• Journal of Electrochemical Science and Technology
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• 제2권1호
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• pp.14-19
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• 2011

Quasi-equilibrium profiles are analyzed through galvanostatic intermittent titration technique (GITT) and potentiostatic intermittent titration technique (PITT) to study the charge/discharge mechanism in multicomponent olivine structure ($LiMn_{1/3}Fe_{1/3}Co_{1/3}PO_4$). From GITT data, the degree of polarization is evaluated for the three regions corresponding to the redox couples of $Mn^{2+}/Mn^{3+}$, $Fe^{2+}/Fe^{3+}$ and $Co^{2+}/Co^{3+}$. From PITT data, the current vs. time responses are examined in each titration step to find out the mode of lithium de-intercalation/intercalation process. Furthermore, lithium diffusivities at specific compositions (x in $Li_xMn_{1/3}Fe_{1/3}Co_{1/3}PO_4$) are also calculated. Finally, total capacity ($Q^{total}$) and diffusional capacity ($Q^{diff}$) are obtained for some selected voltage steps. The entire study consistently confirms that the charge/discharge mechanism of multicomponent olivine cathode is associated with a one-phase reaction rather than a biphasic reaction.

• Archives of Pharmacal Research
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• 제7권1호
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• pp.23-31
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• 1984

An improved mass spectrometric method for multicomponent analysis of metabolites in urine, well-suited for clinical biochemistry, is described. The method involves solvent elution of the metabolites from an adsorbent and the concentration of the eluate on a microadsorption column. This is administered by a direct inlet probe into the ionizing source of field ionization mass spectrometry (FIMS), which yield a molecular weight profile of the metabolites. The procedure provides rapidly (within one hour) reproducible profiles from a small volume of urine. The optimization of the sampling technique and the reproducibility are discussed.

• 한국전산유체공학회지
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• 제12권1호
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• pp.60-67
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• 2007

In this paper, the dispersion controlled dissipative (DCD) scheme is reviewed and then extended to simulate chemically reacting gas flows in multicomponent mixtures in the presence of strong shock waves. Furthermore, the properties of the reactive DCD (DCD-R) scheme are discussed, followed by several applications. The DCD scheme has been shown to have the following features: high accuracy and robustness for reacting gas flows in the presence of strong shock waves and contact discontinuities, and algorithmic simplicity.

• 한국연소학회:학술대회논문집
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• 한국연소학회 2012년도 제45회 KOSCO SYMPOSIUM 초록집
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• pp.335-338
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• 2012

The present study focuses mainly on modeling the ordinary diffusion flux of species. According to CHEMKIN, both the mixture-averaged approach, Fick's formula, and the full multicomponent approach are implemented in the framework of opensource OpenFOAM. Also the Stefan-Maxwell approach is coded and validated together against measurements of laminar hydrogen jet flame. In the case of viscosity and conductivity of mixture, the mixture-averaged approach is applied and thermal diffusion is not considered in this work. Results show that there are no distinct deviations in three different approaches of diffusion of species in the present hydrogen flame condition.

• 산업기술연구
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• 제18권
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• pp.267-275
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• 1998

Continuous thermodynamics has been applied for modeling of phase equilibria in multicomponent mixtures, to avoid disadvantages of the pseudo-component and key-component method. In this paper continuous thermodynamic relations formulated by using the Pate-Teja equation of state were adopted for calculations of phase equilibria in natural gas mixtures, crude oil mixtures and mixtures extracted by supercritical $CO_2$ fluids. Calculations of phase equilibria were performed by two procedures ; a moment method coupled with the beta distribution function and a quadrature method combined with Gaussian-Legendre polynomials. Calculated results were compared with experimental data. It was showed that continuous thermodynamic frameworks considered in this paper were well-matched to experimental data.

• 지구물리와물리탐사
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• 제16권1호
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• pp.6-17
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• 2013

다성분 탄성파탐사자료를 이용할 경우, P파 뿐만 아니라 PS파를 함께 이용함으로써 공극유체의 판별, 암상의 특성규명, 고해상도의 영상화 등에 유리한 장점들이 있다. 하지만 다성분 탄성파탐사를 통하여 획득한 수직 성분 및 수평 성분 자료에는 각기 다른 특성을 가지는 P파와 PS파가 함께 존재한다. 따라서 다성분 탄성파탐사자료를 이용할 때 P파와 PS파를 분리하는 전처리 과정이 필수적이다. 이 연구에서는, 기존의 정수철, 변중무(2011)가 제안하였던 한 개의 기준 깊이를 이용하여 반사각의 근사값을 계산하고 이를 회전 변환하여 P파와 PS파를 분리하는 방법을 분석한 결과, 다층 구조에서 획득 된 다수의 반사파가 존재하는 자료에의 적용시 한계가 있음을 확인하였다. 이를 개선하기 위하여, 여러 개의 기준 깊이를 이용하여 반사각의 근사값을 계산하고 이를 회전 변환을 한 뒤 중합을 하는 개선된 P파와 PS파의 분리방법을 제안하였다. 마지막으로 이 연구에서 제안하는 방법을 수평 다층 구조의 모델, 단층이 존재하는 모델, Marmousi-2 모델 등에서 획득 된 합성탄성파탐사자료에 적용하여 검증하였다. 그 결과, 급경사 지역이 아닌 완만한 경사의 여러 층이 존재하는 구조에서의 다성분 탄성파탐사자료의 효과적인 파 분리가 가능하였다.

• 지구물리와물리탐사
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• 제14권3호
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• pp.234-241
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• 2011

오일샌드는 고유가로 인하여 최근 활발하게 탐사 및 개발이 진행되고 있다. 오일샌드는 일반적으로 박층으로 존재하기 때문에 이의 탐지를 위해서는 지표 탄성파탐사보다는 시추공 주변의 고해상도 영상화가 장점인 다성분 VSP 탐사가 효과적이다. 또한 중합전 위상막 구조보정의 경우, 단방향 파동방정식을 이용하기 때문에 다성분 자료를 이용한 영상화에 효과적이다. 이 연구에서는 박층 오일샌드의 영상화를 위하여, 다성분 역VSP 탐사자료를 이용한 중합전 위상막 구조보정의 적용성을 고찰하였다. 중합전 위상막 구조보정에 사용할 다성분 역VSP 탐사자료의 전처리 과정으로 입사각과 회전변환을 이용한 파 분리 방법을 제안하고, 이를 합성탄성파탐사자료를 통하여 검증한 결과 파 분리가 효과적으로 되는 것을 확인하였다. 또한 분리된 P파와 PS파 자료를 이용하여 구조보정을 실시하였을 시, PS파 구조보정 결과가 P파 구조보정 결과보다 넓은 반사면의 영상화가 가능하고 고해상도의 영상을 획득하였다. 그리고 캐나다 오일샌드 매장지역을 모사한 합성탄성파탐사자료를 생성하고 이를 영상화 한 결과, P파 구조보정 결과보다 PS파를 이용한 구조보정 결과가 박층 오일샌드의 상 하부 경계면을 정확하게 영상화하였다.

• 한국신뢰성학회:학술대회논문집
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• 한국신뢰성학회 2000년도 추계학술대회
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• pp.411-411
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• 2000

Consider the problem of estimating the reliability of a multicomponent stress-strength system which functions if at least r of the k identical components simultaneously function. All stresses and strengths are assumed to be independent random variables with two parameter Weibull distributions. First, we derive reference priors and probability matching priors which are noninformative priors. We next investigate sufficient conditions for propriety of posteriors under reference priors and probability matching priors. Finally, we provide, using these priors, some numerical results for Bayes estimates of the reliability by applying Gibbs sampling technique.

• Bulletin of the Korean Chemical Society
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• 제34권8호
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• pp.2431-2435
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• 2013

A simple and efficient method for the synthesis of spiro[4H-pyran-oxindole] derivatives by means of three-component reactions between isatins, malononitrile or ethyl cyano-acetate, and 1,3-dicarbonyl compounds in the presence of catalytic amount of magnesium perchlorate in 50% aqueous ethanol medium has been described.

• 대한기계학회논문집B
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• 제25권9호
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• pp.1175-1182
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• 2001

Chemical compositions of polydisperse SiO$_2$/TiO$_2$multicomponent aggregates were measured for different heights from the burner surface and different mobility diameters of aggregates. SiO$_2$/TiO$_2$multicomponent particles were generated in a hydrogen/oxygen coflow diffusion flame from two sets of precursors: TTIP(titanium tetraisopropoxide), TEOS(tetraethylorthosilicate). To maintain 1:1 mole ratio of TTIP:TEOS vapor, flow rate of carrier gas $N_2$was fixed at 0.6lpm for TTIP, at 0.1lpm for TEOS. In-situ sampling probe was used to supply particles into DMA(differential mobility analyzer) which was calibrated with using commercial DMA(TSI, model 3071A) and classifying monodisperse multicomponent particles. Classified monodisperse particles were collected with electrophoretic collector. The distributions of composition from particles to particle were determined using EDS(energy dispersive spectrometry) coupled with TEM(transmission electron microscope). The chemical(atomic) compositions of classified monodisperse particle were obtained for different heights; z=40mm, 60mm, 80mm. The results suggested that the chemical(atomic) composition of SiO$_2$decreased with the height from burner surface and the composition of SiO$_2$and TiO$_2$approached to the value of 1 to 1 fat downstream. It is also found that the composition of SiO$_2$decreases as the mobility diameter of aggregate increases.