• Title/Summary/Keyword: NO degradation

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Methodology to Simultaneously Optimize the Inlet Ozone Concentration to Oxidize NO and Relative Humidity Composition for the $NO_x$ Degradation using Soil Bio-filter

  • Cho, Ki-Chul;Hwang, Kyung-Chul
    • Journal of Korean Society for Atmospheric Environment
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    • v.24 no.E2
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    • pp.83-91
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    • 2008
  • This work investigated the methodology to simultaneously optimize the ozone and relative humidity composition for the $NO_x$ degradation using soil biofilter. Experiments were made as a function of inlet ozone concentration ($0{\sim}1,770\;ppb$) and relative humidity ($38{\sim}81%$). Factorial design ($2^2+3$) and response surface methodology by central composite designs were used to examine the role of two factors and optimal response condition on $NO_x$ degradation. It was found that a second-order response surface model can properly interpret the experimental data with an $R^2$-value of 0.9730 and F-value of 71.83, based on which the maximum $NO_x$ degradation was predicted up to 92.8% within our experimental conditions.

Evaluation of Natural Attenuation of Petroleum Hydrocarbons in a Shallow Sand Aquifer: a Modeling Study (자연저감 모델링 연구)

  • 이진용;이명재;이강근;이민효;윤정기
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2001.04a
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    • pp.128-131
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    • 2001
  • We evaluated natural attenuation of petroleum hydrocarbons in a shallow aquifer using a modeling study. The studied shallow aquifer was severely contaminated with petroleum hydrocarbons, especially toluene, ethylbenzene and xylenes (i.e, TEX). The exact spill history was not known. Therefor we used a contaminant level in May 1999 (the first sampling date of our integrated study) as an initial contaminant concentration. we calibrated required transport parameters using the contamination levels obtained from groundwater analyses in September of 1999. For fate and transport of the petroleum contaminants, five case 2 with sorption and degradation. case 3 with sorption and degradation (half decay constant compared with case 2), case 4 with degradation but no sorption, and case 5 with sorption but no degradation. For sorption and degradation, a linear sorption isotherm and first order irreversible decay was assumed, respectively and no additional contamination source to groundwater is also assumed.

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Characteristics of AC Hot-carrier-induced Degradation in nMOS with NO-based Gate Dielectrics (NO기반 게이트절연막 NMOS의 AC Hot Carrier 특성)

  • Chang, Sung-Keun;Kim, Youn-Jang
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.17 no.6
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    • pp.586-591
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    • 2004
  • We studied the dependence of hot-tarrier-induced degradation characteristics on nitrogen concentration in NO(Nitrided-Oxide) gate of nMOS, under ac and dc stresses. The $\Delta$V$_{t}$ and $\Delta$G$_{m}$ dependence of nitrogen concentration were observed, We observed that device degradation was suppressed significantly when the nitrogen concentration in the gate was increased. Compared to $N_2$O oxynitride, NO oxynitride gate devices show a smaller sensitivity to ac stress frequency. Results suggest that the improved at-hot carrier immunity of the device with NO gate may be due to the significantly suppressed interface state generation and neutral trap generation during stress.ess.

A Study of Optimal Mixture Fraction of Soil Bio-Filter for Removing NOX (질소산화물 제거를 위한 최적 토양 바이오 필터 혼합비 도출에 관한 연구)

  • Cho, Ki-Chul;Lee, Nae-Hyun
    • Journal of Environmental Science International
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    • v.16 no.11
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    • pp.1247-1255
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    • 2007
  • Soil biofiltration is an environmentally-sound technology for elimination of VOCs, odorous and $NO_X$ compounds from a low concentration, high volume waste gas streams because of its simplicity and cost-effectiveness. This study investigated the optimal mixture fraction of briquet ash, compost, soil and loess for $NO_X$ degradation. Extreme vertices design was used to examine the role of four components on $NO_X$ degradation. Under our experimental conditions, 74.5% of $NO_X$ degradation was observed, using a model mixture(25% briquet ash, 10% compost, 30% soil and 40% loess) containing 100 ppb of NO. It was shown that experimental design analysis could allow selecting optimal conditions in such biodegradation processes in this study.

Effects of Enzyme Application Method and Levels and Pre-treatment Times on Rumen Fermentation, Nutrient Degradation and Digestion in Goats and Steers

  • Hong, S.H.;Lee, B.K.;Choi, N.J.;Lee, Sang S.;Yun, S.G.;Ha, J.K.
    • Asian-Australasian Journal of Animal Sciences
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    • v.16 no.3
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    • pp.389-393
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    • 2003
  • Present study investigate the effect of enzyme supplementation, methods (applied to rumen or enzyme treated diet) compared with no enzyme diet, on rumen fermentation and apparent nutrient digestibility in a $3{\times}3$ Latin square design with three rumen cannulated Korean Native goats. In situ rumen degradation kinetics was studied in three rumen cannulated Holstein steers. Three diets were, no enzyme, 1% enzyme in rumen and 1% enzyme in diet. The enzyme was sprayed onto forage, and the forage: concentrate ratio was 30:70. Degradation kinetics was studied with three enzyme levels (0, 1 and 2%, w/w) and four pre-treatment times (0, 1, 12 and 24 h). Results suggested that enzyme application method did not affect rumen fermentation, ruminal enzyme activity and total tract apparent digestibility. Nutrient degradation rate and effective degradability of DM, NDF and ADF increased with increasing enzyme level and pre-treatment times. Degradation of nutrients was affected by enzymes levels or pre-treatment times. Therefore, it is probable that the improved degradation may be due to the supplemented exogenous hydrolytic enzymes under a certain condition.

The Effect of $SO_2$ on the Degradation of Chlorophyll in Green perilla (Perilla frutescens Suwon No. 8) (($SO_2$ 에 의한 들깨(수원(水原) 8호(號))의 엽록체분해(葉綠體分解)에 대하여)

  • Kim, Jeong-Gyu;Lim, Soo-Kil
    • Korean Journal of Environmental Agriculture
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    • v.6 no.2
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    • pp.73-76
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    • 1987
  • The effects of light, active oxygen, inorganic $SO_3\;^{-2}\;ion$, $SO_2$ fumigation duration, $SO_2$ concentration on the degradation of photosynthetic pigments in Green perilla (Perilla frutescens Suwon No. 8) fumigated by $SO_2$ were investigated inside a phytotron. The results were as follows: 1. With the increase of the $SO_2$ dosage, visible injury and the degradation of chlorophyll increased. 2. The degradation of chlorophyll b was less than that of chlorophyll a and the carotinoid was more easily degratated than chlorophyll b. 3. The degradation of chlorophyll by $SO_2$ fumigation was induced directly by $SO_2$, itself. 4. Light is necessary to the degradation of chlorophyll. $SO_2$ and $O_2^-$ made in the photolysis process of the water molecule were the major components in the degradation of chlorophyll.

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RUMEN DEGRADABILITY OF ITALIAN RYEGRASS (Lolium multiflorum, L) HARVESTED AT THREE DIFFERENT GROWTH STAGES IN SHEEP

  • Fariani, A.;Warly, L.;Matsui, T.;Fujihara, T.;Harumoto, T.
    • Asian-Australasian Journal of Animal Sciences
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    • v.7 no.1
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    • pp.41-48
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    • 1994
  • This experiment was carried out in order to evaluate the chemical composition and rumen degradation characteristics of Italian ryegrass harvested at three different growth stages, i,e. pre-blooming, early-blooming and late-blooming. Degradation values were obtained by incubation of the samples using the nylon bag technique on the rumen of sheep fed a normal diet (Timothy hay with 200 g/d concentrate per head) for 12, 24, 36, 48 and 72 hours, respectively. Neutral detergent fiver (NDF) content was highest at late-blooming (64.4%) while no difference was found among the pre-blooming and early-blooming (49.4% vs 48.3%). However, acid detergent fiber (ADF) content markedly increased from 30.0% at pre-blooming to 35.4% and 46.4% at early-blooming and late-blooming, respectively. Lignin and silica contents also increased as advancing maturity of the grass, Rumen degradation of dry matter (DM) significantly reduced (p < 0.05) as advancing maturity of the grass. Ruman degradation cellulose and ADF at pre-blooming were significantly higher (p < 0.05) than those of early-blooming and late-blooming. However, no significant differences were observed among the early-blooming and late-blooming. With advancing maturity, rumen degradation of NDF and hemicellulose significantly reduced (p < 0.05) at the incubation times.

Kinetics of Metolachlor Degradation by Zerovalent Iron (Zerovalent Iron에 의한 Metolachlor의 분해 Kinetics)

  • Kim, Su-Jung;Oh, Sang-Eun;Yang, Jae-E.
    • Korean Journal of Environmental Agriculture
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    • v.26 no.1
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    • pp.55-61
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    • 2007
  • Metolachlor may pose a threat to surface and ground water qualities due to its high solubility in water, Zerovalent iron (ZVI) releases $e^-$ which can degrade the organochlorinated compounds. The objective of this research was to evaluate the kinetics of metolachlor degradation as affected by ZVI sources [Peerless unannealed (PU) and Peerless annealed (PA)] and ZVI levels (1 and 5%) under batch conditions at different metolachlor concentrations (200 and 1000 mg/l) and temperatures (15, 25, and $35^{\circ}C$). The effectiveness of ZVI on metolachlor degradation was assessed by characterizing the dechlorinated metolachlor byproduct molecules. Metolachlor degradation by ZVI followed the first-ordered kinetics with a higher rate constant at higher level of ZVI treatment. At 5% (w/v) of PU and PA treatment, the half-lives of metolachlor degradation were 9.93 and 6.51 h and all of the initial metolachlor were degraded in 72 and 48 h, respectively. Rate constants (k) of metolachlor degradation were higher at the lower initial metolachlor concentration. The metolachlor degradation by ZVI was temperature dependent showing that the rate constant (k) at 15, 25, and $35^{\circ}C$ were 0.0805, 0.1017, and 0.3116 /h, respectively. The ZVI-mediated metolachlor degradation yielded two byproduct molecules identified as dechlorinated metolachlor $(C_{13}H_{18}NO)$ and dechlorinated-dealkylated metolachlor $(C_{12}H_{17}NO)$. The PA ZVI was more effective than PU ZVI in metolachlor degradation.

Characteristics of Organic Acid Degradation by Yeast (고농도 유기산폐수의 효모에 의한 분해연구)

  • 김석원;허병기;김은기
    • KSBB Journal
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    • v.14 no.2
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    • pp.136-140
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    • 1999
  • Characteristics of organic acid degradation by isolated yeast strain was investigated. Optimum initial pH was 5. Increase in cell mass was proportional to the decrease in organic acid degradation. Also no accumulation of byproduct was observed during degradation. Acetic acid degraded fast, followed by butyric acid and propionic acid in order. No significant substrate inhibition was observed up to 12 g/L of acetic acid 7 g/L of propionic acid, respectively. However, inhibition of butyric acid was significant above 4 g/L. Cell mass yield was 0.2-0.4 g cell/g acids and decreased at high decreased at high organic acid concentration. 95% of organic acid (7.5 g/L), corresponding to 13,000 ppm, was degraded in 30-40 hours.

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Effect of Acanthopanax senticosus Extracts on Alcohol Degradation and Anti-Inflammatory Activity in Mice (가시오가피 추출물의 알코올 분해 및 항염증 효과)

  • Yoon, Taek-Joon;Jo, Seon-Yoong
    • The Korean Journal of Food And Nutrition
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    • v.23 no.4
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    • pp.542-548
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    • 2010
  • This study was conducted to investigate the effects of Acanthopanax senticosus extracts(ASE) on alcohol administered mice. The administration of Acanthopanax senticosus extracts(60 mg/kg) had beneficial actions toward alcohol degradation in acute alcohol treated mice. In the acute alcohol degradation experiment, serum alcohol concentration were lower 3 and 6 hours after taking ethanol(5 g/kg) in ASE treated mice. The oral administration of ASE showed decreased gastric mucous membrane damage produced in ethanol treated mice. In addition, intraperitoneal(i.p.) administration of ASE showed antiinflammatory effects in inhibition tests of vascular permeability produced by acetic acid. ASE also reduced concentrations of nitric oxide(NO), tumor necrosis alpha(TNF)-${\alpha}$ and interleukin(IL)-6 in macrophages that were activated by LPS. These results demonstrate that Acanthopanax senticosus extracts possesses the potential to stimulate alcohol degradation and inhibit inflammatory effects in mice.