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Analysis Study on 32nd OPCW Proficiency Test Sample with GC-TSQ CI (GC-TSQ CI 분석법을 이용한 제32차 OPCW 숙련도 시험 시료 분석 연구)

  • Kim, Hyunsuk;Jung, Changhee;Lee, Yonghan
    • Journal of the Korea Institute of Military Science and Technology
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    • v.17 no.6
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    • pp.828-835
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    • 2014
  • GC-TSQ CI technique was applied for analysis of samples for the $32^{nd}$ OPCW proficiency test. Eight chemical weapon convention(CWC) related chemicals were identified by product ion mode analysis with GC-TSQ in the samples. Choice of specific precursor ion made it possible to supply selective total ion chromatograms(TICs) of target molecule. GC-TSQ CI anaylsis technique was useful method for chemical warfare agent verification because analysis selectivity was improved by choice of mother molecule as precursor ion and gave mass spectra.

Optically induced rotation of combined Mie particles within an evanescent field of a gaussian beam (가우스형 에바네슨트파의 광압에 의한 Mie 입자 결합체들의 회전)

  • 송영곤
    • Korean Journal of Optics and Photonics
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    • v.10 no.1
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    • pp.5-9
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    • 1999
  • We demonstrate a windmill type rotation of combined Mie particles caused by the evanescent field generated at the surface of a Gadolinium Gallium Garnet prism where a linearly polarized Nd:YAG laser beam (of wavelength 532 nm and power 100 mW) is totally reflected. The combined particles (e.g., doublets, triplets or quadruplets) consisting of polystyrene latex (or yeast) spheres with diameters of 3~5 m are reported to rotate at 0.1~1 rpm in water when the particles are slightly displaced from the center of the evanescent field.

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Stability and Electronic Properties of the Adsorption of Molecular Hydrogen on Metal-containing Single-walled Carbon Nanotubes

  • Michael, Mananghaya
    • Journal of the Korean Chemical Society
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    • v.59 no.5
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    • pp.429-433
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    • 2015
  • The binding ability and hydrogen storage capacity of nitrogen doped carbon nanotube with divacancy (4NDCNxNT) that is decorated with transition metals was investigated based on density functional theory calculations. Results indicate that scandium shows an ideal reversible hydrogen binding capability with promising system-weight efficiency compared with other transition metals when functionalized with 4ND-CNxNT. The (Sc/4ND)10-CNxNT can store up to 50H2 molecules, corresponding to a maximum gravimetric density of 5.8 wt%. Detailed structural stability and electronic properties were reported as hydrogen molecules were absorbed. It takes about 0.16 eV/H2 to add one H2 molecule, which assures reversible storage of H2 molecules under ambient conditions.

Material Dependence of Laser-induced Breakdown of Colloidal Particles in Water

  • Yun, Jong-Il
    • Journal of the Optical Society of Korea
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    • v.11 no.1
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    • pp.34-39
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    • 2007
  • Laser-induced breakdown of colloidal suspensions, such as polystyrene, $ZrO_2$, and $SiO_2$ particles in diameters of 100-400 nm in water is investigated by nanosecond flash-pumped Nd:YAG laser pulses operating at a wavelength ${\lambda}$= 532 nm. The breakdown threshold intensity is examined in terms of breakdown probability as a function of laser pulse energy. The threshold intensity for $SiO_2$ particles ($1.27{\times}10^{11}\;W/cm^2$) with a size of 100 nm is higher than those for polystyrene and $ZrO_2$ particles with the same size, namely $5.7{\times}10^{10}$ and $5.5{\times}10^{10}\;W/cm^2$, respectively. Results indicate that the absorption of five photons is required to induce ionization of $SiO_2$ particles, whereas the other particles necessitate four-photon absorption. These breakdown thresholds are compared with those measured by nanosecond pulses from a diode-pumped Nd:YAG laser having a different focusing geometry.

The effects of EDTA and pulsed Nd:YAG laser on apical leakage of canal obturation

  • Kwon, Jin-Soo;Lee, Hee-Joo;Hur, Bock
    • Proceedings of the KACD Conference
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    • 2001.11a
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    • pp.563.1-563
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    • 2001
  • The purpose of this study was to evaluate the effects of EDTA and pulsed Nd:YAG laser on apical of canal obturation. Forty-eight single-rooted teeth were used in thes study. The teeth were instrumented up to a size 40 K-file and irrigated with 2.5% NaOCl between each file size. And the teeth were divided into 4 groups. In group A, the root canals were irrigated with a final flush of 5ml 2.5% NaOCl as a control group.(omitted)

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The Characteristics of Resonant Stimulated Raman Scattering in the water droplet (미세 물방울에서의 공명 유도라만산란의 특성)

  • 문희종;김광훈;임용식;고춘수;이재형;장준성
    • Korean Journal of Optics and Photonics
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    • v.6 no.4
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    • pp.337-344
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    • 1995
  • We have detected the resonant stimulated Raman scattering signal when the Q-switched Nd:YAG laser beam are incident on the $35~62{\mu}m$ sized water droplet as pump beam. The signals appeared as uniformly spaced peaks and the intervals between peaks become narrow as the droplet size increases. Also we have confirmed the morphology dependent resonances (MDR's) characteristic of the stimulated Raman scattering signal when the water droplet becomes nearly spherical shape after two water droplets are coupled to a droplet. The error in the measured intervals between MDR's of same mode order is about 5%.out 5%.

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Effect of additives on the microstructure of $PbNb_2{O_6}$ ceramics ($PbNb_2{O_6}$ 세라믹스에서 미세구조에 미치는 첨가제의 영향)

  • 김영상;안형식;오영우
    • Electrical & Electronic Materials
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    • v.7 no.5
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    • pp.417-424
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    • 1994
  • PbNb$_{2}$O$_{6}$ piezoelectric ceramics have good properties, but the applications of them have been limited due to the problems of microstructures. In the present study, effects of additives on the phase stability, microstructure, and electrical proper-ties of ferroetectric phase were investigated. La$_{2}$O$_{3}$, Nd$_{2}$O$_{3}$ and Sm$_{2}$O$_{3}$ were added with the amounts of 1, 3, 5 mol% respectively. The results showed that single orthorhombic(ferroelectric phase) phase compared with the mixed phase of pure PbNb2O6 was obtained. In the case of 5 mol% Nd$_{2}$O$_{3}$ addition, relative density of >95% and dense microstructure with -2.mu.m grain size were obtained.d.

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Sr, Nd and Pb isotopic investigations of ultramafic xenoliths and their host basalts from Jeju Island, Baekryeong Island, Boeun and Ganseong, Korea: Implications for a large-scale difference in the source mantle beneath East Asia

  • Park, Seong-Hee;Kwon, Sung-Tack;Hee Sagong;Cheong, Chang-Sik
    • Proceedings of the Mineralogical Society of Korea Conference
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    • 2001.06a
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    • pp.75-75
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    • 2001
  • We report Sr, Nd and Pb isotope data of clinopyroxene separates from ultramafic xenoliths and their host basaltic rocks in Jeju Island, Baekryeong Island, Boeun and Ganseong, Korea. The isotopic data of the xenoliths and host basalts are distinctly different from those of Korean basement rocks. Except for two xenoliths from Ganseong, all samples in this study have isotopic ratios within the combined range of MORB-OIB data. All basaltic rocks have Nd-Sr-Pb isotope compositions different from those of xenoliths, indicating that the host basaltic magma did not derive from the lithospheric mantle where the xenoliths originated. The range of isotopic composition of xenoliths is much greater than that observed in host basalts, which reflects small-scale heterogeneity of the lithospheric mantle. The greater isotopic heterogeneity of the lithospheric mantle probably reflects its long-term stability. The spinel peridotite xenolith data of Jeju Island, Baekryeong Island and Boeun display mixing hyperbolas between DMM and EM II end members. Since Jeju basalts have EM II-like isotopic signature, the mixing relationship shown by the isotopic data of the Jeju xenoliths can be interpreted as the result of infiltration of metasomatic fluid or melt derived from basaltic magma into DMM-like lithospheric mantle. In contrast to other xenolith sites, the Ganseong xenoliths are dominantly clinopyroxene megacryst and pyroxenite. Clinopyroxene megacrysts have different isotopic ratios from their host basalt, reflecting its exotic origin. Two Ganseong xenoliths (wherlite and clinopyroxenite) have much enriched Sr and Nd isotopic ratios and Nd model ages of 2.5-2.9 Ga, and plot in an array away from the MORB-OIB field. The mantle xenoliths from Korean Peninsula have similar $\^$87/Sr/$\^$86/Sr,$\^$143/Nd/$\^$144/Nd and $\^$207/Pb/$\^$204/Pb ratios to, but higher $\^$208/Pb/$\^$204/Pb ratios than, those from eastern China, indicating that Korean xenoliths are derived from the lithospheric mantle with higher Th/U ratio compared with Chinese ones. The isotopic data of xenolith-bearing basalts of Baekryeong Island and Ganseong, along with Ulreung and Dok Islands, show a mixing trend betlveen DMM and EM I in Sr-Nd-Pb isotopic correlation diagrams, which is also observed in tile northeastern Chinese basalts. However, the Jeju volcanic rocks show an EM II signature that is observed in southeastern Chinese basalts. The isotopic variations in volcanic rocks from the northern and southern portions of the East Asia reflect a large-scale isotopic heterogeneity in their source mantle.

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Evaluation of bone formation by recombinant human BMP-2 and rapid prototype titanium cap in rabbit calvaria using micro computed tomography (RP titanium cap과 rhBMP-2를 이용하여 형성된 신생골의 미세전산화단층촬영을 이용한 평가)

  • Han, Man-Seung;Jung, Seung-Gon;Kim, Bang-Sin;Yang, Ji-Woong;Kook, Min-Suk;Park, Hong-Ju;Ryu, Sun-Youl;Oh, Hee-Kyun
    • Journal of the Korean Association of Oral and Maxillofacial Surgeons
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    • v.36 no.6
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    • pp.466-472
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    • 2010
  • Introduction: This study examined the effect of recombinant human bone morphogenetic protein (rhBMP)-2 and $\beta$-tricalcium phosphate ($\beta$-TCP) on new bone formation in a rabbit calvarium using a rapid prototype titanium cap (RP Ti cap). Materials and Methods: Eight New Zealand white rabbits were used in this study. Hemispherical RP Ti caps (10 mm in diameter) were implanted subperiosteally on the rabbit calvaria. $\beta$-TCP was filled in the RP Ti cap in the control group, and rhBMP-2 soaked $\beta$-TCP was used in experimental group. The rabbits were sacrificed 2 and 4 weeks after the operation. The volume and pattern of newly formed bone was analyzed by micro computed tomography (CT). Results: Macroscopically, there were no abnormal findings in any of the animals. The micro CT images revealed new bone from the calvaria that expanded gradually toward the top of the titanium cap, particularly along the inner surface of the titanium cap in the experimental group at 4 weeks after grafting. There was no significant difference in new bone volume ratio between the control and experimental groups at 2 weeks after grafting. There was a statistically significant difference in the new bone volume ratio between the experimental ($14.1{\pm}1.8\;%$) and control ($7.2{\pm}1.5\;%$) groups at 4 weeks after grafting (P<0.01). Conclusion: The RP Ti cap can effectively guide new bone formation and rhBMP-2 can induce the new bone formation.