• 제목/요약/키워드: NOx,

검색결과 2,537건 처리시간 0.032초

Performance evaluation of nitrate removal in high TDS wet scrubber wastewater by ion exchange resin with dissolved air flotation (DAF) process

  • Kim, Bongchul;Yeo, Inseol;Park, Chan-gyu
    • Membrane and Water Treatment
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    • 제13권1호
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    • pp.1-6
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    • 2022
  • The regulations of the International Maritime Organization (IMO) have been steadily strengthened in ship emissions. Accordingly, there is a growing need for development of related technologies for the removal of contaminants that may occur during the treatment of SOx and NOx using a wet scrubber. However, this system also leads to wastewater production when the exhaust gas is scrubbed. In this research, we evaluated the performance of an ion selective resin process in accordance with scrubber wastewater discharge regulations, specifically nitrate discharge, by the IMO. Accelerated real and synthetic wastewater of wet scrubbers, contained high amounts of TDS with high nitrate, is used as feed water in lab scale systems. Furthermore, a pilot scale dissolved air flotation (DAF) using microbubble generator with ion exchange resin process was combined and developed in order to apply for the treatment of wet scrubber wastewater. The results of the present study revealed that operating conditions, such as resin property, bed volume (BV), and inlet wastewater flow rate, significantly affect the removal performance. Finally, through a pilot test, DAF with ion exchange resin process showed a noticeable improvement of the nitrate removal rate compared to the single DAF process.

광촉매 시멘트의 이산화질소 분해에 따른 내구성에 관한 연구 (Durability of Photocatalytic Cementitious Materials Exposed to Nitrogen Dioxide)

  • 이보연
    • 한국건축시공학회:학술대회논문집
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    • 한국건축시공학회 2014년도 춘계 학술논문 발표대회
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    • pp.248-249
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    • 2014
  • Photocatalytic cement is receiving attention due to its high oxidation power that oxidizes nitrogen oxides (NOx), thus contributing to clean atmospheric environment. However, there has not been a thorough investigation on durability of a parent material, cementitious material, as a result of photocatalytic reactions. In this study, durability of photocatalytic cementitious materials exposed to nitrogen dioxide (NO2) gas was examined. Titanium dioxide (TiO2) nanoparticles containing cement paste samples were exposed to cycles of NO2 with UV light, followed by wetting and drying to simulate environmental condition. The surface of samples was characterized mechanically, chemically, and visually during the cycling. The results indicate that the photocatalytic efficiency decreased with continued NO2 oxidation due to calcium carbonate formation. The pits found from SEM demonstrate that chemical deterioration have occurred, such as acid attack or leaching. In conclusion, the photocatalytic reactions and its product could alter cementitious materials chemically and mechanically which could further affect long-term durability.

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Framework to Compute Vehicle Emission Costs Associated with Work Zones

  • Shrestha, K. Joseph;Adebiyi, Jeremiah;Uddin, Mohammad Moin;Sturgill, Roy
    • 국제학술발표논문집
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    • The 9th International Conference on Construction Engineering and Project Management
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    • pp.952-959
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    • 2022
  • Active construction work zones will result in longer travel time and/or longer travel distances for road users because of reduced speed limits and/or detours. This results in increased fuel consumption and increased emissions of harmful gases such as Carbon Monoxide (CO), Nitrogen Oxides (NOx), and Sulfur Oxides (SOx), which causes discomfort to the environment and road users around the work zone. The impact of such emissions should be considered while designing work zones or determining the number of days the roadway will be allowed to be closed partially or fully. This study develops a methodology to compute additional road user costs associated with such work zones. To achieve this goal, a) an extensive literature review is conducted, b) a framework to compute emission cost is developed, c) emission rates are computed for all counties (95) of the state of Tennessee, and d) a case study is conducted to demonstrate the use of the framework to estimate the additional impact of emission because of the work zone. For the case study conducted, the emission cost was computed to be $10,653.60 for the duration of the project. State DOTs can account for such road user costs while selecting contractors using A+B bidding. Accounting for such impact of emission will also indicate the agency's willingness to consider sustainability as a part of the business practices.

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LNG-DF추진 중형선박의 지속가능한 기본설계 대안을 위한 전과정평가(LCA) 분석 (Analysis of Life Cycle Assessment (LCA) for Sustainable Basic Design Alternatives for Medium-Sized LNG-DF Propulsion Ship)

  • 정기석;이동건
    • 대한조선학회논문집
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    • 제60권5호
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    • pp.358-366
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    • 2023
  • Due to the International Maritime Organization's (IMO) environmental regulations on NOx and SOx, LNG-fueled eco-friendly ships are gaining attention worldwide, and various eco-friendly ships are being proposed and demanded for conversion to eco-friendly ships in Korea, as the eco-friendly ship law has recently been enforced. In this study, the initial basic design was performed to convert an existing Marine Gas Oil (MGO) fueled ship into an LNG-DF propulsion ship, targeting medium-sized ship, to select the fuel tank capacity and main dimensions and appropriate fuel ratio between the two fuels. In particular, Sustainable basic design method considering environmental impact were proposed by performing a Life Cycle Assessment (LCA) throughout the design process, and various design options were compared and analyzed to meet different design conditions by applying them.

다수 부분 예혼합 화염의 화염날림 유속 확대 (Nozzle configurations for partially premixed interacting jet flame to enhance blowout limits)

  • 이병준;김진현
    • 한국연소학회:학술대회논문집
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    • 한국연소학회 2004년도 제29회 KOSCI SYMPOSIUM 논문집
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    • pp.79-84
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    • 2004
  • For the non-premixed interacting jet flames, it has been reported that if eight small nozzles are arranged along the circle of 40 $^{\sim}$ 72 times the diameter of single jet, the flames are not extinguished over 2oom/s. In this research, experiments were extended to the partially premixed cases to reduce both flame temperature and NOx emission. Nine nozzles were used- eight was evenly located along the perimeter of the imaginary circle and one at the geometric centre. The space between nozzles, S, the equivalence ratio, ${\Phi}$, the exit velocity and the role of the jet from the centre nozzle were considered. Normally, flame was lifted and flame base was located inside the imaginary circle made by the nozzle. As nozzles went away from each other, blowout velocity increased and then decreased. The maximum blowout velocity diminished with the addition of air to the fuel stream. When the fuel and/or oxidizer were not fed through the centre nozzle, the maximum blowout velocity obtained by varying Sand ${\Phi}$ was around 160m/s. Optimum nozzle separation distance at which peak blowout velocity obtained also decreased with ${\Phi}$ decrease. Flame base became leaner as approaching to the blowout. It seemed that lots of air was supplied to the flame stabilizing region by the entrainment and partially premixing. To approve this idea and to enhance the blowout velocity, fuel was supplied to the centre region. With the small amount of fuel through the centre nozzle, partially premixed flame could be sustained till sonic velocities. It seemed that the stabilizing mechanism in partially premixed interacting flame was different from that of non-premixed case because one was stabilized by the fuel supply through the centre nozzle but the other destabilized.

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휴대용 가스렌지 연소에 의한 공기오염물질의 발생량 및 실내환경의 필요 환기량 (Source Emission Rate on Air Pollutants from Portable Gas Range and Optimal Ventilation Rate in Indoor Environment)

  • 임성국;김영희;양원호
    • 한국환경보건학회지
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    • 제33권2호
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    • pp.92-97
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    • 2007
  • A series of source tests were conducted to characterize emissions of nitrogen oxide(NOx, NO, $NO_2$), carbon mon oxide(CO), carbon dioxide$(CO_2)$ and total VOCs from portable combustion devices in steady-state using well-mixed chamber. Since use of portable gas range is widespread in houses and restaurants in Korea, it is important to characterize the emission of air pollutants and suggest optimum ventilation rate. Ranges of emission rates of air pollutants from portable gas ranges were $NO \;0.551\sim0.939mg/hr,\;NO_2\;0.354\sim1.080mg/hr,\;NO_x\;1.207\sim1.631mg/hr,\;CO\;1.389\sim4.21mg/hr,\;CO_2\;2426.823\sim2973.495mg/hr$, and VOCs $0\sim0.119mg/h$. Mean of personal exposure and indoor environment level of $NO_2$ by combustion of portable gas range were 74.7 ppb and 65.4 ppb, respectively, suggesting persons using portable gas range in houses and restaurants might be highly exposed. Required ventilation rate to control the air pollutants emitted from portable gas range was maximumly $3.131m^3/hr$ on the basis of $NO_2$ indoor air quality standard.

SCR Pilot Plant 성능실험 및 공정 설계 (Process Design and Performance Test of the SCR Pilot Plant)

  • 김정일;장인갑;선칠영
    • 청정기술
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    • 제9권2호
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    • pp.71-79
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    • 2003
  • 화력발전소에서 배출되는 질소산화물 제어를 위한 선택적 촉매 환원 공정은 안정적이며 고효율 설계가 가능하여 범용적으로 사용되고 있는 기술이다. 선택적 촉매 환원 공정의 최적 설계를 위해서는 촉매 특성에 따른 설계기술이 정립되어야 하며, 다양한 조건에 대한 설계경험이 필요하다. 본 연구에서는 SCR 공정의 설계자료 도출을 위해 설계/제작된 $1,000Nm^3/hr$급 SCR 파일럿 플랜트를 이용하여 반응온도, $NH_3/NO$ 몰비, 공간속도, 선속도 및 압력손실 등의 설계변수에 대한 성능실험을 수행하고, 도출된 실험 결과를 통한 설계과정을 기술하였다.

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Metal-Urea-Montmorillonite Hybrid Incorporated with Citric Acid

  • Kim, Kwang Seop;Kim, Min-Tae;Ryu, Jin-Hee;Choi, Jong-Seo;Park, Ki Do;Kang, Hang-Won;Park, Man
    • 한국토양비료학회지
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    • 제46권6호
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    • pp.610-614
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    • 2013
  • Massive intercalation of urea into montmorillonite (MUCH) was recently proposed to enhance urea use efficiency through smart suppression of emission of $NH_3$ and NOx. This study was to synthesize citrate-incorporated MUCH (Cit-MUCH) which can enhance suppression of $NH_3$ volatilization. The XRD pattern of Cit-MUCH was very similar to that of MUCH to indicate successful incorporation of citric acid into MUCH. Incorporation of citric acid was confirmed by the existence of $COO^-$ symmetric stretching vibration. During the initial 4 days after application, $NH_3$ volatilization from both bare and perilla-planted soils was much more suppressed by application of Cit-MUCH than MUCH. A peak volatilization rate decreased from 28.3 N mg $m^{-2}\;h^{-1}$ of MUCH-broadcasted soil to 22.2 N mg $m^{-2}\;h^{-1}$ of Cit-MUCH-broadcast soil. $NH_3$ volatilization was less in planted soil than bare soil for 72 hrs after application. These results showed that incorporation of citric acid led to increase in suppression of ammonia volatilization from urea-applied soils.

Low Calorific Gasturbine 매립지 적용 및 유리온실 운용기술 설계 (Design for Landfill Gas Application by Low Calorific Gas Turbine and Green House Optimization Technology)

  • 허광범;박정극;이정빈;임상규
    • 한국신재생에너지학회:학술대회논문집
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    • 한국신재생에너지학회 2010년도 춘계학술대회 초록집
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    • pp.244.1-244.1
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    • 2010
  • Bio energy development by using Low Calorific Gas Turbine(LCGT) has been developed for New & Renewable energy source for next generation power system, low fuel and operating cost method by using the renewable energy source in landfill gas (LFG), Food Waste, water waste and Livestock biogas. Low calorific fuel purification by pretreatment system and carbon dioxide fixation by green house system are very important design target for evaluate optimum applications for bio energy. Main problems and accidents of Low Calorific Gas Turbine system was derived from bio fuel condition such as hydro sulfide concentration, siloxane level, moisture concentration and so on. Even if the quality of the bio fuel is not better than natural gas, LCGT system has the various fuel range and environmental friendly power system. The mechanical characterisitics of LCGT system is a high total efficiency (>70%), wide range of output power (30kW - 30MW class) and very clean emmission from power system (low NOx). Also, we can use co-generation system. A green house designed for four different carbon dioxide concentration from ambient air to 2000 ppm by utilizing the exhaust gas and hot water from LCGT system. We look forward to contribute the policy for Renewable Portfolio Standards(RPS) by using LCGT power system.

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과급 디젤엔진에서 선회비 변경에 따른 흡기 포트유동 및 엔진성능 특성에 관한 연구 (A Study on the Characteristics of Intake Port Flow and Performance with Swirl Ratio Variance in a Turbocharged D.I. Diesel Engine)

  • 윤준규;차경옥
    • 대한기계학회논문집B
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    • 제24권9호
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    • pp.1185-1194
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    • 2000
  • The characteristics of intake port flow and engine performance with swirl ratio variance in a turbocharged D.I. diesel engine were studied in this paper. The intake port flow is important factor which have influence on the engine performance and exhaust emission because the properties in the injected fuel depend on the combustion characteristics. Through these experiments it can be expected to satisfy performance and emission by optimizing the main parameters; the swirl ratio of intake port, injection timing and compression ratio. The swirl ratio for ports was modified by hand-working and measured by impulse swirl meter. For the effects on performance and emission, the brake torque and brake specific fuel consumption were measured by engine dynamometer, NOx and smoke were measured by gas analyzer and smoke meter. The results of steady flow test are as follows; as the valve eccentricity ratio are closed to cylinder wall, the flow coefficient and swirl intensity are increased. Also we realized that there is a trade-off that the increase of swirl ratio decreases mean flow coefficient and increases the Gulf factor. And the optimum parameters to meet performance and emission through engine test are as follows; the swirl ratio 2.43, injection timing BTDC 13oCA and compression ratio 15.5.