conducted for the investigation of the fuel alteration of MBTU (medium-Btu) gas in IGCC gas turbine combustor. The computational analysis method of the gas turbine combustor is constructed by incorporating MBTU gas reaction and fuel NOx models into commercial CFD code. With the use of the present analysis method, comparisons are made on the flow velocity, the chemical species and the temperature distributions, and on the flame shape and behavior of gas turbine combustor firing natural gas and MBTU gases (coal gas, heavy residue oil gas). Furthermore, the NOx formation characteristics and the turbine matching condition of the combustor are analyzed. Based on the computed analysis results, the present study provides the directions for the redesign and the design modification of IGCC gas turbine combustor firing MBTU gas as alternative fuel.

• Korean Chemical Engineering Research
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• v.49 no.1
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• pp.89-94
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• 2011

DeNOx characteristics of hybrid SNCR-SCR process have been investigated in a pilot scale flow reactor. DeNOx efficiency of SNCR reaction was about 80% at $970^{\circ}C$ and hybrid SNCR-SCR process showed 92% at $940^{\circ}C$ with NSR = 2.0. Compared to SNCR process alone, hybrid SNCR-SCR process was more effective at cool side, which is lower than $940{^{\circ}C}$. It should be also noted that ammonia slip from hybrid SNCR-SCR process was below 1ppm at the condition of higher space velocity and the required catalyst volume can be decreased to 2/3 of SCR process. Key factors for DeNOx efficiency of hybrid SNCR-SCR process were found to be $NH_3$ concentration and NOx selectivity of urea injected in SNCR process.

• Journal of Korean Society of Environmental Engineers
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• v.22 no.12
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• pp.2247-2254
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• 2000

This study was carried out to investigate the reaction characteristics of NOx with reagents to grope the power consumption rate reduction and NOx removal rate improvement for the non-thermal plasma denitrification process. The experiments were performed using the real flue gas and wire-plate type plasma reactor. and the flow rate of real flue gas is $20Nm^3/hr$. Paraffinic and olefinic hydrocarbons and ammonia were used as reagents. Olefinic hydrocarbon oxidizes NO more actively than paraffinic hydrocarbon under the non-thermal plasma conditions, resulting in the generation of large amount of $NO_2$ and a very small amount of CO. When the initial NOx concentration increases. oxidation rate of NO decreases and the consumption rate of olefinic hydrocarbon increases significantly. On the other hand. $NH_3$ did not promote reduction reaction with NO under non-thermal plasma conditions. however, there was a tendency that the NHa was effective to remove the $NO_2$ oxidized by olefinic hydrocarbon.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.28 no.12
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• pp.1616-1624
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• 2004

The conditional moment closure(CMC) model has been implemented in context with the unstructured-grid finite-volume method which efficiently handle the physically and geometrically complex turbulent reacting flows. The validation cases include a turbulent nonpremixed CO/$H_2$/$N_2$ Jet flame and a turbulent nonpremixed $H_2$/CO flame stabilized on an axisymmetric bluff-body burner. In terms of mean flame field, minor species and NO formation, numerical results has the overall agreement with expermental data. The detailed discussion has been made for the turbulence-chemistry interaction and NOx formation characteristics as well as the comparative performance for CMC and flamelet model.

• 한국연소학회:학술대회논문집
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• 2006.04a
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• pp.111-120
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• 2006

The fully coupled conditional moment closure(CMC) model has been developed to realistically simulate the structure of complex turbulent nonpremixed syngas flame, in which the flame structure could be considerablyl influenced by the turbulence, transport history, and heat transfer as well. In order to correctly account for the transport effect, the CMC transport equations fully coupled with the flow and mixing fields are numerically solved. The present CMC approach has successfully demonstrated the capability to realistically predict the detailed structure and the overall combustion characteristics. The numerical results obtained in this study clearly reveal the importance of the convective and radiative heat transfer in the precise structure and NOx emission of the present confined combustor with a cooling wall.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.21 no.5
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• pp.659-669
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• 1997

The effects of exhaust gas recirculation on diesel engine combustion and soot/NOx emissions are numerically studied. The primary and secondary atomization is modelled using the wave instability breakup model. Autoignition of a diesel spray is modelled using the Shell ignition model. Soot formation is kinetically controlled and soot oxidation is represented by a model which account for surface chemistry. The NOx formation is based on the extended Zeldovich NOx model. Effects of injection timing and concentration of $O_{2}$ and CO$_{2}$ on the pollutant formation and the combustion process are discussed in detail.

• Journal of Korean Society of Environmental Engineers
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• v.22 no.4
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• pp.671-678
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• 2000

Reaction characteristics of simultaneous removal of SOx and NOx have been investigated in a thermogravimetric analyzer and tubular fixed bed reactor using the $CuO/{\gamma}-Al_2O_3$ sorbent/catalyst. Sulfur removal capacity of $CuO/{\gamma}-Al_2O_3$ sorbent/catalyst is largely enhanced above both the temperature of $450^{\circ}C$ and the loading of 6wt% due to the participation of alumina support in a sulfation reaction. The NO reduction efficiency of 8wt% $CuO/{\gamma}-Al_2O_3$ sorbent/catalyst shows the maximum value at $370^{\circ}C$ and then decreases with the increase of reaction temperature due to the oxidation of $NH_3$ gas. The presence of sulfate on the surface of sorbent/catalyst enhances the optimum reaction temperature showing the maximum deNOx efficiency. In the simultaneous removal of SOx and NOx at $250^{\circ}C$. deNOx activity of $CuO/{\gamma}-Al_2O_3$ sorbent/catalyst is rapidly decreased due to the formation of ammonium salts such as $NH_4HSO_4$. In the simultaneous removal reaction of SOx and NOx, the optimum temperature showing the maximum deNOx efficiency increases to $400^{\circ}C$ due to the presence of $SO_2$ gas.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.19 no.9
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• pp.474-481
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• 2018

The policy-making and technological development of eco-friendly automobiles designed to increase their supply is ongoing, but the internal combustion engine still accounts for approximately 95% of automobiles in use. To meet the stricter emission regulations of internal combustion engines based on fossil fuels, the proportion of after-treatments for vehicles and (ocean going) vessels is increasing continuously. As diesel engines have high power and good fuel economy in addition to less CO2 emissions, their market share is increasing not only in commercial vehicles, but also in passenger cars. Because of the characteristics of the diesel combustion, however, NOx is generated in localized high-temperature combustion regions, and particulates are formed in the zones of diffusion combustion. LNT and urea-SCR catalysts have been developed for the after-treatment of exhaust gas to reduce NOx in diesel vehicles. This study examined the effect of a containing promoter on SCR catalysts to cope with the severe exhaust gas regulation. The de-NOx performance of the Mn-SCR catalyst was the best, and the de-NOx performance was improved as the ion exchange rate between Mn ion and Zeolyst was good and the activation energy was low. The de-NOx performance of the 7Cu-15Ba/78Zeoyst catalyst was 32% at $200^{\circ}C$ and 30% at $500^{\circ}C$, and showed the highest performance. The NOx storage material of BaO loaded as a promoter was well dispersed in the Cu-SCR catalyst and the additional de-NOx performance of BaO was affected by the reduction reaction of the Cu-SCR catalyst. Among the three catalysts, the 7Cu-15Ba/Zeolyst SCR catalyst was resistant to thermal degradation. The same type of CuO due to thermal degradation migrates and agglomerates because BaO reduces the agglomeration of the main catalyst CuO particles.