• 제목/요약/키워드: N deposition

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Distribution and Characteristics of the Sedimentary Basin Offshore San-in to Tsushima Islands (일본 산닌-쓰시마 해양에 존재하는 퇴적분지의 분포와 특성)

  • Park Se-Jin
    • The Korean Journal of Petroleum Geology
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    • v.10 no.1_2 s.11
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    • pp.34-39
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    • 2004
  • This article discusses stratigraphy and geological history of continental shelf area covering of offshore San-in to Tsushima islands. Geological data from 5 wells and detailed seismic surveys indicate that sediments in the studied area are divided into 4 stratigraphic groups ranging from Oligocene to Tertiary in age, namely X, H, K, and D groups in ascending order. The oldest X group of Oligocene time comprises paralic sediments including volcanics deposited in the initial stage of basin-formation. N group of mainly lower Miocene time consists of deep marine sediment, representing the highest stage of transgression. Sediments of the K group of middle Miocene time show distinct off-lapping depositional pattern during the basinfilling stage. The youngest D group covers these older groups unconformably. Strong deformation of sediments prior to the deposition of the D group formed many anticlinal structures. Five exploratory wells were drilled at the selected structures, where only minor gas shows were encountered. The area provides the enough palaeotemperature to mature the source rocks at moderate depth.

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Copper Sulfide Nanowires for Solar Cells (태양전지용 $Cu_2S$ 나노와이어의 제작 및 특성분석)

  • Lim, Young-Seok;Kang, Yoon-Mook;Kim, Won-Mok;Kim, Dong-Hwan
    • 한국신재생에너지학회:학술대회논문집
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    • 2006.06a
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    • pp.166-169
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    • 2006
  • We fabricated hexagonal copper sulfide $Cu_2S$ nanowires to obtain a larger contact area of $Cu_2S/CdS$ solar cell. Copper sulfide nanowires were grown on Cu foil at room temperature by gas-sol id reaction. The size, density and shape of nanowires seemed to be affected by the change or reaction time temperature, crystallographic orientation of Cu foil, and molar ratio of the mixed gas. We controled the length and the diameter of the nanowires and we obtained suitable nanowire arrays which has fitting size for uniform deposition with n-type CdS. CdS layer was deposited on the nanowire array by electrodeposition and it seemed to be uniform. The $Cu_2S/CdS$ nanowires/CdS junction showed diode characteristics, A large contact area is expected with the $Cu_2S/CdS$ nanowire structure as compared with the $Cu_2S/CdS$ thin film.

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Atomic Force Microscopy Study on Correlation between Electrical Transport and Nanomechanical properties of Graphene Layer

  • Kwon, Sang-Ku;Choi, Sung-Hyun;Chung, H.J.;Seo, S.;Park, Jeong-Young
    • Proceedings of the Korean Vacuum Society Conference
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    • 2010.08a
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    • pp.85-85
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    • 2010
  • Graphene, the building block of graphite, is one of the most promising materials due to their fascinating electronic transport properties. The pseudo-two-dimensional sp2 bonding in graphene layers yields one of the most effective solid lubricants. In this poster, we present the correlation between electrical and nanomechanical properties of graphene layer grown on Cu/Ni substrate with CVD (Chemical Vapor Deposition) method. The electrical (current and conductance) and nanomechanical (adhesion and friction) properties have been investigated by the combined apparatus of friction force microscopy/conductive probe atomic force microscopy (AFM). The experiment was carried out in a RHK AFM operating in ultrahigh vacuum using cantilevers with a conductive TiN coating. The current was measured as a function of the applied load between the AFM tip and the graphene layer. The contact area has been obtained with the continuum mechanical models. We will discuss the influence of mechanical deformation on the electrical transport mechanism on graphene layers.

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Spheroidization of Pure-vanadium Powder using Radio Frequency Thermal Plasma Process (RF 플라즈마를 이용한 순수 바나늄 분말의 구상화 거동 연구)

  • Adomako, Nana Kwabena;Yang, Seungmin;Lee, Min Gyu;Reddy, N.S.;Kim, Jeoung-Han
    • Journal of Powder Materials
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    • v.26 no.4
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    • pp.305-310
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    • 2019
  • In the present work, spheroidization of angular vanadium powders using a radio frequency (RF) thermal plasma process is investigated. Initially, angular vanadium powders are spheroidized successfully at an average particle size of $100{\mu}m$ using the RF-plasma process. It is difficult to avoid oxide layer formation on the surface of vanadium powder during the RF-plasma process. Titanium/vanadium/stainless steel functionally graded materials are manufactured with vanadium as the interlayer. Vanadium intermediate layers are deposited using both angular and spheroidized vanadium powders. Then, 17-4PH stainless steel is successfully deposited on the vanadium interlayer made from the angular powder. However, on the surface of the vanadium interlayer made from the spheroidized powder, delamination of 17-4PH occurs during deposition. The main cause of this phenomenon is presumed to be the high thickness of the vanadium interlayer and the relatively high level of surface oxidation of the interlayer.

Surface Properties of ACL Thin Films Depending on Process Conditions (공정 조건에 따른 비정질 탄소막 표면 물성분석)

  • Kim, Kwang Pyo;Choi, Jeong Eun;Hong, Sang Jeen
    • Journal of the Semiconductor & Display Technology
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    • v.18 no.2
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    • pp.44-47
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    • 2019
  • Amorphous carbon layer (ACL) is actively used as an etch mask. Recent advances in patterning ACL requires the next level of durability of hard mask in high aspect ratio etch in near future semiconductor manufacturing, and it is worthwhile to know the surface property of ACL thin film to enhance the property of etch hard mask. In this research, ACL are deposited by 6 inch plasma enhanced chemical vapor deposition system with $C_3H_6$ and $N_2$ gas mixture. Surface properties of deposited ACL are investigated depending on gas flow, pressure, RF power. Fourier transform infrared is used for the analysis of surface chemistry, and X-ray photoemission spectra is used for the structural analysis with the consideration of the contents of $sp^2$ and $sp^3$ through fitting of C1s. Also mechanical properties of deposited ACL are measured in order to evaluate hardness.

Effect of Plasma Enhancement on the Al-doped ZnO Thin Film Synthesis by MOCVD (유기금속화학기상증착법에 의한 ZnO:Al 필름 합성에서 플라즈마 인가 효과)

  • Seomoon, Kyu
    • Journal of the Korean Solar Energy Society
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    • v.39 no.1
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    • pp.33-40
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    • 2019
  • Al-doped ZnO (AZO) thin films were synthesized on Si(100) wafers via plasma enhanced metal organic chemical vapor deposition (PE-MOCVD) method using diethyl zinc (DEZ) and N-methylpyrrolidine alane (MPA) as precursors. Effects of Al/Zn mixing ratio, plasma power on the surface morphology, crystal structure, and electrical property were investigated with SEM, XRD and 4-point probe measurement respectively. Growth rate of the film decreased slightly with increasing the Al/Zn mixing ratio, however electrical property was enhanced and resistivity of the film decreased greatly about 2 orders from $9.5{\times}10^{-1}$ to $8.0{\times}10^{-3}{\Omega}cm$ when the Al/Zn mixing ratio varied from 0 to 9 mol%. XRD analysis showed that the grain size increased with increasing the Al/Zn mixing ratio. Growth rate and electrical property were enhanced in a mild plasma condition. Resistivity of AZO film decreased down to $7.0{\times}10^{-4}{\Omega}cm$ at an indirect plasma of 100 W condition which was enough value to use for the transparent conducting oxide (TCO) material.

Tuning the Interference Color with PECVD Prepared DLC Thickness (PECVD를 이용한 DLC 두께 제어에 따른 간섭색 구현)

  • Park, Saebom;Kim, Kwangbae;Kim, Hojun;Kim, Chihwan;Choi, Hyun Woo;Song, Ohsung
    • Korean Journal of Materials Research
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    • v.31 no.7
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    • pp.403-408
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    • 2021
  • Various surface colors are predicted and implemented using the interference color generated by controlling the thickness of nano-level diamond like carbon (DLC) thin film. Samples having thicknesses of up to 385 nm and various interference colors are prepared using a single crystal silicon (100) substrate with changing processing times at low temperature by plasma-enhanced chemical vapor deposition. The thickness, surface roughness, color, phases, and anti-scratch performance under each condition are analyzed using a scanning electron microscope, colorimeter, micro-Raman device, and scratch tester. Coating with the same uniformity as the surface roughness of the substrate is possible over the entire experimental thickness range, and more than five different colors are implemented at this time. The color matched with the color predicted by the model, assuming only the reflection mode of the thin film. All the DLC thin films show constant D/G peak fraction without significant change, and have anti-scratch values of about 19 N. The results indicate the possibility that nano-level DLC thin films with various interference colors can be applied to exterior materials of actual mobile devices.

Selective Emitter Formation of Borosilicate-Glass (BSG) Layer using UV Laser (UV Laser를 이용한 Borosilicate-Glass (BSG)층의 선택적 에미터 형성)

  • Kim, Ga Min;Chang, Hyo Sik
    • Korean Journal of Materials Research
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    • v.31 no.12
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    • pp.727-731
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    • 2021
  • In this study, we have investigated a selective emitter using a UV laser on BBr3 diffusion doping layer. The selective emitter has two regions of high and low doping concentration alternatively and this structure can remove the disadvantages of homogeneous emitter doping. The selective emitters were fabricated by using UV laser of 355 nm on the homogeneous emitters which were formed on n-type Si by BBr3 diffusion in the furnace and the heavy boron doping regions were formed on the laser regions. In the optimized laser doping process, we are able to achieve a highly concentrated emitter with a surface resistance of up to 43 Ω/□ from 105 ± 6 Ω/□ borosilicate glass (BSG) layer on Si. In order to compare the characteristics and confirm the passivation effect, the annealing is performed after Al2O3 deposition using an ALD. After the annealing, the selective emitter shows a better effect than the high concentration doped emitter and a level equivalent to that of the low concentration doped emitter.

Overcoming Encouragement of Dragon Fruit Plant (Hylocereus undatus) against Stem Brown Spot Disease Caused by Neoscytalidium dimidiatum Using Bacillus subtilis Combined with Sodium Bicarbonate

  • Ratanaprom, Sanan;Nakkanong, Korakot;Nualsri, Charassri;Jiwanit, Palakrit;Rongsawat, Thanyakorn;Woraathakorn, Natthakorn
    • The Plant Pathology Journal
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    • v.37 no.3
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    • pp.205-214
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    • 2021
  • The use of the supernatant from a Bacillus subtilis culture mixed with sodium bicarbonate was explored as a means of controlling stem brown spot disease in dragon fruit plants. In in vitro experiments, the B. subtilis supernatant used with sodium bicarbonate showed a strong inhibition effect on the growth of the fungus, Neoscytalidium dimidiatum, the agent causing stem brown spot disease and was notably effective in preventing fungal invasion of dragon fruit plant. This combination not only directly suppressed the growth of N. dimidiatum, but also indirectly affected the development of the disease by eliciting the dragon-fruit plant's defense response. Substantial levels of the pathogenesis-related proteins, chitinase and glucanase, and the phenylpropanoid biosynthetic pathway enzymes, peroxidase and phenyl alanine ammonia-lyase, were triggered. Significant lignin deposition was also detected in treated cladodes of injured dragon fruit plants in in vivo experiments. In summary, B. subtilis supernatant combined with sodium bicarbonate protected dragon fruit plant loss through stem brown spot disease during plant development in the field through pathogenic fungal inhibition and the induction of defense response mechanisms.

Monsoonal sediment transport along the subaqueous Mekong Delta: An analysis of surface sediment grain-size changes

  • Thanh C., Nguyen;An T., Dang;Khuong N.T., Tran
    • Ocean Systems Engineering
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    • v.12 no.4
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    • pp.403-411
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    • 2022
  • Annually, about 48-60% of sediment discharge of the Mekong River is delivered near the mouths of the Mekong River branches which is mostly coinciding with the southwest (SW) monsoon. This sediment budget in turn will be southwestwardly transported along the coast of the Mekong Delta (MD) during the northeast (NE) monsoon. Analysis of monsoonal changes in grain-size distribution (GSD) of surface sediment contributes to a better understanding of erosion and deposition processes along the MD. This study aims to figure out changes in GSD and sediment textures along the MD between SW and NE monsoons based on 183 surficial sediment samples collected along the MD during two field surveys carried-out in October 2016 and February-March 2017. Compared to the GSD during the SW and NE monsoon, the GSD along the MD changed significantly, especially in the estuary areas and along the coast of Bac Lieu and Ganh Hao. Whereas, in the west coast of the MD, GSD seem no changes between the two seasons. These changes in seabed sediment suggest that sediment with grain-sizes ranging from silt to fine sand can be transported during only a NE season.