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Double Salt Precipitation Behavior of Rare Earth by Sodium Sulfate in Sulfuric Liquor of Waste Permanent Magnet Scrap (폐 영구자석 스크랩 황산침출용액으로부터 황산나트륨에 의한 희토류 원소 복염침전 거동 고찰)

  • Yoon, Ho-Sung;Kim, Chul-Joo;Chung, Kyeong Woo;Kim, Ji-Hye;Lee, Eun-Ji;Yoo, Seung-Joon
    • Resources Recycling
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    • v.26 no.5
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    • pp.39-47
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    • 2017
  • In this study, the precipitation of rare earth-sodium sulfate with sodium sulfate was conducted in order to separate rare earth from Fe in rare earth sulfate solution. Neodymium (Nd) was easily precipitated as Nd-sulfate salt with sodium sulfate, on the other hand, excessive sodium sulfate was needed for the precipitation of Dy-sulfate salt. Also neodymium not only promoted the precipitation of dysprosium sulfate salt but also increased recovery of dysprosium sulfate salt in sulfuric acid solution. At the condition of $60^{\circ}C$ precipitation temperature, 3 h reaction time, 7 equivalents sodium sulfate, the recovery of neodymium and dysprosium sulfate salt was 99.7% and 94.3% respectively from the sulfuric acid solution containing Nd of 23.39 mg/ml and Dy of 8.67 mg/ml. Lastly, from the results of separation of Dy to Nd by the method of sulfate double salt, the effect of salting out with NaCl is important to increase the grade of Dy, and 98.7% of Dy grade could be obtained in this study.

An Experimental Study on Improved Fuel Economy and Lower Exhaust Emissions of New Automotive Engine adopting Split Cooling System

  • Oh, C.S.;Lee, J.H.;Shin, S.Y.;Kim, W.T.
    • Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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    • 2002.10b
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    • pp.407-408
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    • 2002
  • This paper presents a split cooling system for a new inline 4-cylinder automotive engine. The split cooling system circulates coolant to the cylinder head and cylinder block separately. The coolant flow in the cylinder block is controlled by a $2^{nd}$ Thermostat installed at the outlet of cylinder block. The $2^{nd}$ thermostat closes when the coolant temperature is low. And this makes the coolant flow in cylinder block nearly stagnant, thereby reducing the coolant-side heat transfer coefficient and raising cylinder bore temperature. The $2^{nd}$ thermostat starts to open when the coolant temperature reaches a specified temperature. The test results on engine dynamometer show improved fuel economy and lower exhaust emission which result from the decrease in friction works and cooling loss. Also, several vehicle tests, with application of the new engine have been performed. Fuel economy improvement of 0.5{\sim}2.0%$ yields from different test modes and details are discussed in this paper.

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Introduction and Expression of a Thaumatin-like Protein from Rice in American Ginseng Following Agrobacterium-mediated Transformation

  • Chen, W.P.;Punja, Z.K.
    • Journal of Ginseng Research
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    • v.27 no.1
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    • pp.17-23
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    • 2003
  • Agrobacterium-mediated transformation of American ginseng (Panax quinquefolius L.) with strain LBA 4404 containing a rice thaumatin-like protein gene is described. The selectable markers used were phosphinothricin acetyltransferase and hygromycin phosphotransferase genes. Epicotyl explants from seedlings were precultured for 5-7 days on Murashige and Skoog medium with ${\alpha}$-naphthaleneacetic acid and 2,4 dichlorophenoxyacetic acid at 10 ${\mu}$M and 9 ${\mu}$M, respectively (ND medium), prior to Agrobacterium infection. The explants were immersed in a bacterial suspension for 20 min. A post-infection co-culture period of 3-4 days was provided on ND medium. Selection for transformed calli was conducted on ND medium with 20 mg/L phosphinothricin followed by 100 mg/L hygromycin over an 8-month period. it transformation frequency of 24.8% was achieved at the callusing phase. The presence of the transgenes in calli was confirmed by Southern hybridization and polymerase chain reaction analysis. The expression of the thaumatin-like protein gene in ginseng calli was demonstrated by Western blot analysis. Somatic embryos were produced from both transgenic calli and suspension cultures, and plantlets were recovered that expressed the transgenic thaumatin-like protein gene.

On a Split Model for Analysis Techniques of Wideband Speech Signal (광대역 음성신호의 분할모델 분석기법에 관한 연구)

  • Park, Young-Ho;Ham, Myung-Kyu;You, Kwang-Bock;Bae, Myung-Jin
    • The Journal of the Acoustical Society of Korea
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    • v.18 no.7
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    • pp.80-84
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    • 1999
  • In this paper, the split model analysis algorithm, which can generate the wideband speech signal from the spectral information of narrowband signal, is developed. The split model analysis algorithm deals with the separation of the 10/sup th/ order LPC model into five cascade-connected 2/sup nd/ order model. The use of the less complex 2/sup nd/ order models allows for the exclusion of the complicated nonlinear relationships between model parameters and all the poles of the LPC model. The relationships between the model parameters and its corresponding analog poles is proved and applied to each 2/sup nd/ order model. The wideband speech signal is obtained by changing only the sampling rate.

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Structural, Optical and Electrical Properties of AI Doped ZnO Thin Films Prepared by Nd:YAG-PLD Technology (Nd:YAG-PLD법에 의해 제작된 ZnO:AI 박막의 구조적, 광학적, 전기적 특성)

  • No, Im-Jun;Lim, Jae-Sung;Lee, Cheon;Shin, Paik-Kyun
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.56 no.9
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    • pp.1596-1601
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    • 2007
  • Aluminum doped zinc oxide (AZO) thin films were deposited on coming glass substrates using an Nd:YAG pulsed laser deposition technology. The AZO thin films were deposited with various growth conditions such as the substrate temperature and oxygen partial pressure. In this work, we used various measurement technologies in order to investigate the electrical, structural, and optical properties of the AZO thin films. Among the AZO thin films, the one prepared at the substrate temperature of $300^{\circ}C$ and oxygen partial pressure of 5 mTorr showed the best properties of an electrical resistivity of $4.63{\times}10^{-4}{\Omega}{\cdot}cm$, a carrier concentration of $9.25{\times}10^{20}cm^{-3}$, and a carrier mobility of $31.33cm^2/V{\cdot}s$. All the AZO thin films showed an high average optical transmittance over 90 % in visible region.

Mechanism of Intercalation Compounds in Graphite with Hydrogen Sulfate (I. Study of Intermediate Phase between 2 Stage and 1 Stage in Graphite Hydrogen Sulfate with Anodic Oxidation) (흑연에 황산을 Intercalation 시킬때의 Mechanism 규명 (I. 전기적 산화방법에 의한 Graphite Salts의 중간상에 관한 연구))

  • 고영신;한경석;이풍헌
    • Journal of the Korean Ceramic Society
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    • v.22 no.6
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    • pp.5-8
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    • 1985
  • Graphite has been oxidized to graphite hydrogen sulfate in concentrated $H_2SO_4$. Anodic oxidation and chemical oxidation of graphite in $H_2SO_4$ generally leads to the formation of intercalation compounds of the ionic salt type through incorporation of $H_2SO_4^-$ions and $H_2SO_4$ molecules into the graphite. Several other reactions also accur at various points of the charging cycle. But there is no satisfactory kinetics and mechanism of intercalationin graphite. We have studied them with anodic oxidation and chemical oxidation. We found six distinct phenomena between 2nd stage and 1st stage in chemical oxidation. We examined them in detail by the following in the measurements electrical oxidation. X-ray diffractions UV-Vis spectroscopy density measurements. We could obtained a equation for kinetic according to the reaction rate from this results and mechanism of intercalation between 2nd stage and 1st stage with hydrogen sulfate in graphite. Three thesis were written for the mechanism of intercalation compounds in graphite with hydrogen sulfate ; first thesis is anodic oxidation second thesis is chemical oxidation and definition of transit phase between 2nd etc the third thesis is the kinetic mechanism of intercalation compounds in graphite with Hydrogen sulfate. This thesis is the first paper among three thesis as anodic oxidation.

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Effect of Defoliation on Seed Development of Rye and Triticale Cultivar (전엽이 팔당호밀과 신기호밀의 종실발육에 미치는 영향)

  • 노창우;차영훈;김태수;권규칠;박연규
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.35 no.3
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    • pp.211-217
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    • 1990
  • This study was carried out to elucidate the effect of different time and severity of defoliation on the dry matter accumulation in grain of rye (cv, Paldanghomil) and triticale (cv, Sinkihomil). The weight of the 2nd leaf blade was the greatest and this was followed by the 3rd and flag leaf in that order. The chlorophyll content in leaf blade and sheath were decreased at lower leaf position (flag > 2nd > 3rd). The average chlorophyll content of rye was higher than that of triticale. The earlier and severer defoliation was made, the more grain weight was its was decreased. As the time of defoliation was made later and the degree of its was small, 1,000 grain weight was increased. The results showed that the effect of defoliation on 1,000 grain weight followed the order of the flag, the 2nd and the 3rd leaf. The greatest 1,000 grain weight was observed at the middle part of panicle, which followed by the top and bottom part in that order.

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Growth of Issatchenkia orientalis in Aerobic Batch and Fed-batch Cultures

  • Shin, Hyung-Tai;Lim, Yoo-Beom;Koh, Jong-Ho;Kim, Jong-Yun;Baig, Soon-Yong;Lee, Jae-Heung
    • Journal of Microbiology
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    • v.40 no.1
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    • pp.82-85
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    • 2002
  • The aerobic batch growth of Issatchenkia orientalis DY252 with glucose and fructose medium was investigated at 32$\^{C}$ and pH 5.0. Aerobic ethanol production was evident with yeast I, orientalis. A diauxic lag of about 1 h between growth on glucose and growth on ethanol during batch culture was observed. However, no diauxic growth occurred with fructose. As the incubation temperature was increased from 32 to 39$\^{C}$, viability at the end of each batch culture declined significantly, from 93 to 43%, Unlike the effect of temperature, viability was not greatly affected by incubation pH, and cell yield values in a range of 0.45-0.48 were obtained. In order to overcome overflow metabolism, a fedbatch culture under glucose limitation was carried out. Compared with aerobic batch culture, about 10% improvement in cell yield was achieved with a fed-batch culture in optimal conditions.

Detection Characteristics of Blood Lipid Lower Agents (BLLAs) in Nakdong River Basin (낙동강 수계에서의 고지혈증 치료제 검출 특성)

  • Son, Hee-Jong;Seo, Chang-Dong;Yeom, Hoon-Sik;Song, Mi-Jung;Kim, Kyung-A
    • Journal of Environmental Science International
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    • v.22 no.12
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    • pp.1615-1624
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    • 2013
  • The aims of this study were to investigate and confirm the occurrence and distribution patterns of blood lipid lower agents (BLLAs) in Nakdong river basin (mainstream and its tributaries). 4 (atorvastatin, lovastatin, mevastatin and simvastatin) out of 5 statins and 2 (clofibric acid and zemfibrozil) out of 3 fibrates were detected in 29 sampling sites and simvastatin (>50%) was predominant compound followed by atorvastatin, lovastatin and clofibric acid. The total concentration levels of BLLAs on April, August and November 2009 in surface water samples ranged from ND~25.7 ng/L, ND~18.8 and ND to 38.8 ng/L, respectively. The highest concentration level of BLLAs in the mainstream and tributaries in Nakdong river were Goryeong and Jincheon-cheon, respectively. The sewage treatment plants (STPs) along the river affect the BLLAs levels in river and the BLLAs levels decreased with downstream because of dilution effects.

Optical and Long After-Glow Characteristics of $Eu^{2+}$, $Nd^{3+}$ doped $BaAl_{2}O_{4}$ Phosphorescent Crystals (($Eu^{2+}$, $Nd^{3+}$를 도핑시킨 $BaAl_{2}O_{4}$ 형광체의 광학 및 장잔광특성)

  • Kim, Jeong-Hwan;Kim, Byung-Gyu;Lee, Dong-Kyu
    • Journal of the Korean Applied Science and Technology
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    • v.19 no.3
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    • pp.174-180
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    • 2002
  • In recent days, the study of a new phosphorescent phosphor has been performed in order to overcome the defect of sulfide phosphor and increase the brightness and long after-glow characteristic of phosphorescent phosphor. Particularly, sulfide phosphor usually used is so chemically unstable that the study of oxide phosphors are processing. $Eu^{2+}$, $Nd^{3+}$ doped Ba-Al-O phosphors sintered at $600{\sim}1500^{\circ}C$ for 2hours had the PL emission spectrum and after-glow over $1200^{\circ}C$. In this system, as the mole concentration of alumina increases, emission bands of phosphors moved from 500nm to 380nm. The optimum concentration of flux was 5wt% and after-glow characteristics of phosphors were found at the host material molar ratio ($BaCO_{3}:Al_{2}O_{3}$), 1:1 and 1:3.