• Title/Summary/Keyword: Multicomponent

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Ultraviolet Spectrophotometric Analysis of 2-Aminonaphtalene Sulfonic Acids (2 - 아미노나프탈렌술폰산류의 자외선분광 광도법에 의한 분석)

  • Sohn, Joo-Hwan;Kim, Joo-Youn
    • Journal of the Korean Applied Science and Technology
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    • v.3 no.2
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    • pp.23-28
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    • 1986
  • The sulfuric acid sulfonation mixtures of 2-aminonaphthalene, contained 2-aminonaphthalene, Dahl's acid, Broenner's acid, amino-F-acid and Baden acid, can be determined quantitatively by multicomponent spectrophotometric analysis. The analysis was performed in diluted sodium hydroxide aqueous solution and based on the ultraviolet absorption of the sodium salts of each isomers. The determination of quantity of each isomers was performed by subjection the absorbances of the unknown mixture and of its constituents, gathered at a large number of wavelengths, to a least square treatment by an electronic personer computer. This method provided a rapid analysis of such complex mixture, and the standard deviation was ${\pm}1.65$ mole %.

THE DYNAMICAL EVOLUTION OF GLOBULAR CLUSTERS WITH STELLAR MASS LOSS

  • Kim, Chang-Hwan;Chun, Mun-Suk;Min, Kyung-W.
    • Journal of Astronomy and Space Sciences
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    • v.8 no.1
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    • pp.11-23
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    • 1991
  • The dynamical evolution of globular clusters is studied using the orbit-averaged multicomponent Fokker-Planck equation. The original code developed by Cohn(1980) is modi-fied to include the effect of stellar evolutions. Plommer's model is chosen as the initial density distribution with the initial mass function index $\alpha$=0.25, 0.65, 1.35, 2.35, and 3.35. The mass loss rate adopted in this work follows that of Fusi-Pecci and Renzini(1976). The stellar mass loss acts as the energy source, and thus affects the dynamical evolution of globular clusters by slowing down the evolution rate and extending the core collapse time Tcc. And the dynamical length scale $$R_c, $$R_h is also extended. This represents the expansion of cluster due to the stellar mass loss.

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Study on control of orientation of multicomponent thin film by laser ablation (레이저 어블레이션에 의한 다성분 박막의 방향성 제어 연구)

  • Park, Joo-Hyung;Lee, Sang-Yeol
    • Proceedings of the KIEE Conference
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    • 1997.07d
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    • pp.1226-1228
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    • 1997
  • 펄스 레이저 증착법을 이용하여 MgO 기판 위에 YBCO 박막을 c 축으로 성장시켰다. 이를 위하여 다양한 두께의 YBCO 박막을 여러 온도에서 증착시킴으로서 두께와 온도에 따른 YBCO 박막의 방향성을 조사하였다. 레이저원으로는 Nd:YAG 레이저의 355 nm의 파장을 이용하였으며, 증착시 기판온도는 $700^{\circ}C$$750^{\circ}C$에서 박막의 두께를 $3,000{\AA}$, $10,000{\AA}$, $20,000{\AA}$ 등으로 변화시켜 증착하였다. 이렇게 증착되어진 박막의 표면은 SEM으로 관촬되어졌으며, Raman Spectrascopy로 박막을 분석하였고, XRD를 사용하여 그 박막의 배향성을 연구하였다. 본 논문에서는 이와 같은 분석과 연구를 통하여 증착되어진 다성분 박막의 배향성이 기판온도와 박막두께에 따라 민감하게 변화함을 체계적으로 분석하였으며, 그 결과 기판온도와 박막 두께에 따른 YBCO 박막의 a 축, c 축 성장의 의존성을 확인하였다.

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Development of certified reference material (CRM)s for surface analysis I : alloy thin film for surface compositional analysis (표면분석용 인증표준물질의 개발 I : 표면조성분석용 합금박막 표준물질)

  • 김경중;박용섭;문대원
    • Journal of the Korean Vacuum Society
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    • v.8 no.3B
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    • pp.276-282
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    • 1999
  • For the quantitative surface analysis of multicomponent materials, algorithms for the compensation of the matrix effect and surface compositional change by ion beam sputtering must be established and reference materials having certified compositions are necessary. These certified reference material (CRM)s are needed for the improvement of instrument performance, inter-laboratory comparison and quantitative surface analysis. Surface analysis group of KRISS developed alloy thin film CRMs by and ion beam sputter deposition system and in-situ surface analysis system to control the composition of alloy thin films The real compositions of the CRMs were certified by inductively coupled plasma-atomic emission spectroscopy (ICP-AES).

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Prediction and Representation of Boiling Points for Combustible Solution of Quaternary Systems (4성분계 가연성 혼합용액의 끓는점 예측 및 표현)

  • 김문갑;하동명;이영세
    • Journal of the Korean Society of Safety
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    • v.13 no.4
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    • pp.192-198
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    • 1998
  • MRSM(modified response surface methodology)-2 model is presented for the prediction of boiling points in combustible solution of quaternary systems. This model requires only normal boiling points of pure substances and group-group parameters which are based on the group-group concepts without the use of experimental data under consideration. By means of this methodology, it is possible to predict the boiling points of the combustible mixture of quaternary systems by plotting of isothermal lines using computer graphics. The proposed methodology has been tested and compared successfully with reported boiling points in journals for the combustible solution of quaternary systems. It is hoped eventually that this methodology will permit prediction of the flash point and flammability limit for the combustible mixture of multicomponent systems.

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Modeling of High Pressure Droplet Vaporization with Flash Phase Equilibrium Calculation (플래시 상평형 방법에 의한 고압 액적 기화 모델)

  • 이강원;윤웅섭
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2002.04a
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    • pp.65-69
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    • 2002
  • Unsteady vaporization of a droplet quiescent in a high pressure environment are studied with emphasis placed oil the modeling of equilibrium at vapor-liquid interface. Complete set of conservation equations for liquid and gas phases is numerically time integrated. Vapor-liquid interfacial thermodynamics are solved by f]ash equilibrium calculation method. The model was proper]y validated with experiment and the improvement in the solution accuracy was made. Vaporization of n-pentane fuel droplet in nitrogen background gas is examined. Effects of ambient gas solubility, property variation, transient diffusion, and multicomponent transport on the droplet vaporization are investigated systematically. High-pressure effects on the droplet vaporization is examined and discussed.

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Risk assessment of steel and steel-concrete composite 3D buildings considering sources of uncertainty

  • Lagaros, Nikos D.
    • Earthquakes and Structures
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    • v.6 no.1
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    • pp.19-43
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    • 2014
  • A risk assessment framework for evaluating building structures is implemented in this study. This framework allows considering sources of uncertainty both on structural capacity and seismic demand. In particular randomness on seismic load, incident angle, material properties, floor mass and structural damping are considered; in addition the choice of fibre modelling versus plastic hinge model is also considered as a source of uncertainty. The main objective of this work is to study the contribution of these sources of uncertainty on the fragilities of steel and steel-reinforced concrete composite 3D building structures. The fragility curves are expressed in the form of a two-parameter lognormal distribution where vertical statistics in conjunction with metaheuristic optimization are implemented for calculating the two parameters.

High-Pressure Droplet Vaporization with Emphasis on the Vapor-Liquid Equilibrium Calculation (플래쉬 상평형 계산에 의한 고압 액적기화의 수치적 연구)

  • Lee, Kang-Won;Chae, Jong-Won;Yoon, Woong-Sup
    • 한국연소학회:학술대회논문집
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    • 2001.06a
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    • pp.106-118
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    • 2001
  • A rigorous study of single droplet vaporization under quiescent high pressure atmosphere is attempted adopting method of flash evaporation calculation for vapor-liquid equilibrium. Results due to flash method shows excellent agreement with measurement. Also shown is the present model fairly capable of depicting transients of droplet vaporization under high pressure environment, such as ambient gas solubility, property variation, and multicomponent transports. Systematic treatment of these effects with emphasis on vapor-liquid phase equilibrium revealed; conventional treatment for subcritical droplet vaporization, such as $d^2$-law, leads to erroneous prediction of droplet history, augmented gas solubility is significant under supercritical pressure, and vaporization rate proportionally increase with pressure.

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Experimental Study on Microexplosive Burning of Binary Fuel Droplets (이성분 연료 액적 연소에 관한 실험적 연구)

  • Ghassemi, Hojat;Baek, Seung-Wook;Khan, Qasim Sarwar
    • 한국연소학회:학술대회논문집
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    • 2005.10a
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    • pp.110-119
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    • 2005
  • The combustion characteristics of binary component single droplets hanging at the tip of a quartz fiber are studied experimentally at different environmental pressures and temperatures under normal gravity. Normal Heptane and Normal Hexadecane are selected as two fuels with high difference in boiling temperatures. A falling electrical furnace in a high pressure vessel has provided high temperature environment. Nitrogen and air have formed the environment to study evaporation and combustion, respectively. The initial diameter of droplet was ranging from 1.1 to 1.3 mm. The evaporation and combustion processes were recorded by a high speed digital camera. Some characteristics of droplet burning under different environment conditions and different droplet composition have been investigated. Microexplosion of droplet take places under atmospheric pressure. Bubble formation and its consequent result, incomplete droplet disintegration which presents in all binary compositions, do not appear at high pressure. The initiation of combustion, always takes place in the bottom of droplet due to buoyancy effect of relatively cold fuel vapor. Also, the burning of binary droplet produces soot when the pressure is high.

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Studies on the Synthesis of the Isomeric 1-naphtholsulfonic Acids and Analysis of their Mixtures (1-나프톨 술폰산 이성체의 합성 및 혼합물의 분석에 관한 연구)

  • Sohn, Joo-Hwan;Kim, Kwang-Jea;Lee, Seung-Yeell
    • Journal of the Korean Applied Science and Technology
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    • v.6 no.2
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    • pp.21-28
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    • 1989
  • 1-naphthol-2-sulfonic acid and 1-naphthol-4-sulfonic acid were synthesized under the dissolution of 1-naphthol in 2-nitrotoluene with stirring 98.08-90% sulfuric acid at $5-95^{\circ}C$ for 1-5 hours. As the reaction temperatures and the reaction time were raised, the yield of 2-sulfonate was decreased, while that of 4-sulfonate was increased. But we could not observe the tendency to the various reaction concentrations of sulfuric acids. The mixtures of two isomeric 1-naphtholulfonic acids in excess concentrated sulfuric acids was quantitatively determinded by using multicomponent spectrophotomeric analysis method on the basis of the ultraviolet absorption peak of the sulfonic acids. The standard deviation in this method was ${\pm}\;2.6$, and the above method seem to be rapid and accurate.