• 제목/요약/키워드: ND4

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Nd-Sr Isotope and Gas Composition for the Sangdong Granites Related to the Tungsten-Molybdenum Ore Mineralization (상동 중석-몰리브덴 광상의 광화관련 상동화강암의 Nd-Sr 동위원소비 및 가스 성분)

  • Kim, Kyu Han;Shin, Yu Hee
    • Economic and Environmental Geology
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    • 제28권2호
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    • pp.139-145
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    • 1995
  • Tungsten skarn mineralization of the Sangdong mine is localized in the interbedded limestone layers of the Myobong Slate Formation and in the limestone of the Pungchon Limestone Formation of Cambrian age. Fluid inclusion, gas composition and Nd-Sr isotope for granites and skarns have been investigated. Gas compositions show $CO_2$ rich in the Sangdong granite and CH, rich in the Nonggeori and Eopyeong granites. The initial $^{87}Sr/^{86}Sr$ and $^{143}Nd/^{144}Nd$ ratios of the Sangdong granites have 0.714~0.716(${\varepsilon}_{Sr}$=138~162) and 0.51173~0.51178(${\varepsilon}_{Nd}$=-14.4~15.5), respectively. And their two stage model ages range from 1687 to 1764 Ma. The granite characterized by high strontium initial ratios and negative eNd value could have originated from the old continental crust source. Low homogenization temperature of the Sangdong granite having $203{\sim}296^{\circ}C$ with 1.9~9.2 NaCl equiv. wt% indicates the post-magmatic hydrothermal alteration temperature. Skarn ore fluid responsible for tungsten mineralization has been evolved from CH, rich fluid of early pyroxene garnet skarn to $CO_2$ rich later quartz-mica skarn.

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Coercivity of Near Single Domain Size Nd2Fe14B-type Particles

  • Kwon, H.W.;Yu, J.H.
    • Journal of Magnetics
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    • 제17권3호
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    • pp.185-189
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    • 2012
  • The coercivity of near single domain size $Nd_2Fe_{14}B$-type particles prepared by ball milling of HDDR-treated $Nd_{12.5}Fe_{80.6}B_{6.4}Ga_{0.3}Nb_{0.2}$ alloy was investigated. The feasibility of a surface nitrogenation for improving the coercivity stability of the fine $Nd_2Fe_{14}B$-type particles was also studied. The near single domain size $Nd_2Fe_{14}B$-type particles had a high coercivity of over 9 kOe. However, the coercivity radically deteriorated as the temperature increased in air (< 2 kOe at $200^{\circ}C$). This coercivity reduction was attributed to the soft magnetic phases, ${\alpha}$-Fe and $Fe_3B$, which formed on the surface of the fine particle due to oxidation. Surface nitrogenation of the fine particles significantly improved the stability of their coercivity. The improvement in coercivity stability was attributed to the formation of a thin nitrogenated layer on the surface of the fine $Nd_2Fe_{14}B$-type particles, which enhanced the anisotropy field and gave improved resistance to oxidation (dissociation).

Effect of oxygen pressure on properties of $NdBa_2Cu_3O_{7-{\delta}}$ films on $SrTiO_3$ (100) substrates grown by pulsed laser deposition

  • Wee, Sung-Hun;Moon, Seung-Hyun;Park, Chan;Yoo, Sang-Im
    • Progress in Superconductivity and Cryogenics
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    • 제6권4호
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    • pp.9-12
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    • 2004
  • We report a successful fabrication of high-$J_C$ $NdBa_2Cu_3O_{7-{\delta}}$ (NdBCO) films on (100) $SrTiO_3$ substrates by pulsed laser deposition (PLD) in high oxygen pressures ranging from 400 to 800 mTorr. Fabricated NdBCO films exhibited only c-axis orientation, good out-of-plane and in-plane textures, and also excellent superconducting properties, including critical temperature ($T_C$) and critical current density ($J_C$) of above 90 K and the highest of $3.1MA/cm^2$ at 77 K in self-field, implying that NdBCO is a perspective alternative to YBCO for coated conductor. In low oxygen pressures ranging from 100 to 200 mTorr, however, the films showed a-, c-mixed orientation and degraded $T_{C,zero}$ values due to the formation of $Nd_{1+x}Ba_{2-x}Cu_3O_{7-{\delta}}$-type solid solutions with an excessive substitution of $Nd^{3+}$ ions for the $Ba^{2+}$ sites.

Effect of Nd:YAG Laser Irradiation to Mental Region for Sensory Nerve Conduction Change (하악 이공부에 조사된 Nd:YAG 레이저가 감각신경전도변화에 미치는 영향)

  • Jeon, Jae-Woo;Kim, Kyoung-Hee;Ko, Myong-Yun;Ahn, Yong-Woo;Park, Jun-Sang
    • Journal of Oral Medicine and Pain
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    • 제30권4호
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    • pp.447-455
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    • 2005
  • The purpose of this study was to examine the effect of Nd:YAG laser irradiation for sensory nerve conduction change. Nd:YAG laser was irradiated to mental region for 5 minutes with the parameters that 10 Hz and 20 Hz of 100 mJ/pulse. Target size of irradiation was 30 mm diameter of circle and target-tip distance was about 10 mm. Therefore, the power density were 212 $mW/cm^2$ and 424 $mW/cm^2$. Sensory nerve conduction was evaluated with $Neurometer^{\circled}$ CPT/C before and after Nd:YAG laser irradiation. As an outcomes, the current perception threshold(CPT) and pain tolerance threshold(PTT) were obtained. We made a comparison of these two values and the results were as follows. 1. There was no significant difference in CPT at 1W, 10 Hz and 2 W, 20 Hz Nd:YAG laser irradiation. 2. There was no significant difference in PTT at 10 Hz, 20 Hz of 100 mJ/pulse Nd:YAG laser. 3. There were no significant differences in CPT and PTT between 1 W, 10 Hz group and 2 W, 20 Hz group. Therefore, We can make a conclusion that Nd:YAG laser irradiation to mental region have no effect on mental nerve conduction in our study model.

Effect of quenching rate and crystallization behavior on the magnetic properties of annealed Nd-Fe-B ribbons (Melt-spun Nd-Fe-B 리본의 자기적 특성에 미치는 급속응고속도 및 결정화 거동의 영향)

  • 이경섭;서수정
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • 제8권4호
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    • pp.655-659
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    • 1998
  • The effect of quenching speed of melt-spinning on intrinsic coercivity ($_iH_c$$) of annealed ribbons and the crystallization behavior from amorphous $Nd_{14.73}Fe_{78.67}B_{6.60}$ alloy have been studied. We have found that the intrinsic coecivity for annealed melt-spun ribbon is reduced with increasing of quenching rate. $\alpha$-Fe and $Fe_3B$ were formed as intermediate phases prior to the formation of $Nd_2Fe_{14}B$ phase during crystallization. The $Fe_3B$ is disappeared with crystallization of $Nd_2Fe_{14}B$ phase. But the $\alpha$-Fe phase is retained in fully crystallized ribbon by annealing. The intrinsic coercivity loss of annealed ribbon with increasing of quenching speed is believed to be due to existence of soft magnetic phase $\alpha$-Fe in annealed ribbons.

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Wound Healing After Gingivectomy Using Pulsed Nd : YAG Laser In The Rat (백서에서 Pulsed Nd : YAG Laser에 의한 치은절제술후의 치유양상)

  • Kim, Ok-Su;Chung, Hyun-Ju
    • Journal of Periodontal and Implant Science
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    • 제26권1호
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    • pp.293-308
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    • 1996
  • Recently, dental laser have been applied for removal of soft tissues, hemostasis and blood coagulation, removal of benign and malignant tumor, treatment of leukoplakia, aphthous ulcer and herpetic lesion, implant second surgery, removal of granulation tissue, frenectomy, clinical crown lengthening, gingivectomy, gingivoplasty, and treatment of dentin hypersensitivity. Even though the frequency of laser treatment is increasing, the research on the healing process after gingivectomy using pulsed Nd : YAG laser is very rare. The purpose of this study was to observe and compare the wound healing after gingivectomy using scalpel and pulsed Nd : YAG laser in the rat. Gingivectomy was performed using pulsed Nd : YAG laser(SUNRISE Technologies, U.S.A., 1.5 Watts, 10 pps) on the buccal gingiva of right maxillary first molar and using scalpel(No.12) on the contralateral side. Those sites treated by surgical scalpel were designated as the control, and by pulsed Nd : YAG laser as the experimental group. Animals were sacrificed at 1, 2, 3, 5, 7, 11 and 14 days postoperatively, and specimens were histologically observed under light microscope. The results were as follows : 1. Clinical observation Normal color and shape were observed at the 5th day ill the control group and the 7th day in the experimental group. 2. Histologic findings 1) In the control group, denser inflammatory infiltration was observed. 2) Epithelialization started at the 2nd day in the control group, similar to the experimental group, and completed at the 11th to the 14th day postoperatively. 3) In the experimental group, connective tissue showed the vacuole formation and degenerative change during early healing period. Healing of connective tissue was slower in the experimental group than in the control group by 2 days. 4) In the both groups, wound healing was completed at the 2nd week. From this study, gingivectomy using pulsed Nd : YAG laser seems to result in a little delayed wound healing process, compared to the gingivectomy using scalpel. Considering the clinical advantages of laser surgery, pulsed Nd : YAG laser might be useful device for gingivectomy.

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Synthesis and Properties of Oxygen-bridged Aromatic Polyesters Based on Isomeric Naphthalenediols

  • Park, E-Joon;Park, Bong-Ku;Kim, Jae-Hoon;Lee, Sang-Chul;David J. T. Hill
    • Macromolecular Research
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    • 제8권1호
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    • pp.12-18
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    • 2000
  • Six aromatic polyesters with ether-linkages were prepared from 4,4'-oxybis(benzoic acid) and naphthalenediol (ND) isomers which were 1,4-, 1,5-, 1,6-, 2,3-, 2,6- and 2,7-derivatives. The solution viscosity numbers ranged from 0.23 to 0.65 dL/g. The glass transition temperatures ranged from 142 to 179$\^{C}$. The initial decomposition temperatures were all above 400$\^{C}$, and the residue weights at 600$\^{C}$ were in the range of 50-64%. Only the polyesters derived from 1,5- and 2,6-NDs, which have a linear linking mode, were found to be semicrystalline and could form thermotropically nematic phase. Multiple melting phenomena and annealing of the polyester derived from 1,5-ND and related polymers are described. The experimental results show that the polyester derived from 1,4-ND of linear shape was amorphous and non-liquid crystalline. Particularly, the polyester derived from 2,3-ND could form a smectic mesophase as banana-shaped molecules, and this is ascribed to the C/sub_2v/ symmetry where highly kinked molecules are packed in the same direction.

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The Preparation and Characterization of BNdT Thin Films by MOD Process (MOD법을 이용한 BNdT박막의 제조 및 특성 연구)

  • Kim, Ki-Beom;Jang, Gun-Eik
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 한국전기전자재료학회 2002년도 하계학술대회 논문집 Vol.3 No.2
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    • pp.861-864
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    • 2002
  • Ferroelectric $Bi_{4-x}Nd_xTi_3O_{12}$(BNdT) thin films with the composition(x=0.75) were prepared on pt/Ti/$SiO_2$/Si(100) substrate by metal-organic deposition. The electrical and structural characteristics of BNdT thin films were investigated to develop ferroelectric thin films for capacitor layers of FRAM. After spin coating, thin films were annealed at $650^{\circ}C$ for 1hour in oxygen atmosphere. Scanning electron micrographs showed uniform surfaces composed of rod-like grains. The $Bi_{4-x}Nd_xTi_3O_{12}$(X=0.75) thin film capacitors with a Pt top electrode showed better ferroelectric properties. At the applied voltage of 5V, the dielectric constant$(\varepsilon_r)$, dissipation factor$(tan{\delta})$, remanent polarization(2Pr) and nonvolatile swiching charge of the $Bi_{4-x}Nd_xTi_3O_{12}$(x=0.75)thin films were about 346.7, 0.095, $56{\mu}C/cm^2$ and $38{\mu}C/cm^2$ respectively. Also the capacitor did not show any significant fatigue up to $8{\times}10^{10}$ read/write switching cycles at a frequency of 1MHz.

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Characteristics on Surface Hardening by using of Continuous Wave Nd:YAG Laser of Cold-Work Die Steel(STD11) about Variation of Focal Lens F-number (초점렌즈 F-수 변화에 의한 냉간금형강 STD11 의 연속파 Nd:YAG 레이저 표면경화 특성)

  • Hwang, Chan-Youn;Yang, Yun-Seok;Lee, Ka-Ram;Yoo, Young-Tae
    • Journal of the Korean Society for Precision Engineering
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    • 제29권4호
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    • pp.395-408
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    • 2012
  • An experimental investigation with 2.8kW Nd:YAG laser system was carried out to study the effects of different laser process parameters on the microstructure and hardness of STD11. The optical lens with the elliptical profile are designed to obtain a wide surface hardening area with uniform hardness. The Laser beam is allowed to scan on the surface of the work piece varying the power (1600, 1800 and 1900kW) and traverse speed (200, 400, 600, 800 and 1000mm/min) at three different F-numbers of lens. After laser surface treatment three zones, In the microstructure have been observed : melted zone(decarburization), heat affected zone(martensite), and the substrate.

Exchange Coupling in Massively Produced Nd2Fe14B+Fe3B Nanocomposite Powders

  • Yang, Choong Jin;Park, Eon Byung;Han, Jong Soo;Kim, Eung Chan
    • Journal of Magnetics
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    • 제9권2호
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    • pp.27-33
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    • 2004
  • Magnetic properties of $Nd_4Fe_{77.5}B_{18.5}$ compound in term of exchange coupling between $Nd_2Fe_{14}B$ and $Fe_3B$ magnetic nano crystals in melt spun powders were characterized by varying the quenching speed in mass production line. The exchange coupled phenomenon was characterized as functions of nano crystal size and volume fraction of each magnetic phase which was possible by employing Henkel plot (${\delta}M$) and refined Mossbauer spectroscopy. The optimized magnetic properties obtained from the present volume production line were: $B_r= 11.73 kG,{_i}H_c/ = 3.082 kOe$, and $(BH)_{max} = 12.28 MGOe.$ The volume fraction of each magnetic phase for those conditions giving the grain size of 10 nm were ${\alpha}-Fe; 4.2%, Fe_3B; 60.1 %$, and $Nd_2Fe_{14}B; 35.7%$. The superior magnetic properties in the $Nd_2Fe_{14}Fe_3B$ based nanocomposites were confirmed to be dependant on the volume fraction of $Fe_3B$.