• Title/Summary/Keyword: N transfer

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Methyl Linoleate Oxidation via Electron Transfer in Competition with $^1O_2$ Formation Photosensitized N-Acetyl-L-Tryptophan 3-Methyl Indole

  • Yoon, Min-Joong;Song, Moon-Young;Cho, Dae-Won
    • Bulletin of the Korean Chemical Society
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    • 제6권5호
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    • pp.291-295
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    • 1985
  • The efficiency of photosensitization of methyl linoleate (ML) oxidation by N-acetyl-L-trypophan(NAT) and 3-methyl indole(scatole) was markedly enhanced by increased concentration of ML in ethanol solution. The fluorescence intensities of sensitizers were observed to be quenched by ML, indicating that ML interacts with the indole excited singlet state. The inhibition of photosensitization by azide demonstrated a possible role of singlet oxygen in the photosensitization. The steady state kinetic treatment of azide inhibition of photosensitization was expected to show linear increase of reciprocal yield of ML oxidation product vs. reciprocal ML concentration at constant azide concentration, but the actual slope was nonlinear. This indicates another competing reaction involved in the photosensitization, As a possible competing reaction, electron transfer from ML to the excited sensitizer was proposed, since the measured fluorescence quenching rate constant closely resembled electron transfer rate constant determined from ML concentration dependence of oxidation product formation.

추적 가능한 가명 은밀 획득 프로토콜 (Private Pseudonym Retrieval with Controlled Traceability)

  • 양대헌;이경희
    • 정보보호학회논문지
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    • 제16권5호
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    • pp.113-118
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    • 2006
  • 가명을 이용한 시스템에서는 가명을 발급한 기관에게도 사용자의 익명성이 유지되어야 하며, 다만 정책적으로 사용자가 규칙을 어겼을 때는 가명으로부터 사용자의 신원정보를 추적할 수 있어야 한다. 이 논문에서는 m--out-of-n oblivious transfer와 cut-and-choose 기술을 이용하여 추적 가능한 가명 은닉 획득 프로토콜을 제안한다.

Push-To-Talk 재난 서비스 환경에서 전송 지연 최소화를 위한 고속 데이터 복사 및 키 성능 지표 개선 방안 (Methods of High-speed Data Copy and Key Performance Indicator Enhancement for Minimizing the Transfer Delay in the Public Safety Push-To-Talk Service)

  • 채용두;최윤호;정우석;남백산;김주엽
    • 한국통신학회논문지
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    • 제41권11호
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    • pp.1481-1489
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    • 2016
  • 유무선 통신 기술 및 Internet Protocol (IP) 기술의 발전 및 보편화에 따라 최근 다양한 데이터 서비스가 등장하게 되었다. 이에 따라 1:1 데이터 전송을 주된 형태로 하는 전통적인 서비스와는 다르게, 1:N 데이터 전송을 활용하는 다양한 서비스가 등장하고 있으며, 이 서비스들은 1:N 전송의 효율성 및 성능 향상을 요구하고 있다. 특히 최근 많은 관심을 받고 있는 국가재난안전통신망에서 가장 중요한 서비스인 Push-To-Talk (PTT) 서비스의 경우 서비스 서버가 다수의 그룹 수신자에게 동일한 음성 데이터를 실시간 및 최소 지연 시간으로 전달해야 한다. 본 논문에서는 이런 서비스 요구 경향에 따라, 동일 데이터를 다수의 수신자에게 전달하기 위한 효율을 높이는 방법을 제시한다. 또한, 실제 유무선 통신망이 구축된 필드 환경에서 1:N 전송 성능을 어느 정도까지 높일 수 있는지 그 가능성에 대해 PTT 서비스 핵심 성능 지표 관점에서 분석해보고자 한다.

Silver Colloidal Effects on Excited-State Structure and Intramolecular Charge Transfer of p-N,N-dimethylaminobenzoic Acid Aqueous Cyclodextrin Solutions

  • 최정관;김양희;윤민중;이승준;김관;정새채
    • Bulletin of the Korean Chemical Society
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    • 제22권2호
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    • pp.219-227
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    • 2001
  • The silver colloidal effects on the excited-state structure and intramolecular charge transfer (ICT) of p-N,N-dimethylaminobenzoic acid (DMABA) in aqueous cyclodextrin (CD) solutions have been investigated by UV-VIS absorption, steady-state and time-resolved fluorescence, and transient Raman spectroscopy. As the concentration of silver colloids increases, the ratio of the ICT emission to the normal emission (Ia /Ib) of DMABA in the aqueous $\alpha-CD$ solutions are greatly decreased while the Ia /Ib values in the aqueous B-CD solutions are significantly enhanced. It is also noteworthy that the ICT emission maxima are red-shifted by 15-40 nm upon addition of silver colloids, implying that DMABA encapsulated in $\alpha-CD$ or B-CD cavity is exposed to more polar environment. The transient resonance Raman spectra of DMABA in silver colloidal solutions demonstrate that DMABA in the excited-state is desorbed from silver colloidal surfaces as demonstrated by the disappearance of νs (CO2-)(1380 cm-1 ) with appearance of ν(C-OH)(1280 cm -1) band, respectively. Thus, in the aqueous B-CD solutions the carboxylic acid group of DMABA in the excited-state can be readily hydrogen-bonded with the secondary hydroxyl group of B-CD while in aqueous and $\alpha-CD$ solutions the carboxylic acid group of DMABA has the hydrogen-bonding interaction with water. Consequently, in the aqueous B-CD solutions the enhancement of the Ia /Ia value arises from the intermolecular hydrogen-bonding interaction between DMABA and the secondary hydroxyl group of B-CD as well as the lower polarity of the rim of the B-CD cavity compared to bulk water. This is also supported by the increase of the association constant for DMABA/ B-CD complex in the presence of silver colloids.

교육훈련, 서번트 리더십, 자기효능감, 교육훈련 전이, 지식공유 간의 구조적 관계 분석 (An analysis of structural relationships among employee training, servant leadership, self-efficacy, transfer behavior of training, and knowledge sharing)

  • 송인숙;권상집
    • 지식경영연구
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    • 제18권4호
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    • pp.261-286
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    • 2017
  • Key factors enhancing transfer behavior of training and knowledge sharing are of great interest to researchers and executives because training transfer and knowledge sharing activities are remarkable predictors of organizational growth. This study investigates the core motivations for boosting transfer behavior of training and knowledge sharing. To empirically test the impacts of employee training, servant leadership and self-efficacy, a survey was conducted in small-medium sized companies. The data (N=292) were analyzed using structural equation modeling analysis. The results indicate that higher employee training positively leads to self-efficacy and transfer behavior of training. Servant leadership is positively leads to self-efficacy, transfer behavior of training, and knowledge sharing. Self-efficacy of employees induces greater transfer behavior of training and knowledge sharing. Finally, transfer behavior of training encourages workers to increase knowledge sharing. This study represents an initial step to examine the psychological mechanism of improving employees' transfer behavior of training and knowledge sharing activities based on the employee training qualities and servant leaderships.

Liquid Scintillation Counting 에서의 Dimethylaniline 에 依한 消光機構 (Mechanism of Quenching by Dimethylanilines in Liquid Scintillation Counting)

  • 이익춘
    • 대한화학회지
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    • 제8권2호
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    • pp.43-46
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    • 1964
  • Quenching constants, q, determined for N,N-dimethylanilines by liquid scintillation counting indicate that the quenching involves an energy transfer process to these compounds causing strong n-${\pi}$ interaction within the quencher molecule, which is then followed by an non-radiative degradation of the excitation energy to ground state.

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삼차원 조도관의 압력손실 및 열전달 성능에 대한 실험적 연구 (An Experimental Study on the Pressure Drop and Heat Transfer Performance in Tubes with Three Dimensional Roughness)

  • 김내현
    • 설비공학논문집
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    • 제7권2호
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    • pp.276-286
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    • 1995
  • In this study, pressure drop and heat transfer coefficients were measured in tubes with three dimensional roughness. Dimples were made by rotating the saw-tooth shaped finning disc on the outer tube surface. Resultant dimple shape was oval. Friction and heat transfer tests were performed with a range of roughness variables-roughness height 'e', axial roughness pitch 'p', circumferential roughness pitch 'z'. Within the test range, tube with e=0.5mm, z=5mm, p=3mm performed best. The efficiency ratio(rati of the heat transfer improvement and the pressure drop increase) of the tube approached 1.0 at low Reynolds number, and it was higher than that of the two-dimensional roughess tube of the same roughness height. Test data were predicted by 'discrete element method'. Results show that discrete element method underpredicts the friction data by 2% to 32%, and overpredicts the heat transfer data by-12% to 113%.

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Two Dimensional Transfer Modes in $CH_2$ Spin System

  • NamGoong Hyun
    • 한국자기공명학회논문지
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    • 제10권1호
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    • pp.59-73
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    • 2006
  • Spin-lattice relaxation pathway of $CH_2$ spin system by two dimensional NOESY sequence has been discussed. Two-dimensional spectra governed by dipolar relaxation mechanism were simulated in term of transfer mode, the generalization of conventionally used magnetization mode in one dimension. The transfer matrix directly related to the Redfield relaxation matrix can be constructed by the multiplet of transfer mode. The observable relaxation transfer modes causes to variation of the off-diagonal signal intensity of phase sensitive NOESY spectra from which variable spectral density can be extracted with simple group theoretical calculation. The variation of the J-coupling peak intensity as a function of the mixing time in 2-D spectra for $n-Undecane-5-^{13}C$ and Bromoacetic $2-^{13}C$ acid has been theoretically traced.

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차원 해석을 통한 GMA 용접의 금속이행 현상에 관한 분석 (Investigation on Metal Transfer in GMA Welding through Dimensional Analysis)

  • 최상균;유중돈
    • Journal of Welding and Joining
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    • 제17권1호
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    • pp.62-70
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    • 1999
  • Since various parameters including the welding conditions and material properties are involved in metal transfer, it is difficult to figure out the effects of each parameter. In this study, dimensional analysis in performed to reduce the number of the parameters and to reveal the effect of each parameter on metal transfer. Dimensionless parameters are derived based on the inertia force and surface tension, and their contributions on metal transfer are estimated by analyzing the calculated results using the volume of fluid (VOF) method. Among several dimensionless parameters, $N_{SE}(=$\mu$_{0}I^{2}/d_{w}${\gamma}$)$ which represents the ratio of the electromagnetic force to surface tension, is found to be appropriate to describe metal transfer and estimate the transition current. Predicted results of transition current and drop size are in reasonably good agreements with available experimental date which show the validity of proposed dimensional analysis.

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원자로 냉각재 펌프의 과도 상태의 유동 및 열전달 해석 연구 (Flow and Heat Transfer Analysis of Reactor Coolant Pump in Transient Conditions)

  • 허남건;김성원;유기풍;김승태
    • 유체기계공업학회:학술대회논문집
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    • 유체기계공업학회 1999년도 유체기계 연구개발 발표회 논문집
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    • pp.245-251
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    • 1999
  • The structural analysis of a reactor coolant pump(RCP) of a nuclear power plant is very important for the safety assessment of the plant. Accurate boundary conditions for the heat transfer coefficient are required for reliable thermal stress analysis of the pump casing, especially in transient operations of the pump since the coolant properties are largely dependent on operational conditions. In the present study, a 3D mixed flow type coolant pump was modeled from the RCP drawings and analyzed in the steady state and number of transient flow conditions by using a commercial code STAR-CD. From the result of the computation, it is seem that the average heat transfer coefficients for the cases considered are found to be the suggested values of the manufacturer, Westinghouse Energy System. The unevenness in local heat transfer coefficients, however, is found to be considerable so that the use of average heat transfer coefficients in all boundaries might not give reliable thermal stresses.

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