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Electrochemical Characteristic on Lithium Intercalation into the Interface between Organic Electrolyte and Amorphous WO3 Thin Film Prepared by e-beam Evaporation Method (e-beam 증발법으로 제조된 비정질 WO3박막과 전해질 계면으로 삽입되는 리튬의 층간 반응에 관한 전기화학적 특성)

  • Min, Byoung-Chul;Sohn, Tae-Won;Ju, Jeh-Beck
    • Applied Chemistry for Engineering
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    • v.8 no.6
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    • pp.1022-1028
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    • 1997
  • This work was performed to study the characteristics of electrochemical intercalation reactions occurring at the interface between the organic electrolyte and tungsten trioxide thin film (thickness of $4000{\AA}$) prepared by e-beam evaporation method as cathodically coloring oxide with regard to the electrochromism by the intercalating reactions of the lithium cation in the 1M $LiClO_4/PC$ organic solution. The characteristics of electrochemical intercalation reactions were investigated by various DC electrochemical methods such as cathodic Tafel polarization test, multiple and the single sweep cyclic voltammetry and the coulomety titrations method. The surfaces of thin films were observed with the patterns of X ray diffraction after the coloring and bleaching reactions. In comparison with the previous results that $WO_3$ thin film intersely detached from the surface of electrode when the hydrogen cation was intercalated into $WO_3$ thin film in the o.1N $H_2SO_4$ aqueous solution, the intercalation reaction of lithium cation into $WO_3$ thin film in the 1M $LiClO_4/PC$ organic solution was shown that the stable bleaching and coloration was appeared within 1.0V of the applied overpotential. When the overpotential of electrochromic reaction for lithium cation in the 1M $LiClO_4/PC$ organic solution had been applied up to 1.5V, the accumulation phenomenon of lithium in amorphous $WO_3$ thin film layer occurred because the inserted lithium into amorphous $WO_3$ thin layer for coloring process was not fully removed from the thin layer to the electrolyte during bleaching process. It was found that there is a limitation of applied overpotential for coloring process by the reduction of the current densities of bleaching and coloration after few number of coloring and bleaching cycles.

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Effect of Internal Stress on Cyclic Fatigue Failure in ProTaper Universal (ProTaper Universal에 축적된 내부 응력이 피로 파절에 미치는 영향)

  • Jo, Yun-Sung;Kim, Jin-Woo;Cho, Kyung-Mo;Park, Se-Hee
    • Journal of Dental Rehabilitation and Applied Science
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    • v.28 no.1
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    • pp.57-66
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    • 2012
  • The purpose of this study was to evaluate the relation between intentionally induced internal stress and cyclic fatigue failure of ProTaper Universal. ProTaper Universal (Dentsply Maillefer) S1, S2, F1, F2, F3, F4 and F5 (25 mm length) were used in this study. To give the internal stress, the ProTaper Universal were put into the .02 taper Endo-Training-Bloc (Dentsply Maillefer) until auto-stop by torque controlled motor. The rotation speed was 300 rpm and torque value was 1.0 Ncm. ProTaper Universal were grouped by the induced number of internal stress and randomly distributed among one control group and three experimental groups (n=10). The four groups were Stress 0 (control), Stress 1, Stress 2 and Stress 3. These instruments were rotated until separation. For cyclic fatigue measurement, inclined plane was used and time for separation was recorded. It was statistically analyzed using two-way ANOVA and Duncan post-hoc test at 95% confidential level. In all ProTaper Universal, there was statistically significant decrease on time for separation in Stress 3. In F2 and F3, there were statistically significant difference between control group and all experimental groups. And in F4 and F5, Stress 2 and 3 groups showed significantly lower cyclic fatigue resistance from Stress 0 group. In the limitation of this study, cyclic fatigue failure of ProTaper Universal is influenced by accumulated internal stress.

Locating Microseismic Events using a Single Vertical Well Data (단일 수직 관측정 자료를 이용한 미소진동 위치결정)

  • Kim, Dowan;Kim, Myungsun;Byun, Joongmoo;Seol, Soon Jee
    • Geophysics and Geophysical Exploration
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    • v.18 no.2
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    • pp.64-73
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    • 2015
  • Recently, hydraulic fracturing is used in various fields and microseismic monitoring is one of the best methods for judging where hydraulic fractures exist and how they are developing. When locating microseismic events using single vertical well data, distances from the vertical array and depths from the surface are generally decided using time differences between compressional (P) wave and shear (S) wave arrivals and azimuths are calculated using P wave hodogram analysis. However, in field data, it is sometimes hard to acquire P wave data which has smaller amplitude than S wave because microseismic data often have very low signal to noise (S/N) ratio. To overcome this problem, in this study, we developed a grid search algorithm which can find event location using all combinations of arrival times recorded at receivers. In addition, we introduced and analyzed the method which calculates azimuths using S wave. The tests of synthetic data show the inversion method using all combinations of arrival times and receivers can locate events without considering the origin time even using only single phase. In addition, the method can locate events with higher accuracy and has lower sensitivity on first arrival picking errors than conventional method. The method which calculates azimuths using S wave can provide reliable results when the dip between event and receiver is relatively small. However, this method shows the limitation when dip is greater than about $20^{\circ}$ in our model test.

Liberating and Reviving the Concept of EA Business Architecture (EA 비즈니스 아키텍처 개념의 개방과 확대에 대한 제언)

  • Juhn, Sung Hyun
    • Journal of Information Technology and Architecture
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    • v.10 no.4
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    • pp.435-449
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    • 2013
  • The performance of Enterprise Architecture (EA) in the Korea's public IT domain produces mixed results and responses. On the one hand, EA earns positive remarks and enthusiasm as a central government-wide IT governance framework with its significant IT budget saving records. At the same time, however, the response to EA at the department and agency level is tainted with disappointment, fatigue, and reluctance. This essay suggests that this is perhaps caused by the sterile lackluster concept of EA Business Architecture employed in the current EA practice of the enterprise. The possibility for liberating and reviving the concept of EA Business Architecture is explored. Various conceptual axes and branches of EA Business Architecture are identified based upon extensive EA field experience and observations, and discussions are made on how the concept of EA Business Architecture can be expanded and amplified on those conceptual axes and branched. The resulting EA Business Architecture conceptualization is consolidated into an illustrative typology for EA Business Architecture. In the end the theoretical and practical implications of the research are discussed along with its contribution and limitation.

A Study of Evaluation Indices for Selecting Castle Remains Maintenance and Restoration Sections (성곽유적의 정비복원(整備復元) 대상구간 선정을 위한 평가지표 연구)

  • Kim, Hong-Gon;Choi, Key-Soo
    • Journal of the Korean Institute of Traditional Landscape Architecture
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    • v.30 no.1
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    • pp.1-13
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    • 2012
  • Most of all Castle Remains in Korea were built on an axis of development with a scale of great magnitude. Because of its characteristics, the restoration and conservation plans should be phased in over medium and long term. There is no standards for evaluating the value of Castle Remains to set up the restoration and conservation sections. Some plans were set up through the value evaluation of its Castle Remains but those plans didn't have Evaluation System and different weight depending on different environment between Sanseong(mountain fortress) and Eupsung(fortress built in villages). To solve the limitation of Evaluation System of Castle Remains, this study try to approach in the Evaluation System methodology for selecting restoration sections. The results of its study follow below. First, this study drew the Evaluation Indices for selecting restoration sections of Castle Remains. There are three kinds of Elements(upper Index) and nine kinds of Evaluations(low Index). Second, Calculation of weight index by index on the questionnaire survey from expers through the relative importance analysis of AHP. Third, This study suggests the specific Evaluation System according to types; Sanseong(mountain fortress) and Eupsung(fortress built in villages);. Therefore, this study suggests standards to select the priority list for the restoration and conservation plan process and it can be used one of important standards in future plans.

Daily Variation of Size-Fractionated Chlorophyll a Concentrations and Water Conditions Associated with Freshwater Discharge during Summer in the Yeongsan River Estuary (영산강 하구의 하계 담수 방류와 연관된 크기별 Chlorophyll a와 수환경의 일간 변동)

  • Kim, Sehee;Shin, Yongsik
    • Journal of Marine Life Science
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    • v.5 no.2
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    • pp.72-80
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    • 2020
  • A sea dike in the Yeongsan River estuary was constructed in 1981 to supply water and reclaim tidal flats for agriculture, separating the estuary into the freshwater and seawater zones. However, the sluice gates are frequently opened and freshwater is discharged in summer when more rainfall is recorded than other seasons, then converting the estuary to brackish water system. In this study, the direct effect of freshwater discharge was investigated by monitoring daily variation in water properties and phytoplankton size structure before and after the freshwater discharge events from 2013 to 2015. Freshwater discharge resulted in a sharp decrease in salinity and dissolved oxygen (DO) at surface water whereas it increased the turbidity of water column. However, salinity did not decrease sharply in 2014 when freshwater was discharged one day before the monitoring and salinity remained low prior to the monitoring. Levels of nutrients especially dissolved inorganic nitrogen (DIN) increased after the discharge and this contributed to potential limitation of nutrients such as P or Si rather than N in the estuary. Freshwater discharge also caused the changes in phytoplankton biomass (chlorophyll a) and size structure although their responses were different between years. The changes may affect growth of grazers and thus structure of marine food web by alternating food availability in the Yeongsan River estuary.

The Influence of Cultural Program Commitment on Career Perception & Development of Children and Adolescents Using Local Children Centers' Services - The Mediating Effects of Self-Efficacy Moderated by Social Support (지역아동센터 이용 아동·청소년의 문화프로그램 몰입이 진로인식 및 진로발달에 미치는 영향 - 사회적지지에 의해 조절된 자기효능감의 매개효과)

  • Jang, Sun-Hwa
    • Journal of Digital Convergence
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    • v.19 no.4
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    • pp.193-204
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    • 2021
  • The purpose of this study was to examine the mediating effect of self-efficacy moderated by social support in the influence of local children's center cultural program commitment on career awareness and development of children and adolescents using Local Children Centers' Services. For this purpose, the questionnaires of local children's center cultural program commitment, career awareness and development, social support, and self-efficacy was conducted to 190 elementary school students in the 3rd grade and middle and high school in 22 children's centers in N city. The statistical packages were SPSS PC+ 25.0 and SPSS MACRO. The main results are as follows: First, cultural program commitment had positive correlation with self-efficacy, social support, career awareness and career development. Also, self-efficacy had a positive correlation with social support, career awareness and career development, and social support had a positive correlation with career awareness and career development. Second, the hypothesis model was supported that cultural program commitment positively affects career awareness mediated by self-efficacy moderated by social support. In other words, the more they participated and commited in cultural programs, the more self-efficacy increased leading to more career awareness. Also, the more social support was felt, the more the positive influence of cultural program commitment on self-efficacy increased. The hypothesis model was supported that cultural program commitment positively affects career development mediated by self-efficacy moderated by social support. In other words, the more they participated and commited in cultural programs, the more self-efficacy increased leading to more career development. Also, the more social support was felt, the more positive influence of cultural program commitment on self-efficacy increased. The limitation and future tasks were discussed.

A Novel Therapeutic Effect of a New Variant of CTLA4-Ig with Four Antennas That Are Terminally Capped with Sialic Acid in the CTLA4 Region

  • Piao, Yongwei;Yun, So Yoon;Kim, Hee Soo;Park, Bo Kyung;Ha, Hae Chan;Fu, Zhicheng;Jang, Ji Min;Back, Moon Jung;Shin, In Chul;Won, Jong Hoon;Kim, Dae Kyong
    • Biomolecules & Therapeutics
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    • v.30 no.6
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    • pp.529-539
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    • 2022
  • Rheumatoid arthritis (RA) is a multifactorial immune-mediated disease, the pathogenesis of which involves different cell types. T-cell activation plays an important role in RA. Therefore, inhibiting T-cell activation is one of the current therapeutic strategies. Cytotoxic T-lymphocyte antigen 4-immunoglobulin (CTLA4-Ig), also known as abatacept, reduces cytokine secretion by inhibiting T-cell activation. To achieve a homeostatic therapeutic effect, CTLA4-Ig has to be administered repeatedly over several weeks, which limits its applicability in RA treatment. To overcome this limitation, we increased the number of sialic acid-capped antennas by genetically engineering the CTLA4 region to increase the therapeutic effect of CTLA4-Ig. N-acetylglucosaminyltransferase (GnT) and α2,6-sialyltransferase (α2,6-ST) were co-overexpressed in Chinese hamster ovary (CHO) cells to generate a highly sialylated CTLA4-Ig fusion protein, named ST6. The therapeutic and immunogenic effects of ST6 and CTLA4-Ig were compared. ST6 dose-dependently decreased paw edema in a mouse model of collagen-induced arthritis and reduced cytokine levels in a co-culture cell assay in a similar manner to CTLA4-Ig. ST6- and CTLA4-Ig-induced T cell-derived cytokines were examined in CD4 T cells isolated from peripheral blood mononuclear cells after cell killing through irradiation followed by flow- and magnetic-bead-assisted separation. Interestingly, compared to CTLA4-Ig, ST6 was substantially less immunogenic and more stable and durable. Our data suggest that ST6 can serve as a novel, less immunogenic therapeutic strategy for patients with RA.

Multiple Aging Trajectories of the Elderly in Korea (한국 노인의 노화궤적 연구)

  • Kim, Sojin
    • 한국노년학
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    • v.39 no.1
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    • pp.37-60
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    • 2019
  • This study was attempt to derive the aging trajectories of Korean elderly people and identify its characteristics. In particular, this study used the successful aging model of Rowe and Kahn as an analytical framework. Using the Korean Longitudinal Study of Ageing(KLoSA), this study applied group-based multi-trajectory analysis to identify multiple aging trajectories in sample of Korean elder aged 65~74(n=2,682). This study also used several demographic characteristics as baseline predictors to identify the characteristics of each aging trajectory. Five dimensions were analyzed in the multi-trajectory model: chronic disease, physical functional limitation, cognitive functioning, depressive symptom and social engagement. As a result of the analysis, five aging trajectories were identified: successful aging(17.8%), usual aging (33.9%), health declining aging(18.2%), pathological aging(7.9%), and aging with mild cognitive impairment(22.1%). In general, the odds of experiencing successful aging were high in men, low-aged, highly educated, high-income, and spousal elderly. On the other hand, for the elderly, who are under-educated, low-income, and high-aged, there was a high probability of experiencing a relatively difficult aging process. In particular, the odds of experiencing a mild cognitive impairment aging was high in older, lower-income women without a spouse.

Effect of attachments and palatal coverage of maxillary implant overdenture on stress distribution: a finite element analysis (상악 임플란트 피개의치에서 유지장치 종류와 구개 피개 유무에 따른 응력분포에 대한 유한요소분석)

  • Park, Jong-Hee;Wang, Yuan-Kun;Lee, Jeong-Jin;Park, Yeon-Hee;Seo, Jae-Min;Kim, Kyoung-A
    • Journal of Dental Rehabilitation and Applied Science
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    • v.36 no.2
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    • pp.70-79
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    • 2020
  • Purpose: The purpose of this study was to evaluate the effect of attachments and palatal coverage on stress distribution in maxillary implant overdenture using finite element analysis. Materials and Methods: Four maxillary overdenture 3-D models with four implants placed in the anterior region were fabricated with computer-aided design. 1) Ball-F: Non-splinted ball attachment and full palatal coverage, 2) Ball-P: Non-splinted ball attachment and U-shaped partial palatal coverage, 3) Bar-F: Splinted milled bar attachment and full palatal coverage, 4) Bar-P: Splinted milled bar attachment and U-shaped partial palatal coverage. Stress distribution analysis was performed with ANSYS workbench 14. 100 N vertical load was applied at the right first molar unilaterally and maximum stress was calculated at the implant, peri-implant bone and mucosa. Results: The use of the ball attachment showed lower maximum stress on implant and peri-implant bone than the use of the milled bar attachment. But it showed contrary tendency in the mucosa. Regardless of attachment, full palatal coverage showed lower maximum stress on implant, peri-implant bone and mucosa. Conclusion: Within the limitation of this study, ball attachment improved stress distribution on implant and peri-implant bone rather than milled bar attachment in maxillary implant overdenture. Also, full palatal coverage is more favorable in stress distribution.