• Korean Journal of Environmental Agriculture
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• v.26 no.1
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• pp.1-6
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• 2007

In view of energy supply, biogas can be seen as alternative fuel by substituting considerable amount of fossil fuel and may be utilized for heat and power production or for transport fuel production ($CH_4-enriched$ biogas). The aim of this research is to analyse the emission of $NO_x$ and CO from biogas fired combustion engine for electric power production. The result indicate a significant effect of biogas composition ($CH_4-CO_2$ ratio) and biogas flow rate on the air pollutants emission. The emission factors from this study were compared with those of U.S. EPA. Low $CH_4-CO_2$ ratio condition typically shows the lower $NO_x$ and CO emission than higher $CH_4-CO_2$ ratio condition. At normal $CH_4-CO_2$ ratio (7:3) emission factors of $NO_x$ and CO were 1.29 and 30.43 g/MMBtu, respectively. At low $CH_4-CO_2$, ratio (6:4) emission factors of $NO_x$ and CO were 0.646 and 60.86 g/MMBtu, respectively, It should be emphasized that the actual emission may vary considerably from these results due to operating conditions including torque load and engine speed.

• Journal of Korean Society for Atmospheric Environment
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• v.13 no.6
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• pp.451-461
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• 1997

The soil NO flux measurements in Korea were made from 17 May 1997 to 16 June 1997 on grass land at Kunsan National University in southwestern Korea by using flow-through chamber technique. The experiment was conducted in an effort to determine the role of natural emissions of NO on rural atmospheric photochemistry, and to understand the soil NO emission mechanism with respect to soil parameters. Soil NO fluxes were measured every minutes and averaged in every 15 minutes as well as soil temperature. Soil samples were analyzed for $NO_3^-, NH_4^+$, and moisture in soil. Soil nitrate was not detected in most times, and total N-containing was limited in site soils. There was a optimum range of soil moisture and temperature for soil NO flux. The overall average of soil NO emission rates were found to be 1.30 $\pm 0.92 ngNm^{-2}s^{-1}$ (n=1219), and ranged from 0.01 ngNm^{-2}s^{-1}$ to 5.62 ngNm^{-2}s^{-1}$. Diurnal variation of soil NO emission was typical, which was in higher level during daytime, and was in lower level over the night. NO flux showed a strong soil temperature dependence $(r^2=0.78)$, but not with soil moisture and soil N-containing during this experimental period; NO fluxes increased exponentially as soil temperature increased. In order to assure the relevant relationship between soil NO flux and the soil parameters, long-term soil flux measurement on different types of land use should be planned and conducted continuously.

• Journal of Korean Society for Atmospheric Environment
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• v.29 no.6
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• pp.745-756
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• 2013

The purpose of this study is to evaluate representativeness of fuel-based emission factors. Twelve light-duty diesel vehicles which meet Euro-3 to 5 legislative emission limits were selected for emission tests. Second-by-second modal emission rates of vehicles were measured on a standard laboratory chassis dynamometer system. An off-cycle driving cycle was developed as a representative Korean real-world on-road driving cycle. Fuel-based emission factors were developed for short trip segments that involved in the selected driving cycle. Each segment was defined to have unit travel distance, which is 1 km, and characterized by its average speed and Relative Positive Acceleration (RPA). Fuel-based $NO_x$ emission factors demonstrate relatively good representativeness in terms of vehicle operation conditions. $NO_x$ emission factors are estimated to be within ${\pm}20%$ of area-wide emission factor under more than 40% of total driving situations. This result implies that the fuel-based $NO_x$ emission factor could be practically implemented into the on-road emission management strategies, such as a remote sensing device (RSD). High emitting vehicles as well as high emitting operating conditions heavily affect on the mean values and distributions of CO and THC emission factors. Few high emitting conditions are pulling up the mean value and biasing the distributions, which weaken representativeness of fuel-based CO and THC emission factors.

• 한국연소학회:학술대회논문집
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• 2003.05a
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• pp.129-136
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• 2003

Numerical study with momentum-balanced boundary conditions has been conducted to grasp chemical effects of added $CO_{2}$ and $H_{2}O$ to fuel- and oxidizer-sides on flame structure and NO emission behavior in $CH_{4}$/Air counterflow diffusion flames. The dilution with $H_{2}O$ results in significantly higher flame temperatures and NO emission, but dilution with $CO_{2}$ has much more chemical effects than that with $H_{2}O$. Maximum reaction rate of principal chain branching reaction due to chemical effects decreases with added $CO_{2}$. but increases with added $H_{2}O$. The NO emission behavior is closely related to the production rate of OH, CH and N. The OH radical production rate increases with added $H_{2}O$ but those of CH, N decrease. On the other hand the production rates of OR CH and N decrease with added $CO_{2}$. It is found that NO emission behavior is considerably affected by chemical effects of added $CO_{2}$ and $H_{2}O$.

• Applied Chemistry for Engineering
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• v.20 no.6
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• pp.675-680
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• 2009

This article describes NO emission characteristics in SM coal combustion. Combustion experiments was performed in the method of increasing temperature after feeding coal and feeding coal after increasing temperature. NOx emission is in inverse proportion to combustion temperature at the fuel rich condition and it was caused by conversion fuel N to $N_{2}$ at the strong reduction condition. In addition, feeding gas flow rate increased as total fuel NOx increase by conversion of fuel N to NO at the oxidation condition. It could be separated in total fuel-N, volatile-N, char-N to NO according to analysis of total fuel NO emission from char combustion at each temperature. In the result, almost total NOx emission was caused by volatile-N in SM-coal.

• Journal of Korean Society for Atmospheric Environment
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• v.25 no.5
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• pp.369-381
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• 2009

The objective of this study was to simulate surface air pollutants and to examine reliability of mobile emission for CMAQ system using an observation-based approach in the Seoul Metropolitan Area. Accurate assessment of emissions from mobile source is one of the most debatable parts in the entire emissions inventory process. For this study, we evaluated the official emission inventories of Volatile Organic Compounds (VOCs) and nitrogen oxides ($NO_x$) using an observation-based approach. In this paper, we achieved VOCs/CO and $NO_x$/CO ratios derived from ambient measurements taken from June to August of 2005 in early morning (07:00~08:00). And we compared them with those derived from the emission inventory. Based on these ratios and on the assumption that official inventory of CO emissions is reasonably accurate, mobile emissions of $NO_x$ seem to be slightly overestimated and VOCs emissions significantly underestimated. The results of simulations using modified emission of mobile source were in closer agreement with the observation results except NO. Predicted NO values based on revised $NO_x$ emissions were considerably lower than the observed values. Using modified emission inventories brings the modeled values into closer agreement with observed ozone levels in Seoul. Especially in case of CO, $NO_x$ and VOCs emission, the modified values were suitable for simulating ozone levels in Seoul and Gyeonggi. However, ozone values predicted using the modified emissions were higher than the observed and predicted values based on original emissions. According to the 95 percentile ozone concentrations, emission revised by CO, $NO_x$ and VOCs from mobile source was the best for predicting high concentration.

• Journal of Environmental Science International
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• v.17 no.12
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• pp.1413-1419
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• 2008

The Kyoto Protocol, that had been in force from February 16, 2005, requires significant reduction in $CO_2$ emissions for all anthropogenic sources containing transportation, industrial, commercial, and residential fields, etc, and automotive emission standards for air pollutants such as particulate matter (PM) and nitrogen oxides $(NO_x)$ become more and more tight for improving ambient air quality. This paper has briefly reviewed homogeneous charge compression ignition (HCCI) combustion technology offering dramatic reduction in $CO_2,\;NO_x$ and PM emissions, compared to conventional gasoline and diesel engine vehicles, in an effort of automotive industries and their related academic activities to comply with future fuel economy legislation, e.g., $CO_2$ emission standards and corporate average fuel economy (CAFE) in the respective European Union (EU) and United States of America (USA), and to meet very stringent future automotive emission standards, e.g., Tier 2 program in USA and EURO V in EU. In addition, major challenges to the widespread use of HCCI engines in road applications are discussed in aspects of new catalytic emissions controls to remove high CO and unburned hydrocarbons from such engine-equipped vehicles.

• Journal of Korean Society for Atmospheric Environment
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• v.11 no.E
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• pp.31-43
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• 1995

Natural emissions of NOx from soils were measured at an agricultural corn field during 3 weeks of growing season in summer (from May to June) 1995. This experiment was conducted in an effort to characterize the role of soil NOx on tropospheric ozone formation in rural atmosphere, and understand the natural NOx emission mechanism with respect to soil parameters. NO fluxes were ranged from 3.1 ng Nm$^{-2}s^{-1}$ to 259.0 ng Nm$^{-2}s^{-1}$, and average NO flux during experimental period was found to be 47.6 $\pm$ 50.6 ng Nm$^{-2}s^{-1}$ with 732 number of data. Diurnal variation of NO flux was shown clearly with daytime maximum and nighttime minimum. NO fluxes were correlated with soil temperature. Exponential soil temperature dependency of NO fluxes was found with 0.0160$^{circ}C^{-1} of k and r^2=0.508$, which agrees well to the value estimated at corn fields in eastern United States. The significant increases of NO fluxes from agricultural soil were detected after applying N fertilizers to soil. THe mechanisms attributed to this are enhanced biological nitrification and denitrification. In the view of rural ozone formation, the roles of natural NO emissions are very essential, especially in NOx - limited region such as southern United States.

• Korean Journal of Soil Science and Fertilizer
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• v.44 no.6
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• pp.1232-1238
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• 2011

This experiment was conducted to measure concentration of dissolved $N_2O$ in ground-water of 59 wells and to make emission factor for assessment of indirect $N_2O$ emission at agricultural sector in agricultural areas of Gyeongnam province from 2007 to 2010. Concentrations of dissolved $N_2O$ in ground-water of 59 wells were ranged trace to $196.6{\mu}g-N\;L^{-1}$. $N_2O$ concentrations were positively related with $NO_3$-N suggesting that denitrification was the principal reason of $N_2O$ production and $NO_3$-N concentration was the best predictor of indirect $N_2O$ emission. The ratio of dissolved $N_2O$-N to $NO_3$-N in ground-water was very important to make emission factor for assessment of indirect $N_2O$ emission at agricultural sector. The mean ratio of $N_2O$-N to $NO_3$-N was 0.0035. It was greatly lower than 0.015, the default value of currently using in the Intergovernmental Panel on Climate Change (IPCC) methodology for assessing indirect $N_2O$ emission in agro-ecosystems (IPCC, 1996). It means that the IPCC's present nitrogen indirect emission factor ($EF_{5-g}$, 0.015) and indirect $N_2O$ emission estimated with IPCC's emission factor are too high to use adopt in Korea. So we recommend 0.0034 as national specific emission factor ($EF_{5-g}$) for assessment of indirect $N_2O$ emission at agricultural sector. Using the estimated value of 0.0034 as the emission factor ($EF_{5-g}$) revised the indirect $N_2O$ emission from agricultural sector in Korea decreased from 1,801,576 ton ($CO_2$-eq) to 964,645 ton ($CO_2$-eq) in 2008. The results of this study suggest that the indirect Emission of nitrous oxide from upland recommend 0.0034 as national specific emission factor ($EF_{5-g}$) for assessment of indirect $N_2O$ emission at agricultural sector.

• 한국연소학회:학술대회논문집
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• 2012.04a
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• pp.263-266
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• 2012

The characteristics of mild combustion and pollutant emission were investigated computationally with supplied air stream temperature and dilution rate in jet flame. The air was diluted with main combustion products. As dilution rate increased at fixed air temperature, the temperature distribution of burner inside was uniformed and the maximum mole fraction of CO and NO was decreased. In addition, emission indices for NO, CO, and $CO_2$ were compared with air temperature and dilution rate.