• Title/Summary/Keyword: N-IR

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고밀도 반응성 이온 식각을 이용한 IrMn 자성 박막의 식각

  • Lee, Tae-Yeong;So, U-Bin;Kim, Eun-Ho;Lee, Hwa-Won;Jeong, Ji-Won
    • Proceedings of the Korean Vacuum Society Conference
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    • 2011.02a
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    • pp.168-168
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    • 2011
  • 정보화 사회가 도래함으로 개인별 정보 이용량이 급격히 증가하였고 스마트폰과 같은 모바일 기기의 개발로 정보 이용량이 최고치를 갱신 중이다. 이러한 흐름 속에 사람들은 빠른 처리 속도와 고도의 저장 능력을 요구하게 되고 이에 따라 새로운 Random Access Memory에 대한 연구가 활발히 진행되고 있다. 현재 Dynamic Random Access Memory (DRAM)가 눈부신 발전과 성과를 이룩하고 있지만 전원 공급이 중단 될 경우 저장된 내용들이 지워진다는 단점을 가지고 있다. DRAM의 장점에 이러한 단점을 보완할 수 있는 차세대 반도체 소자로 주목 받고 있는 것이 Magnetic Random Access Memory (MRAM)이다. DRAM에서 Capacitor와 유사한 기능을 하는 MTJ stack은 tunneling magnetoresistance (TMR) 현상을 나타내는 자기저항 박막을 이용하여 MRAM 소자에 집적된다. 본 연구에서는 MRAM의 자성 재료로 구성된 MTJ stack을 효과적으로 식각하고 우수한 식각 profile을 얻는 동시에 재증착의 문제를 해결하는데 목적을 둔다. 본 IrMn 자성 박막의 식각 연구는 유도결합 플라즈마 반응성 이온 식각 (Inductively Coupled Plasma Reactive Ion Etching: ICPRIE)법을 이용하여 진행되었다. 특히 본 연구에서는 종래의 $Cl_2$, $BCl_3$ 그리고 HBr과 같은 부식성 가스가 아닌 부식성이 없는 $CH_4$가스를 선택하여 그 농도를 변화시키면서 식각하였고 더 나아가 $O_2$를 첨가하면서 그 효과를 극대화하려고 시도하였다. IrMn 자성 박막의 식각 속도, TiN 하드 마스크에 대한 식각 선택도 그리고 profile 등이 조사되었고 최종적으로 X-ray photoelectron spectroscopy (XPS)를 이용하여 식각 메카니즘을 이해하려고 하였다.

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Effect of Thermal Annealing on Nanoscale Thickness and Roughness Control of Gravure Printed Organic Light Emitting for OLED with PVK and $Ir(ppy)_3$

  • Lee, Hye-Mi;Kim, A-Ran;Kim, Dae-Kyoung;Cho, Sung-Min;Chae, Hee-Yeop
    • 한국정보디스플레이학회:학술대회논문집
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    • 2009.10a
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    • pp.1511-1514
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    • 2009
  • Organic light emitting layer in OLED device was formed by gravure printing process in this work. Organic surface coated by gravure printing typically showed relatively bad uniformity. Thickness and roughness control was characterized by applying various mixed solvents in this work. Poly (N-vinyl carbazole) (PVK) and fact-tris(2-phenylpyridine)iridium($Ir(ppy)_3$) are host dopant system materials. PVK was used as a host and Ir(ppy)3 as green-emitting dopant. To luminance efficiency of the plasma treatment on etched ITO glass and then PEDOT:PSS spin coated. The device layer structure of OLED devices is as follow Glass/ITO/PEDOT:PSS/PVK+Ir(ppy)3-Active layer /LiF/Al. It was printed by gravure printing technology for polymer light emitting diode (PLED). To control the thickness multi-printing technique was applied. As the number of the printing was increased the thickness enhancement was increased. To control the roughness of organic layer film, thermal annealing process was applied. The annealing temperature was varied from room temperature, $40^{\circ}C$, $80^{\circ}C$, to $120^{\circ}C$.

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Properties of the Phosphorous Polymer Light Emitting Diodes with PVK:Ir(ppy)$_3$ Emission layer (PVK:Ir(ppy)$_3$ 발광부를 갖는 고분자 인광 발광다이오드의 특성평가)

  • Baek, Seung-Jun;Gong, Su-Cheol;Lee, Ho-Sub;Jang, Seong-Kyu;Chang, Ho-Jung
    • Proceedings of the KAIS Fall Conference
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    • 2010.05a
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    • pp.363-365
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    • 2010
  • 고분자 발광다이오드(polymer light emitting diode, PLED)는 초박막화, 초경량화가 가능하며 간단한 용액공정 으로 향후 휨성(flexible) 디스플레이로의 응용이 가능할 것으로 기대되고 있다. 본 연구에서는 녹색 고분자 유기 발광다이오드를 제작하고, 효율을 향상 시키고자 이중 발광층을 두어 전기 광학적 특성을 평가하였다. ITO/Glass기판 위에 정공주입층으로 PEDOT:PSS [poly(3,4-ethylenedio xythiophene):poly(styrene sulfolnate)]를 발광물질로는 형광 발광물질인 PVK(poly-vinylcarbazole)와 인광 발광 물질인 Ir(ppy)$_3$[tris(2-phenylpyridine) iridium(III)]를 각각 host와 dopant로 사용하였다. 정공 차단층 및 전자 수송층 두 개의 역할로 사용 가능한 TPBI(1,3,5-tris(2-N-phenylbenzimidazolyl) benzene)를 진공 열증착법으로 막을 형성하였다. 전자주입층으로 LiF(lithium flouride)와 음극으로 Al(aluminum)을 증착하여 최종적으로 ITO/PEDOT:PSS/PVK:Ir(ppy)$_3$/TPBI/LiF/Al 구조를 갖는 녹색 형광:인광 혼합 유기 발광 다이오드를 제작하였다.

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Role of Tumor Necrosis Factor-${\alpha}$ Promoter Polymorphism and Insulin Resistance in the Development of Non-alcoholic Fatty Liver Disease in Obese Children

  • Yang, Hye-Ran;Ko, Jae-Sung;Seo, Jeong-Kee
    • Pediatric Gastroenterology, Hepatology & Nutrition
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    • v.15 no.1
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    • pp.44-51
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    • 2012
  • Purpose: Tumor necrosis factor-${\alpha}$ (TNF-${\alpha}$) polymorphism has been suggested to play an important role in the pathogenesis of non-alcoholic fatty liver disease (NAFLD) in obese adults, and known to be a mediator of insulin resistance. In this study, we evaluated the role of TNF-${\alpha}$ promoter polymorphisms and insulin resistance in the development of NAFLD in obese children. Methods: A total of 111 obese children (M:F=74:37; mean age, $11.1{\pm}2.0$ yrs) were included. The children were divided into 3 groups: controls (group I, n=61), children with simple steatosis (group II, n=17), and children with non-alcoholic steatohepatitis (group III, n=33). Serum TNF-${\alpha}$ levels, homeostasis model assessment of insulin resistance (HOMA-IR), and TNF-${\alpha}$ -308 and -238 polymorphisms were evaluated. Results: There were no differences in TNF-${\alpha}$ polymorphism at the -308 or the -238 loci between group I and group II + III ($p$=0.134 and $p$=0.133). The medians of HOMA-IR were significantly different between group I and group II + III ($p$=0.001), with significant difference between group II and group III ($p$=0.007). No difference was observed in the HOMA-IR among the genotypes at the -308 locus ($p$=0.061) or the -238 locus ($p$=0.207) in obese children. Conclusion: TNF-${\alpha}$ promoter polymorphisms at the -308 and -238 loci were not significantly associated with the development of NAFLD in children; nevertheless, insulin resistance remains a likely essential factor in the pathogenesis of NAFLD in obese children, especially in the progression to NASH.

RETRIEVAL OF LOCAL INTERPLANETARY DUST EMISSIVITY BY ASTRO-F

  • HONG S. S.;KWON S. M.;PYO J.;UENO M.;ISHIGURO M.;USUI F.;WEINBERG J. L.
    • Journal of The Korean Astronomical Society
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    • v.37 no.4
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    • pp.159-169
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    • 2004
  • This is a proposal to probe local part of the interplanetary dust (IPD) cloud complex and retrieve mean volume emissivity of the local IPDs at mid-infrared wavelengths. This will be done by monitoring, with Infrared Camera (IRC) aboard the ASTRO-F, the annual modulation of the zodiacal emission. In pointing mode of the ASTRO-F mission the spacecraft can make attitude maneuvering over approximately ${\pm}1^{\circ}$ range centered at solar elongation $90^{\circ}$ in the ecliptic plane. The attitude maneuvering combined with high sensitivity of the IRC will provide us with a unique opportunity observationally to take derivatives of the zodiacal emission brightness with respect to the solar elongation. From the resulting differential of the brightness over the ${\pm}1^{\circ}$ range, one can directly determine the mean volume emissivity of the local IPDs with a sufficient accuracy to de-modulate the annual emissivity variations due to the Earth's elliptical motion and the dis-alignment of the maximum IPD density plane with respect to the ecliptic. The non-zero eccentricity ($e_{\oplus}$= 0.0167) of the Earth's orbit combined with the sensitive temperature dependence of the Planck function would bring modulations of amplitude at least $3.34\%$ to the zodiacal emission brightness at mid-infrared wavelengths, with which one may determine the IPD temperature T(r) and mean number density n(r) as functions of heliocentric distance r. This will in turn fix the power-law exponent $\delta$ in the relation $T(r) = T_o(r/r_o)^{-\delta}$ for the dust temperature and v in $n(r) = n_o(r/r_o)^-v$ for the density. We discuss how one may de-couple the notorious degeneracy of cross-section, density, reference temperature $T_o$ and exponent $\delta$.

Rice-based breakfast improves fasting glucose and HOMA-IR in Korean adolescents who skip breakfast, but breakfast skipping increases aromatic amino acids associated with diabetes prediction in Korean adolescents who skip breakfast: a randomized, parallel-group, controlled trial

  • Kim, Hyun Suk;Jung, Su-Jin;Jang, Soyoung;Kim, Min Jung;Cha, Youn-Soo
    • Nutrition Research and Practice
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    • v.16 no.4
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    • pp.450-463
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    • 2022
  • BACKGROUND/OBJECTIVES: Adolescents who skip breakfast have an increased prevalence of chronic diseases. Thus, we aimed to evaluate whether the intake of rice-based breakfast had positive effects on blood glucose indices and to determine the possibility of diabetes prevalence in Korean youths who habitually skip breakfast. SUBJECTS/METHODS: In this randomized parallel-group controlled trial, 81 subjects who were suitable for compliance among 105 middle-and high-school students aged 12-18 years who usually skipped breakfast were included in this study (rice-meal group [RMG], n = 26; wheat-meal group [WMG], n = 29; general-meal group [GMG], n = 26). The RMG and WMG received a rice-based breakfast and a wheat-based breakfast for 12 weeks, respectively. The anthropometric indices, blood glucose indices, and metabolites were measured at baseline and the endpoint, respectively. RESULTS: The mean body weights in the RMG, WMG, and GMG groups at the endpoint were 62.44 kg, 61.80 kg, and 60.28 kg, respectively, and the mean body weights of the WMG and GMG groups at the endpoint were significantly higher than that at baseline (P < 0.05). The levels of fasting insulin and homeostasis model assessment of insulin resistance (HOMA-IR) values were significantly decreased in the RMG group at the endpoint compared to baseline (P < 0.05, P < 0.05, respectively). The levels of tryptophan and tyrosine in the WMG group at the endpoint were significantly higher than that those at baseline (P < 0.01, P < 0.05, respectively). CONCLUSIONS: Rice-based breakfast has positive effects on fasting insulin levels and HOMA-IR in Korean adolescents who skip breakfast. Additionally, it was found that a skipping breakfast could increase the prevalence of diabetes in adolescents who skip breakfast. Therefore, in addition to reducing breakfast skipping, it is vital to develop a rice-based menu that fits teenage preferences to prevent chronic diseases such as diabetes.

Diaminoplatinum(II) Complexes of Glutamic Acid: Obvious Chelating Isomerization

  • Young-A Lee;Jongki Hong;Ok-Sang Jung;Youn Soo Sohn
    • Bulletin of the Korean Chemical Society
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    • v.15 no.8
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    • pp.669-673
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    • 1994
  • Coordination isomers of cis-(N-N)Pt(Glu) prepared by reaction of cis-(N-N)Pt($SO_4$) (N-N=2$NH_3$, ethylenediamine(en),(R,R)-1,2-diaminocyclohexane (DACH), N,N,N',N'-tetramethylethylenediamine (TMEDA)) with barium glutamate in water have been monitored and characterized by $^1H-NMR$, $^{13}C-NMR$, IR, and mass spectra. The reaction at room temperature affords the mixture of O,O'-and N, ${\alpha}$ O-chelated platinum(II) complexes. The O,O'-chelate initially formed isomerized to N,${\alpha}$O-chelate on standing for a long time or increasing temperature. The ratio of the two isomers at room temperature depends on the nature of the nitrogen donor coligand (N-N).

Studies on Screening Rice Cultivars for Drought Resistance I. Screening at Seedling Stage (수도 한발저항성 품종 선발에 관한 연구)

  • Hak-Soo SUH
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.24 no.3
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    • pp.7-12
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    • 1979
  • Seven hundred and forty eight rice cultivars were screened for drought tolerance at seedling stage in a special green house. A number of cultivars such as Wonkiljo, Hanyangdo, YR 52-$_{x}\textrm{BF}_7-67, Satominori, Mamoriaka, Akanomochi 114, Thkebenimochi, IR 937-55-3, IR2735-F_3B-6-2, IR 2871-53-2, $_{x}\textrm{BFI76}^9/Dwan, Khoo lliok Mali-4-2-105, Os6, Palawan, IRAT10, TOS 2583 and H-l05 seemed to be tolerant to drought at seedling stage. There was negative correlation between drought resistance score and growth of plant height and water content of culm and leaf after drought treatment, and highly positive correlation between resistance to blast and resistance to drought at seedling stage. There was no relationship between drought resistance and germination speed, plant height before drought treatment.

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Solvent Extraction for the Separation of Pd(II), Pt(IV), Ir(IV) and Rh(III) from 3 M Hydrochloric Acid Solution (3 M의 염산용액에서 팔라듐(II), 백금(IV), 이리듐(IV) 및 로듐(III)의 분리를 위한 용매추출)

  • Nguyen, Thi Hong;Lee, Man Seung
    • Resources Recycling
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    • v.26 no.3
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    • pp.26-31
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    • 2017
  • LIX 63 showed a selectivity for the extraction of Pd(II) over other PGMs, such as Pt(IV), Ir(IV) and Rh(III) from 6 M HCl solution. Moreover, HCl solution has significant effect on the oxidation-reduction reaction between Ir(IV) and LIX 63. Therefore, the applicability of employing LIX 63 for the separation of the 4 PGMs was investigated from 3 M HCl solution. From 3 M HCl solution, only Pd(II) was selectively extracted by LIX 63 and its extraction percentage was higher than from 6 M HCl solution. Extraction of the Pd(II) free raffinate with TBP led to the selective extraction of Pt(IV). After oxidation of Ir(III) with $NaClO_3$ to Ir(IV), extraction of the Pt(IV) free raffinate with Aliquat 336 selectively extracted Ir(IV). For each extraction step, optimum stripping conditions were obtained. By this process, it was possible to separate the 4 PGMs by solvent extraction from 3 M HCl solution.