• Title/Summary/Keyword: NIR analysis

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Classification of papers using IR and NIR spectra and principal component analysis (IR 및 NIR 스펙트럼과 주성분 분석을 통한 지종의 분류)

  • Kim, Kang-Jae;Eom, Tae-Jin
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.48 no.1
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    • pp.34-42
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    • 2016
  • In this study, we classified three copying papers and Korean, Chinese, and Japanese traditional papers using IR and/or NIR spectra and principal component analysis. Various chemicals are used when producing fine papers. In this case, the IR method to analyze functional groups is suitable for the classification of paper. On the other hand, NIR analysis is more suitable for the classification of traditional papers, as it uses nearly raw materials (pulp). Therefore, principal component analysis using IR and NIR depending on the paper production process will be the classification tool of paper.

Comparison of Korean and Japanese Rice Cultivars in Terms of Physicochemical Properties (I) The Comparison of Korean and Japanese Rice by NIR and Chemical Analysis (한국 쌀과 일본 쌀의 물리화학적 특성 연구 (I) NIR을 사용한 한국 쌀과 일본 쌀의 품질 비교)

  • 김혁일
    • Journal of the East Asian Society of Dietary Life
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    • v.14 no.2
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    • pp.135-144
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    • 2004
  • A total of 40 Korean and Japanese rice varieties were evaluated for their main chemical components, physical properties, cooking quality, pasting properties, and instrumental measurements. Based on their quality evaluations, it was concluded that Korean and Japanese rice varieties were not significantly different in the basic components of NIR (Near Infra Red) data and the chemical analysis from the uncooked brown and milled rices. Korean rice had a little bit higher protein and amylose contents but much lower fat acidity than those of Japanese rice from the chemical analysis. From all the data of three different kinds of NIR methods, Korean and Japanese milled rice were very similar except the taste score. Japanese rice showed a slightly higher taste score, a little bit higher lightness and whiteness, but lower yellowness and redness than Korean one. From all those data of NIR and the chemical analysis, Korean and Japanese rices had very similar components except the fat content.

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Thermal denaturation analysis of protein

  • Miyazawa, Mitsuhiro
    • Proceedings of the Korean Society of Near Infrared Spectroscopy Conference
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    • 2001.06a
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    • pp.1628-1628
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    • 2001
  • Near infrared (NIR) spectroscopy is a powerful technique for non-destructive analysis that can be obtained in a wide range of environments. Recently, NIR measurements have been utilized as probe for quantitative analysis in agricultural, industrial, and medical sciences. In addition, it is also possible to make practical application on NIR for molecular structural analysis. In this work, Fourier transform near infrared (FT-NIR) measurements were carried out to utilize extensively in the relative amounts of different secondary structures were employed, such as Iysozyme, concanavalin A, silk fibroin and so on. Several broad NIR bands due to the protein absorption were observed between 4000 and $5000\;^{-1}$. In order to obtain more structural information from these featureless bands, second derivative and Fourier-self-deconvolution procedures were performed. Significant band separation was observed near the feature at $4610\;^{-1}$ ,. Particularly the peak intensity at $4525\;^{-1}$ shows a characteristic change with thermal denaturation of fibroin. The structural information can be also obtained by mid-IR and CD spectral. Correlation of NIR spectra with protein structure is discussed.

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Rapid Compositional Analysis of Naphtha by Near-Infrared Spectroscopy

  • 구민식;정호일;이준식
    • Bulletin of the Korean Chemical Society
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    • v.19 no.11
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    • pp.1189-1193
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    • 1998
  • The determination of total paraffin, naphthene, and aromatic (PNA) contents in naphtha samples, which were directly obtained from actual refining process, has been studied using near-infrared (NIR) spectroscopy. Each of the total PNA concentrations in naphtha has been successfully analyzed using NIR spectroscopy. Partial least squares (PLS) regression method has been utilized to quantify the total PNA contents in naphtha from the NIR spectral bands. The NIR calibration results showed an excellent correlation with those of conventional gas chromatography (GC). Due to its rapidity and accuracy, NIR spectroscopy is appeared as a new analytical technique which can be substituted for the conventional GC method for the quantitative analysis of petrochemical products including naphtha.

Comparison of Near-Infrared Spectroscopy with Raman Spectroscopy from the Point of Nondestructive Analysis of Biological Materials

  • Takeyuki Tanaka;Hidetoshi Sato;Jung, Young-Mee;Yukihiro Ozaki
    • Near Infrared Analysis
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    • v.1 no.2
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    • pp.9-20
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    • 2000
  • Recently, near-infrared (NIR) spectroscopy and Raman spectroscopy have received keen interest as powerful techniques for nondestructive analysis of biological materials. The purpose of this review paper is to compare the advantages of NIR and Raman spectroscopy in the nondestructive analysis. Both methods are quite unique and often complementary. For example. NIR spectroscopy is very useful in monitoring in situ the content of components inside biological materials while Raman spectroscopy is very suitable for identifying micro-components on the surface of biological materials. In this article specific characters of the two spectroscopic methods are discussed first and then several examples of applications of NIR and Raman spectroscopy to the biological nondestructive analysis are introduced.

Algorithm for Finding the Best Principal Component Regression Models for Quantitative Analysis using NIR Spectra (근적외 스펙트럼을 이용한 정량분석용 최적 주성분회귀모델을 얻기 위한 알고리듬)

  • Cho, Jung-Hwan
    • Journal of Pharmaceutical Investigation
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    • v.37 no.6
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    • pp.377-395
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    • 2007
  • Near infrared(NIR) spectral data have been used for the noninvasive analysis of various biological samples. Nonetheless, absorption bands of NIR region are overlapped extensively. It is very difficult to select the proper wavelengths of spectral data, which give the best PCR(principal component regression) models for the analysis of constituents of biological samples. The NIR data were used after polynomial smoothing and differentiation of 1st order, using Savitzky-Golay filters. To find the best PCR models, all-possible combinations of available principal components from the given NIR spectral data were derived by in-house programs written in MATLAB codes. All of the extensively generated PCR models were compared in terms of SEC(standard error of calibration), $R^2$, SEP(standard error of prediction) and SECP(standard error of calibration and prediction) to find the best combination of principal components of the initial PCR models. The initial PCR models were found by SEC or Malinowski's indicator function and a priori selection of spectral points were examined in terms of correlation coefficients between NIR data at each wavelength and corresponding concentrations. For the test of the developed program, aqueous solutions of BSA(bovine serum albumin) and glucose were prepared and analyzed. As a result, the best PCR models were found using a priori selection of spectral points and the final model selection by SEP or SECP.

Analysis of Crop Protection Products using FT-NIR (FT-NIR을 이용한 농약제품분석)

  • Choi, Dal-Soon;Kwon, Oh-Kyung;Kwon, Hye-Young;Hong, Su-Myeong;Kyung, Suk-Hun;Choi, Ju-Hyun
    • The Korean Journal of Pesticide Science
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    • v.10 no.2
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    • pp.84-90
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    • 2006
  • In the field of agriculture, FT-NIR mainly has been used in qualitative management of produces without sample preparation with a data set built from a quantitative value of sample components confirmed by another analytical instrument. On the other hand, inert materials of crop protection products nearly haven't examined instrumental analysis because of analytical problems of high-molecular inert materials and a variety of formulation type. This study, results make it possible to solve an analytical problems of crop protection products using FT-NIR chemometrics technique from spectrum calculator module.

Image Processing for Recognition of Cow Teats and Selection of a NIR Filter for Robot Milking System (로봇 착유시스템을 위한 NIR 필터 선정 및 유두인식 영상처리)

  • Kim W.;Lee D. W.
    • Journal of Biosystems Engineering
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    • v.30 no.5 s.112
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    • pp.299-305
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    • 2005
  • This study was developed image processing algorithm for recognition of few teats of a cow in the image using black and white camera attached with infrared filter. Spectroscopic analysis was used for selection of a NIR filter to separate teats from udder skin in the image captured. To verify the performance of image processing algorithm was developed and NIR filter was selected, carried out an experiment with cows. NIR band-pass filter was used to pass the 975nm band of light spectrum. The image processing algorithm was developed could recognize all teats and the process time was 0.9 second to recognize the all teats and to acquire end position of teats.

The Quantification and Validation of Loxoprofen using Near-infrared(NIR) Spectrum Method (근적외부스펙트럼 측정법을 이용한 록소프로펜의 정량화 및 밸리데이션)

  • Choi, Sung-Up
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.15 no.1
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    • pp.396-401
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    • 2014
  • In this study, we used NIR spectrum method instead of conventional HPLC method to shorten the analysis and manufacturing time of the loxoprofen products. Loxoprofen mixtures with other pharmaceutical additives were prepared and evaluated by the NIR spectrometer and the HPLC system. Validation of both methods was performed for specificity, accuracy and precision. NIR spectrometer method was validated and revealed proper results for the in-process quality control in the pharmaceutical field. In conclusion, NIR spectrometry can be replaced by HPLC method.

Defect Detection of ‘Fuji’ Apple using NIR Imaging(I) -Optical characteristics of defects and selection of significant wavelelength- (근적외선 영상을 이용한 후지사과의 결점 검출에 관한 연구 (I) -결점의 광학적 특성 구명 및 유의파장 선정-)

  • 이수희;노상하
    • Journal of Biosystems Engineering
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    • v.26 no.2
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    • pp.169-176
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    • 2001
  • Defect of apple was depreciated the product value and causes storage disease seriously. To detect the defect of ‘Fuji’apple with machine vision system, the optical characteristics of defect should be investigated. In this research, absorbance spectra of defect were acquired by spectrophotometer in the range of visible and NIR region(400∼1,100nm) and L*a*b* color values were also acquired by colorimeter. NIR machine vision system was constructed with B&W camera, frame grabber, 16 tungsten-halogen lamps, variable focal length lens and NIR bandpass filter which was mounted to lens outward. Average gray values of defect at 15 NIR wavelength were acquired and the significant NIR wavelength was selected by comparing Mahalanobis distance between sound and defective apple. As the result of Mahalanobis distance analysis, the significant wavelength to discriminate the defectives in ‘Fuji’apple were found to be 720nm for scab and 970nm for bruise and cuts and 920nm was also effective regardless of defective types.

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