• Title/Summary/Keyword: N-R Method

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Quantifying nitrogen source contribution ratios using stable isotope method: Application of Bayesian mixing model (안정동위원소를 이용한 하천에서의 질소오염원 기여율 정량화: Bayesian 혼합모델의 적용)

  • Nam, Tae-Hui;Ryu, Hui-Seoung;Kang, Tae-Woo;Han, Yeong-un;Kim, Jihyun;Lee, Kyounghee;Hwang, Soonhong;Kim, Kyunghyun
    • Journal of Korean Society on Water Environment
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    • v.35 no.6
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    • pp.510-519
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    • 2019
  • The 'Stable Isotope Analysis in R' (SIAR), one of the Bayesian mixing models for stable isotopes, has been proven to be useful for source apportionment of nitrates in rivers. In this study, the contribution ratios of nitrate sources were quantified by using the SIAR based on nitrogen and oxygen stable isotope measurements in the Yeongsan River. From the measurements, it was found that the values of δ15N-NO3 and δ18O-NO3 ranged from -8.2 ‰ to +13.4 ‰ and from +2.2 ‰ to +9.8 ‰, respectively. We further analyzed the contribution ratios of the five nitrate sources by using the SIAR. From the modeling results, the main nitrate source was found to be soil N (29.3 %), followed by sewage (26.7 %), manure (19.6 %), chemical fertilizer (17.9 %) and precipitation (6.3 %). From the results, it was found that the anthropogenic sources, i.e., sewage, manure and chemical fertilizer contribute 64.2% of the total nitrate inflow from the watershed. Due to the significant correlation of δ15N-NO3 and lnNO3- in this study, the fractionation factors reflecting the biogeochemical processes of stable isotope ratios could be directly obtained. This may make the contribution ratios obtained in this study more precise. The fractionation factors were identified as +3.64 ± 0.91 ‰ for δ15N-NO3 (p<0.01) and -5.67 ± 1.73 ‰ for δ18O-NO3(p<0.01), respectively, and were applied in using the SIAR. The study showed that the stable isotope method using the SIAR could be applied to quantitatively calculate the contribution ratios of nitrate sources in the Yeongsan River.

Synthesis of Cathode Materials LiNi1-yCoyO2 from Various Starting Materials and their Electrochemical Properties

  • Song, Myoung-Youp;Rim, Ho;Bang, Eui-Yong;Kang, Seong-Gu;Chang, Soon-Ho
    • Journal of the Korean Ceramic Society
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    • v.40 no.6
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    • pp.507-512
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    • 2003
  • The LiN $i_{l-y}$ $Co_{y}$ $O_2$ samples were synthesized at 80$0^{\circ}C$ and 85$0^{\circ}C$, by the solid-state reaction method, from the various starting materials LiOH, L $i_2$C $O_3$, NiO, NiC $O_3$, $Co_3$ $O_4$, CoC $O_3$, and their electrochemical properties are investigated. The LiN $i_{l-y}$ $Co_{y}$ $O_2$ pre-pared from L $i_2$C $O_3$, NiO, and $Co_3$ $O_4$ exhibited the $\alpha$-NaFe $O_2$ structure of the rhombohedral system (space group; R3m). As the Co content increased, the lattice parameters a and c decreased. The reason is that the radius of Co ion is smaller than that of Ni ion. The increase in da shows that two-dimensional structure develops better as the Co content increases. The LiN $i_{0.7}$ $Co_{03}$. $O_2$[HOO(800,0.3)] synthesized at 80$0^{\circ}C$from LiOH, NiO, and $Co_3$ $O_4$ exhibited the largest first discharge capacity 162 mAh/g. The size of particles increases roughly as the valve of y increases. The samples with the larger particles have the larger first discharge capacities. The cycling performances of the samples with the first discharge capacity larger than 150 mAh/g were investigated. The LiN $i_{0.9}$ $Co_{0.1}$ $O_2$[COO(850,0.1)] synthesized at 85$0^{\circ}C$ from L $i_2$C $O_3$, NiO, and $Co_3$ $O_4$ showed an excellent cycling performance. The sample with the larger first discharge capacity will be under the more severe lattice destruction, due to the expansion and contraction of the lattice during intercalation and deintercalation, than the sample with the smaller first discharge capacity. As the first discharge capacity increases, the capacity fading rate thus increases.increases.s.s.s.

『Chūn-qiū』Wáng-lì(『春秋』王曆)① - A Study on the Discussion of 'the Changes in the Names of Months and a Season(改月改時)' in the calendar of 『Chūn-qiū(春秋)』 since Song(宋) Dynasty (『춘추(春秋)』왕력(王曆)① - 송대(宋代) 이후 춘추력수(春秋曆數)의 개월(改月)·개시(改時) 논의에 대한 소고(小考))

  • Seo, Jeong-Hwa
    • (The)Study of the Eastern Classic
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    • no.67
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    • pp.345-378
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    • 2017
  • In the scriptures of "$Ch{\bar{u}}n-qi{\bar{u}}$(春秋)", the expression method of '$Ch{\bar{u}}n-w{\acute{a}}ng-zh{\bar{e}}ng-yu{\grave{e}}$(春王正月 : It's spring. It's the first month regulated by the king.)' was used as Jì-yuè-fǎ(紀月法 : the rules to determine the first month(正月)), the month of winter solstice was regarded as the first month of a year, and three years since then were named as $Ch{\bar{u}}n$(春 : spring). With regard to this "$Ch{\bar{u}}n-qi{\bar{u}}$"Wáng-lì("春秋"王曆 : the calendar regulated by the king of $Zh{\bar{o}}u$(周) dynasty in "$Ch{\bar{u}}n-qi{\bar{u}}$"), depending on whether Confucius(孔子) changed and recorded the names of the months and the season or not, there were three different arguments; the theory that 'Confucius changed the names of both the months and the season'(孔子改月 改時說), the view that 'Confucius changed the name of the season, not the names of the months'(孔子不改月 改時說), and then the theory that 'Confucius changed neither the names of the months nor the name of the season'(孔子不改月 不改時) since Song(宋) dynasty. The first view was taken by $Hh{\acute{u}}-{\bar{a}}n-gu{\acute{o}}$(胡安國) and $C{\grave{a}}i-ch{\acute{e}}n$(蔡沈), and the second theory was mentioned by Chéng-yí(程?) and Zhū-zǐ(朱子). The advocates of the third view had become remarkable since Ming(明) dynasty, and one of representatives was Wàng-yáng-míng(王陽明). All of them based their arguments on ancient scriptures and Confucian legal books, and there were cases of taking the same records as the support for different opinions. Confucius' so-called 'Chūn-qiū-bǐ-fǎ(春秋筆法 : the method to describe historical facts by making clear discrimination between right and wrong)' and '$Sh{\grave{u}}-{\acute{e}}r-b{\grave{u}}-zu{\grave{o}}$(述而不作 : the attitude to succeed virtuous men's achievements and only explain and describe them not creating and adding new contents)' could come from thoughts of $Z{\bar{u}}n-w{\acute{a}}ng$(尊王 : to respect the king with the virtues of benevolence, righteousness, propriety, wisdom and sincerity). Therefore, even though Confucius is assumed to have been the writer of "$Ch{\bar{u}}n-qi{\bar{u}}$(春秋)", whether he actually changed and recorded the names of the months and the season in the calendar used in "$Ch{\bar{u}}n-qi{\bar{u}}$" is doubtful. These theories on Confucius's intervention in the calendar of "$Ch{\bar{u}}n-qi{\bar{u}}$" hadn't been discussed as conflicting in reality until Tang(唐) dynasty.

Characteristics of Total Carbon and Total Organic Carbon Using Elemental Analyzer in Hyung-Do Intertidal Zone Sediments (원소분석기를 이용한 형도 퇴적물의 총탄소 및 총유기탄소 특성)

  • Lee, Jun-Ho;Park, Kap-Song;Woo, Han-Jun
    • Economic and Environmental Geology
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    • v.45 no.6
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    • pp.673-684
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    • 2012
  • Quantitative understanding of total carbon, total inorganic carbon and total organic carbon contained in ocean sediments is a basic data for interpretation of oceanic sediment environments. Elemental analyzer(EA) is frequently used for the analysis of carbon contents in inland soils and ocean sediments. Carbon and nitrogen contents of the soil reference material analyzed by an EA were 2.30% and 0.21% with standard deviations of 0.02 and 0.01, respectively. Relative standard deviations were 0.01 and 0.06, respectively, representing a high precision. Regression analysis of TOC and TC analysis results for the samples with TOC of less than 2.0% for the site in Hyung-Do showed a linear relationship with a slope of 0.9743($R^2$=0.9989, n=38), and the results of a relationship regression analysis between total organic carbon contents less than 0.5% and average grain size except for two samples showed a linear relationship with a slope of 0.0444($R^2$=0.6937 n=36). TOC contents of surface sediments were in the ranges of 0.10~1.67%(Average $0.26{\pm}0.37%$) with TOC values of 1.67% at S02 sampling site, 1.13% at S07 sampling site, and less than 1.00% at remaining sites. In the case of PC 01 core sediments, TOC showed the highest value of 0.20% near 70 cm. In the case of PC 02 core sediments, the highest value of 0.24% was indicated near 60 cm. The analysis method of organic carbon obtained from Hyung-Do Intertidal zone sediment sample results may be considered applicable to an organic carbon analysis for ocean sediments and useful for organic carbon analysis experiments of ocean sediments with a reduction in time required for the analysis and a high precision coupled with a high accuracy.

A Comparison of Species Composition and Stand Structure of the Forest Vegetation between Inhabited and Uninhabited Island in the South Sea, Korea (유인도서와 무인도서 산림식생의 종조성 및 군락 구조 비교)

  • Kim, Jun-Soo;Jeon, Chul-Hyun;Jung, Sung-Cheol;Kim, Chan-Soo;Won, Hyun-Gyu;Cho, Joon-Hee;Cho, Hyun-Je
    • Korean Journal of Environment and Ecology
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    • v.30 no.4
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    • pp.771-782
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    • 2016
  • For basic information collection for the ecological management of forest vegetation in Korean island areas, forest vegetation between inhabited(Daemodo) and uninhabited(Gudo) island was classified in the Z-M phytosociological method and their ecological characteristics in terms of both floristic composition and structure analyzed. Forest vegetation of Daemodo and Gudo were divided into a total of 11 units and 8 units, respectively. Total cover and species diversity index(H') of forest vegetation showed significant differences between the two island, Daemodo has a high value in the tree layer, but, Gudo has a high value in the shrub layer. Composition of Life forms, Daemodo was N-$R_5-D_2$-e and Gudo MM-$R_5-D_2$-e. Family importance value(FIV), Daemdo has a high value in Theaceae(12.2) and Pinaceae(12.0) and Gudo in Lauraceae(16.5) and Fagaceae (11.6). The percentage of the total number of species in the family level, Daemodo is Asteraceae(4.5%) was the highest and Gudo is Liliaceae(7.3%). Indicator species of forest vegetation of the two islands, Daemodo is Nanophanerophytes(N) including Smilax china, Ligustrum japonicum and Eurya japonica was significant inicator species and Gudo is Megaphanerophytes(MM) including Dendropanax morbiferus, Castanopsis sieboldii and Actinodaphne lancifolia.

Analysis of Antioxidant Activity and Serotonin Derivatives in Safflower (Carthamus tinctorius L.) Germplasm Collected from Five Countries (국외 수집 홍화 유전자원의 항산화 활성 및 세로토닌 유도체 함량 분석)

  • Jung, Yi Jin;Assefa, Awraris Derbie;Lee, Jae Eun;Lee, Ho Sun;Rhee, Ju Hee;Sung, Jung Sook
    • Korean Journal of Plant Resources
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    • v.32 no.5
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    • pp.423-432
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    • 2019
  • In order to select potential plant resources as functional materials and natural antioxidants, we evaluated antioxidant activity and serotonin derivatives of safflower germplasm collected from five countries. N-(p-Coumaroyl) serotonin (CS) and N-feruloylserotonin (FS) were analyzed by using Ultra Performance Liquid Chromatography (UPLC). Total polyphenol content (TPC) was determined by Folin-Ciocalteu method and antioxidant activities were estimated by 2,2-diphenyl-1-picryl-hydrazil (DPPH), 2,2'-azino-bis(3-ethylbenzothiazoline-6-sulphonic acid) diammonium salt (ABTS), Ferric reducing antioxidant power (FRAP) and Reducing power (RP) assays. The TPC showed a range of 28.25 to $90.53{\mu}g$ gallic acid equivalent (GAE)/mg dried extract (DE). DPPH, ABTS, FRAP and RP assay were in the range of 18.76 to 93.98, 48.91 to 163.73, 3.80 to 132.29 and 26.32 to $80.08{\mu}g$ ascorbic acid equivalent (ASCE)/mg DE, respectively. Among the five countries, safflower seed collected from Iran had the highest levels of serotonin derivatives and antioxidant activities than other countries (p<0.05). CS showed high correlation with TPC, ABTS and DPPH (r=0.673,0.727,0.820), and FS showed high correlation with DPPH (r=0.740). Accessions IT321214 and IT321215 could be useful for development of new functional materials and could be used as a source of valuable natural antioxidant materials.

Lowess and outlier analysis of biological oxygen demand on Nakdong main stream river (낙동강 본류 측정소들의 생물학적 산소요구량 수치에 대한 비모수적 회귀분석과 특이점분석)

  • Kim, Jong Tae
    • Journal of the Korean Data and Information Science Society
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    • v.25 no.1
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    • pp.119-130
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    • 2014
  • This paper is based on water information system of NIE, National Institute of Environmental Research. We used monthly data of water quality from January, 2013 to August, 2013 starting from measuring point A (nbA) to measuring point N (nbN) located along the Nakdong river main stream. Statistical water quality analysis of BOD (biological oxygen demand) is specified by R programming depending on month, year, and points. Based on BOD measured from Nakdong river's measuring points, we used exploratory data analysis and locally weighted scatter plot smoother (Lowess) trend analysis, which is a method of non-parametic regression analysis, to analyze long-term water tendency and water quality distribution depending on points. Also, we analyzed the period and the measuring point of which the outliers are abundant. As a result, compared to BOD measured in nbM located in Busan along the downstream, BOD measured in nbG located in Daegu and nbI located in Changwon along the midstream showed higher rate of water pollution at a severe level.

Chemical/Electro-Chemical Method for Swine Wastewater Treatment (화학적/전기화학적 방법을 이용한 돈사폐수 처리)

  • Yoon, S.J.;Jo, W.S.;Kim, C.H.;Park, J.I.;Shin, J.S.;Ra, C.S.
    • Journal of Animal Science and Technology
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    • v.45 no.4
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    • pp.641-648
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    • 2003
  • In a batch mode treatment process, which electrolyzes the wastewater after derivation of N-P crystal formation and recovery, the characteristics of pollutant removal induced with the changes of loading rate and hydraulic retention time were studied. $MgCl_2$ was used as Mg source for the formation of struvite and the molar ratio of $MgCl_2$ to $PO_4^{3-}$ in influent was 1.3. When analyzing the average treatment efficiencies and removal characteristics obtained from four separate operations (Run I, II, III, IV), removal efficiencies of PO43- was not function of its loading rate. Under a condition of sufficient aeration and Mg source provided, over 88% of $PO_4^{3-}$ was eliminated by the formation of MAP without any pH adjustment, in spite of loading rate variation. An optimum-loading rate of NH4-N to achieve high removal efficiency was approximately $100g/m^3/d$. Below that loading rate, the removal of NH4-N was proportional to the loading rate into the system, and hence stable and high removal efficiency, over 90%, was achieved. However, when the loading rate increased over that rate, removal efficiency began to drop and fluctuate. Removal efficiency of TOCs was dependant upon the hydraulic retention time ($r^2$=0.97), not upon the loading rate. Stable and high color removal (94%) was obtained with 2 days of HRT in electrolysis reactor.

The Effect of Nasal Packing with Rolled Silastic Sheet after Closed Reduction of Nasal Bone Fracture (비골 골절 교정 후 Rolled Silastic Sheet를 이용한 비강 충진의 효과)

  • Son, Kyung-Min;Yang, Jeong-Yeol;Kim, Gyu-Bo;Han, Yun-Ju;Cheon, Ji-Seon
    • Archives of Plastic Surgery
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    • v.38 no.5
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    • pp.602-608
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    • 2011
  • Purpose: Nasal bone fracture is the most common type of facial bone fracture and most of nasal bone fracture is combined with septal fracture frequently. Nasal septum is important to support the distal nose and to maintain the nasal airway. But nasal septal fractures are usually unrecognized and untreated at the time of operation. Recently, various materials were using for nasal packing after closed reduction, however these materials are not focused on the correction of nasal bone and nasal septal fracture and many patients are suffered from nasal packing materials. Thus, the purpose of this study is to compare routine packing materials and rolled silastic sheet with respect to postoperative effect of correction of nasal bone fracture and discomfort of nasal packing materials. Methods: We examined 320 patients treated nasal bone fracture from January 2008 to December 2010. For Group I (n=92), $Merocel^{(R)}$ was used for nasal packing, for Group II (n=152) vaseline gauze was used, and Rolled silastic sheet (RSS) with vaseline gauze packing (VGP) was used for Group III (n=76). Under the general anesthesia, all patients were operated by closed reduction and nasal packing was done using three kinds of packing materials. At the time of postoperative 7 days, packing material was removed and studied for pt's satisfaction and postop. complications. Results: In patients with RSS with VGP, the complaints (nasal obstruction, foreign compressive sensation and discomfort during food ingestion) of keeping the nasal packing were decreased ($p$ <0.05) and the postoperative complication (deviation) were decreased comparing to vaseline gauze packing and $Merocel^{(R)}$ packing, however, these differences were not statistically significant ($p$ >0.05). Conclusion: Postoperative nasal packing with RSS with VGP was more comfortable to the patients and it was more effective method to correct the nasal bone fracture and nasal septal fracture.

A Study on the Reduction of Non-Point Source Pollution loads from Small Agricultural Watershed by Applying Surface Covering Scenario using HSPF Model (HSPF 모델을 이용한 지표피복 시나리오 적용에 따른 농촌 소유역에서의 비점원오염 저감연구)

  • Jung, Chung-Gil;Park, Jong-Yoon;Kim, Sang-Ho;Kim, Seong-Joon
    • Proceedings of the Korea Water Resources Association Conference
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    • 2012.05a
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    • pp.103-103
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    • 2012
  • 본 연구에서는 시험포장($1276.6m^2$)에서의 지표피복 BMPs (Best Management Practices) 시나리오를 적용하여 얻은 평균 유출저감율을 HSPF 모델에 적용하여 유역차원에서의 비점원오염 저감효과를 평가하고자 한다. 본 연구에서는 별미천 유역($1.21km^2$)을 대상으로 모형의 적용을 위한 입력자료로 기상자료와 지형자료를 구축하였으며 기상자료로 수원, 양평, 이천 기상관측소 자료를 구축하였으며, 지형자료로 격자크기 2m의 DEM (Digital Elevation Model)과 토지이용도는 2006년 5월 1일 QuickBird 영상을 제공받아 기존 환경부, 건교부, USGS의 토지피복분류체계 및 현장조사를 통하여 QuickBird 영상으로부터 추출 가능한 정밀농업정보에 대한 항목을 결정하였으며, 정사보정된 QuickBird 영상을 스크린 디지타이징 기법(On-Screen Digitizing Method)을 이용하여 총 21개 토지이용항목의 정밀토지이용도를 구축하였다. 실제모니터링으로 측정된 자료를 바탕으로 수위-유량곡선 산정 및 오염부하곡선을 선정, 2011년 6월 8일부터 10월 31일 분석기간으로 HSPF 모델링을 실시하였으며 모의결과 월별 통계에 따른 적용성 분석으로 RMSE (Root Mean Square Error) 는 1.15 ~ 1.76(mm/day), $R^2$는 0.62 ~ 0.78, Nash-Sutcliffe model efficiency (NSE)는 0.62 ~ 0.76로 모의치는 실측치와 유의성이 있는 것으로 분석되었다. 또한, Sediment, T-N, T-P의 $R^2$는 각각 0.72, 0.62, 0.63으로 상관성을 보이는 것으로 분석되었다. 시험포장으로부터 얻어진 event별 볏짚을 이용한 지표피복시나리오적용 후 밭에서의 평균 유출 약 10 % 유출율 감소 조건과 실제 평균 비점원오염 저감효과 89.7 % ~ 99.4 %의 결과로부터 지표피복효과의 침투효과를 HSPF 모델로 적용하기 위해 침투량(INFILT)를 조절하여 평균유출 약 10 %가 감소되는 16.0 mm/hr 값을 선정하였다. 그 결과, Sediment. T-N, T-P의 평균 저감율은 각각 87.2 %, 28.5 %, 85.1 %로 나타났으며 이는 시험포장에서의 실제 평균 비점오염 저감효과 89.7 % ~ 99.4 %에 근접함을 알 수 있었다. 이 결과로부터 침투량 조절에 따른 지표피복(침투짚단)효과는 Sediment, T-P에서 저감효율이 80 % 이상으로 높았지만 T-N은 약 30 %로 낮은 저감율을 보임으로써 저감효과가 크지 않음을 나타냈다.

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